JP5777462B2 - Hairdressing mist cosmetics - Google Patents

Description

  The present invention relates to a hair mist cosmetic.

  Conventionally, there is mist cosmetics as cosmetics for discharging a liquid content composition filled in a cosmetic spray container such as a pump container in a mist form. Since these mist cosmetics have the advantage that they can be uniformly applied over a wide range, they are also used as hairdressing cosmetics.

So far, mist cosmetics for hairdressing have been blended with a set agent such as a film forming agent in order to impart a sufficient hairstyling function (see, for example, Patent Documents 1 to 4). However, in the mist cosmetics for hairdressing, when a set agent such as a film-forming agent that is widely used is blended, although sufficient hair-styling power can be imparted, a strong film is formed, so that re-hairing properties are improved. There is a problem of being inferior. Further, there is a problem that the discharge port is clogged by long-term use, and the mist-like discharge form cannot be maintained.

  For this reason, attempts have been made to impart a hair styling function using a specific oil component (see, for example, Patent Document 5). However, in the mist cosmetics for hairdressing, when a set agent such as a specific oily component is blended, not only the hairstyling function is inferior to the film-forming agent, but also a sticky feeling peculiar to the oily component occurs, and the feeling of use and texture There is a problem that gets worse.

  Usually, in hairdressing cosmetics, attempts are made to mix powder in order to suppress the deterioration of the feeling of use and texture, but there is a problem that when the powder is mixed, the hair styling function cannot be fully exhibited. . Furthermore, when the powder is blended with a mist cosmetic filled with a liquid content composition, the powder settles and agglomerates in the composition during standing storage, resulting in poor dispersibility during use and clogging. There is also a problem that causes it.

Japanese Patent Laid-Open No. 5-97636 JP-A-8-217649 JP 2003-26541 A JP 2003-81786 A JP 2009-191046 A

  The present invention has been made in view of the above-described conventional technology, and can perform hair styling without a sticky feeling that could not be achieved with a mist cosmetic that exhibits the conventional hair styling function, and has an excellent effect on re-styling. It is an object of the present invention to provide a mist cosmetic for hair styling that exhibits.

  The present inventor has conducted earnest research to develop a mist cosmetic that can fully exhibit the hair-styling function, and found that silicic anhydride, which is a powder component, exhibits an excellent hair-styling function. The two-layered mist cosmetic containing ingredients has excellent powder component dispersibility, and when applied to the hair, surprisingly, it is possible to adjust the hair without stickiness and softly increase the volume of the entire hair. In addition, the present inventors have found that re-hairdressing is possible, and the present invention has been completed.

That is, the present invention
[1] A hair mist cosmetic used for hair styling , wherein the content is discharged in a mist form by a pump-type dispenser or a trigger-type dispenser, wherein the content is ( A) A two-layer composition comprising a lower powder layer and an upper liquid layer, containing silicic anhydride, (B) ethanol, (C) water, and (D) a polyhydric alcohol and / or (E) a surfactant. Monodea is, the a component (B), wherein (C) the mass content ratio of the component, (B) :( C) = 1: 2~1: the 40 range der wherein Rukoto styling For mist cosmetics,
[2] The hair mist cosmetic according to [1], wherein the component (A) satisfies an oil absorption of 100 to 1000 mL / 100 g.
[3] The mass content ratio of the component (A) and the component (B) satisfies the range of (A) :( B) = 1: 1 to 1:50 [1] Or the mist makeup for hairdressing according to [2], and [4] any one of [1] to [3], wherein the component (E) is a nonionic surfactant and / or a cationic surfactant The present invention relates to a mist cosmetic for hairdressing according to the above.

  The hairdressing mist cosmetic of the present invention is excellent in dispersibility of the powder component and can be uniformly applied to the hair in a wide range in the form of a mist, so that the hair can be styled without stickiness and the entire hair is soft and volume In addition to being able to improve, it also has an excellent effect on re-styling.

  Furthermore, the mist cosmetic for hairdressing of the present invention has the effect of suppressing the phenomenon that the lower layer powder layer solidifies during stationary storage, so-called caking, and excellent redispersibility of the powder component. Moreover, since it is excellent in redispersibility, there is an effect that even if it is used for a long time, there is no clogging of the discharge port, and the mist-like discharge form can be maintained.

