JP5275618B2 - Non-contact fungicide composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a non-contact type fungicide composition exhibiting an excellent fungicidal performance without making contact with a material to be protected from fungi, and also maintaining a good scent tone without jointly using a deodorant, etc. <P>SOLUTION: This non-contact type antifungal composition contains the following components (a) and (b), and the fungicide composition package is obtained by housing the composition into a container. (a): At least 1 kind selected from compounds expressed by formula: R<SP>1</SP>-O(AO)<SB>n</SB>(1) [wherein, R<SP>1</SP>is a 6-11C alkyl; A is a 2-3C alkylene; (n) is a number of 1 to 3, which shows the mean number of moles of addition; and nAs are each the same or different, provided that ethylene glycol monohexyl ether is excluded]. (b) At least 1 kind selected from perfume ingredients having &ge;170 and &le;280&deg;C boiling point and &ge;1 and &le;4 logP value, and also having any one of hydroxy or aldehyde group. <P>COPYRIGHT: (C)2009,JPO&amp;INPIT

Description

  The present invention relates to a non-contact type fungicide composition and a package thereof.

  Generally, clothes are used in a cycle of “wear → washing → storage” after purchase, but it is important to protect (care) from troubles such as mold and odor that are anxious during storage. . Conventional antifungal agents are powders or crystals such as methyl paraoxybenzoate, ethyl paraoxybenzoate, benzoic acid, sodium benzoate, orthophenylphenol, or liquids such as 2-phenoxyethanol and benzalkonium chloride, In either case, the mold-proof performance cannot be sufficiently imparted unless the mold is brought into contact with the article to be protected.

On the other hand, techniques related to non-contact type antifungal agents have been disclosed, but there are problems such as insufficient antifungal performance and strong base odor, making it difficult to use alone. Patent Document 1 discloses a technique related to a composition for spatial disinfection containing glycol ether. Patent Document 2 discloses a technique related to a non-contact type low odor insect repellent. Patent Document 3 discloses a technique relating to an antifungal fragrance composition.
JP 2007-97738 A JP 2000-319110 A JP 2002-179509 A

  In the technology of Patent Document 1, propylene glycol monomethyl ether, propylene glycol-n-propyl ether, etc. are evaporated using a heater, etc., and the anti-mold performance at natural volatilization at room temperature is low and sufficient performance is expressed. This requires a large amount of base. In the technology of Patent Document 2, since the odor of ethylene glycol monohexyl ether is too strong, it is difficult to use it alone, and it is necessary to use an odor reducing agent or a vaporization regulator in combination. In the technique of Patent Document 3, a fragrance selected from aliphatic or aromatic aldehydes, aliphatic alcohols and phenols and a fragrance selected from aliphatic alcohols, phenols, acetals and esters are used in combination. However, the mold prevention performance is not enough.

  Therefore, the problem of the present invention is to provide excellent antifungal performance without direct contact with the article to be protected, and to maintain a good fragrance without using an odor reducing agent or the like. It is in providing a mold prevention agent composition.

  The inventors of the present invention use a specific alkyl glycol ether in combination with a specific fragrance component because it has excellent antifungal performance even when it is not in contact with the object to be protected and has low odor. It was found that the mold prevention performance can be further improved while maintaining the above.

That is, the present invention provides a non-contact type fungicide composition containing the following components (a) and (b), and a fungicide composition comprising the non-contact type fungicide composition housed in a container. Provide a product package.
(A): At least one selected from compounds represented by the general formula (1) R ¹ —O (AO) _n H (1)
[Wherein, R ¹ is an alkyl group having 6 to 11 carbon atoms, A is an alkylene group having 2 to 3 carbon atoms, n is a number of 1 to 3 indicating the average number of added moles, and n A's are the same. It may be different. However, ethylene glycol monohexyl ether is excluded. ]
(B): at least one selected from fragrance components having a boiling point of 170 ° C. or higher and 280 ° C. or lower, a log P value of 1 or higher and 4 or lower, and having one of either a hydroxy group or an aldehyde group

  The non-contact type fungicide composition of the present invention and the package thereof can exhibit an excellent fungicide function in a wide range without contacting the product to be protected, and have a good fragrance because of its low odor. Tones can be maintained.

