JP3871698B2 - Absorbent articles - Google Patents

Description

  The present invention relates to absorbent articles such as disposable diapers, sanitary napkins, and incontinence pads.

  Absorbents for absorbent articles using continuous filament spread tows are known. For example, an absorber comprising a tow layer of crimpable acetate fibers and a pulverized pulp layer laminated on one side of this layer, in which both layers are integrated by pressing in the thickness direction of the absorber, is known. (See Patent Document 1). According to this absorber, the diffusibility of body fluid is improved. However, since acetate fibers have a lower water absorption capacity than pulp, a large amount of pulverized pulp must be used to increase the absorption capacity of the absorber. As a result, the absorber becomes thick, and the wearing feeling of the absorbent article is lowered.

  Also, it is known that the water-absorbing core is composed of an upper layer, a lower layer and an absorbent layer located between both layers, and a fiber layer made of acetate fiber tow is disposed on the spray layer of the superabsorbent polymer as the absorbent layer. (See Patent Document 2). A part of the superabsorbent polymer is bonded to the lower layer by an adhesive, and another part is housed in the fiber layer of the tow. In this water-absorbent core, although a part of the superabsorbent polymer is accommodated in the fiber layer of the tow, most of the superabsorbent polymer is bonded to the lower layer. That is, a fiber layer of tow and a spray layer of superabsorbent polymer exist separately. As a result, when the water absorbing core is deformed during wearing of the absorbent article due to the wearer's movement, the structure is easily broken.

  As an absorption layer having a continuous filament tow, one in which the tow extends in the thickness direction of the absorption layer is also known (see Patent Document 3). According to Patent Document 3, the excrement moves from the top to the bottom through the gap between the fibers of the tow and can be separated from the wearer's skin, so that it does not cause stuffiness or rash. Has been. In order for this absorption layer to have such a structure, the length of the tow needs to be long to some extent. Therefore, the absorption layer becomes thick.

JP-A-57-160457 Special table 2004-500165 gazette JP 2001-276125 A

  Therefore, the objective of this invention is providing the absorbent article which can eliminate the various fault which the prior art mentioned above has.

The present invention is an absorbent article comprising an absorbent comprising a web in which crimped long fibers are oriented in one direction, and a superabsorbent polymer embedded and supported in the web,
The web has a high fiber amount region and a low fiber amount region respectively extending in the orientation direction of the long fibers, and these regions are alternately arranged in parallel in a direction perpendicular to the orientation direction of the long fibers. The object is achieved by providing an absorbent article.

  In the present invention, the long fiber web constituting the absorbent body has a high fiber amount region and a low fiber amount region, and these regions are alternately arranged in parallel. It can be drawn out and can be used for absorbing liquid without leaving the entire area of the absorber. Further, the absorbent body exhibits a stripe pattern due to the high fiber content region and the low fiber content region, thereby visually giving a dry feeling. Moreover, the area | region of a high fiber amount gives cushioning properties, eliminates the fitting property to a body, and the discomfort at the time of mounting | wearing, and gives a good touch feeling to an absorbent article.

  The present invention will be described below based on preferred embodiments with reference to the drawings. The absorbent article of the present invention is mainly used for absorbing and holding excretory body fluids such as urine and menstrual blood. The absorbent article of the present invention includes, for example, disposable diapers, sanitary napkins, incontinence pads, etc., but is not limited thereto, and widely includes articles used for absorbing liquid discharged from the human body. .

  The absorbent article of the present invention typically includes a top sheet, a back sheet, and a liquid-retaining absorbent body disposed between both sheets. As the top sheet and the back sheet, materials usually used in the technical field can be used without particular limitation. For example, as the surface sheet, liquid permeable sheets such as various nonwoven fabrics and perforated films subjected to a hydrophilic treatment can be used. As the back sheet, a liquid-impermeable or water-repellent sheet such as a thermoplastic resin film or a laminate of the film and a nonwoven fabric can be used. The back sheet may have water vapor permeability. The absorbent article may further include various members according to specific uses of the absorbent article. Such members are known to those skilled in the art. For example, when applying an absorbent article to a disposable diaper or a sanitary napkin, a pair or two or more pairs of three-dimensional guards can be disposed on the left and right sides of the topsheet.

  FIG. 1 schematically shows an embodiment of an absorbent body in an absorbent article according to the present invention. The absorbent body 1 of the present embodiment is characterized by being thin and having a low basis weight while having a sufficient absorption capacity. The absorbent body 1 having such characteristics includes a long fiber web (hereinafter referred to as a web) 2 containing a superabsorbent polymer 3. In FIG. 1, the upper surface is a surface facing the wearer's skin (skin facing surface), and the lower surface is a surface facing the back sheet (skin non-facing surface).

  The long fibers constituting the web 2 may be either hydrophilic or hydrophobic. What is used in the present invention as a long fiber having hydrophilicity is a long fiber that is inherently hydrophilic, and inherently has no hydrophilicity, but is hydrophilic by being subjected to a hydrophilic treatment. Both of the long fibers to which is given are included. As a long fiber that does not inherently have hydrophilicity but has been rendered hydrophilic by being subjected to a hydrophilic treatment, various synthetic fibers, that is, single fibers such as polyethylene, polypropylene, polyethylene terephthalate, and the like A composite fiber containing two or more kinds of the above-mentioned resin, which has been surface-treated with a surfactant, is used. Preferable long fibers are long fibers that retain bulkiness even when wet. Particularly, the above-described synthetic fibers, nylon, acrylic, acetate, and rayon long fibers are preferable. In particular, acetate, which is a fiber having a moisture content of less than 10%, is particularly preferable because it inherently has hydrophilicity. As the acetate, cellulose triacetate and cellulose diacetate are preferable. Here, the moisture content is a value measured in an environment of 25 ° C. and a relative humidity of 65%.

  In the present specification, the hydrophilic web refers to one having a Klem water absorption measured in the orientation direction of preferably 20 mm or more, more preferably 30 mm or more. The measurement of Klem water absorption is performed, for example, as follows. The superabsorbent polymer is removed from the portion of the absorber 1 containing the superabsorbent polymer, and the crimped rate of the long fiber in the absorber 1 is maintained, and the web of the long fiber is used to absorb the Krem. Measure the degree. For the measurement, ion-exchanged water colored with 0.3% red No. 2 (external addition) is used. The height from the water surface 30 seconds after the setting is taken as the Klem water absorption. The Klem water absorption is measured according to JISP8141 (1996) “Test method for water absorption by the Krem method of paper and paperboard”. As the measurement direction, only the longitudinal direction of the absorber 1 is measured. The test piece has a width of 15 mm. The average value of the measured values of the three test pieces is taken as the Krem water absorption. Depending on the test piece, the Klem water absorption varies in the width direction. In this case, a value obtained by substantially averaging (visually) the width direction is taken as the measurement value.

When the operation of removing the superabsorbent polymer from the absorbent body is performed, the web density ρ1 in the absorbent body may be different from the web density ρ2 after the superabsorbent polymer is removed. Therefore, before removing the superabsorbent polymer from the absorbent body, the web density ρ1 in the absorbent body was measured in advance, and the web density ρ2 after the superabsorbent polymer was removed was measured in advance. After adjusting the state of the web after the superabsorbent polymer is removed so as to be the same as the density ρ1, the Krem water absorption is measured. In order to adjust the density ρ2 to the density ρ1, for example, the web after the superabsorbent polymer is removed may be compressed, and the Klem water absorption is measured in that state. The density ρ1 was, for example, 0.03 to 0.05 g / cm ³ .

The density ρ1 (g / cm ³ ) of the web in the absorber is calculated from the basis weight (g / cm ² ) of the web and the thickness (cm) of the web. The basis weight of the web is calculated from the weight (g) after removing the superabsorbent polymer from the absorbent body and the area (cm ² ). On the other hand, the thickness of the web is measured by the following method. A wrinkle is extended by applying a load of 24.5 kPa to the absorbent body taken out from the absorbent article in advance for 12 hours. Next, a weight is placed on an acrylic plate having a size of 5 cm × 5 cm on the absorber, and the thickness is measured under a state where a load of 0.245 kPa is applied. Specifically, a cross section of the absorber is cut out with a razor blade, the range of the absorber including the web is observed with a 10-fold stereo microscope, and the thickness of the web in the absorber is measured. The number of measurement points is 5, and the average value is the thickness. If the measured value fluctuates by 20% or more, delete the data and add another measured value.

