JPS5935939B2 - 水性澱粉接着剤に関する改良 - Google Patents
水性澱粉接着剤に関する改良Info
- Publication number
- JPS5935939B2 JPS5935939B2 JP7492574A JP7492574A JPS5935939B2 JP S5935939 B2 JPS5935939 B2 JP S5935939B2 JP 7492574 A JP7492574 A JP 7492574A JP 7492574 A JP7492574 A JP 7492574A JP S5935939 B2 JPS5935939 B2 JP S5935939B2
- Authority
- JP
- Japan
- Prior art keywords
- starch
- fragments
- particles
- weight
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002472 Starch Polymers 0.000 title claims description 89
- 235000019698 starch Nutrition 0.000 title claims description 88
- 239000008107 starch Substances 0.000 title claims description 74
- 239000000853 adhesive Substances 0.000 title claims description 56
- 230000001070 adhesive effect Effects 0.000 title claims description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 38
- 239000002245 particle Substances 0.000 claims description 71
- 239000000725 suspension Substances 0.000 claims description 35
- 239000012634 fragment Substances 0.000 claims description 28
- 230000008961 swelling Effects 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 12
- 238000013467 fragmentation Methods 0.000 claims description 8
- 238000006062 fragmentation reaction Methods 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 6
- 239000007900 aqueous suspension Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920000881 Modified starch Polymers 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 235000019426 modified starch Nutrition 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 48
- 239000000123 paper Substances 0.000 description 10
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 10
- 238000004513 sizing Methods 0.000 description 10
- 238000001035 drying Methods 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 238000013508 migration Methods 0.000 description 9
- 230000005012 migration Effects 0.000 description 9
- 229920002261 Corn starch Polymers 0.000 description 8
- 239000008120 corn starch Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 239000011521 glass Substances 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 229920001592 potato starch Polymers 0.000 description 6
- 240000008042 Zea mays Species 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 235000005822 corn Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 3
- ZFIVKAOQEXOYFY-UHFFFAOYSA-N Diepoxybutane Chemical compound C1OC1C1OC1 ZFIVKAOQEXOYFY-UHFFFAOYSA-N 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 240000003183 Manihot esculenta Species 0.000 description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 2
- 239000007832 Na2SO4 Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 240000006394 Sorghum bicolor Species 0.000 description 2
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- -1 succinic anhydride Chemical class 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 1
- DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 description 1
- JPSKCQCQZUGWNM-UHFFFAOYSA-N 2,7-Oxepanedione Chemical compound O=C1CCCCC(=O)O1 JPSKCQCQZUGWNM-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- CMDGQTVYVAKDNA-UHFFFAOYSA-N propane-1,2,3-triol;hydrate Chemical compound O.OCC(O)CO CMDGQTVYVAKDNA-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Bag Frames (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3101673 | 1973-06-29 | ||
| GB3101673A GB1420392A (en) | 1973-06-29 | 1973-06-29 | Aqueous starch adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5076142A JPS5076142A (da) | 1975-06-21 |
| JPS5935939B2 true JPS5935939B2 (ja) | 1984-08-31 |
Family
ID=10316659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7492574A Expired JPS5935939B2 (ja) | 1973-06-29 | 1974-06-28 | 水性澱粉接着剤に関する改良 |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPS5935939B2 (da) |
| BE (1) | BE816742A (da) |
| DE (1) | DE2431199C2 (da) |
| DK (1) | DK148917C (da) |