[(A) component]
The component (a) of the present invention is at least one selected from the compounds represented by the general formula (1).

In the general formula (1), R ¹ is an alkyl group having 6 to 11 carbon atoms, and the alkyl group may be linear or branched. Specific examples of R ¹ include groups such as hexyl, heptyl, octyl, 2-ethylhexyl, nonyl, decyl, isodecyl, undecyl and the like. A is an alkylene group having 2 to 3 carbon atoms, and the alkylene group may be linear or branched, and n A's may be the same or different. Specific examples of A include a propylene group (propane-1,2-diyl group), an ethylene group, and a trimethylene group, and a propylene group and an ethylene group are preferable. n is a number of 1 to 3 indicating the average number of moles added, and a number of 1 to 2 is preferred. However, since ethylene glycol monohexyl ether has a strong odor and cannot fully exhibit the performance of the present invention, it is excluded from the compound represented by the general formula (1).

As the compound represented by the general formula (1), R ¹ is an alkyl group having 6 to 11 carbon atoms, A is a propylene group, n is a number having 1 to 2, and R ¹ has 6 to 11 carbon atoms. Preferred are an alkyl group, a compound in which A is an ethylene group and n is 2, and a compound in which R ¹ is an alkyl group having 7 to 11 carbon atoms, A is an ethylene group and n is 1.

  Specific examples of the component (a) include, for example, propylene glycol monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, dipropylene glycol monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, tripropylene glycol monoalkyl. (Alkyl group having 6 to 11 carbon atoms) ether, ethylene glycol monoalkyl (alkyl group having 7 to 11 carbon atoms) ether, diethylene glycol monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, triethylene glycol monoalkyl (alkyl Group having 6 to 11 carbon atoms, trimethylene glycol monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, di (trimethylene glycol) monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, tri (tri Methylene glycol) monoal Le (number of carbon atoms in the alkyl group 6-11) ether.

  Among these, from the viewpoint of fungicidal effect, propylene glycol monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, dipropylene glycol monoalkyl (alkyl group having 6 to 11 carbon atoms) ether, ethylene glycol monoalkyl ( Alkyl group carbon number 7-11) ether and diethylene glycol monoalkyl (alkyl group carbon number 6-11) ether are preferred.

  Further, from the viewpoint of low odor, dipropylene glycol monohexyl ether, dipropylene glycol monoheptyl ether, propylene glycol monooctyl ether, dipropylene glycol monooctyl ether, propylene glycol mono-2-ethylhexyl ether, dipropylene glycol mono- 2-ethylhexyl ether, propylene glycol monononyl ether, dipropylene glycol monononyl ether, propylene glycol monodecyl ether, dipropylene glycol monodecyl ether, propylene glycol monoisodecyl ether, dipropylene glycol monoisodecyl ether, propylene glycol monoun Decyl ether, dipropylene glycol monoundecyl ether, diethylene glycol Cole monohexyl ether, diethylene glycol monoheptyl ether, ethylene glycol monooctyl ether, diethylene glycol monooctyl ether, ethylene glycol mono-2-ethylhexyl ether, diethylene glycol mono-2-ethylhexyl ether, ethylene glycol monononyl ether, diethylene glycol monononyl ether, ethylene More preferred are glycol monodecyl ether, diethylene glycol monoisodecyl ether, ethylene glycol monoisodecyl ether, diethylene glycol monoisodecyl ether, ethylene glycol monoundecyl ether, and diethylene glycol monoundecyl ether.

  (A) component of this invention can be used 1 type or in mixture of 2 or more types.