As the long fiber, a crimped one is used. The long fiber has a crimp rate (JIS L0208) of preferably 10 to 90%, more preferably 10 to 60%, and still more preferably 10 to 50%. By forming a web from crimped long fibers, it becomes easy to stably embed and support a large amount of superabsorbent polymer in the web, even when a large amount of superabsorbent polymer is used. The extreme movement and dropout are less likely to occur. There is no particular limitation on the means for crimping the long fibers. Further, the crimp may be two-dimensional or three-dimensional. The crimp rate is defined as a percentage of the difference between the length A when the long fiber is stretched and the length B of the original long fiber with respect to the length A when stretched, and is calculated from the following equation: .
Crimp rate (%) = ((A−B) / A) × 100

  The length of the original long fiber means a length in which both ends of the long fiber are connected with a straight line when the long fiber is in a natural state. The natural state means a state in which one end of the long fiber is fixed to a horizontal plate and hung downward by its own weight. The length when the long fiber is stretched refers to the length at the minimum load when the long fiber is stretched until there is no crimp.

  The crimp rate of the long fibers is as described above, and the number of crimps is preferably 2 to 25, particularly 4 to 20, especially 10 to 20 per cm.

  There is no restriction | limiting in particular in the fiber diameter of a long fiber. In general, satisfactory results are obtained by using long fibers of 1 to 10 dtex, in particular 1.7 to 7.8 dtex. In the present invention, the long fiber means a fiber having a fiber length of preferably 70 mm or more, more preferably 80 mm or more, and even more preferably 100 mm or more when the fiber length is measured by the average fiber length measurement method (Method C) of JIS L1015. Say. However, when the total length of the web to be measured is less than 100 mm, preferably 50% or more, more preferably 70% or more, more preferably 80% or more of the fibers in the web extend over the entire length of the web. In this case, it is assumed that the fibers of the web are long fibers. The long fibers used in the present invention are generally called continuous filaments. A bundle of continuous filaments oriented in one direction is generally called a tow. Therefore, the long fiber in the present invention is a concept including a continuous filament. The web in which the long fibers are oriented is a concept including a bundle of long fibers (so-called tow) as a raw material for forming the web and a tow layer of continuous filaments. In addition, fibers (cut fibers) in which part of the long fibers are cut and the fiber length is less than the above value may be mixed in the absorbent body.

  In the absorbent body 1 according to the present embodiment, the long fibers constituting the web 2 are oriented in one direction in the plane direction of the absorbent body 1. When the liquid is absorbed by the absorbent body 1 due to the orientation of the long fibers in one direction, the liquid diffuses preferentially in the orientation direction of the long fibers. That is, it diffuses preferentially in the planar direction of the absorber. Conversely, diffusion in the direction perpendicular to the orientation direction of the long fibers is suppressed. When long fibers are oriented in the longitudinal direction of the absorbent article, liquid leakage (lateral leakage) from the side of the absorbent article is effectively prevented.

  The orientation of the long fiber may be as long as the vector connecting the start point and end point of the long fiber is oriented in the plane direction, and a part of the long fiber is in the vertical direction (twist or entanglement between the start point and end point) (the thickness of the absorber) Including the ones that face (direction). More specifically, the degree of orientation of the long fibers is preferably 1.2 or more, particularly 1.4 or more in terms of the degree of orientation. In this embodiment, the degree of orientation is measured using a Microwave molecular orientation analyzer MOA-2001A manufactured by KANZAKI. The sample size is 100 mm in the longitudinal direction and 50 mm in width, and the average value of three points is the degree of orientation. When the sample size is less than this size, measurement is performed by arranging a plurality of samples so as not to overlap each other.

  When the long fibers are oriented in the longitudinal direction of the absorbent article, it is preferable that the absorbent body does not have a linear bond line that crosses the orientation direction of the long fibers. When such an adhesive line exists, smooth diffusion of the liquid in the orientation direction of the long fibers is interrupted, which may cause side leakage.

  When long fibers are oriented in the width direction of the absorbent article, diffusion in the longitudinal direction of the absorbent article is suppressed, and spot absorptivity is obtained. In this case, in order to prevent liquid leakage (lateral leakage) from the side, the absorbent body preferably has a linear bonding line that crosses the orientation direction of the long fibers. “Linear” means a continuous line that suppresses permeation of liquid, and it is not necessary that individual seal lines and the like are continuous without interruption. For example, if the liquid movement can be prevented by arranging the intermittent seal lines in layers, it is linear. In addition to the linear shape, the linear shape may be a curved shape or a broken line shape. The width of the line is preferably 0.2 to 15 mm.

  The bonding line may be formed only in the web 2. When the absorbent body 1 is configured by wrapping the web 2 in tissue paper or the like, for example, in the case of the embodiment shown in FIG. 7 described later, even if an adhesive line is formed over the entire thickness direction of the absorbent body 1. good. Furthermore, you may form including a surface sheet. In any case, it is preferable that an adhesive line is formed at least in the longitudinal center of the absorbent article. Moreover, the adhesion line may be formed outward from both side edges in the width direction of the absorbent body. By providing an adhesive line in this way, even if the liquid moves in the web due to capillary action, it will not contact the adhesive line and prevent further movement, so liquid leakage from the side is unlikely to occur. Become.

  In FIG. 1, long fibers extend in a direction perpendicular to the paper surface and are oriented in this direction. Long fibers exist over the entire length of the absorber. However, it is not necessary for the long fibers to exist over the entire length of the absorbent body, and it is sufficient if the long fibers are present in the excretory part-facing region of the absorbent body 1 on condition that the fiber length described above is satisfied.

  The web 2 has a high fiber amount region (hereinafter referred to as a high fiber amount region) 2a and a low fiber amount region (hereinafter referred to as a low fiber amount region) 2b extending in the orientation direction of the long fibers. These regions 2a and 2b are alternately arranged in parallel in a direction (direction indicated by X in FIG. 1) orthogonal to the orientation direction of the long fibers. The high fiber amount region 2a is a region where the fiber amount per unit area is relatively high when viewed in a cross section in the thickness direction of the web. The low fiber amount region 2b is a region where the amount of fibers per unit area of the web is relatively low.

  The widths of the high fiber amount region 2a and the low fiber amount region 2b (the width in the X direction in FIG. 1) are not critical in the present embodiment, and the widths of the regions 2a and 2b may be the same or different. May be. When the widths of both the regions 2a and 2b are different, the width of the high fiber amount region 2a may be larger than the width of the low fiber amount region 2b or, conversely, the width of the low fiber amount region 2b. However, the width may be larger than the width of the high fiber amount region 2a. Depending on the manufacturing method of the web 2, in the extreme case, the width of the low fiber amount region 2b may be much smaller than the width of the high fiber amount region 2a.

  Whatever the width of each region, the absorbent body 1 of the present embodiment having the web 2 in which these regions are alternately arranged is different in the amount of fibers when viewed through the top sheet. Exhibits a stripe pattern caused by This gives the user a visually dry feeling. In particular, when the regions 2a and 2b are arranged so as to extend in the longitudinal direction of the absorbent article, the tendency is further increased.

  Depending on the production method of the web 2, the high fiber amount region 2a and the low fiber amount region 2b each have a width of 0.5 to 20 mm, particularly 2 to 10 mm, so that the stripe pattern can be clearly seen over the surface sheet. It is preferable from the point of being visually recognizable and the point of the improvement of the absorbability mentioned later.

