JPH0631327B2 - ゼオライトベ−タ−による炭化水素油の同時接触水素化分解、水素化脱ろう方法 - Google Patents

ゼオライトベ−タ−による炭化水素油の同時接触水素化分解、水素化脱ろう方法

Info

Publication number: JPH0631327B2
Authority: JP; Japan
Prior art keywords: zeolite; oil; silica; catalyst; zeolite beta
Prior art date: 1982-05-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP58085986A

Other languages

English (en)

Japanese (ja)

Other versions

JPS58210994A (ja

Inventor

レニ・バ−ナ−ド・ラピア

ランダル・デビツド・パ−トリツジ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Oil Corp

Original Assignee

Mobil Oil Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-05-18

Filing date

1983-05-18

Publication date

1994-04-27

1983-05-18 Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp

1983-12-08 Publication of JPS58210994A publication Critical patent/JPS58210994A/ja

1994-04-27 Publication of JPH0631327B2 publication Critical patent/JPH0631327B2/ja

2009-04-27 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 title claims description 94
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 89
229910021536 Zeolite Inorganic materials 0.000 title claims description 86
238000000034 method Methods 0.000 title claims description 52
229930195733 hydrocarbon Natural products 0.000 title claims description 15
150000002430 hydrocarbons Chemical class 0.000 title claims description 15
239000004215 Carbon black (E152) Substances 0.000 title claims description 12
238000004517 catalytic hydrocracking Methods 0.000 title description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 42
239000003054 catalyst Substances 0.000 claims description 34
230000008569 process Effects 0.000 claims description 30
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
238000009835 boiling Methods 0.000 claims description 23
239000000377 silicon dioxide Substances 0.000 claims description 21
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 20
230000002378 acidificating effect Effects 0.000 claims description 16
238000005984 hydrogenation reaction Methods 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 15
239000002184 metal Substances 0.000 claims description 15
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
239000000203 mixture Substances 0.000 claims description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
229910052721 tungsten Inorganic materials 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 10
229910052739 hydrogen Inorganic materials 0.000 claims description 10
229910052759 nickel Inorganic materials 0.000 claims description 10
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 9
239000010937 tungsten Substances 0.000 claims description 9
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
229910052697 platinum Inorganic materials 0.000 claims description 6
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims description 4
229910052750 molybdenum Inorganic materials 0.000 claims description 4
239000011733 molybdenum Substances 0.000 claims description 4
229910052763 palladium Inorganic materials 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
229910052741 iridium Inorganic materials 0.000 claims description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
229910052703 rhodium Inorganic materials 0.000 claims description 2
239000010948 rhodium Substances 0.000 claims description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
239000003921 oil Substances 0.000 description 26
239000000047 product Substances 0.000 description 23
239000002253 acid Substances 0.000 description 21
238000006243 chemical reaction Methods 0.000 description 12
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
150000001768 cations Chemical class 0.000 description 8
239000007789 gas Substances 0.000 description 8
239000011148 porous material Substances 0.000 description 8
238000000354 decomposition reaction Methods 0.000 description 7
239000000126 substance Substances 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
150000007513 acids Chemical class 0.000 description 6
229910052782 aluminium Inorganic materials 0.000 description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
230000003197 catalytic effect Effects 0.000 description 6
238000000605 extraction Methods 0.000 description 6
238000001354 calcination Methods 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
239000000463 material Substances 0.000 description 5
229910000510 noble metal Inorganic materials 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
-1 alkali metal cations Chemical class 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000011159 matrix material Substances 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
125000003367 polycyclic group Chemical group 0.000 description 4
230000002829 reductive effect Effects 0.000 description 4
238000011282 treatment Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
229910004298 SiO 2 Inorganic materials 0.000 description 3
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
238000004458 analytical method Methods 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000004927 clay Substances 0.000 description 3
238000005336 cracking Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000012467 final product Substances 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
150000004706 metal oxides Chemical class 0.000 description 3
239000011707 mineral Substances 0.000 description 3
239000008188 pellet Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000002994 raw material Substances 0.000 description 3
239000011734 sodium Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
239000007858 starting material Substances 0.000 description 3
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
230000008859 change Effects 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
239000000499 gel Substances 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
150000007522 mineralic acids Chemical class 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
150000007524 organic acids Chemical class 0.000 description 2
230000036961 partial effect Effects 0.000 description 2
239000010970 precious metal Substances 0.000 description 2
239000002243 precursor Substances 0.000 description 2
230000009467 reduction Effects 0.000 description 2
238000010025 steaming Methods 0.000 description 2
XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
238000002411 thermogravimetry Methods 0.000 description 2
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
229910017090 AlO 2 Inorganic materials 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229910004283 SiO 4 Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
YCOASTWZYJGKEK-UHFFFAOYSA-N [Co].[Ni].[W] Chemical compound [Co].[Ni].[W] YCOASTWZYJGKEK-UHFFFAOYSA-N 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000011959 amorphous silica alumina Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
229940045985 antineoplastic platinum compound Drugs 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
239000010953 base metal Substances 0.000 description 1
229910001423 beryllium ion Inorganic materials 0.000 description 1
LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000002091 cationic group Chemical class 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910052570 clay Inorganic materials 0.000 description 1
239000003245 coal Substances 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
NVIVJPRCKQTWLY-UHFFFAOYSA-N cobalt nickel Chemical compound [Co][Ni][Co] NVIVJPRCKQTWLY-UHFFFAOYSA-N 0.000 description 1
239000010779 crude oil Substances 0.000 description 1
230000020335 dealkylation Effects 0.000 description 1
238000006900 dealkylation reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical compound OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 description 1
RMGVZKRVHHSUIM-UHFFFAOYSA-N dithionic acid Chemical compound OS(=O)(=O)S(O)(=O)=O RMGVZKRVHHSUIM-UHFFFAOYSA-N 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000010763 heavy fuel oil Substances 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
238000007327 hydrogenolysis reaction Methods 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000010687 lubricating oil Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000005259 measurement Methods 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
125000002950 monocyclic group Chemical group 0.000 description 1
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 description 1
IQZPDFORWZTSKT-UHFFFAOYSA-N nitrosulphonic acid Chemical compound OS(=O)(=O)[N+]([O-])=O IQZPDFORWZTSKT-UHFFFAOYSA-N 0.000 description 1
239000010742 number 1 fuel oil Substances 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000003058 platinum compounds Chemical class 0.000 description 1
CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000007142 ring opening reaction Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical group CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
DAFQZPUISLXFBF-UHFFFAOYSA-N tetraoxathiolane 5,5-dioxide Chemical compound O=S1(=O)OOOO1 DAFQZPUISLXFBF-UHFFFAOYSA-N 0.000 description 1
230000036962 time dependent Effects 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
238000004448 titration Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers

