JPS5938650A - Gas chromatograph with specimen pre-treating apparatus - Google Patents
Gas chromatograph with specimen pre-treating apparatusInfo
- Publication number
- JPS5938650A JPS5938650A JP14942682A JP14942682A JPS5938650A JP S5938650 A JPS5938650 A JP S5938650A JP 14942682 A JP14942682 A JP 14942682A JP 14942682 A JP14942682 A JP 14942682A JP S5938650 A JPS5938650 A JP S5938650A
- Authority
- JP
- Japan
- Prior art keywords
- column
- section
- specimen
- sample
- gas chromatograph
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 238000004811 liquid chromatography Methods 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims description 10
- 239000003480 eluent Substances 0.000 claims description 7
- 230000008016 vaporization Effects 0.000 claims description 4
- 239000007789 gas Substances 0.000 abstract description 27
- 239000012159 carrier gas Substances 0.000 abstract description 6
- 238000001514 detection method Methods 0.000 abstract description 2
- 230000006866 deterioration Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 238000001704 evaporation Methods 0.000 abstract 2
- 230000008020 evaporation Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 1
- 239000006200 vaporizer Substances 0.000 description 7
- 238000007664 blowing Methods 0.000 description 4
- 238000004817 gas chromatography Methods 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 241000277269 Oncorhynchus masou Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/26—Conditioning of the fluid carrier; Flow patterns
- G01N30/38—Flow patterns
- G01N30/46—Flow patterns using more than one column
- G01N30/461—Flow patterns using more than one column with serial coupling of separation columns
- G01N30/465—Flow patterns using more than one column with serial coupling of separation columns with specially adapted interfaces between the columns
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/84—Preparation of the fraction to be distributed
- G01N2030/8411—Intermediate storage of effluent, including condensation on surface
- G01N2030/8417—Intermediate storage of effluent, including condensation on surface the store moving as a whole, e.g. moving wire
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/80—Fraction collectors
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
Description
【発明の詳細な説明】
この発明は、試料前処稗装圓付ガスクロマトグフ７に関
し、ざらに詳しくは、試料から不要成分を予め取り除く
ための前処耶装置ｑを具備してカるガスクロマトグラフ
に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a gas chromatograph 7 equipped with a sample pretreatment device, and more specifically, a gas chromatograph equipped with a pretreatment device q for removing unnecessary components from a sample in advance. Regarding tographs.
ガスクロマトグラフの分離カラムには、充てんカラムや
キャピラリーカラムが用いられるが、特にキャピラリー
カラムを用いて高沸点成分（分子縫が６００以上）を含
んでいる試料をくり返して測定する場合、高分子化合物
がキャピラリーカラム中に残シ、こり、らの高分子物質
のためにカラムの性峠を低下させてしまうことがある。Packed columns and capillary columns are used as separation columns in gas chromatographs, but especially when using a capillary column to repeatedly measure samples containing high-boiling components (molecular stitches of 600 or more), polymer compounds may be contained in the capillary column. Residues, dirt, and other polymeric substances may reduce column performance.
したがって、カラムの性能低下につながる不要な成分
を除くことができかつ目的成分のみをカラムに導入でき
るシステムが望１Ｊする。Therefore, it is desirable to have a system that can remove unnecessary components that lead to a decrease in column performance and introduce only target components into the column.
この発明は、このような事情に鑑みてなされたものでち
ゃ、端的に述べれば、試料を液体クロマトグラフィーに
より粗分離し、目的部分のみを補集し、これを気化して
ガスクロマトグラフィーに付しうるようにする６；１処
理装陥をガスクロマトグツ７のカラムの前に設けてなる
ガスクロマトグラフを提供するものである。This invention was made in view of the above circumstances. To put it simply, a sample is roughly separated by liquid chromatography, only the target portion is collected, and this is vaporized and subjected to gas chromatography. The present invention provides a gas chromatograph in which a 6:1 processing equipment is provided in front of a column of a gas chromatograph 7.
Ｖ、下、区１に示す実施例に基いて、この発明をｄγ２
細に説明する。 ただし、これによりこの発明が限定さ
れるものではない。V, lower, based on the embodiment shown in Section 1, the present invention is applied to dγ2
Explain in detail. However, this invention is not limited thereby.
