JPS5734101A - Novel polymerization process - Google Patents
Novel polymerization processInfo
- Publication number
- JPS5734101A JPS5734101A JP10929680A JP10929680A JPS5734101A JP S5734101 A JPS5734101 A JP S5734101A JP 10929680 A JP10929680 A JP 10929680A JP 10929680 A JP10929680 A JP 10929680A JP S5734101 A JPS5734101 A JP S5734101A
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- aqueous solution
- hydrated gel
- agitating shafts
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To improve productivity and operability, by radical-polymerizing monomers in an aqueous solution in a vessel having a plurality of agitating shafts while granulating a hydrated gel-like polymer which forms as the polymerization progresses by a shearing force given by the rotation of the agitating shafts.
CONSTITUTION: In the radical polymerization, in an aqueous solution, of a monomer component which, when polymerized in an aqueous solution, forms a crosslinked structure and becomes a hydrated gel-like polymer, e.g., a monomer mixture comprising acrylic acid and ethylene glycol; said polymerization is carried out by using a polymerization vessel having a plurality of rotary agitating shafts, such as a double-arm kneader, preferably, in the presence of a nonionic surfactant and/or polyethylene glycol. The radical polymerization in an aqueous solution is continued while a hydrated gel-like polymer formed with the progress of the polymerization is granulated by a shearing force given by the rotation of the agitating shafts. This makes it possible to obtain hydrated gel-like polymer particles having excellent fluidity, uniform particle size and easiness in handling.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10929680A JPS5734101A (en) | 1980-08-11 | 1980-08-11 | Novel polymerization process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10929680A JPS5734101A (en) | 1980-08-11 | 1980-08-11 | Novel polymerization process |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5734101A true JPS5734101A (en) | 1982-02-24 |
JPH0219122B2 JPH0219122B2 (en) | 1990-04-27 |
Family
ID=14506574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10929680A Granted JPS5734101A (en) | 1980-08-11 | 1980-08-11 | Novel polymerization process |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5734101A (en) |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5915409A (en) * | 1982-07-20 | 1984-01-26 | Kyoritsu Yuki Kogyo Kenkyusho:Kk | Production of liquid stabilizer |
JPS609639U (en) * | 1983-06-30 | 1985-01-23 | 日本電産コパル株式会社 | Initial impact force stabilization structure of print head of dot printer |
JPS609638U (en) * | 1983-06-30 | 1985-01-23 | 日本電産コパル株式会社 | Gap regulation device for electromagnetic plunger in print head of dot printer |
JPS6055002A (en) * | 1983-09-07 | 1985-03-29 | Nippon Shokubai Kagaku Kogyo Co Ltd | Novel continuous polymerization |
US4625001A (en) * | 1984-09-25 | 1986-11-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for continuous production of cross-linked polymer |
JPS62100507A (en) * | 1985-10-19 | 1987-05-11 | バスフ アクチェンゲゼルシャフト | Continuous manufacture of bridged fine grain gel polymer |
USRE32649E (en) * | 1985-06-18 | 1988-04-19 | The Procter & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
US4920202A (en) * | 1987-04-30 | 1990-04-24 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of hydrophilic polymer from hydrated gel polymer |
US4985514A (en) * | 1987-08-10 | 1991-01-15 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of water absorbent resin |
US5250640A (en) * | 1991-04-10 | 1993-10-05 | Nippon Shokubai Co., Ltd. | Method for production of particulate hydrogel polymer and absorbent resin |
US5275773A (en) * | 1991-02-01 | 1994-01-04 | Nippon Shokubai Co., Ltd. | Method for production of particulate hydrated gel polymer and absorbent resin |
JPH06234557A (en) * | 1993-01-13 | 1994-08-23 | Rhone Poulenc Chim | Cement composition containing alkali- swellable latex and cement obtained from these compositions |
US5382610A (en) * | 1990-12-21 | 1995-01-17 | Nippon Shokubai Co., Ltd. | Water absorbent matter and method for producing it as well as water absorbent and method for producing it |
WO2003022896A1 (en) | 2001-09-12 | 2003-03-20 | Dow Global Technologies Inc. | A continuous polymerization process for the manufacture of superabsorbent polymers |
US7265190B2 (en) | 2002-11-07 | 2007-09-04 | Nippon Shokubai Co., Ltd. | Process and apparatus for production of water-absorbent resin |
JP2009091526A (en) * | 2007-10-12 | 2009-04-30 | Nippon Shokubai Co Ltd | Method for producing polymer, cement admixture polymer, cement admixture, and cement composition |
WO2010095427A1 (en) | 2009-02-17 | 2010-08-26 | 株式会社日本触媒 | Polyacrylic acid-based water-absorbing resin powder and method for producing the same |
US9074030B2 (en) | 2010-06-30 | 2015-07-07 | Nippon Shokubai Co., Ltd. | Polyacrylic acid-type water absorbent resin and method for producing same |
US9334376B2 (en) | 2009-12-24 | 2016-05-10 | Nippon Shokubai Co., Ltd | Water-absorbable polyacrylic acid resin powder, and process for production thereof |
WO2022065365A1 (en) | 2020-09-25 | 2022-03-31 | 株式会社日本触媒 | Method for producing water-absorbing resin powder |