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Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

JP58085986A 1982-05-18 1983-05-18 ゼオライトベ−タ−による炭化水素油の同時接触水素化分解、水素化脱ろう方法 Expired - Lifetime JPH0631327B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US37942182A	1982-05-18	1982-05-18
US379421		1982-05-18

Publications (2)

Publication Number	Publication Date
JPS58210994A JPS58210994A (ja)	1983-12-08
JPH0631327B2 true JPH0631327B2 (ja)	1994-04-27

Family

ID=23497202

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58085986A Expired - Lifetime JPH0631327B2 (ja)	1982-05-18	1983-05-18	ゼオライトベ−タ−による炭化水素油の同時接触水素化分解、水素化脱ろう方法

Country Status (21)

Country	Link
EP (1)	EP0094827B1 (el)
JP (1)	JPH0631327B2 (el)
KR (1)	KR910001498B1 (el)
AR (1)	AR244779A1 (el)
AT (1)	ATE15910T1 (el)
AU (1)	AU563075B2 (el)
BR (1)	BR8302595A (el)
CA (1)	CA1196880A (el)
DE (1)	DE3360923D1 (el)
DK (1)	DK161461C (el)
ES (1)	ES8407089A1 (el)
FI (1)	FI71504C (el)
GR (1)	GR78562B (el)
IN (1)	IN158145B (el)
MY (1)	MY8700240A (el)
NO (1)	NO831715L (el)
NZ (1)	NZ204093A (el)
PH (1)	PH17912A (el)
PT (1)	PT76706B (el)
SG (1)	SG77586G (el)
ZA (1)	ZA833588B (el)