第１図に示す（１）は、この発明のガスクロマトグラフ
の一実施例でを）す、ギヤリア溶媒送液ポンプ（２）、
試料導入部（３）、液体クロマトグラフ用カラム（４）
、液体クロマトグラフ用検出器（５）、濃縮器（７）。(1) shown in FIG. 1 is an embodiment of the gas chromatograph of the present invention, a gearia solvent pump (2),
Sample introduction part (3), liquid chromatography column (4)
, a liquid chromatograph detector (5), and a concentrator (7).
気化器（８）、ガスクロマトグフ７用ギヤピラリーカラ
ム圓およびガスクロマトグラフ用検出器ａθが１暇に連
設されて基本的ＩＣ構成されている。 （９１はキャリ
ア溶媒槽、α０は制御部、１１１１はギヤリアガス吹込
管、１１９１μカラムオープンである。A basic IC configuration includes a vaporizer (8), a gear pillar column for the gas chromatograph 7, and a detector aθ for the gas chromatograph, which are connected in series. (91 is a carrier solvent tank, α0 is a control unit, 1111 is a gear rear gas blowing pipe, and 1191 μ column open.
上記（＋、（ｌ （ＩＱ１９１の構成は、各々公知のガ
スクロマｉ・グフフにおけるものと同じであり、こり、
らけガスクロマトグラフ部ａ（すしてひとまとめに考え
られる。The configuration of the above (+, (l) IQ191 is the same as that of the well-known gas chroma i/gufufu, and the stiffness,
Rake gas chromatograph section a (considered collectively).
上記（２）〜（５１および（９１の構成は、各々公知の
液体クロマトグラフにおけるものと同じであ勺、これら
は液体クロマトグラフ部（６）としてひと昔とめに考え
られる。The configurations of (2) to (51) and (91) above are the same as those in known liquid chromatographs, and these can be considered as the liquid chromatograph section (6) for a while.
さらに液体クロマトグラフ部（６）とｅ輪姦（７）と気
化器（８）とは、ガスクロマトグラフ部（１υに対する
試料前処理部（１３としてひと１とめに考えられる。Furthermore, the liquid chromatograph section (6), the e-gang (7), and the vaporizer (8) can be collectively considered as the sample pretreatment section (13) for the gas chromatograph section (1υ).
濃縮器（ハおよび気化器（８１の構造は、第２「１に示
すように、各々加熱ブロック（１７１および１１１１１
で囲寸れた小室である。 それらの間の連通部にはＡヤ
リアガス吹込管（１１１の開ロシ０）が設けらｈていて
、画室にキャリアカスを吹込めるようになっている。The structure of the concentrator (1) and vaporizer (81) is as shown in 2.1.
It is a small room surrounded by An A-type gas blowing pipe (opening point 0 of 111) is provided in the communication portion between them, so that carrier residue can be blown into the compartment.
ｆｌｔ縮器輪姦）の土壁には排気口１２１１があり、濃
縮器（７）内ＫＩ！７で込まれたキャリアガスはその排
気口＋Ｊ１１から抵抗管（２２１を通って排出される。There is an exhaust port 1211 on the soil wall of the flt condenser gangbang), and there is an exhaust port 1211 inside the concentrator (7) KI! The carrier gas introduced in 7 is discharged from its exhaust port +J11 through a resistance pipe (221).
一方、気化器（８）に飲込’１１１−ｆｃキャリアガ
スはガスクロマトグラフ部（Ｉｔ） Ｉｃ Ｒ，入する
。 液体クロマトグラフ部（６）がら延出びｉ７ている
流路（２，１＋は、ｆ！１縮部（７）内にｉ１１設され
ており、溶離液をσ；′１縮部（７）内の試料ボートｆ
２４＋の試料Ｉ１１． ＣＩ！５１Ｉｔｉ（２Ｉｓ＋に
注ける」、うになっている。 試料ボー）（２４１）よ
、強イ１７．’ｌｔ件体１って、マグネット（２７１に
より外部から移動させることができる。On the other hand, the swallowed '111-fc carrier gas enters the gas chromatograph section (It) Ic R, into the vaporizer (8). The flow channel (2,1+) extending from the liquid chromatograph section (6) is installed in the f!1 condensation section (7), and the eluent is passed through the σ;'1 condensation section (7). sample boat f
24+ sample I11. CI! 51Iti (can be poured into 2Is+), it is. Sample Bo) (241), strong A17. The body 1 can be moved from the outside using a magnet (271).
