JP4327030B2 - Low Ni austenitic stainless steel with excellent overhanging and rust resistance - Google Patents
Low Ni austenitic stainless steel with excellent overhanging and rust resistance Download PDFInfo
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- 229910000963 austenitic stainless steel Inorganic materials 0.000 title claims description 33
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims description 14
- 238000005482 strain hardening Methods 0.000 claims description 25
- 229910001566 austenite Inorganic materials 0.000 claims description 15
- 229910001220 stainless steel Inorganic materials 0.000 claims description 11
- 239000010935 stainless steel Substances 0.000 claims description 11
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910018553 Ni—O Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 description 18
- 239000010959 steel Substances 0.000 description 18
- 239000000463 material Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 9
- 229910000734 martensite Inorganic materials 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 238000005554 pickling Methods 0.000 description 6
- 230000009466 transformation Effects 0.000 description 6
- 238000000137 annealing Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000005728 strengthening Methods 0.000 description 5
- 238000009864 tensile test Methods 0.000 description 5
- 238000000465 moulding Methods 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000005347 demagnetization Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
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Description
本発明は、省Ｎｉ型のオ−ステナイト系ステンレス鋼であって、軟質で適度な加工硬化性を有し張出し性に優れるとともに，良好な耐発銹性を兼備した低Ｎｉオ−ステナイト系ステンレス鋼に関する。 The present invention is a Ni-saving austenitic stainless steel, which is soft, has an appropriate work-hardening property, has excellent overhanging properties, and has good galling resistance. Related to steel.
オ−ステナイト系ステンレス鋼は、ＪＩＳＧ４３０５に規定される３００系（ＳＵＳ３０４，ＳＵＳ３１６，ＳＵＳ３０１等）や２００系（ＳＵＳ２０１，ＳＵＳ２０２等）のものがある。 As the austenitic stainless steel, there are 300 series (SUS304, SUS316, SUS301, etc.) and 200 series (SUS201, SUS202, etc.) defined in JIS G4305.
３００系のオ−ステナイト系ステンレス鋼は、Ｍｎが２．０質量％以下，Ｎｉが６〜１５質量％程度含まれる。ＳＵＳ３０４に代表されるＮｉ系のオ−ステナイト系ステンレス鋼は、良好な加工性を有し耐食性にも優れる。特に、ＳＵＳ３０４は、オ−ステナイト相が準安定であり，成形加工中にマルテンサイト変態を生じて加工硬化が大きくなるために、張出し性が良好である。しかし、ＳＵＳ３０４は、高価なＮｉを多量に含むことから原料コストが高いという欠点がある。 300 series austenitic stainless steel contains 2.0 mass% or less of Mn and about 6 to 15 mass% of Ni. Ni-based austenitic stainless steel typified by SUS304 has good workability and excellent corrosion resistance. In particular, SUS304 has a good overhanging property because the austenite phase is metastable and a martensitic transformation occurs during the molding process to increase work hardening. However, SUS304 has a drawback that the raw material cost is high because it contains a large amount of expensive Ni.
他方、２００系のオ−ステナイト系ステンレス鋼は、ＮｉをＭｎで置換した高Ｍｎステンレス鋼であり、ＣやＮを多く含むために強度が高く非磁性である。また、Ｎｉ系のオ−ステナイト系ステンレス鋼と比較して原料コストが安価である。しかし、ＳＵＳ２０１やＳＵＳ２０２等に代表される高Ｍｎステンレス鋼は、焼鈍状態において３００系と比較して強度が高いために冷間加工性やプレス成形性に劣るという問題がある。 On the other hand, the 200-series austenitic stainless steel is a high Mn stainless steel in which Ni is replaced with Mn, and has a high strength and is nonmagnetic because it contains a large amount of C and N. Moreover, the raw material cost is low compared with Ni-type austenitic stainless steel. However, high Mn stainless steel represented by SUS201, SUS202, and the like has a problem that it is inferior in cold workability and press formability because it is higher in strength than 300 series in the annealed state.
オ−ステナイト系ステンレス鋼の加工性を改善する手段に関し、Ｍｎが３％未満，Ｎｉが６％以上を含む３００系については従来から多くの検討がなされている。例えば、特許文献１，特許文献２，特許文献３，特許文献４，特許文献５等に開示されているように、プレス成形性等の加工性改善には、Ｃｕの添加が有効に作用することが知られている。
With respect to means for improving the workability of austenitic stainless steel, many studies have been made on the 300 series containing Mn of less than 3% and Ni of 6% or more. For example, as disclosed in
他方、２００系のオ−ステナイト系ステンレス鋼は、電子機器用シャフト材，自転車スポ−クス用線，建築，建材用釘等の高強度非磁性が要求される部材への適用が主体である。そのため、高Ｍｎステンレス鋼は、高強度非磁性化の更なる向上に関し、多くの検討がなされている。例えば、特許文献６，特許文献７等には、高強度・非磁性化には、高Ｎ化とあわせてＭｎやＣｒの増加を抑制してＮｂ，Ｍｏ，Ｐの微量添加が有効に作用することが開示されている。 On the other hand, the 200 series austenitic stainless steel is mainly applied to members requiring high-strength non-magnetism such as shaft materials for electronic equipment, wires for bicycle spokes, nails for construction, and building materials. Therefore, many studies have been made on high Mn stainless steel for further improvement of high strength non-magnetization. For example, in Patent Document 6, Patent Document 7 and the like, to increase the strength and demagnetization, the addition of a small amount of Nb, Mo, and P effectively works by suppressing the increase in Mn and Cr in conjunction with increasing N. It is disclosed.