| ES (1) | ES427765A1 (da) |
| FI (1) | FI65078C (da) |
| FR (1) | FR2235182B1 (da) |
| GB (1) | GB1420392A (da) |
| IT (1) | IT1015427B (da) |
| NL (1) | NL7408780A (da) |
| SE (1) | SE409578B (da) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2414533A1 (fr) * | 1978-01-12 | 1979-08-10 | Roquette Freres | Colles de dextrine |
| EP1176254A1 (en) † | 2000-07-24 | 2002-01-30 | The Dow Chemical Company | Use of dispersions of crosslinked cationic starch in papermaking |
| EP1176255A1 (en) | 2000-07-24 | 2002-01-30 | The Dow Chemical Company | Use of starch dispersions as binder in coating compositions and process for preparing the starch dispersions |
| DE10050241A1 (de) * | 2000-10-11 | 2002-04-25 | Emsland Staerke Gmbh | Fragmentierte Stärke, ihre Herstellung und deren Verwendung |
| US6921430B2 (en) | 2001-05-02 | 2005-07-26 | Ecosynthetix Inc. | Environmentally friendly biopolymer adhesives and applications based thereon |
| FR2855840B1 (fr) | 2003-06-06 | 2006-09-01 | Roquette Freres | Composition a base d'amidon modifie, issu de legumineuses, destinee a l'ennoblissement du papier |
| FR2873701B1 (fr) * | 2004-07-30 | 2006-12-15 | Roquette Freres | Amidon reticule, partiellement soluble, et composition filmogene le contenant |
| US20120141551A1 (en) | 2010-12-02 | 2012-06-07 | Ecosynthetix Ltd. | Aptamer bioconjugate drug delivery device |
| US20120309246A1 (en) | 2011-06-03 | 2012-12-06 | Alexander Tseitlin | Curable biopolymer nanoparticle latex binder for mineral, natural organic, or synthetic fiber products and non-woven mats |
| WO2015013468A1 (en) * | 2013-07-23 | 2015-01-29 | Pioneer Pet Products, Llc | Laminate structural material |
| US9616696B2 (en) | 2013-10-23 | 2017-04-11 | Ecosynthetix Inc. | Coating for paper adapted for inkjet printing |
| EP3077169A4 (en) | 2013-12-05 | 2018-02-28 | EcoSynthetix Ltd. | Formaldehyde free binder and multi-component nanoparticle |
| EP4088744A1 (en) | 2015-10-21 | 2022-11-16 | The Regents Of The University Of Michigan | Detection and treatment of caries and microcavities with nanoparticles |
| EP3178852A1 (de) | 2015-12-11 | 2017-06-14 | Agrana Stärke GmbH | Polysaccharid-klebstoff |
| KR20200135963A (ko) | 2018-03-28 | 2020-12-04 | 그린마크 바이오메디컬 인코포레이티드 | 포스페이트 가교된 전분 나노입자 및 치과 치료 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3014901A (en) * | 1959-08-05 | 1961-12-26 | E Staley Mfg Company Sa | Process for preparing ungelatinized starch ethers |
-
1973
- 1973-06-29 GB GB3101673A patent/GB1420392A/en not_active Expired
-
1974
- 1974-06-21 BE BE7000536A patent/BE816742A/xx not_active IP Right Cessation
- 1974-06-25 IT IT2445974A patent/IT1015427B/it active
- 1974-06-26 FI FI195374A patent/FI65078C/fi active
- 1974-06-27 DK DK346874A patent/DK148917C/da not_active IP Right Cessation
- 1974-06-27 SE SE7408505A patent/SE409578B/xx not_active IP Right Cessation
- 1974-06-28 ES ES427765A patent/ES427765A1/es not_active Expired
- 1974-06-28 NL NL7408780A patent/NL7408780A/xx not_active Application Discontinuation
- 1974-06-28 DE DE19742431199 patent/DE2431199C2/de not_active Expired
- 1974-06-28 JP JP7492574A patent/JPS5935939B2/ja not_active Expired
- 1974-07-01 FR FR7422879A patent/FR2235182B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2235182A1 (da) | 1975-01-24 |
| FI195374A (da) | 1974-12-30 |
| DE2431199A1 (de) | 1975-01-16 |
| SE7408505L (da) | 1974-12-30 |
| DE2431199C2 (de) | 1985-03-21 |
| BE816742A (nl) | 1974-12-23 |
| IT1015427B (it) | 1977-05-10 |
| GB1420392A (en) | 1976-01-07 |
| NL7408780A (da) | 1974-12-31 |
| DK148917B (da) | 1985-11-18 |
| FR2235182B1 (da) | 1978-03-24 |
| DK148917C (da) | 1986-07-28 |
| SE409578B (sv) | 1979-08-27 |
| DK346874A (da) | 1975-02-17 |
| ES427765A1 (es) | 1976-08-01 |
| FI65078C (fi) | 1984-03-12 |
| FI65078B (fi) | 1983-11-30 |
| JPS5076142A (da) | 1975-06-21 |
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