次に作動を酸り１する。 まず濃縮器（７）はキャリア
溶媒を気化【−うる程度の低温たとえば約５０℃にされ
、気化器（８）は試料の目的成分を気化しうる程度の高
温たとえば約２００”Ｃ〜約４００’Ｃにされ、キャピ
ラリーカラムα４１は室温程度にされている。 この状
態で試料が試料導入部（３）に導入される。Next, oxidize the operation. First, the concentrator (7) is heated to a low temperature that is low enough to vaporize the carrier solvent, for example, about 50°C, and the vaporizer (8) is heated to a high temperature that is high enough to vaporize the target component of the sample, such as about 200"C to about 400"C. C, and the capillary column α41 is kept at about room temperature. In this state, the sample is introduced into the sample introduction section (3).
ポンプ（２）でキャリア溶媒を送液すると、試料は液体
クロマトグラフ用カラム（４）で相分離され、液体クロ
マトグラフ用検出器（５）でたとえば第３図（Ａ）のよ
うに各成分が検出される。When the carrier solvent is pumped with the pump (2), the sample is phase-separated in the liquid chromatography column (4), and each component is separated in the liquid chromatography detector (5) as shown in Figure 3 (A). Detected.
いま目的成分が第８図（蜀に示す（ｂ）〜（ｆ）であり
、（ａ）が不要成分であるとすると、（ｂ）〜（ｆ）に
対応する部分の溶１４１Ｌ液を試料皿回）で受けかつ（
ａ） Ｋ対応する部分の溶ｎＷ液を試料皿防）で受ける
ように試料ポートＱ金がマグネツ）（２７＞で移動され
る。 第２図に実線で示す試料ボート＃２＃およびマグ
ネット（５）の位置は、試料皿ωに溶跡液を受ける位置
であシ、破線で示す位置は、試料皿に）に溶離液を受け
る位置である。Now, assuming that the target components are (b) to (f) shown in Figure 8 (Shu) and (a) is an unnecessary component, pour 141L of the solution corresponding to (b) to (f) into a sample dish. times) to receive and receive (
a) The sample port Q gold is moved by the magnet (27) so that the molten nW solution corresponding to K is received by the sample plate (27).The sample boat #2# and the magnet (5 ) is the position where the sample plate ω receives the eluate, and the position indicated by the broken line is the position where the sample plate ) receives the eluent.
試料ボー）＋２４の移動ｔよ、ある成分を検出しｋあと
溶１ｖｆＣ液のその部分が出て来るまでの遅れ時間を考
慮して手動で行うことができるが、好１しくけ、比較回
路とタイマーど市、動式マグネット移動手段とを具備し
てなる制御装置０１負を用いて自動で行わせる。 なお
、成分が＃’ｓｔ’ｒニ一定の試料をルーチンワークと
して分析する場合罠は、液体クロマトグラフィーの開始
から溶離液の目的部分が出て来るまでの時間がｔｌに一
定だから、液体クロマトグラフィーの開始から一定時間
後に試料ボー） ｔ２４＋を移動する制御装圓を用いて
もよく、またこの場合、液体クロマトグラフ用検出器（
５）を省略することができる。This can be done manually, taking into account the delay time until a certain component is detected and that part of the solution comes out, but it is preferable to use the comparison circuit and This is automatically performed using the control device 01, which is equipped with a timer and a dynamic magnetic moving means. Note that when analyzing a sample with constant components #'st'r as a routine work, the problem with liquid chromatography is that the time from the start of liquid chromatography until the target part of the eluent comes out is constant at tl. A control device may be used that moves the sample board (t24+) after a certain period of time from the start of the liquid chromatography detector (t24+).
5) can be omitted.
