JP4077805B2 - 共振器の製造方法 - Google Patents
共振器の製造方法 Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims description 62
- 239000010408 film Substances 0.000 claims description 244
- 239000000758 substrate Substances 0.000 claims description 146
- 239000010409 thin film Substances 0.000 claims description 102
- 238000000034 method Methods 0.000 claims description 69
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 238000001039 wet etching Methods 0.000 claims description 7
- 238000001312 dry etching Methods 0.000 claims description 5
- 229910052594 sapphire Inorganic materials 0.000 claims description 3
- 239000010980 sapphire Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 59
- 238000012986 modification Methods 0.000 description 30
- 230000004048 modification Effects 0.000 description 30
- 229910004298 SiO 2 Inorganic materials 0.000 description 17
- 238000005530 etching Methods 0.000 description 16
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 15
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 13
- 229910010271 silicon carbide Inorganic materials 0.000 description 12
- 239000010931 gold Substances 0.000 description 11
- JNDMLEXHDPKVFC-UHFFFAOYSA-N aluminum;oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Al+3].[Y+3] JNDMLEXHDPKVFC-UHFFFAOYSA-N 0.000 description 10
- 229910019901 yttrium aluminum garnet Inorganic materials 0.000 description 10
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 9
- 229910002601 GaN Inorganic materials 0.000 description 8
- 239000010936 titanium Substances 0.000 description 7
- 238000001771 vacuum deposition Methods 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000005566 electron beam evaporation Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910002704 AlGaN Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- VZPPHXVFMVZRTE-UHFFFAOYSA-N [Kr]F Chemical compound [Kr]F VZPPHXVFMVZRTE-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- VTHAZHHBZCRMKA-UHFFFAOYSA-N boranylidynelanthanum Chemical compound [La]#B VTHAZHHBZCRMKA-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
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- 230000005496 eutectics Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- JVPLOXQKFGYFMN-UHFFFAOYSA-N gold tin Chemical compound [Sn].[Au] JVPLOXQKFGYFMN-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 1
- QNZFKUWECYSYPS-UHFFFAOYSA-N lead zirconium Chemical compound [Zr].[Pb] QNZFKUWECYSYPS-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H3/00—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
- H03H3/007—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
- H03H3/02—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
- H03H9/02—Details
- H03H9/02007—Details of bulk acoustic wave devices
- H03H9/02086—Means for compensation or elimination of undesirable effects
- H03H9/02102—Means for compensation or elimination of undesirable effects of temperature influence
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
- H03H9/15—Constructional features of resonators consisting of piezoelectric or electrostrictive material
- H03H9/17—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
- H03H9/171—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator implemented with thin-film techniques, i.e. of the film bulk acoustic resonator [FBAR] type
- H03H9/172—Means for mounting on a substrate, i.e. means constituting the material interface confining the waves to a volume
- H03H9/173—Air-gaps
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
- H03H9/15—Constructional features of resonators consisting of piezoelectric or electrostrictive material
- H03H9/17—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
- H03H9/171—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator implemented with thin-film techniques, i.e. of the film bulk acoustic resonator [FBAR] type
- H03H9/172—Means for mounting on a substrate, i.e. means constituting the material interface confining the waves to a volume
- H03H9/174—Membranes
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H9/00—Networks comprising electromechanical or electro-acoustic elements; Electromechanical resonators
- H03H9/15—Constructional features of resonators consisting of piezoelectric or electrostrictive material
- H03H9/17—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator
- H03H9/171—Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator implemented with thin-film techniques, i.e. of the film bulk acoustic resonator [FBAR] type