  The hair mist cosmetic of the present invention is a hair mist cosmetic in which the contents are discharged in the form of a mist by a pump-type dispenser or a trigger-type dispenser, wherein the contents are (A) silicic anhydride, (B) A two-layer composition comprising ethanol, (C) water, (D) polyhydric alcohol and / or (E) surfactant, and comprising a lower powder layer and an upper liquid layer.

  The mist shape in the present invention includes a mist shape.

  First, a two-layer composition comprising a powder layer and a liquid layer, which are the contents of the hair mist cosmetic composition of the present invention, will be described.

  In the powder layer constituting the two-layer composition of the present invention, (A) silicic anhydride is used. The component (A), silicic anhydride, is a powder blended in the composition as a component capable of styling hair without a sticky feeling, having excellent hair styling ability, and capable of re-styling hair.

  In the present invention, it is preferable to use a material satisfying the oil absorption (mL / 100 g) described later from the viewpoint of sufficiently exerting the hair-styling power and enabling hair re-styling.

  More specifically, the amount of oil absorption per 100 g of silicic anhydride preferably satisfies the range of 100 to 1000 mL / 100 g, more preferably 150 to 800 mL / 100 g, and even more preferably 200 to 700 mL. / 100g range. The oil absorption is a value measured according to the method described in JIS K5101.

  In addition, a commercial item can also be used for the silicic acid anhydride of (A) component as it is. Specifically, commercially available silicic anhydride products include, for example, AEROSIL 50, 90G, 130, 150, 200, 300, 380, 200V, OX50 (trade names, all manufactured by Nippon Aerosil Co., Ltd.); Sunsphere H- 31, H-51, H-121, H-201, H-32, H-52, H-122, H-33, H-53 (trade names, all manufactured by AGC S-Tech) Can do.

  The content of the component (A) is not particularly limited as long as the desired effect is sufficiently imparted, but usually, from the viewpoint of being able to style hair without stickiness and exhibiting sufficient hair-styling power. 0.2 mass% or more is preferable, More preferably, it is 0.5 mass% or more. Moreover, from a viewpoint of a usability | use_condition, 10 mass% or less is preferable, More preferably, it is 5 mass% or less. From these viewpoints, the content of the component (A) is preferably 0.2 to 10% by mass, and more preferably 0.5 to 5% by mass.

  (B) ethanol is mix | blended with the liquid layer which comprises the two-layer type composition of this invention. (B) If ethanol of a component can be used as a cosmetic raw material, it will not be specifically limited. The content of the component (B) is not particularly limited as long as the desired effect is sufficiently imparted, but usually 2% by mass or more is preferable in the composition from the viewpoint of quick drying after coating, and more preferable. Is 5% by weight or more. Moreover, from a dispersible viewpoint at the time of preparation, 60 mass% or less is preferable, More preferably, it is 40 mass% or less. From these viewpoints, the content of the component (B) is preferably 2 to 60% by mass, and more preferably 5 to 40% by mass.

  In the two-layer composition of the present invention, from the viewpoint of initial hair styling, the mass content ratio of the component (A) and the component (B) is (A) :( B) = 1: 1 to 1. : 50 is preferably satisfied, and more preferably (A) :( B) = 1: 5 to 1:40. When the amount of the component (B) is less than 1 part by mass relative to 1 part by mass of the component (A), drying is slow at the time of hairdressing, which is not preferable. Moreover, when there are more (B) components than 50 mass parts with respect to 1 mass part of (A) component, since drying becomes quick at the time of hairdressing and hairdressing becomes difficult, it is unpreferable.

  (C) Water is mix | blended with the liquid layer which comprises the two-layer type composition of this invention. Although the water of (C) component will not be specifically limited if it can be used as a cosmetic raw material, For example, purified water is used. The content of the component (C) is not particularly limited as long as the desired effect is sufficiently imparted, but is usually preferably 50% by mass or more, more preferably from the viewpoint of dispersibility during preparation. Is 60% by weight or more. Moreover, from a quick-drying viewpoint, 95 mass% or less is preferable, More preferably, it is 90 mass% or less. From these viewpoints, the content of the component (C) is preferably 50 to 95% by mass, more preferably 60 to 90% by mass.