In the high fiber amount region 2a and the low fiber amount region 2b, the fiber amount in these regions may be changed stepwise or may be continuously changed. Fiber weight in the high fiber content region 2a is preferably from 10 to 200 g / m ^2, and still more preferably from 20 to 100 g / m ^2. On the other hand, amount of fibers in the low fiber content region 2b is preferably at 20 g / m ² or less, more preferably 3 to 10 g / m ^2. The fiber amount W1 in the high fiber amount region 2a is larger than the fiber amount W2 in the low fiber amount region 2b. Preferably, the fiber amount W1 in the high fiber amount region 2a is twice or more the fiber amount W2 in the low fiber amount region 2b. It is.

  The amount of fiber is determined as follows. An absorber is prepared in a state where a load of 24.5 kPa is applied in advance for 12 hours to remove the effects of thickness recovery, wrinkles, and the like. First, the weight of the absorber cut into 10 cm × 10 cm is measured, and the basis weight of the entire absorber is calculated. In addition, the amount of the superabsorbent polymer is quantified, and the basis weight of the superabsorbent polymer is subtracted from the basis weight of the entire absorber to calculate the average basis weight of the fibers in the absorber. The amount of the superabsorbent polymer in the absorber is determined by measuring the weight and area of the entire absorber, then immersing the absorber in an ascorbic acid solution and exposing it to sunlight to dissolve the superabsorbent polymer, and washing with water. It can calculate by calculating | requiring the amount of residual fibers. Next, the absorbent body is cut out in a direction orthogonal to the orientation direction of the long fibers, and the high fiber region and the low fiber region are separated by the area ratio of the fibers in the cut out section. The absorber is cut with a cutter to cut out a cross section, and an area corresponding to a width of 50 mm is divided and imaged and captured as image data. An individual imaging range is 5 mm × 5 mm, and this is enlarged 25 times to capture each imaging range continuously. The obtained image is processed using image analysis processing software (Image-Pro plus, Media Cybernetics), and the area occupied by the fibers (that is, the sum of the cross-sectional areas of the individual fibers) is calculated for each image. The measurement is an average of 5 points. The area occupied by the fiber when the thickness of the web is assumed to be constant is calculated from the average basis weight of the fiber measured in advance and the cross-sectional area of one fiber (this area is referred to as the average area). A region in which the measured fiber occupies an area that is equal to or greater than the average area is defined as a high fiber amount region, and a region that is less than the average area is defined as a low fiber amount region.

  The number of the high fiber amount region 2a and the low fiber amount region 2b is not particularly limited, but 3 to 50 repeating units in the direction indicated by X in FIG. It is preferable that ~ 30 are juxtaposed in view of the fact that the stripe pattern can be clearly visually recognized through the surface sheet and the improvement in absorbability described later.

Since the web 2 has a high fiber amount region 2a and a low fiber amount region 2b, the basis weight of the web 2 means the average basis weight of the entire web including both regions. The basis weight of the web 2, in the case of using the absorbent body 1, for example in disposable diapers for infants, 120~400g / m ^2, particularly preferably a 150 to 300 g / m ^2. When used for a sanitary napkin, it is preferably 35 to 200 g / m ² , particularly 50 to 150 g / m ² . When used for an incontinence pad, it is preferably 35 to 500 g / m ² , particularly 50 to 400 g / m ² .

  A superabsorbent polymer is buried and supported in the web 2. The superabsorbent polymer 3 is generally in the form of particles, but may be fibrous. When using a particulate superabsorbent polymer, if the shape is an indeterminate type, a block type, or a bowl type, embed it on the web 2 at a basis weight of the same amount or more and 10 times or less. Can do. Further, in the case of a spherical particle aggregation type or a spherical type, it can be embedded and supported at a basis weight of the same amount or more and 5 times or less with respect to the web. For these particle shapes, it is desirable to select the former when it is particularly desired to achieve both high absorption and thinning, and the latter when importance is placed on the texture (reduction of the feeling of shaving of the superabsorbent polymer).

  In FIG. 1, a state in which the superabsorbent polymer 3 is biased and exists in a portion extending from the center in the thickness direction to the lower portion of the web 2 is shown. That is, the superabsorbent polymer 3 is biased and carried on the skin 2 non-facing surface side of the web 2. However, depending on the manufacturing conditions of the absorbent body 1, almost all of the superabsorbent polymer 3 may be embedded and supported uniformly in the web 2. “Uniform” means that when the superabsorbent polymer is completely uniformly arranged in the thickness direction or the width direction of the absorbent body 1 and when a part of the absorbent body 1 is taken out, This refers to the case where the variation in the abundance has a distribution within twice the basis weight. Such a variation is caused by rarely supplying a superabsorbent polymer excessively and producing a part with an extremely high spraying amount in manufacturing an absorbent article. In other words, the above “uniform” includes cases where inevitably variations occur, and does not include cases where the superabsorbent polymer is distributed so as to intentionally vary.

  When the superabsorbent polymer 3 is present in a biased state as shown in FIG. 1, the diffusibility of the liquid is high and the liquid absorbability of the entire absorbent body is high. Is preferred. Contrary to FIG. 1, when the superabsorbent polymer 3 is biased and present in a portion extending from the center in the thickness direction to the top of the web 2, that is, biased toward the skin-facing surface side of the web 2. In this case, since the liquid spot absorbability is high, it is suitable as an incontinence pad for light incontinence and an absorbent body for sanitary napkins.

  Since the long fiber has crimps, the long fiber has a large number of spaces capable of holding particles. The superabsorbent polymer is retained in the space. As a result, even if a large amount of superabsorbent polymer is sprayed, the extreme movement or dropout is less likely to occur. Moreover, even if a wearer performs intense operation | movement, the structure of the absorber 1 becomes difficult to be destroyed. Depending on the superabsorbent polymer used, the crimp rate and the amount of long fibers used are adjusted as appropriate. Even in the conventional absorbent body, if the amount of the fiber material is increased, a large amount of the superabsorbent polymer can be retained, but in this case, the basis weight and thickness of the absorbent body are increased. On the other hand, in this embodiment, it is easy to make the amount of the superabsorbent polymer relatively large with respect to the amount of the fiber material. Specifically, the basis weight of the superabsorbent polymer is preferably not less than the basis weight of the web, more preferably not less than 2 times, more preferably not less than 3 times when viewed from the whole absorbent body. As a result, the absorber 1 is made thinner and has a lower basis weight. The upper limit of the ratio of the basis weight of the superabsorbent polymer to the basis weight of the web is determined from the viewpoint of extreme movement of the superabsorbent polymer and prevention of falling off. Although depending on the degree of crimp of the long fibers, if the upper limit is about 10 times, the superabsorbent polymer is unlikely to move or drop out even if the wearer performs a violent operation. The specific basis weight of the superabsorbent polymer is determined from the relative ratio of the basis weight of the web described above on the condition that the basis weight of the web satisfies the above-described range.

  The following method can be used as an evaluation method to the extent that the superabsorbent polymer is buried and supported. The central part in the longitudinal direction of the web produced to 100 mm × 200 mm is cut to obtain a 100 mm × 100 mm test piece. This cut surface is directly below, and vibration is applied to the left and right 20 times at a speed of once / second with an amplitude of 5 cm. Measure the weight of polymer dropped from the cut surface. When the weight of the dropped superabsorbent polymer is 25 wt% or less, particularly 20 wt% or less, especially 10 wt% or less, based on the total amount of the superabsorbent polymer present in the test piece, It can be said that this is a state in which the extreme movement and dropout of the functional polymer are difficult to occur.