上述した通り、低Ｎｉオ−ステナイト系ステンレス鋼は、ＳＵＳ３０４に代表されるＮｉ系のステンレス鋼が使用されるプレス成形用途へ適応するための加工性の改善を意図したものでない。すなわち、ＳＵＳ３０４と同等以上の優れた張出し性を具備した低Ｎｉオ−ステナイト系ステンレス鋼は未だ出現していないのが現状である。 As described above, the low Ni austenitic stainless steel is not intended to improve the workability for adapting to the press forming application in which the Ni stainless steel represented by SUS304 is used. That is, the present situation is that a low Ni austenitic stainless steel having an overhanging property equivalent to or better than that of SUS304 has not yet appeared.
本発明は、上述した低Ｎｉオ−ステナイト系ステンレス鋼の加工性を改善すべく案出されたものであり、Ｃ＋ＮやＭｎ等の元素，オ−ステナイト安定度の指標Ｍｄ３０値（℃），積層欠陥エネルギ−の生成指標ＳＦＥ（ｍＪ／ｍ2）が特定条件を満足するよう成分設計を行うことにより、ＳＵＳ３０４と同等以上の張出し性を具備し，ＳＵＳ３０４と遜色ない耐発銹性を有する低Ｎｉオ−ステナイト系ステンレス鋼を提供することを目的とする。 The present invention has been devised to improve the workability of the above-described low Ni austenitic stainless steel, elements such as C + N and Mn, an austenite stability index Md30 value (° C.), lamination By designing the components so that the defect energy generation index SFE (mJ / m 2 ) satisfies a specific condition, the Ni is low Ni having an overhanging property equal to or higher than that of SUS304 and having an anti-fogging property comparable to that of SUS304. An object is to provide an austenitic stainless steel.
（１）本発明の低Ｎｉオ−ステナイト系ステンレス鋼は、その目的を達成するために、質量％で、Ｃ＋Ｎ：０．０３〜０．２０％，Ｓｉ：１％以下，Ｍｎ：２〜７％，Ｃｒ：１０〜１６％，Ｎｉ：１〜６％，Ｃｕ：１〜３％，残部Ｆｅおよび不可避的不純物からなり、オ−ステナイト安定度の指標Ｍｄ３０値と積層欠陥エネルギ−の生成指標ＳＦＥが下記を満足するように成分設計されていることを特徴とする。
３０＜Ｍｄ３０＜６５，４０＜ＳＦＥ＜７０
Ｍｄ３０（℃）：４９７−４６２（Ｃ＋Ｎ）−９．２Ｓｉ−８．１Ｍｎ−１３．７Ｃｒ−２０（Ｎｉ＋Ｃｕ）−１８．５Ｍｏ
ＳＦＥ（ｍＪ／ｍ2）：６．２Ｎｉ＋１８．６Ｃｕ＋０．７Ｃｒ＋３．２Ｍｎ＋９．３Ｍｏ−５３
（２）この低Ｎｉオ−ステナイト系ステンレス鋼は、良好な耐発銹性を得るために、Ｓ：０．００２５質量％以下、Ｐ：０．０４０質量％以下とすることができる。
（３）この低Ｎｉオ−ステナイト系ステンレス鋼は、良好な耐発銹性を得るために、Ｍｏを０．３〜３．０質量％含むことができる。
（４）高い加工率で張出し加工ができるプレス成形性を確保するには、Ｃ＋Ｎが０．２質量％以下，引張試験で求められる０．２％耐力が３００ＭＰａ未満，真応力−対数伸び歪曲線で公称歪１０％と３０％の勾配である加工硬化指数ｎが０．４０〜０．６０，伸びを４５％以上とする。
(1) The low Ni austenitic stainless steel of the present invention is, in mass%, C + N: 0.03 to 0.20%, Si: 1% or less, Mn: 2 to 7 in order to achieve the object. %, Cr: 10 to 16%, Ni: 1 to 6%, Cu: 1 to 3%, balance Fe and inevitable impurities, and austenite stability index Md30 value and stacking fault energy generation index SFE Is designed to satisfy the following conditions.
30 <Md30 <65, 40 <SFE <70
Md30 (° C): 497-462 (C + N) -9.2Si-8.1Mn-13.7Cr-20 (Ni + Cu) -18.5Mo
SFE (mJ / m 2 ): 6.2Ni + 18.6Cu + 0.7Cr + 3.2Mn + 9.3Mo-53
(2) This low Ni austenitic stainless steel can be made to have S: 0.0025 mass% or less and P: 0.040 mass% or less in order to obtain good galling resistance.