WO2022163849A1 (en) | 2021-01-29 | 2022-08-04 | 株式会社日本触媒 | Method for producing water-absorbent resin |
WO2023190494A1 (en) | 2022-03-30 | 2023-10-05 | 株式会社日本触媒 | Method for producing water-absorbing resin powder |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5493089A (en) * | 1977-06-28 | 1979-07-23 | Nitto Chem Ind Co Ltd | Preparation of acrylamide polymer |
-
1980
- 1980-08-11 JP JP10929680A patent/JPS5734101A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5493089A (en) * | 1977-06-28 | 1979-07-23 | Nitto Chem Ind Co Ltd | Preparation of acrylamide polymer |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5915409A (en) * | 1982-07-20 | 1984-01-26 | Kyoritsu Yuki Kogyo Kenkyusho:Kk | Production of liquid stabilizer |
JPH0229081B2 (en) * | 1982-07-20 | 1990-06-27 | Kyoritsu Juki Kogyo Kenkyusho Kk | |
JPS609639U (en) * | 1983-06-30 | 1985-01-23 | 日本電産コパル株式会社 | Initial impact force stabilization structure of print head of dot printer |
JPS609638U (en) * | 1983-06-30 | 1985-01-23 | 日本電産コパル株式会社 | Gap regulation device for electromagnetic plunger in print head of dot printer |
JPH0214361B2 (en) * | 1983-09-07 | 1990-04-06 | Nippon Shokubai Kagaku Kogyo Kk | |
JPS6055002A (en) * | 1983-09-07 | 1985-03-29 | Nippon Shokubai Kagaku Kogyo Co Ltd | Novel continuous polymerization |
US4625001A (en) * | 1984-09-25 | 1986-11-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for continuous production of cross-linked polymer |
USRE32649E (en) * | 1985-06-18 | 1988-04-19 | The Procter & Gamble Company | Hydrogel-forming polymer compositions for use in absorbent structures |
US4769427A (en) * | 1985-10-19 | 1988-09-06 | Basf Aktiengesellschaft | Continuous preparation of finely divided gel-like crosslinked polymers |
JPS62100507A (en) * | 1985-10-19 | 1987-05-11 | バスフ アクチェンゲゼルシャフト | Continuous manufacture of bridged fine grain gel polymer |
US4920202A (en) * | 1987-04-30 | 1990-04-24 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of hydrophilic polymer from hydrated gel polymer |
US4985514A (en) * | 1987-08-10 | 1991-01-15 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of water absorbent resin |
US5382610A (en) * | 1990-12-21 | 1995-01-17 | Nippon Shokubai Co., Ltd. | Water absorbent matter and method for producing it as well as water absorbent and method for producing it |
US5275773A (en) * | 1991-02-01 | 1994-01-04 | Nippon Shokubai Co., Ltd. | Method for production of particulate hydrated gel polymer and absorbent resin |
US5250640A (en) * | 1991-04-10 | 1993-10-05 | Nippon Shokubai Co., Ltd. | Method for production of particulate hydrogel polymer and absorbent resin |
JPH06234557A (en) * | 1993-01-13 | 1994-08-23 | Rhone Poulenc Chim | Cement composition containing alkali- swellable latex and cement obtained from these compositions |
WO2003022896A1 (en) | 2001-09-12 | 2003-03-20 | Dow Global Technologies Inc. | A continuous polymerization process for the manufacture of superabsorbent polymers |
US7265190B2 (en) | 2002-11-07 | 2007-09-04 | Nippon Shokubai Co., Ltd. | Process and apparatus for production of water-absorbent resin |
JP2009091526A (en) * | 2007-10-12 | 2009-04-30 | Nippon Shokubai Co Ltd | Method for producing polymer, cement admixture polymer, cement admixture, and cement composition |
US9243079B2 (en) | 2009-02-17 | 2016-01-26 | Nippon Shokubai Co., Ltd. | Polyacrylic acid-based water-absorbing resin powder and method for producing the same |
US8791210B2 (en) | 2009-02-17 | 2014-07-29 | Nippon Shokubai Co., Ltd. | Polyacrylic water-absorbent resin powder and method for producing the same |
JP2014237846A (en) * | 2009-02-17 | 2014-12-18 | 株式会社日本触媒 | Polyacrylic acid-based water absorbing resin powder and method for producing the same |
WO2010095427A1 (en) | 2009-02-17 | 2010-08-26 | 株式会社日本触媒 | Polyacrylic acid-based water-absorbing resin powder and method for producing the same |
US9334376B2 (en) | 2009-12-24 | 2016-05-10 | Nippon Shokubai Co., Ltd | Water-absorbable polyacrylic acid resin powder, and process for production thereof |
US9074030B2 (en) | 2010-06-30 | 2015-07-07 | Nippon Shokubai Co., Ltd. | Polyacrylic acid-type water absorbent resin and method for producing same |
US9315640B2 (en) | 2010-06-30 | 2016-04-19 | Nippon Shokubai Co., Ltd. | Polyacrylic acid-type water absorbent resin and method for producing same |
WO2022065365A1 (en) | 2020-09-25 | 2022-03-31 | 株式会社日本触媒 | Method for producing water-absorbing resin powder |
KR20230057408A (en) | 2020-09-25 | 2023-04-28 | 가부시키가이샤 닛폰 쇼쿠바이 | Method for producing water absorbent resin powder |
WO2022163849A1 (en) | 2021-01-29 | 2022-08-04 | 株式会社日本触媒 | Method for producing water-absorbent resin |
KR20230125045A (en) | 2021-01-29 | 2023-08-28 | 가부시키가이샤 닛폰 쇼쿠바이 | Method for producing water absorbent polymer |
WO2023190494A1 (en) | 2022-03-30 | 2023-10-05 | 株式会社日本触媒 | Method for producing water-absorbing resin powder |
KR20240157709A (en) | 2022-03-30 | 2024-11-01 | 가부시키가이샤 닛폰 쇼쿠바이 | Method for producing absorbent resin powder |
Also Published As
Publication number | Publication date |
---|---|
JPH0219122B2 (en) | 1990-04-27 |
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