[Component (b)]
The component (a) of the present invention alone exhibits antifungal performance under non-contact conditions, but by using the component (b) of the present invention in combination, the antifungal performance is further improved while maintaining a good fragrance. Can be increased.

  Component (b) of the present invention has a boiling point of 170 ° C. or more and 280 ° C. or less, preferably 170 to 260 ° C., a log P value of 1 or more and 4 or less, preferably 1.0 to 3.5, and a hydroxy group or aldehyde A fragrance ingredient having one of the groups.

  Here, the “log P value” is a logarithmic value of the 1-octanol / water partition coefficient of the compound, and in the partition equilibrium when the compound is dissolved as a solute in the two-liquid solvent system of 1-octanol and water. , Means the ratio of the equilibrium concentration of the solute in each solvent and is generally indicated in the form of log “log P” with respect to the base 10. That is, the log P value is an index of lipophilicity (hydrophobicity). The larger the value, the more hydrophobic, and the smaller the value, the more hydrophilic.

  For the log P value, see, for example, Daylight Chemical Information Systems, Inc. A logP value published in a database available from (Daylight CIS) or the like can be referred to as an actual measurement value. Further, when there is no actual measurement value, it can be calculated by a program “CLOGP” (Daylight CIS) or the like, and among them, calculation by the program “CLOGP” is preferable because of high reliability.

  In the program “CLOGP”, the value of “calculated logP (ClogP)” calculated by the Hansch, Leo fragment approach is output together with the measured value of logP, if any. The fragment approach is based on the chemical structure of the compound and takes into account the number of atoms and the type of chemical bond (A. Leo, Comprehensive Medicinal Chemistry, Vol. 4, C. Hansch, P. G. Sammens, J. et al. B. Taylor and CA A. Ramsden, Eds., P. 295, Pergamon Press, 1990). Since this ClogP value is currently the most common and reliable estimate, it is preferable to use the ClogP value instead when there is no measured value of logP when selecting a compound. In the present invention, either an actual measured value of logP or a ClogP value calculated by the program “CLOGP” may be used. However, when there is an actual measured value, it is preferable to use the actual measured value.

  Specific examples of the component (b) include linalool, geraniol, nerol, citronellol, myrcenol, lavandulol, tetrahydrogeraniol, tetrahydrolinalool, hydroxycitronellol, dihydromyrcenol, α-terpineol, terpinene-4-ol, isopulegol, 2,4-dimethyl-3-cyclohexene-1-methanol (manufactured by IFF: Floralol), 4-isopropylcyclohexanol (manufactured by Givaudan-Roure: Forrussia), 4-isopropylcyclohexanemethanol (manufactured by Firmenich: Mayor), 1- (4-Isopropylcyclohexyl) -ethanol (manufactured by H & R: mugetanol), 2,2-dimethyl-3- (3-methylphenyl) -propanol (Wacke (Manufactured by: Magantol), ambrinol, 1-octen-3-ol, dimethol, decenol, 2,6-nonadienol, 10-undecenol, trans-2-cis-6-nonadienol, benzyl alcohol, phenylethyl alcohol, Phenoxyethyl alcohol, phenylpropyl alcohol, phenylhexanol, carvacrol, eugenol, isoeugenol, citral, citronellal, hydroxycitronellal, perylaldehyde, nonylaldehyde, decylaldehyde, undecylaldehyde, trimethylhexylaldehyde, 2,6- Nonadienal, cis-4-decenal, benzaldehyde, phenylacetaldehyde, phenylpropylaldehyde, cinnamic aldehyde, hydrotropic Examples include aldehyde, anisaldehyde, p-methylphenylacetaldehyde, cuminaldehyde, cyclamenaldehyde, and laral.