(3) This low Ni austenitic stainless steel can contain 0.3 to 3.0% by mass of Mo in order to obtain good cracking resistance.
(4) In order to ensure press formability that can be stretched at a high processing rate, C + N is 0.2% by mass or less, 0.2% proof stress obtained by a tensile test is less than 300 MPa, and true stress-logarithmic elongation strain curve The work hardening index n, which is a gradient of 10% nominal strain and 30%, is 0.40 to 0.60, and the elongation is 45% or more.
本発明の低Ｎｉオ−ステナイト系ステンレス鋼は、Ｃ＋Ｎ：０．０３〜０．２０％，Ｍｎ：２〜７％，３０＜Ｍｄ３０＜６５，４０＜ＳＦＥ＜７０とする成分設計を採用しているため、０．２％耐力が３００ＭＰａ未満の軟質で適度な加工硬化性を有し，高い加工率で張出し加工ができる優れたプレス成形性を有する。必要に応じて、ＳやＰの不純物元素を低減し，Ｍｏを添加することにより、更に良好な耐発銹性を兼備することができる。従って、従来の低Ｎｉオ−ステナイト系ステンレス鋼ではなし得なかった成形加工が可能であり、良好な耐発銹性を兼備することから、ＳＵＳ３０４に代表されるＮｉ系ステンレス鋼が使用されている成形加工用の材料として広範囲な分野で適用可能である。 The low Ni austenitic stainless steel of the present invention adopts a component design such that C + N: 0.03 to 0.20%, Mn: 2 to 7%, 30 <Md30 <65, 40 <SFE <70. Therefore, it has a soft and moderate work curability with a 0.2% proof stress of less than 300 MPa, and an excellent press formability capable of being stretched at a high processing rate. If necessary, the impurity elements of S and P can be reduced and Mo can be added to further improve the rust resistance. Therefore, it is possible to perform the forming process that could not be achieved with the conventional low Ni austenitic stainless steel, and since it has good galling resistance, Ni stainless steel represented by SUS304 is used. It can be applied in a wide range of fields as a material for molding.
本発明の低Ｎｉオ−ステナイト系ステンレス鋼は、Ｃ＋Ｎ，Ｍｎ，オ−ステナイト安定度の指標Ｍｄ３０値（℃），積層欠陥エネルギ−の生成指標ＳＦＥ（ｍＪ／ｍ2）が適正範囲を満足する成分設計を採用することにより、ＳＵＳ３０４と同等以上の張出し性を具備している。必要に応じて、ＳやＰの不純物元素を低減し，Ｍｏを添加することにより、更に良好な耐発銹性を得ることができる。 In the low Ni austenitic stainless steel of the present invention, C + N, Mn, austenite stability index Md30 value (° C.), stacking fault energy generation index SFE (mJ / m 2 ) satisfy an appropriate range. By adopting the component design, it has an overhang property equal to or higher than that of SUS304. If necessary, the impurity element of S or P can be reduced and Mo can be added to obtain even better weathering resistance.
以下、本発明の低Ｎｉオ−ステナイト系ステンレス鋼の成分設計に関する作用効果とその限定理由を説明する。 Hereafter, the effect regarding the component design of the low Ni austenitic stainless steel of this invention and the reason for the limitation are demonstrated.
Ｃ＋Ｎ：０．０３〜０．２０％
ＣやＮは、オ−ステナイト相の安定化やδフェライト相の生成抑制に有効な元素である。他方、これら元素は、固溶強化により鋼材の０．２％耐力を上昇させて加工性を低下させる。そこで、Ｃ＋Ｎの上限は０．２０％とした。ＮはＣと比較して０．２％耐力を上昇させる作用が大きいために、ＮはＣより低く設計することが好ましい。本発明が目的とする高い加工率で張出し加工などのプレス成形が要求される用途には、Ｃ＋Ｎを０．２０％以下（Ｎ＜Ｃ）に設計することにより、鋼材の０．２％耐力を３００ＭＰａ未満に軟質化することが有効である。好ましくは、Ｃ＋Ｎを０．１５％以下とする。
C + N: 0.03 to 0.20%
C and N are effective elements for stabilizing the austenite phase and suppressing the formation of the δ ferrite phase. On the other hand, these elements increase the 0.2% proof stress of the steel material by solid solution strengthening and reduce workability. Therefore, the upper limit of C + N is set to 0.20%. Since N has a large effect of increasing the proof stress by 0.2% compared to C, it is preferable to design N to be lower than C. For applications that require press forming such as overhanging at a high processing rate that is the object of the present invention, the C + N is designed to be 0.20% or less (N <C), so that the 0.2% proof stress of the steel material can be achieved. It is effective to soften to less than 300 MPa. Preferably, C + N is 0.15% or less.