  In the two-layer composition of the present invention, from the viewpoint of dispersibility during preparation, the mass content ratio of the component (B) and the component (C) is (B) :( C) = 1: 1. It is preferable that it is prepared so as to satisfy the range of ˜1: 50, more preferably (B) :( C) = 1: 2 to 1:40.

  The liquid layer constituting the two-layer composition of the present invention includes (D) a polyhydric alcohol and / or (E) interface from the viewpoint of enhancing the redispersibility of the powder as component (A). An active agent is blended.

  Examples of the (D) component polyhydric alcohol include glycols, glycerins, sugar alcohols and the like. More specifically, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2-butanediol, 1,2-pentane. Glycols such as diol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol; glycerols such as glycerin, diglycerin, polyglycerin; xylitol, trehalose, maltitol, mannitol, sorbitol, Examples thereof include sugar alcohols such as erythritol, arabitol, ribitol, galactitol, glucitol and erythritol. These (D) components may be used individually by 1 type, and can be used in combination of 2 or more types as appropriate.

  As the suitable component (D), at least one selected from the group of propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, and diglycerin is used from the viewpoint of reducing squeaking during hair styling and redispersibility. It is preferable.

  The content of the component (D) is not particularly limited as long as the desired effect is sufficiently imparted. However, from the above viewpoint, the content is preferably 1% by mass or more, more preferably 2% by mass or more. It is. Moreover, from a viewpoint of hair-styling, 30 mass% or less is preferable, More preferably, it is 20 mass% or less. From these viewpoints, the content of the component (D) is preferably 1 to 30% by mass, and more preferably 2 to 20% by mass.

  In the two-layer composition of the present invention, from the viewpoint of redispersibility, the mass content ratio of the component (A) and the component (D) is (A) :( D) = 1: 0.2. It is preferable to satisfy the range of ˜1: 15, more preferably (A) :( D) = 1: 0.5 to 1:10. When the component (D) is less than 0.2 parts by mass with respect to 1 part by mass of the component (A), the redispersibility is inferior. Moreover, when there are more (D) components than 15 mass parts with respect to 1 mass part of (A) component, since the hair-styling power peculiar to powder is inhibited, it is unpreferable.

  Examples of the component (E) surfactant include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. These (E) components may be used individually by 1 type, and can be used in combination of 2 or more type as appropriate. In the present invention, among these surfactants, it is preferable to use a nonionic surfactant or a cationic surfactant from the viewpoint of enhancing the redispersibility of the powder.

  Preferred nonionic surfactants include, for example, alkyl glucosides, glycerin fatty acid esters, polyglycerin fatty acid esters, ethylene oxide condensates of glycerin fatty acid esters, polyethylene glycol fatty acid esters, propylene glycol fatty acid esters, sorbitan fatty acid esters, sorbitan fatty acid esters. Ethylene oxide condensate, polyoxyalkylene alkyl ether, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene lanolin and the like.