As an evaluation of the extent to which the superabsorbent polymer is buried and supported, a mobility measured by the following method can be employed in addition to the above-described dropout evaluation test. First, an initial weight W0 of a 100 mm × 100 mm measurement sample used for the measurement of the drop-off evaluation test is measured in advance. The measurement sample after the measurement of the drop-off evaluation test is finished is cut in a direction perpendicular to the direction in which the long fibers extend, and is divided into two equal parts. The weight of each of the two halves divided into two is measured, and the weight of the halved fragment having the larger variation from 1/2 of the initial weight W0 of the measurement sample is adopted as the weight W1 for calculating the transfer rate. To do. For example, assuming that the weights of two fractional pieces are W1 ′ and W1 ″, if these W1 ′ and W1 ″ satisfy the following expression, W1 = W1 ′.
| W1'-W0 / 2 |> | W1 "-W0 / 2 |
Using the value of W1 determined in this way and the value of the initial weight W0 of the measurement sample, the movement rate is calculated from the following equation.
Movement rate (%) = {1-W1 / (W0 / 2)} × 100
When the value of the migration rate thus measured is 40% or less, particularly 30% or less, particularly 20% or less, it can be said that the migration of the superabsorbent polymer is difficult to occur.

  In a simple manner, the following evaluation method can be performed on the test piece subjected to the above-described drop-off evaluation test. 50 g of physiological saline (0.9 wt% NaCl) is evenly sprayed on the test piece subjected to the test for dropout evaluation, and the way of swelling of the test piece is visually observed. When the variation in the thickness of the test piece is within 2 times, it can be said that it is difficult for the superabsorbent polymer to move or drop off.

  In each of the evaluation methods described above, when the web is viewed in the horizontal direction, the test piece is sampled from a region where the superabsorbent polymer is dispersed with the same basis weight. Since the web 2 has a high fiber content region 2a and a low fiber content region 2b, the basis weight of the superabsorbent polymer means the average basis weight of the entire web including both regions. If the superabsorbent polymer is biased in the planar direction of the absorbent body, avoid sampling across the biased and unbiased portions.

  When the embedding supportability of the superabsorbent polymer 3 on the web 2 is not sufficient, a hot melt adhesive, various binders (for example, acrylic emulsion adhesive), sugar derivatives such as carboxymethylcellulose and ethylcellulose, polyethylene, polypropylene, polyethylene A thermoplastic resin such as terephthalate can be appropriately added to the web. Furthermore, you may use together the sheet | seat etc. which gave uneven | corrugated processing or flocking.

  As shown in FIG. 1, the superabsorbent polymer has a substantially uniform basis weight in the direction orthogonal to the orientation direction of the long fibers, that is, in the direction indicated by X in FIG. As a result, when the relationship between the fiber amount in the high fiber amount region 2a and the low fiber amount region 2b is observed, the ratio of the high absorbent polymer to the fiber amount (the former / the latter) is lower than that in the high fiber amount region 2a. The quantity region 2b is higher. The establishment of such a relationship is important from the viewpoint of efficient liquid absorption. This is described below.

  2 (a) to 2 (c) show a liquid absorption mechanism by the absorbent body 1 of the present embodiment. A top sheet T is disposed on the absorber 1. The web 2 constituting the absorbent body 1 has a high fiber amount region 2a and a low fiber amount region 2b. Among these regions, since the fiber amount is relatively large, the high fiber amount region 2a preferentially contacts the top sheet T over the low fiber amount region 2b. Therefore, in the surface sheet T, as shown in FIG. 2A, the sheet T is in contact with a region in contact with the high fiber amount region 2a (hereinafter, this region is referred to as a web contact region T2). There is a difference in the drawability of the liquid in a non-region (hereinafter, this region is referred to as a web non-contact region T1). That is, when the liquid L is excreted to the top sheet T in a state where both the web non-contact area T1 where the pressing force is not applied to the top sheet T and the web contact area T2 exist, the liquid L As shown in 2 (b), it is absorbed into the absorbent body 1 through the high fiber amount region 2a (web contact region T2) in contact with the topsheet T. Next, in the surface sheet T, the liquid moves from the web non-contact area T1 toward the web contact area T2 by liquid moving force such as liquid diffusing force or penetrating force. Then, it is again absorbed by the absorbent body 1 through the high fiber amount region 2a.

  Further, as shown in FIG. 2C, when a pressing force is applied to the top sheet T, both the web contact area T2 and the web non-contact area T1 come into contact with the web 2 and When the liquid L is excreted to the top sheet T, the high fiber amount region 2a is more compressed than the low fiber amount region 2b, so that a gradient is generated in the liquid drawing force.

  Therefore, the gradient of the liquid moving force and the liquid drawing force becomes the driving force, and as shown in FIGS. 2B and 2C, the web non-contact area T1 → the web contact area T2 → the high fiber amount. The movement of the liquid in the order of the area 2a is promoted, and the movement of the liquid from the web non-contact area T1 to the low fiber amount area 2b occurs, so that the liquid hardly remains on the top sheet 2. As a result, the top sheet 2 tends to be in a dry state. In addition, the effect of the visual dry feeling due to the stripe pattern generated by the high fiber content region 2a and the low fiber content region 2b is weighted.

  2A to 2C, the liquid absorbed by the absorbent body 1 is first absorbed by the superabsorbent polymer 3 included in the high fiber amount region 2a. In this case, in the high fiber amount region 2a, since the fiber amount is relatively large with respect to the amount of the superabsorbent polymer 3, even if the superabsorbent polymer 3 swells due to liquid absorption, the high fiber amount Long fibers contained in the region 2 a enter between the respective superabsorbent polymers 3. As a result, gel blocking of the superabsorbent polymer 3 is less likely to occur. Further, the long fibers themselves can serve as a liquid guide path and can maintain liquid absorption. When body pressure is applied to the absorbent body 1 due to a change in the body position of the wearer, etc., as shown in FIG. 2 (c), the liquid held in the high fiber amount region 2a has a low fiber amount. Extruded into the region 2b and absorbed by the superabsorbent polymer 3 contained in the region 2b. In addition, the liquid is diffused in the orientation direction because the long fibers are oriented in one direction.

  Thus, according to the absorbent body 1 of the present embodiment, the liquid is absorbed not only in the area where the liquid is excreted but also in a wide area around it. As a result, the absorbent body 1 can be used for liquid absorption without leaving the entire region. That is, efficient liquid absorption can be performed.

The superabsorbent polymer used in the present embodiment has a liquid passage time measured by the following method of 20 seconds or less, particularly 2 to 15 seconds, and particularly preferably 4 to 10 seconds. The measurement of the liquid transit time is as follows. That is, 0.5 g of the superabsorbent polymer was placed in a cylindrical tube having a cross-sectional area of 4.91 cm ² (inner diameter: 25 mmφ) and an openable / closable cock (inner diameter: 4 mmφ). Fill with water and swell the superabsorbent polymer with the saline until it reaches saturation. After the swollen superabsorbent polymer settles, the cock is opened and 50 ml of physiological saline is allowed to pass through. The time required for 50 ml of the physiological saline to pass through is measured, and this time is taken as the liquid passage time.

  The liquid passage time is one of the indexes reflecting the gel strength of the superabsorbent polymer, and the shorter the liquid passage time, the stronger the gel strength.

  Furthermore, it is more preferable to use a superabsorbent polymer having a high liquid passing rate under load. As the superabsorbent polymer, a polymer having a liquid flow rate of 30 to 300 ml / min, preferably 32 to 200 ml / min, more preferably 35 to 100 ml / min is used. When the value of the liquid flow rate is less than 30 ml / min, the superabsorbent polymers saturated and swollen by the liquid absorption adhere to each other under load, and the passage of the liquid is hindered, so that gel blocking easily occurs. The larger the value of the flow rate, the better from the viewpoint of preventing the occurrence of gel blocking. When the liquid flow rate exceeds 300 ml / min, the fluidity of the liquid in the absorber is too high, especially when a large amount of excreta is excreted at once, or in the case of older infants or adults. When the excretion rate is high as described above, the liquid may not be sufficiently fixed and leakage may occur when the absorber is further thinned. In general, increasing the liquid flow rate increases the degree of crosslinking of the superabsorbent polymer, lowering the absorption capacity per unit weight of the superabsorbent polymer, and a large amount of superabsorbent polymer must be used. I must. From these viewpoints, the upper limit value of the flow rate is determined.