しかし、Ｃ＋Ｎが０．０３％未満の場合、オ−ステナイト相を確保することが困難になるばかりでなく，ＣやＮを低減するための製鋼コストの負担を招く。従って、Ｃ＋Ｎの下限は０．０３％とする。好ましくは０．０８％以上とする。 However, when C + N is less than 0.03%, not only is it difficult to secure the austenite phase, but also the burden of steelmaking costs for reducing C and N is caused. Therefore, the lower limit of C + N is 0.03%. Preferably it is 0.08% or more.
Ｍｎ：２〜７％
Ｍｎは溶製時の脱酸剤として使用されることに加え，Ｎｉの代替としてのオ−ステナイト形成元素として有効に作用する。本発明では、これらの作用を得るためにＭｎは２％以上添加する。好ましくは３％以上である。他方、Ｍｎの添加はＳ系介在物の増加をもたらし，耐発銹性を阻害するという問題がある。さらに、Ｍｎの添加量が多いと、オ−ステナイト相が安定となり、成形加工中のマルテンサイト変態（α‘相の生成）が抑制されて張出し性が低下することが分かった。従って、本発明では、耐発銹性の確保と良好な張出し性を得るために、Ｍｎの上限は７％とする。好ましくは６．５％以下である。
Mn: 2-7%
In addition to being used as a deoxidizer during melting, Mn effectively acts as an austenite forming element as a substitute for Ni. In the present invention, 2% or more of Mn is added to obtain these effects. Preferably it is 3% or more. On the other hand, the addition of Mn causes an increase in S-based inclusions, and there is a problem that the rust resistance is inhibited. Furthermore, it was found that when the amount of Mn added is large, the austenite phase becomes stable, the martensite transformation (formation of α ′ phase) during the molding process is suppressed, and the stretchability is lowered. Therefore, in the present invention, the upper limit of Mn is set to 7% in order to secure the rust resistance and obtain the good overhanging property. Preferably it is 6.5% or less.
オ−ステナイト安定度の指標：Ｍｄ３０値（℃）
準安定オ−ステナイト系ステンレス鋼はＭｓ点以上の温度でも塑性加工によってマルテンサイト変態を起こす。加工によって変態点を生じる上限温度はＭｄ値と呼ばれる。すなわち、Ｍｄ値はオ−ステナイトの安定度を示す指標である。そして、引張変形によって３０％の歪を与えたとき、５０％のマルテンサイトが生じる温度をＭｄ３０値という。Ｍｄ３０＝４９７−４６２（Ｃ＋Ｎ）−９．２Ｓｉ−８．１Ｍｎ−１３．７Ｃｒ−２０（Ｎｉ＋Ｃｕ）−１８．５Ｍｏ と定義するＭｄ３０値（℃）を本発明の低Ｎｉオ−ステナイト系ステンレス鋼において３０℃〜６５℃の範囲に設計することにより、本発明が目的とする張出し性が確保されることを見出した。
Austenite stability index: Md30 value (° C)
Metastable austenitic stainless steel undergoes martensitic transformation by plastic working even at temperatures above the Ms point. The upper limit temperature at which the transformation point is generated by processing is called the Md value. That is, the Md value is an index indicating the stability of austenite. The temperature at which 50% martensite is generated when 30% strain is applied by tensile deformation is referred to as the Md30 value. In the low Ni austenitic stainless steel of the present invention, the Md30 value (° C.) defined as Md30 = 497-462 (C + N) -9.2Si-8.1Mn-13.7Cr-20 (Ni + Cu) -18.5Mo It has been found that by designing in the range of 30 ° C. to 65 ° C., the desired overhanging property of the present invention is secured.
Ｍｄ３０値が３０℃より小さい場合、オ−ステナイト安定度が高いために鋼材の加工誘起マルテンサイト変態が抑制されて加工硬化が小さくなり張出し性が低下する。他方、Ｍｄ３０値が６５℃を越える場合、加工誘起マルテンサイトの生成量（α‘相）が多くなり過度な強度上昇により鋼材の伸びが低下する。そのため、良好な張出し性は得られない。Ｍｄ３０値が３０〜６５℃の場合，本発明の低Ｎｉオ−ステナイト系ステンレス鋼は、加工誘起マルテンサイト変態により適度な加工硬化能を有し、良好な張出し性を得ることができる。 When the Md30 value is smaller than 30 ° C., since the austenite stability is high, the work-induced martensitic transformation of the steel material is suppressed, the work hardening is reduced, and the stretchability is lowered. On the other hand, when the Md30 value exceeds 65 ° C., the production amount (α ′ phase) of work-induced martensite increases and the elongation of the steel material decreases due to an excessive increase in strength. Therefore, good overhanging property cannot be obtained. When the Md30 value is 30 to 65 ° C., the low Ni austenitic stainless steel of the present invention has an appropriate work hardening ability due to work-induced martensitic transformation and can obtain good stretchability.