  More specifically, for example, alkyl glucosides such as alkyl (C8-16) glucoside, cetostearyl glucoside, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside; glyceryl monocaprylate, glyceryl monocaprate, glyceryl monolaurate, Glyceryl monomyristate, glyceryl monopalmitate, glyceryl monostearate, glyceryl monoisostearate, glyceryl monobehenate, glyceryl monooleate, glyceryl monoerucate, glyceryl sesquioleate, glyceryl distearate, glyceryl diisostearate, glyceryl diarachiate, etc. Glyceryl fatty acid ester of diglyceryl monocaprylate, decapglyceryl monocaprylate, hexacapric monocaprate Lyceryl, tetraglyceryl monolaurate, hexaglyceryl monolaurate, decaglyceryl monolaurate, poly (4-10) glyceryl monolaurate, decaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monoisostearate, poly (monostearate poly ( 2 to 10) glyceryl, diglyceryl monooleate, hexaglyceryl monooleate, diglyceryl sesquioleate, poly (2-10) glyceryl diisostearate, poly (6-10) glyceryl distearate, diglyceryl triisostearate, Polyglycerol fatty acid ester having a polymerization degree of 2 to 10 as described above, such as poly (10) glyceryl tristearate; polyoxyethylene glycol monostearate Ethylene oxide condensate of glycerin fatty acid ester such as ril, polyoxyethylene glyceryl monooleate; polyethylene glycol fatty acid ester such as polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate; propylene glycol monostearate, monolaurin Propylene glycol fatty acid esters such as propylene glycol acid, propylene glycol monooleate; sorbitan monooleate, sorbitan monostearate, sorbitan monoisostearate, sorbitan monopalmitate, sorbitan monolaurate, sorbitan trioleate, sorbitan tristearate, Sorbitan sesquistearate, sorbitan sesquioleate, sesqui Sorbitan fatty acid esters such as sorbitan isostearate and coconut oil fatty acid sorbitan; polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxymonoisostearate Ethylene oxide condensates of sorbitan fatty acid esters such as ethylene sorbitan, mono-coconut oil fatty acid polyoxyethylene sorbitan, polyoxyethylene sorbitan tristearate, polyoxyethylene sorbitan trioleate; polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, poly Oxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene polyol Dipropylene lauryl ether, polyoxypropylene cetyl ether, polyoxypropylene isocetyl ether, polyoxypropylene stearyl ether, polyoxyalkylene alkyl ethers such as polyoxypropylene oleyl ether can be exemplified.

  Among suitable nonionic surfactants, alkyl glucoside and polyoxyethylene hydrogenated castor oil are more preferably used from the viewpoint of further improving the redispersibility of the powder. Among alkyl glucosides, alkyl (C8-16) Most preferably, glucoside or cetostearyl glucoside is used.

  Preferred examples of the cationic surfactant include alkylamine salts, fatty acid amidoamine salts, monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, and benzalkonium quaternary ammonium salts.

  More specifically, for example, alkylamine salts such as dioctylamine, dimethylstearylamine, trilaurylamine; myristic acid diethylaminoethylamide, palmitic acid diethylaminoethylamide, stearic acid diethylaminoethylamide, stearic acid dimethylaminopropylamide, etc. Fatty acid amidoamine salts; monoalkyl-type quaternary ammonium salts such as lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, stearyltrimethylammonium chloride, alkyl (20-22) trimethylammonium chloride; distearyldimethylammonium chloride; Dicocoyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, isostearyl lauryl dimethyl chloride Dialkyl quaternary ammonium salts such as ruammonium; Trialkyl quaternary ammonium salts such as tri (polyoxyethylene) stearylammonium chloride; Benzalkonium chloride, myristyldimethylbenzylammonium chloride, lauryldimethylbenzylammonium chloride, stearyldimethyl chloride Examples thereof include benzalkonium type quaternary ammonium salts such as benzylammonium.

  Of the suitable cationic surfactants, monoalkyl quaternary ammonium salts and dialkyl quaternary ammonium salts are more preferably used from the viewpoint of further improving the redispersibility of the powder. Most preferably, is used.

  The content of the component (E) is not particularly limited as long as the desired effect is sufficiently imparted. However, from the above viewpoint, the content is preferably 0.1% by mass or more, more preferably 0. 3% by mass or more. Moreover, from a viewpoint of hair-styling, 15 mass% or less is preferable, More preferably, it is 10 mass% or less. From these viewpoints, the content of the component (E) is preferably 0.1 to 15% by mass, more preferably 0.3 to 10% by mass.

  In the two-layer composition of the present invention, from the viewpoint of redispersibility, the mass content ratio of the component (A) to the component (E) is (A) :( E) = 1: 0.05. It is preferable that it is prepared so as to satisfy the range of ˜1: 8, more preferably (A) :( E) = 1: 0.1 to 1: 5. When the component (E) is less than 0.05 parts by mass relative to 1 part by mass of the component (A), the redispersibility is poor, which is not preferable. Moreover, when there are more (E) components than 8 mass parts with respect to 1 mass part of (A) component, since the hair-styling power peculiar to powder is inhibited, it is unpreferable.

  In the two-layer composition of the present invention, components that are usually used in cosmetics in addition to the above-described components, such as preservatives, pH adjusters, fragrances, and humectants, as long as the effects of the present invention are not impaired. A metal sequestering agent and the like can be appropriately blended depending on the purpose.