  The measurement of the flow rate of the superabsorbent polymer 21 is performed under a 2.0 kPa load. This load substantially corresponds to the body pressure applied to the absorbent body while wearing the absorbent article. A specific method for measuring the flow rate is described in paragraph 0005 of Japanese Patent Laid-Open No. 2003-235889, for example. In the present invention, measurement is performed by changing 0.200 g, which is the weight of the sample used in the measurement method described in this publication, to 0.32 g. Specifically, the flow rate is measured by the following procedure.

[Measurement method of flow rate]
A filtering cylindrical tube provided with a wire mesh (mesh size 150 μm) and a narrow tube (inner diameter 4 mm, length 8 cm) with a cock (inner diameter 2 mm) at the lower end of a vertically standing cylinder (inner diameter 25.4 mm). prepare. With the cock closed, 0.32 g of a measurement sample adjusted to a particle size of 850 to 150 μm is put into the cylindrical tube. Next, 50 ml of 0.9% by weight physiological saline is poured into the cylindrical tube. After standing for 30 minutes from the start of pouring physiological saline, a cylindrical rod (21.2 g) having a wire mesh with an opening of 150 μm and a diameter of 25 mm at the tip was inserted into the filtration cylindrical tube, and the wire mesh and Make the measurement sample touch. After 1 minute, a 77.0 g weight is attached to the cylindrical rod and a load is applied to the measurement sample. After another 1 minute, open the cock. The time (T1) (second) until the liquid level of the physiological saline solution reaches the 20 ml scale line from the 40 ml scale line is measured. Using the measured time T1 (seconds), the liquid passing time is calculated from the following equation. In the formula, T0 is the time measured without putting the measurement sample in the filtering cylindrical tube.
Flow rate (ml / min) = 20 × 60 / (T1-T0)

  A more detailed method for measuring the flow rate is described in paragraphs 0008 and 0009 of JP-A-2003-235889. The measuring device is described in FIGS. 1 and 2 of the publication.

  The superabsorbent polymer is not particularly limited as long as it satisfies the above-mentioned characteristics. Specifically, for example, polyacrylic acid soda, (acrylic acid-vinyl alcohol) copolymer, polyacrylic acid soda crosslinked product. , (Starch-acrylic acid) graft polymer, (isobutylene-maleic anhydride) copolymer and saponified product thereof, potassium polyacrylate, and cesium polyacrylate. In order to satisfy the above characteristics, for example, a crosslink density gradient may be provided on the surface of the superabsorbent polymer particles, or the superabsorbent polymer particles may be non-spherical amorphous particles. Specifically, the method described in JP-A-7-18495, column 7 line 28 to column 9 line 6 can be used. Alternatively, by adopting a reverse phase suspension polymerization polymerization method using an anionic surfactant described in Japanese Patent No. 2721658, which is a previous application of the present applicant, as a dispersant, a high liquid flow rate having a desired flow rate is obtained. Absorbent polymer 21 is obtained.

  When the absorbent body 1 according to this embodiment is used in a disposable diaper, the absorbent body 1 is preferably a thin one having a thickness of 1 to 4 mm, more preferably 1.5 to 3 mm. When used for a sanitary napkin, the thickness is preferably 0.5 to 3 mm, more preferably 1 to 2 mm. When used as an incontinence pad, it is preferably 0.5 to 4 mm, more preferably 1 to 3 mm.

  The thickness of the absorber 1 is measured under a state where a weight is placed on an acrylic plate having a size of 5 cm × 5 cm on the absorber 1 and a load of 0.245 kPa is applied. In this embodiment, the thickness was measured using an LK080 class 2 laser displacement meter manufactured by Keyence Corporation. The number of measurement points was an average of 5 points, and when the measurement value fluctuated 20% or more, the data was deleted and another measurement value was added. A 24.5 kPa load was applied to the sample in advance for 12 hours to keep wrinkles extended.

In relation to the thickness of the absorbent body 1, the basis weight of the entire absorbent body 1 including the web 2 and the superabsorbent polymer 3 is 120 to 400 g / m ² when the absorbent body 1 is used for, for example, a disposable diaper, In particular, it is preferably 150 to 300 g / m ² . When used for a sanitary napkin, it is preferably 35 to 200 g / m ² , particularly 50 to 150 g / m ² . When used for an incontinence pad, it is preferably 35 to 500 g / m ² , particularly 50 to 400 g / m ² .

  In the web 2, in addition to the superabsorbent polymer 3, other particles such as activated carbon, silica, alumina, titanium oxide, various viscosity minerals (zeolite, sepiolite, bentonite, cancrinite, etc.) and other organic and inorganic particles ( Deodorant and antibacterial agent) can coexist. As the inorganic particles, those partially substituted with metal sites can be used. Alternatively, various organic and inorganic buffering agents, that is, acetic acid, phosphoric acid, citric acid, succinic acid, adipic acid, malic acid, lactic acid, or salts thereof may be used alone or in combination, or various amino acids may be used. The function of these components is to suppress the smell of excreta absorbed by the absorber and the smell derived from the material. In addition, various organic and inorganic buffering agents have the effect of neutralizing excrement, for example ammonia generated by decomposition of urine, to keep the diaper neutral to weakly acidic, thereby allowing excretion from the diaper to the skin. Even if there is a liquid return of an object, the influence on the skin can be reduced. Alternatively, even if a fiber having an ester in the molecular structure such as acetate fiber is used for the web, the effect of preventing the fiber from being damaged by alkali can be expected.

  In addition, hydrophilic fine powder or short fibers can coexist in the web 2 for the purpose of improving the liquid retention and absorption rate and improving the dryness. Examples of hydrophilic fine powders or short fibers include fibrillated or non-fibrillated cellulose powder, carboxymethyl cellulose and its metal salt, carboxyethyl cellulose and its metal salt, hydroxyethyl cellulose and its derivatives, silk powder, nylon powder, Examples include short fibers such as rayon, cotton, and wool. Among these, it is preferable to use cellulose powder because the above effects can be improved to the maximum. The hydrophilic fine powder or short fiber may be sprayed on the web 2 before the superabsorbent polymer 3 is sprayed, or may be mixed with the superabsorbent polymer 3 and sprayed on the web 2 at the same time.

The absorbent body 1 having the above structure is thin, has a low basis weight, and is highly breathable. The degree of air permeability of the absorbent body 1 is a low value of 0.4 kPa · s / m or less in terms of the air resistance per 100 g / m ^{2 of the} superabsorbent polymer. The smaller the ventilation resistance value, the higher the air permeability. Such a ventilation resistance value is an extremely low value of about 1/2 of the ventilation resistance value of a conventional absorbent body made of a laminate of flap pulp and a superabsorbent polymer. There is no restriction | limiting in particular in the minimum of ventilation resistance value, and the air permeability becomes high, so that the value is small. The ventilation resistance value is measured by an air permeability tester KES-F8 (trade name) manufactured by Kato Tech. According to this apparatus, the pressure loss when a constant flow rate of air (4 cc square cm / sec) is passed is measured.

  Some absorbers according to the present invention have a ventilation resistance value that is less than or equal to the measurement limit of the measuring device, that is, approximately 0.2 kPa · s / m or less. For example, a material in which a superabsorbent polymer is supported in a long fiber web and wrapped with tissue paper without using pulp as a constituent material of the absorbent body can be mentioned. Therefore, in the present invention, there is no lower limit value for the ventilation resistance value. Examples of other materials that are less than or equal to the measurement limit of the measuring device include normal tissue paper, surface sheets, and gauze used for absorbent articles.

The entire absorber 1 has a compression work (WC value) by a KES compression tester in the thickness direction of preferably 0.98 cN · cm / cm ² or more, and more preferably 1.47 cN · cm / cm. cm ² or more. This compression work is measured using a Kato Tech KES-G5 handy compression tester. The measuring method is as follows. A test piece of 5 cm × 10 cm is prepared and attached to a test bench. The specimen is compressed between steel plates having a circular plane with an area of 2 cm ² . The compression speed is 20 μm / sec. The maximum compression load is 4.9 kPa. The recovery process is also measured at the same rate. The compression work WC is expressed by the following equation.