積層欠陥エネルギ−の生成指標：ＳＦＥ（ｍＪ／ｍ2）
ｂｃｃ構造の普通鋼に比較して、ｆｃｃ構造をもつオ−ステナイト系ステンレス鋼は、積層欠陥が生成しやすいために加工硬化が大きい。本発明では、高い加工率で張出し加工などのプレス成形を可能にするために、積層欠陥が生成し難い転位の交差すべりが容易な成分設計を採用している。
Generation index of stacking fault energy: SFE (mJ / m 2 )
Compared to ordinary steel having a bcc structure, an austenitic stainless steel having an fcc structure has a greater work hardening because stacking faults are easily generated. In the present invention, in order to enable press forming such as overhanging at a high processing rate, a component design is adopted in which dislocation crossing that is difficult to generate stacking faults is easy.
近年、ステンレス鋼板は複雑な形状の製品を冷間加工で製造することが多くなっている。このような場合、加工硬化が大きい鋼材は加工の途中に中間焼鈍の工程を挟んで軟化させながら繰り返して大きな加工度を得ることが必要になる。加工硬化が小さい鋼材であれば中間焼鈍の工程を省略して製品加工が可能になり、製品コストの低減に大きく寄与する。本発明者らは、このような観点から、良好な張出し性を得るに必要な加工硬化を担保しつつ，過度な加工硬化を抑制するために、積層欠陥エネルギ−（ＳＦＥ）に及ぼす成分の影響を検討した。その結果、ＳＦＥ（ｍＪ／ｍ2）：６．２Ｎｉ＋１８．６Ｃｕ＋０．７Ｃｒ＋３．２Ｍｎ＋９．３Ｍｏ−５３ と定義されるＳＦＥを４０〜７０の範囲に調整するとき、本発明が目的とする優れた張出し性が発現することを見出した。 In recent years, stainless steel sheets are often produced by cold working of products having complicated shapes. In such a case, it is necessary to repeatedly obtain a high degree of workability for a steel material having a high work hardening while being softened with an intermediate annealing step in the middle of the work. If the steel is low in work hardening, the intermediate annealing process can be omitted, and the product can be processed. This greatly contributes to the reduction in product cost. From these viewpoints, the present inventors have the influence of the component on the stacking fault energy (SFE) in order to suppress excessive work hardening while ensuring work hardening necessary for obtaining good stretchability. It was investigated. As a result, when the SFE defined as SFE (mJ / m 2 ): 6.2Ni + 18.6Cu + 0.7Cr + 3.2Mn + 9.3Mo-53 is adjusted to a range of 40 to 70, the excellent extensibility desired by the present invention is achieved. Was found to be expressed.
ＳＦＥが４０未満の場合、低Ｎｉオ−ステナイト系ステンレス鋼は積層欠陥が生成しやすく加工硬化が大きくなり、本発明が目的とする張出し性が得られなくなる。このとき、引張試験で求められる加工硬化指数ｎ値（真応力−対数伸び歪曲線で公称歪１０％と３０％の勾配）は０．６０を超える。他方、ＳＦＥが７０を超える場合、加工硬化が小さくｎ値は０．４０未満となる。このとき、実用のプレス成形では張出し性が低下するという問題がある。従って、本発明では、引張試験で求められるｎ値は０．４０〜０．６０の範囲であることが好ましい。 When the SFE is less than 40, the low Ni austenitic stainless steel is liable to generate stacking faults, and the work hardening becomes large, and the overhanging property intended by the present invention cannot be obtained. At this time, the work hardening index n value (true stress-logarithmic elongation strain curve, nominal strain of 10% and 30% slope) obtained by a tensile test exceeds 0.60. On the other hand, when SFE exceeds 70, work hardening is small and n value will be less than 0.40. At this time, there is a problem that the stretchability is lowered in practical press molding. Therefore, in this invention, it is preferable that n value calculated | required by a tensile test is the range of 0.40-0.60.
本発明のＣ＋Ｎ：０．０３〜０．２０％，Ｍｎ：２〜７％，Ｍｄ３０値：３０〜６５℃，ＳＦＥ：４０〜７０（ｍＪ／ｍ2）に調整された低Ｎｉオ−ステナイト系ステンレス鋼材は、０．２％耐力が３００ＭＰａ未満の軟質で適度な加工硬化性を有し，高い加工率で張出し加工ができる優れたプレス成形性を有する。また、良好な耐発銹性を兼備している。以下、本発明のＣとＮ，Ｍｎを除く他の合金元素は次の範囲で選定される。 Low Ni austenite system adjusted to C + N: 0.03 to 0.20%, Mn: 2 to 7%, Md30 value: 30 to 65 ° C., SFE: 40 to 70 (mJ / m 2 ) The stainless steel material is soft with a 0.2% proof stress of less than 300 MPa, has an appropriate work hardening property, and has an excellent press formability capable of being stretched at a high processing rate. It also has good rust resistance. Hereinafter, other alloy elements except C, N, and Mn of the present invention are selected in the following range.