  The production method of the two-layer composition of the present invention is not particularly limited as long as it can be produced by a known method. For example, the above-described components are added and a known mixing apparatus such as a disper mixer or a paddle mixer is used. Although the method of mixing etc. can be illustrated, this invention is not limited only to these manufacturing methods.

  Next, the mist cosmetic for hairdressing agents of the present invention will be described.

  The hair mist cosmetic composition of the present invention is characterized in that the two-layer composition comprising the lower powder layer and the upper liquid layer is discharged as a mist using a pump-type dispenser or a trigger-type dispenser. . Moreover, the usage method of the mist cosmetic for hairdressing agents can illustrate the method of spray-applying to hair after fully shaking a two-layer type composition and disperse | distributing a powder uniformly to a liquid layer.

  The amount discharged by a single discharge process of the pump-type dispenser or the trigger-type dispenser is not particularly limited as long as the desired effect is sufficiently exerted, but it is uniformly applied over a wide range without dripping onto the hair. In addition, from the viewpoint of allowing hairstyling without stickiness, the amount is preferably in the range of 0.05 to 1.0 mL / once, more preferably 0.15 to 0.5 mL / once.

  The pump-type dispenser or the trigger-type dispenser used is a dispenser having a function of discharging in a mist form, and is not particularly limited as long as it is generally distributed. Specifically, as a pump type dispenser, Yoshino Kogyo's Y-150 (1 push about 0.15 mL discharge), Mitani Valve Co., Ltd. Z-155 (1 push about 0.15 mL discharge); Trigger type dispenser Examples include M3-M manufactured by Yoshino Kogyo Co., Ltd. (about 0.5 mL discharged once), Z-305, T-305 manufactured by Mitani Valve Co., Ltd. (discharged about 0.3 mL once), and the like. .

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by mass” unless otherwise specified.

(Sample preparation 1)
According to the composition described in Table 1 to Table 4, each two-layer composition of Examples 1 to 8 and Comparative Examples 1 to 7 was prepared and subjected to the following evaluation. The results are shown in Tables 1 to 4. In addition, all evaluation was implemented on the constant conditions of constant temperature and humidity of 23 degreeC and 60% of humidity. The numerical value in parentheses represents the number of added moles of ethylene oxide.

(Test Example 1: Evaluation of redispersibility)
The prepared two-layer composition of each Example and each Comparative Example was filled into a 120 mL transparent glass container. Subsequently, it stood still for 3 days in a 25 degreeC thermostat, and the following operation was repeated every day after 3 days, and the confirmation test about the dispersibility of powder was done.

  A sample was taken out from the thermostatic bath, immediately shaken up and down 5 times, and visually confirmed about the dispersibility of the powder immediately after shaking. After confirmation, each sample was returned to the thermostat and the same test was performed once a day in the morning. This operation was repeated for one month, and the dispersion state was evaluated according to the following criteria.

<Evaluation criteria for redispersibility>
○: No lump of powder remains on the bottom immediately after shaking during the test period, and is completely dispersed. Δ: Some lump of powder remains on the bottom immediately after shaking during the test period. Dispersed when shaked ×: During the test period, a powder lump apparently remains at the bottom immediately after shaking, and does not disperse even after shaking 5 times

(Test Example 2: Evaluation of discharge mode)
The prepared two-layer composition of each Example and each Comparative Example was filled into a 50 mL container equipped with a pump-type dispenser (Y-150, manufactured by Yoshino Kogyo Co., Ltd., discharge amount 0.15 mL / 1 push), It stored in a 40 degreeC thermostat, the following operation was repeated every day, and the confirmation test of the discharge (spray) form was done.

  A sample was taken out from the thermostat and immediately discharged (sprayed) 10 times. After discharge (spraying), each sample was returned to the thermostat and allowed to stand. The test was repeated every week for 4 weeks, and the spray state was evaluated according to the following criteria.