  If the work of compression (WC value) of the absorbent body 1 is not less than the above value, there is no sense of incongruity, and the absorbent article has excellent recoverability after pressure release (for example, after being taken out from a packaging pack) and has cushioning properties. There is an advantage that can be provided. In addition, there is an advantage that the body fits immediately after being taken out from the packaging pack, and quick absorbability of the liquid is expressed. Furthermore, there is an advantage that it becomes very compact by compression.

  The absorptive article of the present invention which comprises absorber 1 of this embodiment may have two or more pairs of a pair of solid gathers which counter mutually. For example, as shown in FIG. 3, an elastic strand 31 extending in the longitudinal direction of the absorbent article is arranged in an extended state on the side edge of the leg fluff 30 extending from the side edge of the absorbent body 1 to the side. 32, and further, a first three-dimensional gather 33 and a second three-dimensional gather 34 having a base end portion are disposed between the leg gather 32 and the side edge of the absorbent body 1. The first three-dimensional gathers 33 are arranged closer to the leg gathers, and the second three-dimensional gathers 34 are arranged closer to the absorber.

  These three gathers located on the leg flaps 32 adjust the contraction force of each gather so that the contraction force of the outermost gather is larger than the contraction force of the gathers located inward. It is preferable. That is, when the contraction force of the leg gather 32 is L1, the contraction force of the first three-dimensional gather 33 is L2, and the contraction force of the second three-dimensional gather 34 is L3, it is preferable that L1> L2, L3. In particular, it is preferable that the gather contraction force gradually decreases from the outermost gather to the inside. That is, it is preferable that L1> L2> L3. The reason is as follows.

  The conventional design method for absorbent articles is to reduce the thickness of the absorbent article and make it difficult to leak liquids, thereby increasing the shrinkage force of gathers and leaving a gap between the wearer's body and the absorbent article. Based on the idea of not. However, if the contraction force of the gathers is too strong, the marks are likely to touch the skin. In addition, when the thin and flexible or absorbent body is used as in the present invention, the absorbent article contracts due to the contraction force of the gathers, making it difficult to wear. If the gather contraction force is too strong, a downward force due to the contraction force acts on the absorbent article during mounting of the absorbent article, and a shift tends to occur. On the other hand, by using two or more pairs of leg gathers and a pair of opposing three-dimensional gathers and having the contraction force as described above, the above-described inconveniences that occur in conventional absorbent articles can be avoided.

  The gather contraction force is measured by the following method. A gather is cut from the absorbent article and used as a measurement sample. A hysteresis curve of the measurement sample is drawn using Tensilon ORIENTEC RTC-1150A. The stress at the return of this hysteresis curve is defined as the contraction force. The speed of pulling and returning is 300 mm / min. The initial length of the sample is 100 mm, and the maximum elongation is 100 mm (twice the original length). The stress at the time of return of the hysteresis curve is a measured value when the sample is returned 50 mm from the maximum elongation. The measurement is an average of 5 points. In the case of a sample whose maximum elongation is less than 100 mm, the elongation is up to 50 mm, and the value at that time is the measured value.

  In order to adjust the contraction force of each gather, for example, methods such as changing the thickness of the elastic body, changing the elongation rate of the elastic body, changing the number of elastic bodies, etc. are used alone or in combination. Moreover, it is preferable that the expansion / contraction area | region of the leg gather 32 is only the crotch part of an absorbent article.

  In the absorbent article shown in FIG. 3, two sets of leg gathers and a pair of opposing three-dimensional gathers are used. Instead of this, in the absorbent article of the present invention including the absorbent body 1 of the present embodiment, two or more pairs of opposing three-dimensional gathers may be used without using leg gathers. For example, in FIG. 4, two sets of three-dimensional gathers, that is, a first three-dimensional gather 33 and a second three-dimensional gather 34 are used. Also in this case, it is preferable that the shrinkage force of the three-dimensional gather is gradually reduced from the outer side in the width direction toward the inner side for the same reason as described above.

  Next, the manufacturing method of the absorber 1 of this embodiment is demonstrated, referring FIG. FIG. 5 shows an apparatus suitably used for manufacturing the absorbent body 1. The manufacturing apparatus includes a fiber opening means 20 for sequentially opening the long fibers 10 during the conveyance thereof.

  The opening means 20 includes opening machines (banding jets) 21, 22, and 23 that sequentially open the long fibers 10 being conveyed. Further, the opening means 20 includes a guide 24 for lowering the long fiber 10 once sent upward between the opening machines 21 and 22, and a feeding roll 25 between the opening machines 22 and 23. And a blooming roll 26.

  The spreaders 21, 22, and 23 are devices that spread air by blowing air to open the long fibers 10 being conveyed. The feeding roll 25 includes a pair of rolls that nip the long fibers 10 opened by the spreader 22 and feed them at a predetermined speed. The blooming roll 26 is provided with a roll 260 and an anvil roll 261 in which a large number of disks are incorporated at predetermined intervals around an axis, and the long fiber 10 in a state where tension is applied is spread. A polymer supply means 27 is provided at a position downstream of the spreader 23. The polymer supply means 27 is a device that uniformly spreads a predetermined amount of the superabsorbent polymer 3 on the long fibers after being wound by the blooming roll 26.

  In the manufacturing method of the absorber 1 using the manufacturing apparatus having the above configuration, the long fibers 10 are conveyed in a state where a predetermined tension is applied thereto. As described above, since the long fibers 10 have crimps, when the tension is applied, the long fibers 10 are easily stretched in the longitudinal direction. Under this state, the long fibers 10 are opened by the spreaders 21, 22, and 23 of the opening means 20 so as to widen the width. By using a plurality of spreaders, the width of the long fibers 10 can be expanded stepwise without difficulty.

  The long fiber 10 is wound by a blooming roll 26 positioned between the spreaders 22 and 23, thereby forming a high fiber amount region and a low fiber amount region. The fiber amount in the high fiber amount region and the low fiber amount region is mainly determined by the thickness of the disk in the roll 260 and the pitch between the disks. The widths of the high fiber amount region and the low fiber amount region are mainly determined by the degree of opening by the opening machine 23 installed on the downstream side of the blooming roll 26.

  The superabsorbent polymer 3 is sprayed on the long fibers 10 in a state where the high fiber amount region and the low fiber amount region are formed. At the time of spreading, the tension for transporting the long fibers 10 is weakened and the stretched state of the long fibers 10 is released. As a result, the long fibers 10 return to the crimped state, and the superabsorbent polymer 3 is dispersed under the state. The long fibers in a crimped state have voids that can accommodate the superabsorbent polymer 3 between the fibers. The superabsorbent polymer is buried and supported in the voids. On the other hand, in the state in which the long fiber 10 is stretched and stretched, a sufficient gap for accommodating the superabsorbent polymer 3 is not formed, so that the superabsorbent polymer 3 is successfully embedded and supported. It is not easy. Simultaneously with the dispersion of the superabsorbent polymer 3, it is effective to promote suction of the polymer 3 by carrying out suction from the surface of the long fiber 10 opposite to the dispersion surface of the polymer 3. The distribution of the polymer 3 in the thickness direction of the web can be changed by appropriately adjusting the degree of suction.

  Next, 2nd and 3rd embodiment of this invention is described, referring FIG.6 and FIG.7. Regarding the points that are not particularly described with respect to these embodiments, the description regarding the above-described embodiments is appropriately applied. 6 and 7, the same members as those in FIGS. 1 to 5 are denoted by the same reference numerals.

  In the absorbent body 1 according to the embodiment shown in FIG. 6, a short fiber stack 4 is laminated on the lower side of the web 2. The short fiber stacking layer 4 may or may not contain a superabsorbent polymer. By disposing the short fiber stack layer 4 on the lower side of the web 2, the stack fiber layer 4 acts as a primary stock layer of the excreted liquid. Even when excreted, it is possible to effectively prevent liquid leakage. From the viewpoint of making this effect more prominent, the superabsorbent polymer embedded and supported in the web 2 is biased and supported on the back sheet facing surface side of the web 2 as shown in FIG. It is preferable. Further, in addition to containing the superabsorbent polymer in the web 2, the liquid leakage effect becomes more remarkable by containing the superabsorbent polymer in the fiber stack layer 4 of the pulp.