Ｓｉ：１％以下
Ｓｉは溶製時の脱酸剤として有効であり、その効果を得るために０．１％以上添加することが好ましい。より好ましくは０．３％以上である。また、Ｓｉは固溶強化およびＳＦＥを低下させて加工硬化を助長する元素である。そのため、本発明の３００ＭＰａ未満の０．２％耐力を得るために上限は１％以下である。好ましくは０．７％以下である。
Si: 1% or less Si is effective as a deoxidizing agent at the time of melting, and in order to obtain the effect, it is preferable to add 0.1% or more. More preferably, it is 0.3% or more. Si is an element that promotes work hardening by reducing solid solution strengthening and SFE. Therefore, the upper limit is 1% or less in order to obtain 0.2% proof stress of less than 300 MPa of the present invention. Preferably it is 0.7% or less.
Ｃｒ：１０〜１６％
Ｃｒはステンレス鋼に要求される耐食性を得るために必要な合金元素であり、１０％以上必要である。好ましくは１２％以上である。他方、Ｃｒは固溶強化およびＳＦＥを低下させて加工硬化を助長する元素である。そのため、本発明の３００ＭＰａ未満の０．２％耐力，加工硬化指数ｎ値が０．６０未満を得るために上限は１６％以下である。好ましくは１５％以下である。
Cr: 10 to 16%
Cr is an alloying element necessary for obtaining the corrosion resistance required for stainless steel, and 10% or more is necessary. Preferably it is 12% or more. On the other hand, Cr is an element that promotes work hardening by reducing solid solution strengthening and SFE. Therefore, the upper limit is 16% or less in order to obtain a 0.2% yield strength and work hardening index n value of less than 0.60 of the present invention less than 300 MPa. Preferably it is 15% or less.
Ｎｉ：１〜６％
Ｎｉは高価な元素であり，６％を超える３００系のオ−ステナイト系ステンレス鋼は原料コストの上昇を招く。従って、Ｎｉは６％以下である。好ましくは５．５％以下である。Ｎｉはオ−ステナイト系ステンレス鋼に必要な元素であり、更に，延性を確保するのに有効な元素である。そのため、下限は１％とする。好ましくは２％以上である。
Ni: 1-6%
Ni is an expensive element, and 300-series austenitic stainless steel exceeding 6% causes an increase in raw material costs. Therefore, Ni is 6% or less. Preferably it is 5.5% or less. Ni is an element necessary for austenitic stainless steel, and is also an element effective for ensuring ductility. Therefore, the lower limit is 1%. Preferably it is 2% or more.
Ｃｕ：１〜３％
Ｃｕは、ＮｉやＭｎの代替としてのオ−ステナイト形成元素として有効に作用する。本発明ではこれらの作用を得るためにＣｕは１％以上添加する。さらに、Ｃｕは軟質化に有効な元素であり，本発明で定義するＭｄ３０値やＳＦＥの調整に有効な合金元素である。本発明ではこれら作用を得るために、好ましくは１．５％以上とする。しかし、過剰量のＣｕ添加は製鋼時のＣｕ汚染や熱間脆性を誘発する問題がある。また、ＳＦＥが過度に上昇して張出し性の低下を招く。そのため、Ｃｕの上限は３％以下とする。
Cu: 1-3%
Cu acts effectively as an austenite forming element as a substitute for Ni and Mn. In the present invention, in order to obtain these effects, Cu is added in an amount of 1% or more. Furthermore, Cu is an element effective for softening, and is an alloy element effective for adjusting the Md30 value and SFE defined in the present invention. In the present invention, in order to obtain these effects, the content is preferably 1.5% or more. However, excessive addition of Cu has a problem of inducing Cu contamination and hot brittleness during steelmaking. Moreover, SFE rises excessively and causes a reduction in overhanging property. Therefore, the upper limit of Cu is 3% or less.
Ｍｏ：０．３〜３％
必要に応じて添加される元素であり、耐発銹性の向上に有効な元素である。また、本発明で定義するＭｄ３０値やＳＦＥの調整にも有効な元素である。これら作用を得るためには、Ｍｏは０．３％以上添加することが好ましい。しかし、Ｍｏは高価な元素であり、過剰な添加はコスト上昇を招く。また、δフェライトの生成や固溶強化により強度上昇する。そのため、Ｍｏの上限は３％以下とすることが好ましい。
Mo: 0.3-3%
It is an element that is added as necessary, and is an element that is effective in improving the rust resistance. It is also an element effective for adjusting the Md30 value and SFE defined in the present invention. In order to obtain these effects, it is preferable to add Mo by 0.3% or more. However, Mo is an expensive element, and excessive addition causes an increase in cost. In addition, the strength increases due to the formation of δ ferrite and solid solution strengthening. Therefore, the upper limit of Mo is preferably 3% or less.