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US4839025A (en) *	1979-10-15	1989-06-13	Union Oil Company Of California	Mild hydrocracking with a catalyst containing non-hydrolyzable halogen
EP0140608B1 (en) *	1983-10-13	1987-04-08	Mobil Oil Corporation	Catalyst and process for hydrocracking and dewaxing hydrocarbon oils
US4568655A (en) *	1984-10-29	1986-02-04	Mobil Oil Corporation	Catalyst composition comprising Zeolite Beta
AU4817385A (en) *	1984-10-29	1986-05-08	Mobil Oil Corporation	Hydrotreating and dewaxing
AU575451B2 (en) *	1984-12-27	1988-07-28	Mobil Oil Corporation	Catalytic cracking of paraffinic feedstocks with zeolite beta
US4911823A (en) *	1984-12-27	1990-03-27	Mobil Oil Corporation	Catalytic cracking of paraffinic feedstocks with zeolite beta
EP0189648B1 (en) *	1984-12-27	1989-08-02	Mobil Oil Corporation	Process for hydrocracking and catalytic dewaxing
ZA864029B (en) *	1985-06-21	1988-01-27	Mobil Oil Corp	Hydrocracking process using zeolite beta
USD304123S (en)	1985-07-23	1989-10-17	South African Polymer Holdings (Proprietary), Limited)	Crate
US4612108A (en) *	1985-08-05	1986-09-16	Mobil Oil Corporation	Hydrocracking process using zeolite beta
US4898846A (en) *	1986-03-21	1990-02-06	W. R. Grace & Co.-Conn.	Cracking catalysts with octane enhancement
US4788378A (en) *	1986-05-13	1988-11-29	Mobil Oil Corporation	Dewaxing by isomerization
US4788370A (en) *	1986-05-13	1988-11-29	Mobil Oil Corporation	Catalytic conversion
US4859312A (en) *	1987-01-12	1989-08-22	Chevron Research Company	Process for making middle distillates using a silicoaluminophosphate molecular sieve
US4851109A (en) *	1987-02-26	1989-07-25	Mobil Oil Corporation	Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
US4812223A (en) *	1987-05-01	1989-03-14	Mobil Oil Corporation	Hydrocracking naphthas using mildly steamed, noble metal-containing zeolite beta
FR2678180B1 (fr) *	1991-06-27	1995-01-27	Inst Francais Du Petrole	Catalyseur de craquage de charges hydrocarbonees riches en composes naphteniques et/ou en paraffines comprenant une zeolithe d'indice de contrainte inferieure a 1 et une matrice.
FR2778410B1 (fr) *	1998-05-06	2000-08-18	Inst Francais Du Petrole	Procede d'hydrocraquage avec un catalyseur a base de zeolithe beta et d'element du groupe vii b
DE69910885T2 (de)	1998-05-06	2004-05-19	Institut Français du Pétrole, Rueil-Malmaison	Katalysator auf Basis von Beta-Zeolith mit Promotorelement und Verfahren zum Hydrocracken
DK0967014T3 (da) *	1998-06-25	2006-07-24	Inst Francais Du Petrole	Hydrokrakningskatalysator, der omfatter en beta-zeolit og et grundstof fra gruppe VB
IT1311512B1 (it)	1999-03-12	2002-03-13	Agip Petroli	Composizione catalitica per l'upgrading di miscele idrocarburiche.
ATE345165T1 (de) *	2002-06-28	2006-12-15	Haldor Topsoe As	Verwendung eines zeolith beta enthaltender katalysators in kohlenwasserstoffumwandlungsverfahren
EP1762606A1 (en)	2005-09-13	2007-03-14	Shell Internationale Researchmaatschappij B.V.	A process for hydrodesulphurisation of a hydrocarbonaceous feedstock
US8263517B2 (en) *	2007-12-28	2012-09-11	Exxonmobil Research And Engineering Company	Hydroprocessing catalysts with low surface area binders
KR101354235B1 (ko) *	2010-04-14	2014-02-13	에스케이이노베이션 주식회사	수소화 탈왁스 공정을 위한 촉매 및 이의 제조 방법

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US3308069A (en)	1964-05-01	1967-03-07	Mobil Oil Corp	Catalytic composition of a crystalline zeolite
US3923641A (en)	1974-02-20	1975-12-02	Mobil Oil Corp	Hydrocracking naphthas using zeolite beta

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CA1064890A (en) *	1975-06-10	1979-10-23	Mae K. Rubin	Crystalline zeolite, synthesis and use thereof
CA1117457A (en) *	1977-03-28	1982-02-02	Christopher Olavesen	Catalytic dewaxing with a hydrogen form zeolite l catalyst
US4222855A (en) *	1979-03-26	1980-09-16	Mobil Oil Corporation	Production of high viscosity index lubricating oil stock
US4434047A (en) *	1981-11-13	1984-02-28	Standard Oil Company (Indiana)	Catalytic dewaxing-hydrotreating process