  Among these, from the viewpoint of antifungal performance, linalool, geraniol, nerol, citronellol, α-terpineol, terpinen-4-ol, isopulegol, 2,4-dimethyl-3-cyclohexene-1-methanol (manufactured by IFF: Florolol), 4-isopropylcyclohexanol (Givaudan-Roure: Forrussia), 4-isopropylcyclohexanemethanol (Firmenich: Mayor), 1- (4-isopropylcyclohexyl) -ethanol (H & R: Mugetanol), 2,2-dimethyl-3- (3-methylphenyl) -propanol (manufactured by Wacker: Magantol), 1-octen-3-ol, decenol, 2,6-nonadienol, benzyl alcohol, phenylethyl Alcohol, phenylpropyl alcohol, carvacrol, eugenol, citral, citronellal, phenylpropylaldehyde, cinnamic aldehyde, anisaldehyde, cuminaldehyde, cyclamenaldehyde, rilal are preferred, and geraniol, nerol, citronellol, α-terpineol, tarpinene- 4-ol, floralol, forrussia, mayol, decenol, 2,6-nonadienol, benzyl alcohol, phenylethyl alcohol, carvacrol, eugenol, citral, phenylpropylaldehyde, cinnamic aldehyde, anisaldehyde, and cuminaldehyde are more preferred.

  (B) component of this invention can be used 1 type or in mixture of 2 or more types.

[Non-contact mold prevention composition and its package]
The non-contact type anti-fungal agent composition of the present invention contains the component (a) and the component (b) of the present invention, and the form thereof may be any form such as gel, powder, granular and liquid. .

  In the non-contact type antifungal agent composition of the present invention, the contents of the component (a) and the component (b) can be appropriately adjusted depending on the type and use form of each component. The content of the component (a) in the composition of the present invention is usually preferably 0.1% by mass or more, more preferably 0.1 to 70% by mass, still more preferably 0.1 to 60% by mass, 50% by mass is particularly preferred. As for content of (b) component, 0.1 mass% or more is preferable normally, 0.1-70 mass% is more preferable, 0.1-60 mass% is still more preferable, 1-50 mass% is especially preferable.

  The blending ratio of the component (a) and the component (b) in the composition of the present invention is such that (a) / (b) (mass ratio) is 100 / 1/100 is preferable, 50/1 to 1/50 is more preferable, and 50/1 to 1/10 is still more preferable.

  When the non-contact type fungicide composition of the present invention is gelled, it is common to use a gelling agent. The gelling agent is not particularly limited. For example, polyvinyl alcohol, polyethylene glycol, polyvinyl pyrrolidone, alginic acid, cellulose, starch, etc., or derivatives or salts thereof formed from water-soluble organic polymers such as vinyl acetate Resin emulsions, synthetic resin emulsions such as vinyl acetate and vinyl chloride copolymer resin emulsions, water soluble emulsions such as rubber latex, carrageenan, agar, gelatin, pectin and other animals, plants, algae, and microorganisms Examples thereof include gelling agents derived from natural products to be extracted.

  In order to disperse and emulsify the component (a) and the component (b) in the gel-like non-contact type fungicide composition, it is preferable to use a surfactant. There is no restriction | limiting in particular as surfactant, At least 1 sort (s) chosen from a nonionic surfactant, a cationic surfactant, an anionic surfactant, and an amphoteric surfactant can be used. .

  Nonionic surfactants include polyoxyalkylene alkyl or alkenyl ether, polyoxyalkylene alkyl phenyl ether, polyoxyalkylene fatty acid ester, polyoxyalkylene sorbitan fatty acid ester or polyoxyalkylene glycerin fatty acid ester, polyoxyalkylene sorbit fatty acid ester , Polyoxyalkylene castor oil or hydrogenated castor oil, alkyl or alkenyl diethanolamide, alkylamine or alkyldimethylamine, alkenylamine or alkenyldimethylamine, polyoxyalkylenealkyl or alkenylamine and the like.