Ｓ：０．００２５％以下
ＭｎＳ等の介在物を形成する不純物元素であり、耐発銹性を阻害する場合がある。そのため、耐発銹性の要求が高い場合は、Ｓを０．００２５％以下とすることが好ましい。より好ましくは、０．００２０％以下である。
S: 0.0025% or less An impurity element that forms inclusions such as MnS, and may impair the rust resistance. Therefore, when the requirement for rust resistance is high, it is preferable to set S to 0.0025% or less. More preferably, it is 0.0020% or less.
Ｐ：０．０４０％以下
Ｐは不純物元素であり，耐発銹性を低下させる場合がある。そのため、耐発銹性の要求が高い場合は、Ｐを０．０４０％以下とすることが好ましい。より好ましくは０．００３５％以下である。
P: 0.040% or less P is an impurity element and may reduce the rust resistance. Therefore, when the requirement for rust resistance is high, it is preferable to set P to 0.040% or less. More preferably, it is 0.0035% or less.
表１の化学組成を有するステンレス鋼を溶製し、加熱温度１２００℃の熱間圧延により板厚４．０ｍｍの熱延鋼板を製造した。熱延鋼板を１１２０℃，均熱時間２分で焼鈍し、酸洗後に板厚１．５ｍｍまで冷間圧延し、更に１０８０℃，均熱時間２分の中間焼鈍を施し、酸洗後，板厚０．７ｍｍの冷延鋼板とし、最終焼鈍を１０８０℃，均熱時間１分で実施した（焼鈍酸洗材）。 Stainless steel having the chemical composition shown in Table 1 was melted, and a hot-rolled steel sheet having a thickness of 4.0 mm was manufactured by hot rolling at a heating temperature of 1200 ° C. Hot-rolled steel sheet was annealed at 1120 ° C for 2 minutes, soaking, cold-rolled to 1.5 mm after pickling, further subjected to intermediate annealing at 1080 ° C for 2 minutes, soaking, and pickled, A cold-rolled steel sheet having a thickness of 0.7 mm was used, and final annealing was performed at 1080 ° C. and a soaking time of 1 minute (annealing pickling material).
焼鈍酸洗材からＪＩＳ１３Ｂ引張試験片を切り出し，引張試験により０．２％耐力，引張強度，伸び，加工硬化指数ｎを測定した。加工硬化指数ｎは、公称歪１０％と３０％に相当する真歪ε10，ε30における真応力δ10，δ30を求め、次式に従って加工硬化指数ｎ値を算出した。
ｎ値＝ｌｎ（ε30／ε10）／ｌｎ（δ30／δ10）
A JIS13B tensile test piece was cut out from the annealed pickling material, and 0.2% proof stress, tensile strength, elongation, and work hardening index n were measured by a tensile test. For the work hardening index n, true stresses δ 10 and δ 30 at true strains ε 10 and ε 30 corresponding to nominal strains of 10% and 30% were obtained, and the work hardening index n value was calculated according to the following equation.
n value = ln (ε 30 / ε 10 ) / ln (δ 30 / δ 10 )
張出し性は、焼鈍酸洗材から９０ｍｍ角の試験片を切り出し，ＪＩＳＺ２２４７に規定するエリクセン試験（Ｂ法：しわ押さえ圧１ｔｏｎ負荷）により評価した。また、絞り張出し複合成形性は、ＪＩＳＺ２２４９に準拠したコニカルカップ試験（１３型）により評価した。
The overhanging property was evaluated by an Erichsen test (Method B:
耐発銹性は、焼鈍酸洗材から１００ｍｍ角の試験片を切り出し，ＪＩＳＺ２３７１に準拠するキャス試験（５０℃，５％ＮａＣｌ＋０．２６ｇ／Ｌ ＣｕＣｌ2＋ＣＨ3ＣＯＯＨ，ｐＨ３．０，１００ｈｒ噴霧）により評価した。 The rust resistance was obtained by cutting a 100 mm square test piece from the annealed pickling material and performing a cast test (50 ° C., 5% NaCl + 0.26 g / L CuCl 2 + CH 3 COOH, pH 3.0, 100 hr spraying) in accordance with JISZ2371. evaluated.
焼鈍酸洗材の０．２％耐力，引張強度，伸び，ｎ値，エリクセン値，ＣＣＶ値，キャス試験の発銹状況を表１に併記して示す。鋼Ｎｏ．１〜６は、本発明で規定した低Ｎｉオ−ステナイト系ステンレス鋼の成分設計条件を満足しており、０．２％耐力が３００ＭＰａ未満，伸びが４５％以上，加工硬化指数ｎが０．４〜０．６の機械的性質を有し，本発明が目標とするＳＵＳ３０４と同等以上のエリクセン値，ＣＣＶ値が得られた。さらに、Ｓ，Ｐを低減してＭｏを添加した鋼Ｎｏ．１，３〜６はＳＵＳ３０４と同等の耐発銹性が得られた。鋼Ｎｏ．７〜１４は、Ｍｄ３０値とＳＦＥの片方あるいは両者が本発明の規定する条件から外れるために、本発明が目標とする加工性（ＳＵＳ３０４と同等以上のエリクセン値とＣＣＶ値）が得られなかったものである。鋼Ｎｏ．１５は加工性の比較となるＳＵＳ３０４である。鋼Ｎｏ．１６〜２６は、本発明が規定する成分範囲を満足しないものであり、目標とする加工性や耐発銹性が得られなかったものである。
鋼材のエリクセン値とＣＣＶ値に及ぼすオ−ステナイト安定度の指標Ｍｄ３０値の影響について検討した結果を図１および図２に示す。図１および図２に示すように、３０＜Ｍｄ３０＜６５に制御することによって、本発明が目標とするＳＵＳ３０４と同等以上の張出し性が得られることが確認できた。 The results of examining the influence of the austenite stability index Md30 value on the Erichsen value and CCV value of steel are shown in FIGS. As shown in FIG. 1 and FIG. 2, it was confirmed that by controlling to 30 <Md30 <65, an overhang property equal to or higher than SUS304 targeted by the present invention can be obtained.