  As the fibers contained in the short fiber stacking layer 4, natural pulp such as wood pulp, hydrophilic fibers such as rayon and cotton, and synthetic pulp made of synthetic resin such as polyethylene and polypropylene can be used. Either natural pulp or synthetic pulp may be used, or both may be used. Since natural pulp is generally a material having high liquid absorption and diffusibility, the liquid absorption capacity of the absorbent body 1 can be increased by using natural pulp. On the other hand, since synthetic pulp has a property of melting when heated to a predetermined temperature, the strength of the absorbent body as a whole can be obtained by melting the synthetic fiber by heating the fiber stack 4 or the absorbent body 1 including the synthetic pulp. Can be increased. The short fiber stacking layer 4 is obtained by depositing the short fibers, or is made of a nonwoven fabric. When the laminated fiber layer 4 consists of a nonwoven fabric, as this nonwoven fabric, an air through nonwoven fabric, a chemical bond nonwoven fabric, a needle punch nonwoven fabric, and an airlaid nonwoven fabric can be used, for example. When natural pulp is used as the short fiber, the short fiber stacking layer 4 is mainly formed by depositing pulp fibers. On the other hand, when synthetic pulp is used as the short fiber, the pulp stacking layer 4 is mainly composed of a nonwoven fabric such as an airlaid nonwoven fabric.

  In addition to the above-described pulp fibers, the short fiber stack 4 includes natural or (semi) synthetic hydrophilic fibers such as rayon, cotton, lyocell, tencel, acetate, polyvinyl alcohol fiber, and acrylic. May be.

  In the absorbent body 1 according to the embodiment shown in FIG. 7, the web 2 including the superabsorbent polymer 3 is covered with the fiber sheet 5. In the present embodiment, one fiber sheet 5 is used. The fiber sheet 5 covers the upper surface and both left and right side surfaces of the web 2. Furthermore, the left and right side portions of the fiber sheet 5 are wound around the lower surface side of the web 2 and overlap at the center portion in the width direction on the lower surface of the web 2. Thus, the lower surface of the web 2 is also covered with the fiber sheet 5.

  By covering the web 2 containing the superabsorbent polymer 3 with the fiber sheet 5, extreme movement and dropping off of the superabsorbent polymer 3 contained in the web 2 can be effectively prevented. Furthermore, since the handling property as the whole absorber 1 becomes favorable, it can be easily conveyed by itself. Moreover, since it can be easily cut or cut into a desired shape, an absorbent body corresponding to the shape of the absorbent article can be easily produced.

  As the fiber sheet 5, a material having a strength sufficient to prevent the superabsorbent polymer from falling off and that does not hinder the permeation of excreted liquid is appropriately used. For example, tissue paper or a non-woven fabric having liquid permeability can be used. The nonwoven fabric may be subjected to a hydrophilic treatment or a hole opening treatment as necessary. Further, a slit may be formed. Alternatively, the fiber sheet 5 may be embossed and the sheet 5 may be softened. When using a nonwoven fabric as the fiber sheet 5, the nonwoven fabric is made of, for example, a fiber using a thermoplastic resin such as polyethylene, polypropylene, polyethylene terephthalate alone, or a composite fiber using these resins. Can be used. Examples thereof include a thermal bond nonwoven fabric, a spunbond nonwoven fabric, a spunbond-meltblown-spunbond nonwoven fabric, a spunbond-meltblown-meltblown-spunbond nonwoven fabric, a needle punched nonwoven fabric, a spunlace nonwoven fabric, and an airlaid nonwoven fabric. In these non-woven fabrics, hydrophilic fibers such as rayon, cotton, lyocell, tencel, acetate, and natural pulp can be coexisted.

  As mentioned above, although this invention was demonstrated based on the preferable embodiment, this invention is not restrict | limited to the said embodiment. For example, you may coat | cover the absorber which concerns on embodiment shown in FIG. 6 with a fiber sheet like the absorber which concerns on embodiment shown in FIG.

  Hereinafter, the present invention will be described in more detail with reference to examples. However, the scope of the present invention is not limited to such examples.

[Example 1]
First, an acetate long fiber tow having crimps was prepared. The fiber diameter of this long fiber was 2.1 dtex, and the total fiber amount of tow was 25,000 dtex. The tow was conveyed under elongation and opened using an air opening device to obtain a spread web. Next, the web was wound through a spread web between a roll in which a large number of disks were incorporated around the axis at predetermined intervals and a smooth receiving roll. Thereafter, the web was adjusted to a width of 100 mm, transferred to a vacuum conveyor in a state where the conveyance speed was reduced, and the web tension on the vacuum conveyor was relaxed to develop crimps. By this operation, a high fiber amount region and a low fiber amount region were formed in the long fiber web. In addition, an appropriate distance between the long fibers and the length of the long fibers for supporting the superabsorbent polymer in the long fiber web and the thickness of the web were developed. The crimp rate of the long fibers in the web was 30%, the number of crimps per cm was 15, and the average basis weight was 26 g / m ² . A superabsorbent polymer was sprayed on the web, and the superabsorbent polymer was buried and supported in the spread web. The basis weight of the superabsorbent polymer was 260 g / m ² . The resulting web, wrapped in tissue paper having a basis weight of 16g / m ² was spray coated with a hot melt adhesive 5 g / m ^2, to obtain an absorbent.

An air-through nonwoven fabric having a basis weight of 25 g / m ² was used as the surface sheet. The air-through nonwoven fabric was composed of a core-sheath type composite fiber (thickness: 2.1 dtex, surface treatment with a surfactant and liquid permeability) having a core made of polypropylene and a sheath made of linear low density polyethylene. A porous film having a basis weight of 20 g / m ² as a backsheet, used was composite by bonding a polypropylene spunbond nonwoven fabric having a basis weight of 20 g / m ² hot melt 1.5 g / m ^2. The porous film is obtained by uniformly molding 100 parts by weight of a linear low density polyethylene resin having a density of 0.925 g / cm ³ , 150 parts by weight of calcium carbonate, and 4 parts by weight of an ester compound as a third component. The film was uniaxially stretched twice in the longitudinal direction. Otherwise, a disposable diaper was obtained in accordance with a normal disposable diaper manufacturing method. The absorber was arranged so that the orientation direction of the web coincided with the longitudinal direction of the diaper.

[Example 2]
Except that the amount of the superabsorbent polymer sprayed was 110 g / m ^{2 in} Example 1, the particles having the high fiber amount region and the low fiber amount region and having the high fiber amount region were opened. A web embedded and supported in the web was obtained. A laminate was obtained by laminating a mixture of fluff pulp and superabsorbent polymer on the web. This mixture has a total basis weight of 300 g / m ² obtained by uniformly mixing 100 parts by weight of the opened fluff pulp and 100 parts by weight of the superabsorbent polymer in an air stream. The basis weights of fluff pulp and superabsorbent polymer in the mixture were 150 g / m ² , respectively. The laminate was wrapped with a hydrophilically treated spunbond-meltblown-spunbond nonwoven fabric (SMS) having a basis weight of 16 g / m ² to obtain an absorbent body. Other than that was carried out similarly to Example 1, and obtained the disposable diaper.

Example 3
In Example 2, the fiber diameter of the long fibers is 6.7 dtex, the total fiber amount of the tow is 17,000 dtex, the crimp rate of the long fibers in the web is 24%, the number of crimps per cm is 10, A laminate was obtained in the same manner as in Example 2 except that the average basis weight of the web was 30 g / m ² . Other than that was carried out similarly to Example 2, and obtained the disposable diaper.