試料皿■ｆ？Ｉｉ）！／（受は入れられた溶離液に含ま
れるキャリア溶媒ケよ、〃１縮器（７）内で加熱これ気
化されてキャリアガスと共に排気口ｃ２１）から排出さ
れる。Sample plate f? Ii)! The carrier solvent contained in the eluent is heated in the condenser (7) and vaporized, and is discharged from the exhaust port c21 along with the carrier gas.
つまυ溶離液がｉ：Ｊ）縮される仁とになる。The eluent becomes i:J) condensed.
適当な所定時間ｔ；）縮が行われた後、試料皿（４）を
気化室（８）内に位ｆｆ５させるように、試料ボート＋
２４１がｉグネット（５）で再び移動される。 第２図
に一点鎖紳で示す試料ボー）２４１およびマグネット罰
の位置は、このときの位置を示す。 図より分るように
、試料皿（ハ）は気化室（８）内に入らないので、結局
、試料皿（２６）内に在る目的成分のみが気化室（８）
で加熱キャピラリーカラム（１４）は室温程１ｆｌ”、
であるから、キャピラリーカラム（１４１に入った目的
成分（よ、カラムの先端部分（１４ａ）で凝縮し、さら
に濃縮される。After the contraction has been carried out for a suitable predetermined time t;), the sample boat +
241 is moved again with i-Gnet (5). The position of the sample board 241 and the magnet penetrating point indicated by a dot chain in FIG. 2 indicates the position at this time. As can be seen from the figure, since the sample dish (c) does not enter the vaporization chamber (8), only the target component present in the sample dish (26) enters the vaporization chamber (8).
The heated capillary column (14) is heated to about 1 fl" at room temperature,
Therefore, the target component that has entered the capillary column (141) is condensed at the column tip (14a) and further concentrated.
最抜は通常のガスクロマトグラフと同様で、カラムオー
ブン朋によりキャピラリーカラムθ４）をステップ列、
温もしくけｊＪニヤー昇滉すれば、凝縮された目的成分
がキャピラリーカラム（１４）で高分離され、ガスクロ
マトグラフ用検出器０９で、第８図（Ｂ）に示すように
、明確に検出される。The extraction process is the same as in a normal gas chromatograph, and the capillary column θ4) is moved in a step column using a column oven.
When heated and heated, the condensed target component is highly separated in the capillary column (14) and clearly detected by the gas chromatograph detector 09 as shown in FIG. 8(B).
以上の説明から理解されるように、この発明は、ギヤリ
ア溶媒送液部、試料導入部、液体クロマトグラフ用カヲ
ムおよび必要に応じ液体クロマトグラフ用検出器をこの
順に連設した液体クロマトグラフ部と、その液体クロマ
トグラフ部から流出する溶離液の目的部分を補集して溶
媒分を除去可能な濃縮部と、その濃縮部での縮した目的
部分を加熱気化する気化部とからなる試料前処乃１装買
を、ガスクロマトグラフ用カラムとガスクロマトグラフ
用検出器とからなるガスクロマトグラフ部の前に設けて
なる試料前処理装置付ガスクロマトグラフを提供するも
のであり、これにより試料中の目的成分のみをガスクロ
マトグラフィーに付すことが可能となり、不要成分（特
に分子量の大きい化合物）によるカラムの劣化および検
出妨害を防ぐことができて、長期間正確で信頼性ある常
用分析を行えるようになる。As can be understood from the above description, the present invention comprises a liquid chromatograph section in which a gear carrier solvent feeding section, a sample introduction section, a liquid chromatograph comb, and, if necessary, a liquid chromatograph detector are connected in this order. , a sample pretreatment system consisting of a concentration section that can collect the target portion of the eluent flowing out from the liquid chromatograph section and remove the solvent, and a vaporization section that heats and vaporizes the target portion contracted in the concentration section. This product provides a gas chromatograph equipped with a sample pretreatment device that is installed in front of a gas chromatograph section consisting of a gas chromatograph column and a gas chromatograph detector, thereby allowing only the target components in the sample to be separated. can be subjected to gas chromatography, preventing column deterioration and detection interference caused by unnecessary components (particularly compounds with large molecular weights), and enabling accurate and reliable regular analysis over a long period of time.