1983
- 1983-05-03 NZ NZ204093A patent/NZ204093A/en unknown
- 1983-05-09 AU AU14377/83A patent/AU563075B2/en not_active Expired
- 1983-05-13 NO NO831715A patent/NO831715L/no unknown
- 1983-05-16 AR AR83293040A patent/AR244779A1/es active
- 1983-05-16 CA CA000428199A patent/CA1196880A/en not_active Expired
- 1983-05-17 FI FI831724A patent/FI71504C/fi not_active IP Right Cessation
- 1983-05-17 AT AT83302774T patent/ATE15910T1/de not_active IP Right Cessation
- 1983-05-17 DK DK219883A patent/DK161461C/da not_active IP Right Cessation
- 1983-05-17 PT PT76706A patent/PT76706B/pt unknown
- 1983-05-17 PH PH28918A patent/PH17912A/en unknown
- 1983-05-17 EP EP83302774A patent/EP0094827B1/en not_active Expired
- 1983-05-17 DE DE8383302774T patent/DE3360923D1/de not_active Expired
- 1983-05-17 BR BR8302595A patent/BR8302595A/pt unknown
- 1983-05-17 ES ES522482A patent/ES8407089A1/es not_active Expired
- 1983-05-18 GR GR71391A patent/GR78562B/el unknown
- 1983-05-18 ZA ZA833588A patent/ZA833588B/xx unknown
- 1983-05-18 JP JP58085986A patent/JPH0631327B2/ja not_active Expired - Lifetime
- 1983-05-18 KR KR1019830002183A patent/KR910001498B1/ko not_active Expired
- 1983-05-18 IN IN619/CAL/83A patent/IN158145B/en unknown
1986
- 1986-09-25 SG SG775/86A patent/SG77586G/en unknown
1987
- 1987-12-30 MY MY240/87A patent/MY8700240A/xx unknown

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US3308069A (en)	1964-05-01	1967-03-07	Mobil Oil Corp	Catalytic composition of a crystalline zeolite
US3923641A (en)	1974-02-20	1975-12-02	Mobil Oil Corp	Hydrocracking naphthas using zeolite beta

Also Published As

Publication number	Publication date
ES522482A0 (es)	1984-08-16
EP0094827A1 (en)	1983-11-23
CA1196880A (en)	1985-11-19
FI71504B (fi)	1986-10-10
NZ204093A (en)	1985-01-31
DK161461B (da)	1991-07-08
FI831724A0 (fi)	1983-05-17
FI831724L (fi)	1983-11-19
JPS58210994A (ja)	1983-12-08
PH17912A (en)	1985-01-25
MY8700240A (en)	1987-12-31
PT76706A (en)	1983-06-01
GR78562B (el)	1984-09-27
KR910001498B1 (ko)	1991-03-09
FI71504C (fi)	1987-01-19
AU563075B2 (en)	1987-06-25
PT76706B (en)	1985-11-28
DK219883D0 (da)	1983-05-17
ATE15910T1 (de)	1985-10-15
NO831715L (no)	1983-11-21
KR840004776A (ko)	1984-10-24
ZA833588B (en)	1984-12-24
AU1437783A (en)	1983-11-24
IN158145B (el)	1986-09-13
EP0094827B1 (en)	1985-10-02
BR8302595A (pt)	1984-01-17
DK219883A (da)	1983-11-19
DE3360923D1 (en)	1985-11-07
AR244779A1 (es)	1993-11-30
DK161461C (da)	1991-12-16
ES8407089A1 (es)	1984-08-16
SG77586G (en)	1987-02-27

Publication	Publication Date	Title
US4486296A (en)	1984-12-04	Process for hydrocracking and dewaxing hydrocarbon oils
KR910001498B1 (ko)	1991-03-09	제올라이트 베타를 사용한 탄화수소 오일의 동시 촉매하이드로 크래킹 및 하이드로탈왁스 공정
US4554065A (en)	1985-11-19	Isomerization process to produce low pour point distillate fuels and lubricating oil stocks
EP0095303B1 (en)	1986-04-30	Catalytic dewaxing process
AU2002314751B2 (en)	2007-03-01	Process for isomerization dewaxing of hydrocarbon streams
US4501926A (en)	1985-02-26	Catalytic dewaxing process with zeolite beta
US4757041A (en)	1988-07-12	Catalysts for cracking and dewaxing hydrocarbon oils
EP1651738B1 (en)	2011-10-12	Hydrocarbon conversion process and catalyst
US4913797A (en)	1990-04-03	Catalyst hydrotreating and dewaxing process
US3790472A (en)	1974-02-05	Hydrocracking process for producing lubricating oils
EP1517749B1 (en)	2006-11-15	Use of a catalyst comprising zeolite beta in hydrocarbon conversion process
US4762813A (en)	1988-08-09	Hydrocarbon conversion catalyst
US5284573A (en)	1994-02-08	Simultaneous catalytic hydrocracking and hydrodewaxing of hydrocarbon oils with zeolite beta
US5128024A (en)	1992-07-07	Simultaneous catalytic hydrocracking and hydrodewaxing of hydrocarbon oils with zeolite beta
JPH0412317B2 (el)	1992-03-04
KR910008565B1 (ko)	1991-10-19	탄화수소 유분을 수소화 분해하고 수소화 탈납하는 촉매 및 방법
JPH08501113A (ja)	1996-02-06	中間留分の水素化分解製法
US4871445A (en)	1989-10-03	Hydrocarbon conversion
CA1254187A (en)	1989-05-16	Hydrocracking catalyst composition and hydrocracking process using same