  Examples of the cationic surfactant include primary amine salts, secondary amine salts, tertiary amine salts, and quaternary ammonium salts.

  Anionic surfactants include alkyl benzene sulfonates, alkyl sulfates or alkenyl sulfates, olefin sulfonates, alkane sulfonates, salts of alkyl polyhydric alcohol ether sulfonates such as alkyl glyceryl ether sulfonates, Examples include higher fatty acid salts, alkyl or alkenyl ether sulfates, alkyl or alkenyl ether carboxylates, and the like.

  Amphoteric surfactants include alkyl or alkenylamine oxide, amidopropylamine oxide (obtained by reacting amide compound of lauric acid and dimethylaminopropylamine with hydrogen peroxide, etc.), dimethyllaurylamine oxide, dimethylamino Examples include betaine acetate, imidazolinium betaine, fatty acid amidopropyldimethylaminoacetic acid betaine, N-acylamino acid or a salt thereof, and N-acylmethyltaurate.

  When the non-contact fungicide composition of the present invention is powdered or granular, as a powder or granular carrier, silica gel, zeolite, calcium silicate, diatomaceous earth, alumina, allophane, vermiculite, perlite, shirasu balloon, sepiolite, Inorganic porous carriers such as kaolin, hydrotalcite, talc, snow tech and bentonite, and organic porous carriers such as activated carbon, pulp, fiber material and synthetic resin can be used.

  When the non-contact type fungicide composition of the present invention is made liquid, the above-mentioned surfactant or a solvent such as alcohol can be used as a solubilizer. The liquid composition can be used by a conventionally known method such as a method of soaking in a core rod, filter paper, nonwoven fabric or the like and volatilizing using a permeable membrane.

  The non-contact type anti-fungal agent composition of the present invention can be added to various solvents, oils, sodium sulfate, sodium sulfate, N, N, It contains other components such as salts such as N-trimethylglycine, pH adjusters, antioxidants, preservatives, bactericides / antibacterial agents, deodorizers, fragrances other than component (b), dyes, and UV absorbers. Can do.

  The non-contact type fungicide composition of the present invention can be provided as a fungicide composition package in a container. The non-contact type fungicide composition of the present invention is air permeable as it is or dissolved in a volatile solvent such as alcohol and remains in a liquid state or in the form of gel, powder, granule or the like. Place in a container. Examples of the breathable container include a bag-like product made of a laminate composed of a breathable thermoplastic resin on the inner surface and a breathable support on the outer surface. For example, a nonwoven fabric is used as the breathable support. And a bag made of laminated paper made by laminating a breathable thermoplastic resin film such as a polyethylene film.

  The non-contact fungicide composition of the present invention and its package can be installed in, for example, a closet, a closet, a shoe box, etc. to prevent the occurrence of mold on clothes, shoes, wall surfaces, floor surfaces, etc. In particular, it is suitable for use in a space storing clothes such as a closet and a closet to prevent generation of mold on the clothes.

Examples 1-11 and Comparative Examples 1-5
Using the following component (a), component (b), and other components, a non-contact type fungicide composition having the formulation shown in Table 1 was prepared. About the obtained non-contact-type antifungal agent composition, antifungal performance and odor were evaluated by the following methods. The results are shown in Table 1.