なお、この発明Ｖ、［、ガスクロマトグラフ用カラムが
充填カラムでもキャピラリーカラムでも効果があるが、
特にキャピラリーカラムの場合に非常に有効である。In addition, this invention V, [, although it is effective whether the column for gas chromatography is a packed column or a capillary column,
It is particularly effective for capillary columns.
Ｆ＋） １図はこの発り１の試料前処理装置付ガスクロ
マトグラフの一丈施例の行１覧成説明図、第２図は濃縮
÷：べおよび気化器の−ｔ７／ｉ成例の断面図、第８図
（Ａ）は８４１図に示す装置において液体クロマトグラ
フ用検出器で得られるクロマトグラムの一例の図、第８
図（Ｂ）は第１図に示す装置においてガスクロマトグラ
フ用検出器で得られるクロマトグラムの一例の図である
。
（１）・・・試料前処理装置付ガスクロマトグツ７ 、
（２１・・・キャリア溶媒送液ポンプ、（３）・・・試
料導入部、（４）・・・液体クロマトグラフ用カラム、
（５）・・・液体クロマトグラフ用検出器、（６）・・
・液体クロマトグラフ部、（７）・・・濃縮器、（８）
・・・気化器、００・・・制御装置、（１１１・・・キ
ャリアガス吹込管、（１３・−・試料前処脚装置、（１
４）・・・キャピラリーカラム、ａＱ・・・ガスクロマ
トグラフ用検出器、０υ・・・ガスクロマトグラフ部、
１１７１１１８１・・・加熱ブロック、（１市・・・カ
ラムオーブン、舛・・・キャリアガス吹込管開口、１２
１１・・排気口、ＱＩＩ＋・・・試料ボー） 、１２：
ｉｌシに）・・・試料皿、（２７１・・・マグネット。
２１F+) Figure 1 is a row 1 list explanatory diagram of the Ichijo example of the gas chromatograph with the sample pretreatment device of this invention 1, and Figure 2 is the cross section of the concentration ÷: -t7/i example of the vaporizer. Figure 8(A) is an example of a chromatogram obtained with a liquid chromatography detector in the apparatus shown in Figure 841.
Figure (B) is a diagram of an example of a chromatogram obtained by a gas chromatograph detector in the apparatus shown in Figure 1. (1)...Gas chromatograph with sample pretreatment device 7,
(21...Carrier solvent feeding pump, (3)...Sample introduction section, (4)...Liquid chromatography column,
(5)...Liquid chromatograph detector, (6)...
・Liquid chromatograph section, (7)... Concentrator, (8)
... vaporizer, 00 ... control device, (111 ... carrier gas blowing pipe, (13 ... sample pretreatment device, (1
4) Capillary column, aQ gas chromatograph detector, 0υ gas chromatograph section,
11711181... Heating block, (1 city... Column oven, Masu... Carrier gas blowing pipe opening, 12
11...exhaust port, QII+...sample bow), 12:
sample plate, (271... magnet. 21
Claims (1)
ラフ用カラムおよび必要に応じ液体クロマトグラフ用検
出器をこの順に連設した液体クロマトグラフ部と、その
液体クロマトグラフ部から流出する溶離液の目的部分を
補集して溶媒外を除去可能な濃縮部と、そのｒ外縮部で
濃縮（７た目的部分を加熱気化する気化部とからなる試
料前処理装置を、ガスクロマトグラフ用カラムとガスク
ロマトグラフ用検出器とからなるガスクロマトグラフ部
の前に設しｊｆｃことを特Ｃ′Ｘ＆とする試料前処埋装
＠Ｈガスクロマトグラフ。1. A liquid chromatograph section in which a carrier solvent feeding section, a sample introduction section, a liquid chromatography column, and a liquid chromatography detector are installed in this order if necessary, and a liquid chromatograph section that is connected in this order to a liquid chromatograph section, and an eluent flowing out from the liquid chromatograph section. The sample pretreatment device consists of a concentrating section that collects the target part and removes the solvent, and a vaporizing part that heats and vaporizes the target part. A sample pretreatment embedding @H gas chromatograph is installed in front of a gas chromatograph section consisting of a gas chromatograph section and a detector.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14942682A JPS5938650A (en) | 1982-08-28 | 1982-08-28 | Gas chromatograph with specimen pre-treating apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14942682A JPS5938650A (en) | 1982-08-28 | 1982-08-28 | Gas chromatograph with specimen pre-treating apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5938650A true JPS5938650A (en) | 1984-03-02 |
| JPH0259427B2 JPH0259427B2 (en) | 1990-12-12 |
Family