<Evaluation criteria for discharge mode>
○: No abnormality is observed in the discharge (spray) state within the observation period, and the mist form is maintained. Δ: The discharge (spray) state is slightly weakened during the observation period, but the mist form is maintained. X: Cannot be discharged (sprayed) in a mist form or not discharged at all within the observation period

(Test Example 3: Evaluation of applicability)
The prepared two-layer composition of each Example and each Comparative Example was filled in a container equipped with a pump-type dispenser (Y-150, manufactured by Yoshino Kogyo Co., Ltd., discharge amount 0.15 mL / 1 push). Subsequently, 20 persons with a sensory evaluation panel used the wig (Lesson Mannequin: manufactured by Eucalyptus Japan Co., Ltd.) to actually spray-apply it to the hair, and “applicability” was subjected to sensory evaluation according to the following evaluation criteria.

<Evaluation criteria for applicability>
○: 16 or more out of 20 respondents can apply uniformly over a wide range Δ: 10 to 15 out of 20 respondents can apply uniformly over a wide area ×: 9 or less out of 20 respondents Reply that it can be applied uniformly over a wide area

(Test Example 4: Evaluation during hair styling)
After the evaluation in Test Example 3, the 20 panelists gave hair to the hair as if they were rubbed together, and sensory evaluation was performed according to the following evaluation criteria for “stickiness” and “hairstyling power” during hairdressing.

  In addition, the evaluation of “hair-styling power” is performed by setting up the hair so that it can be rubbed together. It was.

<Evaluation criteria for stickiness>
○: 16 or more out of 20 responded that there was no stickiness △: 10-15 out of 20 responded that there was no stickiness ×: 9 or less out of 20 responded that there was no stickiness

<Evaluation criteria for hair styling power>
○: 16 or more out of 20 responded that hair styling ability is high △: 10 to 15 out of 20 responded that hair styling ability was high ×: 9 or less of 20 persons answered that hair styling ability was high

(Test Example 5: Evaluation during re-styling)
One hour after the evaluation in Test Example 4, the 20 panelists gave hair to the hair again, and subjected to sensory evaluation according to the following evaluation criteria.

<Evaluation criteria for re-styling>
○: More than 16 out of 20 responded that they can restyle their hair as desired △: 10 to 15 out of 20 responded that they could restyle their hair as intended ×: 9 or fewer out of 20 , You can restyle your hair as you want

  From the results shown in Tables 1 to 4, the mist cosmetic for hairdressing agents of the present invention described in each example is excellent in redispersibility of silicic anhydride, which is the component (A), and thus used for a long time. However, it can be seen that the discharge port is not clogged and the mist-like discharge form is maintained. Furthermore, since it can be uniformly applied over a wide range and can be styled without stickiness, it can fully exhibit the excellent hair styling power of silicic acid anhydride and has an excellent effect on re-styling. I understand that.

  On the other hand, in Comparative Examples 1 to 5 that do not satisfy the configuration of the present invention, the dispersibility of the powder component is inferior, and since it cannot be uniformly applied over a wide range, the hair styling characteristics unique to the present invention cannot be sufficiently exhibited. I understand. Moreover, since it is inferior in the dispersibility of a powder component, when using for a long period of time, it becomes easy to produce clogging of a discharge outlet, and it turns out that a mist-like discharge form cannot be maintained. Moreover, in Comparative Examples 6-7 which replaced the (A) component with other powder, it turns out that the hair-styling characteristic peculiar to this invention cannot fully be exhibited.

Claims (4)

A hair mist cosmetic used for hair styling,
A mist cosmetic for hair styling in which the contents are discharged in the form of a mist by a pump-type dispenser or a trigger-type dispenser,
The content contains (A) silicic anhydride, (B) ethanol, (C) water, and (D) a polyhydric alcohol and / or (E) a surfactant, and a lower powder layer and an upper liquid layer 2-layer composition der consisting is,
Wherein (B) and component mass composition ratio of the component (C), (B) :( C) = 1: 2~1: 40 hairdressing mist cosmetic wherein range der Rukoto of.   The mist cosmetic for hairdressing according to claim 1, wherein the component (A) satisfies an oil absorption of 100 to 1000 mL / 100 g.   The mass content ratio between the component (A) and the component (B) satisfies a range of (A) :( B) = 1: 1 to 1:50. Hair mist cosmetics.   The hair mist cosmetic according to any one of claims 1 to 3, wherein the component (E) is a nonionic surfactant and / or a cationic surfactant.