- H03H9/172—Means for mounting on a substrate, i.e. means constituting the material interface confining the waves to a volume
- H03H9/175—Acoustic mirrors
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H3/00—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
- H03H3/007—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
- H03H3/02—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
- H03H2003/021—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks the resonators or networks being of the air-gap type
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H3/00—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
- H03H3/007—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
- H03H3/02—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
- H03H2003/023—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks the resonators or networks being of the membrane type
-
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03H—IMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
- H03H3/00—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
- H03H3/007—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
- H03H3/02—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
- H03H2003/025—Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks the resonators or networks comprising an acoustic mirror
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/42—Piezoelectric device making
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- Acoustics & Sound (AREA)
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- Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)
Description
図8(a)から図8(e)は第1の従来例に係る共振器の製造方法を示している(特許文献1を参照。)。
図9(a)から図9(f)は第2の従来例に係る共振器の製造方法を示している(特許文献2を参照。)。
本発明に係る第1の実施形態について図1を参照しながら説明する。図1(a)から図1(e)は本実施形態の薄膜バルク音響共振器(FBAR)の製造工程を模式的に示している。
以下に、本発明に係る第1の実施形態の第1変形例について図2を参照しながら説明する。図2(a)から図2(d)は本変形例の共振器の製造方法を模式的に示している。なお、図2において図1と同一の構成要素については同一の符号を付与している。共振器基板1に貫通孔1aを形成するまでは、第1の実施形態と同じであるから説明を省略する。
以下に、本発明に係る第1の実施形態の第2変形例について図3を参照しながら説明する。図3(a)から図3(d)は本変形例の共振器の製造方法を模式的に示している。なお、図3において図1と同一の構成要素については同一の符号を付与している。共振器基板1の上に圧電膜4を形成するまでは、第1の実施形態と同じであるから説明を省略する。
以下に、本発明に係る第2の実施形態について図4を参照しながら説明する。図4(a)から図4(f)は実施形態の共振器の製造方法を模式的に示している。なお、図4において図1と同一の構成要素については同一の符号を付与している。
以下に、本発明に係る第2の実施形態の第1変形例について図5を参照しながら説明する。図5(a)から図5(e)は本変形例の共振器の製造方法を模式的に示している。なお、図5において図1と同一の構成要素については同一の符号を付与している。
以下に、本発明に係る第2の実施形態の第2変形例について図6を参照しながら説明する。図6(a)から図6(e)は本変形例の共振器の製造方法を模式的に示している。なお、図6において図1と同一の構成要素については同一の符号を付与している。
以下に、本発明に係る第3の実施形態について図7を参照しながら説明する。図7(a)から図7(e)は実施形態の共振器の製造方法を模式的に示している。なお、図7において図1と同一の構成要素については同一の符号を付与している。
1a 貫通孔
1b エアギャップ
2 形成用基板
3 バッファ層
3A AlN膜
3B GaN膜
4 圧電膜
5 電極
5A 上部電極
5B 下部電極
8 第1の薄膜
9 第2の薄膜
9a 開口部
9b エアギャップ
9A 導電膜
9B 絶縁膜
10 共振膜
12 第3の薄膜
12a 開口部
12b エアギャップ
14 音響多層膜
15 第4の薄膜
16 第5の薄膜
Claims (13)
- 形成用基板上に、圧電膜、および下部電極となる第2の薄膜を順に形成する工程と、
共振器基板上に、開口部を有する第3の薄膜を形成する工程と、
前記第2の薄膜と前記第3の薄膜とを貼り合わせることによりエアギャップを形成する工程と、
前記エアギャップを形成する工程の後に、前記形成用基板を除去する工程と、
前記形成用基板を除去する工程の後に、前記圧電膜上に上部電極を形成する工程とを備えていることを特徴とする共振器の製造方法。 - 前記第2の薄膜を形成する工程において、前記第2の薄膜はSnを含むように形成し、
前記第3の薄膜を形成する工程において、前記第3の薄膜の表面はAuを含むように形成することを特徴とする請求項1に記載の共振器の製造方法。 - 形成用基板上に、圧電膜、下部電極となる導電膜、および開口部を有する第1の層を順に形成する工程と、
前記第1の層を共振器基板の主面に貼り合わせることによりエアギャップを形成する工程と、
前記エアギャップを形成する工程の後に、前記形成用基板を除去する工程と、
前記形成用基板を除去する工程の後に、前記圧電膜上に上部電極を形成する工程とを備えていることを特徴とする共振器の製造方法。 - 前記第1の層は導電膜であることを特徴とする請求項3に記載の共振器の製造方法。
- 前記形成用基板上に前記圧電膜を形成する工程において、前記形成用基板と前記圧電膜との間にバッファ層を形成する工程を備え、
前記バッファ層は、前記形成用基板上に順に形成されたAlN膜およびGaN膜からなることを特徴とする請求項1〜4の何れか1項に記載の共振器の製造方法。 - 形成用基板上に圧電膜を形成する工程と、
共振器基板に貫通孔を形成する工程と、
前記圧電膜と前記共振器基板とを貼り合わせることによりエアギャップを形成する工程と、
前記エアギャップを形成する工程の後に、前記形成用基板を除去する工程と、
前記形成用基板を除去する工程の後に、前記圧電膜の上に上部電極、前記圧電膜の下に下部電極を形成する工程とを備えていることを特徴とする共振器の製造方法。 - 形成用基板上に圧電膜および下部電極となる第2の薄膜を順に形成する工程と、
共振器基板に貫通孔を形成する工程と、
前記第2の薄膜と前記共振器基板とを貼り合わせることによりエアギャップを形成する工程と、
前記エアギャップを形成する工程の後に、前記形成用基板を除去する工程と、
前記形成用基板を除去する工程の後に、前記圧電膜の上に上部電極を形成する工程とを備えていることを特徴とする共振器の製造方法。 - 形成用基板上に圧電膜および下部電極となる第2の薄膜を順に形成する工程と、
共振器基板に凹部を形成する工程と、
前記第2の薄膜と前記共振器基板とを貼り合わせることによりエアギャップを形成する工程と、
前記エアギャップを形成する工程の後に、前記形成用基板を除去する工程と、
前記形成用基板を除去する工程の後に、前記圧電膜の上に上部電極を形成する工程とを備えていることを特徴とする共振器の製造方法。 - 前記圧電膜を形成する工程の前に、前記形成基板上に第1の薄膜を形成する工程を備え、
前記圧電膜は前記第1の薄膜に接するように形成することを特徴とする請求項1〜8の何れか1項に記載の共振器の製造方法。 - 前記第1の薄膜は導電膜であり、
前記上部電極を形成する工程を省略することを特徴とする請求項9に記載の共振器の製造方法。 - 前記形成用基板をウェットエッチングにより除去することを特徴とする請求項1〜10の何れか1項に記載の共振器の製造方法。
- 前記形成用基板をドライエッチングにより除去することを特徴とする請求項1〜10の何れか1項に記載の共振器の製造方法。
- 前記形成用基板はSiCまたはサファイアからなることを特徴とする請求項1〜12の何れか1項に記載の共振器の製造方法。
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