<Blending ingredients>
(A) Component a-1: Propylene glycol monohexyl ether a-2: Propylene glycol monooctyl ether a-3: Tripropylene glycol monooctyl ether a-4: Dipropylene glycol mono-2-ethylhexyl ether a-5: Propylene Glycol monoisodecyl ether a-6: diethylene glycol monohexyl ether a-7: diethylene glycol monooctyl ether a-8: ethylene glycol mono 2-ethylhexyl ether a-9: ethylene glycol monodecyl ether a-10: diethylene glycol monodecyl ether ( a ′) component (comparative product of component (a))
a′-1: propylene glycol monomethyl ether a′-2: propylene glycol mono-n-propyl ether a′-3: ethylene glycol monohexyl ether (b) component b-1: linalool (boiling point 198 ° C., log P value 2. 55)
b-2: Geraniol (boiling point 230 ° C., log P value 2.77)
b-3: Citronellol (boiling point 225 ° C., log P value 3.26)
b-4: α-Terpineol (boiling point 218 ° C., log P value 2.63)
b-5: Carvacrol (boiling point 238 ° C., log P value 3.40)
b-6: Phenylethyl alcohol (boiling point 220 ° C., log P value 1.18)
b-7: Phenoxyethyl alcohol (boiling point 245 ° C., log P value 1.19)
b-8: Eugenol (boiling point 253 ° C., log P value 2.40)
b-9: Citral (boiling point 228 ° C., log P value 3.12)
b-10: Phenylpropylaldehyde (boiling point 238 ° C., log P value 1.72)
Component (b ′) (Comparative product of component (b))
b′-1: α-pinene (boiling point 156 ° C., log P value 4.18)
b′-2: Farnesol (boiling point 263 ° C., log P value 4.8)
b′-3: methyl isoeugenol (boiling point 270 ° C., log P value 2.96)
(1,2-dimethoxy-4-propenylbenzene, ether compound)
<Anti-mold performance evaluation method>
(1) Preparation of Test Bacteria Aspergillus.niger and Cladosporium spores and mycelia grown on potato dextrose agar (manufactured by Wako Pure Chemical Industries, Ltd.) were dispersed in a sterilized 0.05% Tween80 (Rheodor TW-0120) aqueous solution. A mold suspension of × 10 ⁶ to 1 × 10 ⁷ cells / mL was prepared.

(2) Preparation of mold test piece Cotton melias cloth cut to 3 cm x 3 cm and black dyed cotton broad cloth were sterilized (autoclave: 2 atm (202650 Pa), 125 ° C / 15 min), and 90 mm plastic as shown in Fig. 1 Two pieces each were allowed to stand on Petri dish 1 (Nissui Pharmaceutical, Nissui A Petri dish, sterilized shallow mold). 200 μL of a 2.4% potato dextrose broth aqueous solution (manufactured by Wako Pure Chemical Industries, Ltd.) sterilized on each test cloth was applied, and 100 μL of the above mold suspension was applied as a mold test piece 2, 2 ′.

(3) Mold prevention test A cloth 4 (cotton Melias cloth, 1.5 cm × 1.5 cm) impregnated with the non-contact type mold prevention agent composition described in Table 1 was applied to the center of the lid 3 of the petri dish at 25 ° C. After culturing at 100% RH for 7 days, the growth state of the mold was visually observed and evaluated based on the following five-stage criteria. Among them, those with a rating of-and + suppress the growth of mold, and the antifungal effect can be recognized remarkably. In addition, when the growth state of mold | fungi was observed similarly without sticking the cloth which impregnated the non-contact-type antifungal agent composition on the petri dish lid | cover, it confirmed that the antifungal effect was not recognized. The results are shown in Table 1.
-: No mold growth +: Only mold mycelium grows slightly ++: Mold mycelium only grows +++: Mold mycelium in addition to mold mycelium grows slightly +++++: Both mold spores and mycelia are sufficient <Odor evaluation method>
A total of 10 panelists, 5 males and 5 females in their 30s, and a non-contact type antifungal composition of the formulation shown in Table 1 and the scent of only the component (b) or (b ′) Was evaluated based on the following five-level evaluation criteria, and the average value was obtained. Among these, 1 or more and less than 3 are excellent in odor evaluation. The results are shown in Table 1.