ID=15474842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14942682A Granted JPS5938650A (en) | 1982-08-28 | 1982-08-28 | Gas chromatograph with specimen pre-treating apparatus |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5938650A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61182575A (en) * | 1985-01-25 | 1986-08-15 | ザ ダウ ケミカル カンパニー | Chromatographic device for liquid and gas under on-line coupling, where interface capillary is interposed between pair of capillary chromatograph-column |
| EP0313972A2 (en) * | 1987-10-30 | 1989-05-03 | Idemitsu Kosan Company Limited | Analytical method and apparatus for analyzing liquid substances |
| US5236593A (en) * | 1985-01-25 | 1993-08-17 | The Dow Chemical Company | On-line coupled liquid and gas chromatography system with an interface capillary tube interposed between a pair of capillary chromatographic columns |
| US5522988A (en) * | 1985-01-25 | 1996-06-04 | The Dow Chemical Company | On-line coupled liquid and gas chromatography system with an interface capillary tube interposed between a pair of capillary chromatographic columns |
| WO2005071398A1 (en) * | 2003-12-05 | 2005-08-04 | Saika Technological Institute Foundation | Method of analyzing organic chemical substance and apparatus for analysis |
| JP2008541117A (en) * | 2005-05-20 | 2008-11-20 | ユニバーシダ デ カスティーリャ ラマンチャ | Interface injector device for connecting liquid chromatography and gas chromatography |
| JP2009180618A (en) * | 2008-01-31 | 2009-08-13 | Hitachi High-Technologies Corp | Pretreatment device and liquid chromatograph device |
-
1982
- 1982-08-28 JP JP14942682A patent/JPS5938650A/en active Granted
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61182575A (en) * | 1985-01-25 | 1986-08-15 | ザ ダウ ケミカル カンパニー | Chromatographic device for liquid and gas under on-line coupling, where interface capillary is interposed between pair of capillary chromatograph-column |
| US5236593A (en) * | 1985-01-25 | 1993-08-17 | The Dow Chemical Company | On-line coupled liquid and gas chromatography system with an interface capillary tube interposed between a pair of capillary chromatographic columns |
| US5522988A (en) * | 1985-01-25 | 1996-06-04 | The Dow Chemical Company | On-line coupled liquid and gas chromatography system with an interface capillary tube interposed between a pair of capillary chromatographic columns |
| EP0313972A2 (en) * | 1987-10-30 | 1989-05-03 | Idemitsu Kosan Company Limited | Analytical method and apparatus for analyzing liquid substances |
| WO2005071398A1 (en) * | 2003-12-05 | 2005-08-04 | Saika Technological Institute Foundation | Method of analyzing organic chemical substance and apparatus for analysis |
| JPWO2005071398A1 (en) * | 2003-12-05 | 2007-07-26 | 財団法人雑賀技術研究所 | Organic chemical analysis method and analyzer |
| JP4492541B2 (en) * | 2003-12-05 | 2010-06-30 | 財団法人雑賀技術研究所 | Organic chemical analysis equipment |
| US8042379B2 (en) | 2003-12-05 | 2011-10-25 | Aisti Science Co., Ltd. | Method of analyzing organic chemical substances and apparatus for analysis |
| JP2008541117A (en) * | 2005-05-20 | 2008-11-20 | ユニバーシダ デ カスティーリャ ラマンチャ | Interface injector device for connecting liquid chromatography and gas chromatography |
| JP2009180618A (en) * | 2008-01-31 | 2009-08-13 | Hitachi High-Technologies Corp | Pretreatment device and liquid chromatograph device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0259427B2 (en) | 1990-12-12 |
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