また、積層欠陥エネルギ−の生成指標ＳＦＥと加工硬化指数ｎとの関係を検討した結果、図３に見られるように、４０＜ＳＦＥ＜７０にすることによって、本発明が目標とするｎ値が得られることが確認できた。 Further, as a result of examining the relationship between the stacking fault energy generation index SFE and the work hardening index n, as shown in FIG. 3, by setting 40 <SFE <70, the target n value of the present invention is It was confirmed that it was obtained.
本発明の低Ｎｉオ−ステナイト系ステンレス鋼は、従来の低Ｎｉオ−ステナイト系ステンレス鋼ではなし得なかった成形加工が可能であり、良好な耐発銹性も兼備することから、ＳＵＳ３０４に代表されるＮｉ系ステンレス鋼が使用されている成形加工用の材料として広範囲な分野で適用可能である。 The low Ni austenitic stainless steel of the present invention is representative of SUS304 because it can be formed and cannot be formed by conventional low Ni austenitic stainless steel, and also has good galling resistance. It can be applied in a wide range of fields as a forming material using Ni-based stainless steel.
Claims (4)
３０＜Ｍｄ３０＜６５，４０＜ＳＦＥ＜７０
Ｍｄ３０（℃）：４９７−４６２（Ｃ＋Ｎ）−９．２Ｓｉ−８．１Ｍｎ−１３．７Ｃｒ−２０（Ｎｉ＋Ｃｕ）−１８．５Ｍｏ
ＳＦＥ（ｍＪ／ｍ2）：６．２Ｎｉ＋１８．６Ｃｕ＋０．７Ｃｒ＋３．２Ｍｎ＋９．３Ｍｏ−５３ In mass%, C + N: 0.03 to 0.20%, Si: 1% or less, Mn: 2 to 7%, Cr: 10 to 16%, Ni: 1 to 6%, Cu: 1 to 3%, balance Low Ni-O which is excellent in overhanging property and galling resistance, and is characterized by comprising an austenite stability index Md30 value and a stacking fault energy generation index SFE consisting of Fe and inevitable impurities. Stenitic stainless steel.
30 <Md30 <65, 40 <SFE <70
Md30 (° C): 497-462 (C + N) -9.2Si-8.1Mn-13.7Cr-20 (Ni + Cu) -18.5Mo
SFE (mJ / m 2 ): 6.2Ni + 18.6Cu + 0.7Cr + 3.2Mn + 9.3Mo-53
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| JP5014915B2 (en) * | 2007-08-09 | 2012-08-29 | 日新製鋼株式会社 | Ni-saving austenitic stainless steel |
| JP5421611B2 (en) * | 2009-02-18 | 2014-02-19 | 日新製鋼株式会社 | Stainless steel plate for age-hardening springs |
| JP5421615B2 (en) * | 2009-02-24 | 2014-02-19 | 日新製鋼株式会社 | Ni-saving stainless steel automotive parts |
| CN102471855B (en) * | 2009-09-02 | 2015-10-14 | 新日铁住金不锈钢株式会社 | The Ni-saving type stainless steel of excellent corrosion resistance |
| FR3027080B1 (en) * | 2014-10-10 | 2018-03-09 | Chassis Brakes International B.V. | "ELASTIC RECALL SPRING FOR A BRAKE SKATE HAVING MEANS FOR REAGGING THE WEAR GAME, DISC BRAKE, AND REPLACEMENT KIT" |
| CN112226686A (en) * | 2020-09-29 | 2021-01-15 | 鞍钢联众(广州)不锈钢有限公司 | A kind of stainless steel plate for mine sieve and its manufacturing method |
| CN113981308B (en) * | 2021-09-11 | 2022-08-23 | 广东省高端不锈钢研究院有限公司 | Preparation method of 8K mirror plate manganese-nitrogen series nickel-saving austenitic stainless steel |
| CN117660849B (en) * | 2024-01-31 | 2024-06-04 | 成都先进金属材料产业技术研究院股份有限公司 | Phosphorus-controlled 00Cr21Ni13Mn5N high-nitrogen austenitic stainless steel and production method thereof |
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