1: Maintaining the scent of the component (b) or (b ′) 2: Maintaining the scent of the component (b) or (b ′) 3: Scent of the component (b) or (b ′) Slightly different from the tone 4: There is a difference from the scent of the component (b) or (b ′) 5: There is a significant difference from the scent of the component (b) or (b ′)

  From Table 1, the compositions of Comparative Examples 1 to 5 have insufficient antifungal performance against Aspergillus.niger and Cladosporium, or maintenance of fragrance tone, or both, whereas the compositions of Examples 1 to 11 It can be seen that the contact-type antifungal agent composition has high antifungal performance against both Aspergillus.niger and Cladosporium and maintains the fragrance.

Example 12
A non-contact type anti-fungal agent was impregnated in a non-woven fabric (Toyobo Co., Ltd., Toyobo Spunbond, Borans 4301N) with 150% by mass of the non-contact anti-fungal composition of the formulation shown in Example 9 of Table 1. A composition-impregnated nonwoven fabric was prepared. In the plastic storage box (64 cm × 40 cm × 23 cm, made by Yoshikawa, Neo Tenor Middle M23) having an internal volume of about 60 L, 1.7 g of the non-contact type fungicide composition-impregnated nonwoven fabric and the same mold test as in Example 1 The pieces 2 and 2 'were left standing with the petri dish 1 removed. The mold was cultured at 25 ° C. and 100% RH for 7 days, and the antifungal effect was determined in the same manner as in Example 1. As a result, the determination was “−” for both Aspergillus.niger and Cladosporium, and the mold prevention performance was high. Further, when the odor was evaluated in the same manner as in Example 1, the odor evaluation was “1.5”, and the scent was maintained.

In an Example, it is the schematic of the petri dish used for evaluation of mold prevention performance.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Petri dish 2,2 'Mold test piece 3 Petri dish cover 4 Cloth impregnated with non-contact type fungicide composition

Claims (6)

A non-contact type fungicide composition comprising the following component (a) and component (b):
(A): At least one selected from compounds represented by the general formula (1) R ¹ —O (AO) _n H (1)
[Wherein, R ¹ is an alkyl group having 6 to 11 carbon atoms, A is an alkylene group having 2 to 3 carbon atoms, n is a number of 1 to 3 indicating the average number of added moles, and n A's are the same. It may be different. However, ethylene glycol monohexyl ether is excluded. ]
(B): Geraniol, nerol, citronellol, α-terpineol, terpinen-4-ol, floralol, forrussia, mayol, decenol, 2,6-nonadienol, benzyl alcohol, phenylethyl alcohol, carvacrol, eugenol, citral, phenylpropiol At least one selected from lualdehyde, synamic aldehyde, anisaldehyde and cuminaldehyde The component (a) is a compound in which R ¹ is an alkyl group having 6 to 11 carbon atoms, A is a propylene group (propane-1,2-diyl group), and n is a number of 1 to 2 in the general formula (1) R ¹ is an alkyl group having 6 to 11 carbon atoms, A is an ethylene group, n is 2, and R ¹ is an alkyl group having 7 to 11 carbon atoms, A is an ethylene group, and n is 1. The non-contact type fungicide composition according to claim 1, which is at least one selected.   (A) The component is propylene glycol monohexyl ether, propylene glycol monooctyl ether, tripropylene glycol monooctyl ether, dipropylene glycol mono-2-ethylhexyl ether, propylene glycol monoisodecyl ether, diethylene glycol monohexyl ether, diethylene glycol monooctyl The non-contact type fungicide composition according to claim 1, which is at least one selected from ether, ethylene glycol mono-2-ethylhexyl ether, ethylene glycol monodecyl ether, and diethylene glycol monodecyl ether. Compounding ratio of component (a) and (b) component in the composition, (a) / (b) (mass ratio) = 100 / 1-1 / 100 claims 1-3 non according to any one Contact mold inhibitor composition. The non-contact type fungicide composition according to any one of claims 1 to 4 , which is liquid and is used after being volatilized in a space containing clothing. An antifungal agent composition package comprising the container and the non-contact antifungal agent composition according to any one of claims 1 to 5 .

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