JPS574995A - Preparation of vinylalkoxysilane - Google Patents
Preparation of vinylalkoxysilaneInfo
- Publication number
- JPS574995A JPS574995A JP7943080A JP7943080A JPS574995A JP S574995 A JPS574995 A JP S574995A JP 7943080 A JP7943080 A JP 7943080A JP 7943080 A JP7943080 A JP 7943080A JP S574995 A JPS574995 A JP S574995A
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- acetylene
- formula
- trialkoxysilane
- pph
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
PURPOSE: To obtain the titled compound in high yield safely, by reacting a trialkoxysilane with acetylene in the presence of a catalyst of platinum-phosphine complex at low temperature at low pressure.
CONSTITUTION: A trialkoxysilane (e.g., trimethoxysilane) shown by the formula HSi(OR)3(R is 1W12C alkyl, alkylaryl, aralkyl) is reacted with acetylene in the presence of a catalyst of a complex [e.g., PtCl2(PpH3)2] shown by the formula PtX2(Pph3)2(X2 is halogen, O, alkyl, triphenylphosphine, CO2, CH2=CH2), to give a vinyltrialkoxysilane shown by the formula CH2=CHSi(OR)3. The reaction (2) is suppressed, the formation of bis(trialkoxysilyl)ethane, a by-product, is small, and the reaction (1) is preceded without using excess acetylene. The reaction is carried out at 40W100°C at atmospheric pressure to 0.5kg/cm2.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7943080A JPS574995A (en) | 1980-06-12 | 1980-06-12 | Preparation of vinylalkoxysilane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7943080A JPS574995A (en) | 1980-06-12 | 1980-06-12 | Preparation of vinylalkoxysilane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS574995A true JPS574995A (en) | 1982-01-11 |
JPS6219434B2 JPS6219434B2 (en) | 1987-04-28 |
Family
ID=13689652
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7943080A Granted JPS574995A (en) | 1980-06-12 | 1980-06-12 | Preparation of vinylalkoxysilane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS574995A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005277A2 (en) * | 1978-05-08 | 1979-11-14 | Cpc International Inc. | Process for the microbiological production of oil |
US4444397A (en) * | 1981-12-04 | 1984-04-24 | Senoh Kabushiki Kaisha | Adjusting device for a net pole |
US4558146A (en) * | 1985-01-31 | 1985-12-10 | Union Carbide Corporation | Process for preparing vinylaminosilanes |
US4579965A (en) * | 1985-01-24 | 1986-04-01 | Union Carbide Corporation | Process for preparing vinyl-tri-(tertiary substituted) alkoxysilanes |
US4898961A (en) * | 1989-07-17 | 1990-02-06 | Dow Corning Corporation | Method for preparing alkenylsilanes |
US5041595A (en) * | 1990-09-26 | 1991-08-20 | Union Carbide Chemicals And Plastics Technology Corporation | Method for manufacturing vinylalkoxysilanes |
-
1980
- 1980-06-12 JP JP7943080A patent/JPS574995A/en active Granted
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0005277A2 (en) * | 1978-05-08 | 1979-11-14 | Cpc International Inc. | Process for the microbiological production of oil |
EP0005277A3 (en) * | 1978-05-08 | 1979-12-12 | Cpc International Inc. | Process for the microbiological production of oil |
US4444397A (en) * | 1981-12-04 | 1984-04-24 | Senoh Kabushiki Kaisha | Adjusting device for a net pole |
US4579965A (en) * | 1985-01-24 | 1986-04-01 | Union Carbide Corporation | Process for preparing vinyl-tri-(tertiary substituted) alkoxysilanes |
JPS61172887A (en) * | 1985-01-24 | 1986-08-04 | ユニオン・カーバイド・コーポレーシヨン | Production of vinyl-tri-(substituted) alkoxysilane |
US4558146A (en) * | 1985-01-31 | 1985-12-10 | Union Carbide Corporation | Process for preparing vinylaminosilanes |
US4898961A (en) * | 1989-07-17 | 1990-02-06 | Dow Corning Corporation | Method for preparing alkenylsilanes |
US5041595A (en) * | 1990-09-26 | 1991-08-20 | Union Carbide Chemicals And Plastics Technology Corporation | Method for manufacturing vinylalkoxysilanes |
Also Published As
Publication number | Publication date |
---|---|
JPS6219434B2 (en) | 1987-04-28 |
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