[Comparative Example 1]
100 parts by weight of the opened fluff pulp and 100 parts by weight of the superabsorbent polymer were uniformly mixed in an air stream to obtain a mixture having a total basis weight of 520 g / m ² . The basis weights of the fluff pulp and the superabsorbent polymer were 260 g / m ² , respectively. The obtained mixture was wrapped with a tissue paper having a basis weight of 16 g / m ² to obtain an absorbent. Between the mixture and tissue paper, 5 g / m ² of hot melt pressure-sensitive adhesive was spray-coated and adhered. Except these, it carried out similarly to Example 1, and obtained the disposable diaper.

[Comparative Example 2]
On the skin side of the fluff pulp / superabsorbent polymer mixture produced in Comparative Example 1, an air-through nonwoven fabric having a basis weight of 30 g / m ² (core-sheath type composite fiber having a core made of polypropylene and a sheath made of linear low-density polyethylene, A disposable diaper was obtained in the same manner as in Example 1 except that a thickness of 5.6 dtex and a hydrophilic treatment with a surfactant was laminated.

[Performance evaluation]
About the absorber in the diaper obtained by the Example and the comparative example, the absorption capacity, the structural stability, and the softness | flexibility were evaluated with the following method. Moreover, the dry feeling after liquid absorption was evaluated about the diaper. The results are shown in Table 1 below.

[Absorption capacity]
The obtained absorbent body is fixed to a 45 ° inclined plate, and 40 g of physiological saline is repeatedly injected into the position 200 mm from the upper end of the absorbent body at intervals of 5 minutes. The injection amount from the end to the leakage was compared. The relative value when the absorption capacity of Comparative Example 1 was 1.0 was calculated using the following formula.
Absorption capacity (relative value) = (absorption capacity of sample) / (absorption capacity of comparative example 1)

[Structural stability]
(1) At the time of drying The center part of the absorber produced to 100x200 mm was cut | disconnected, and the absorber of 100x100 mm was obtained. The amount of polymer dropped from the cut surface was measured when the vibration was applied 20 times at a speed of 1 cm / second with an amplitude of 5 cm with the cut surface directly below. The embedding supportability of the superabsorbent polymer was evaluated according to the following criteria.
Of the mixed superabsorbent polymers,
○: The ratio of the superabsorbent polymer that has dropped off is 10% or less.
(Triangle | delta): The quantity of the superabsorbent polymer which dropped out exceeds 10% and is 25% or less.
X: The amount of the superabsorbent polymer dropped off exceeds 25%.
(2) When wet The surface of the absorber cut to 100 × 200 mm was almost uniformly absorbed with 200 g of physiological saline, and then it was visually determined whether the absorber would not be destroyed when the absorber was gently lifted. Also, the weight of the dropped superabsorbent polymer was measured, and the weight of the dropped superabsorbent polymer when dried was divided by the centrifugal retention per unit weight of the dropped superabsorbent polymer measured separately. calculate. Furthermore, the ratio of the superabsorbent polymer dropped off from the relationship with the blending amount of the superabsorbent polymer is calculated. The amount of the superabsorbent polymer blended was determined by immersing the absorbent to be analyzed in advance in an ascorbic acid aqueous solution and exposing it to sunlight for a sufficient amount of time to completely decompose the superabsorbent polymer. Let Washing with water and decomposition are repeated, the superabsorbent polymer is completely dissolved and then dried, and the blending amount of the superabsorbent polymer can be estimated from the difference in the weight of the absorber before the decomposition.
○: The ratio of the superabsorbent polymer dropped off is 10% or less, and the absorber is not destroyed.
(Triangle | delta): The ratio of the superabsorbent polymer which dropped out exceeds 10% and is 25% or less, and there is no destruction of an absorber.
X: The ratio of the superabsorbent polymer dropped off exceeds 25%, or the absorber is destroyed.

[Flexibility]
The flexibility of the absorber was evaluated using a handleometer. The measured value of the handleometer indicates that the smaller the value, the better the ease of wearing and the better the fit. The measurement method using the handle-o-meter is as follows. Measurement is performed according to JIS L1096 (flexibility measurement method). An absorbent body cut by 150 mm in the longitudinal direction and 50 mm in the width direction is arranged in a direction orthogonal to the groove on a support base in which a groove having a width of 60 mm is carved. The force required when the center of the absorber is pushed by a blade having a thickness of 2 mm is measured. The apparatus used in the present invention is a texture testing machine (handle-of-meter method), HOM-3 type, manufactured by Daiei Kagaku Seiki Seisakusho. The average value of the three points is taken as the measured value. Based on the measured values obtained, the flexibility was evaluated according to the following criteria.
○: The measured value of the handle-o-meter is 2N or less.
(Triangle | delta): The measured value of a handle ohm meter exceeds 2N and is 4N or less.
X: The measured value of the handle o meter exceeds 4N.

[Dry feeling]
In the obtained diaper, 40 g of colored physiological saline (coloring was adjusted by dissolving Red No. 1 at a concentration of 0.05%) was injected three times at 5-minute intervals. Ten mothers visually observed the surface condition after absorption and heard the impression. The dry feeling was determined based on Example 1. Further, the amount of liquid remaining on the top sheet was measured. First, the surface sheet of the diaper whose impression was heard was peeled off and the weight was measured (W1). Thereafter, the liquid remaining on the surface sheet was completely wiped off with tissue paper, and the weight of the dried surface sheet was measured (W2). The remaining liquid amount was calculated according to the following formula.
Liquid remaining amount (g) = W1-W2
Based on the mother's impression and the amount of liquid remaining, the dry feeling of diapers was judged according to the following criteria.
○: Six or more mothers answered that they had a dry feeling, and the remaining liquid was 0.3 g or less.
(Triangle | delta): The mother who answered that there is a dry feeling does not reach a majority, or a liquid residue exceeds 0.3g.
X: More than half of the mothers answered that there was no dry feeling, and the remaining liquid exceeded 0.3 g.

  As is clear from the results shown in Table 1, the absorbent capacity of each example is thinner than the absorbent body of the comparative example, but the absorption capacity and the structural stability are the same level as the absorbent body of the comparative example. I understand. Moreover, it turns out that the absorber of each Example is more flexible than the absorber of a comparative example. Furthermore, it turns out that the diaper of each Example has a dry feeling higher than the diaper of a comparative example.

Example 4
In this example, the relationship between the crimp rate of the long fiber web and the loading rate of the superabsorbent polymer was examined. The fiber diameter of this long fiber was 2.1 dtex. This long fiber tow was conveyed under elongation and opened using an air opening device to obtain a spread web. Next, the web was wound through a spread web between a roll in which a large number of disks were incorporated around the axis at predetermined intervals and a smooth receiving roll. Thereafter, the web was adjusted to a width of 100 mm, transferred to a vacuum conveyor in a state where the conveyance speed was reduced, and the web tension on the vacuum conveyor was relaxed to develop crimps. The tension of the web was controlled to prepare a web of acetate long fibers having various crimp rates. As a result, the space between the long fibers was widened to facilitate the entry of the superabsorbent polymer, and the web was thickened to improve the embedding supportability of the superabsorbent polymer. A superabsorbent polymer was sprayed on the web, and the superabsorbent polymer was buried and supported in the spread web. The basis weight of the web was 26 g / m ² . The spreading basis weight of the polymer was 260 g / m ² . As the polymer, a bulk type having an average particle size of 330 μm was used. The above-described structural stability (when dry) test was performed on the absorbent body thus obtained. The weight of the superabsorbent polymer supported on the web after the test is divided by the weight of the superabsorbent polymer blended in the web before the test and multiplied by 100, and the obtained value is multiplied by the superabsorbent polymer. The loading ratio (%). The results are shown in Table 2.

It is a mimetic diagram showing one embodiment of an absorber in an absorptive article of the present invention. It is a figure explaining the absorption mechanism of the liquid by the absorber shown in FIG. It is a schematic diagram which shows the structure of the cross section in the width direction in one Embodiment of the absorbent article of this invention. It is a schematic diagram (figure 3 equivalent figure) which shows the structure of the cross section of the width direction in other embodiment of the absorbent article of this invention. It is a schematic diagram which shows the apparatus preferably used in order to manufacture the absorber shown in FIG. It is a schematic diagram (figure 1 equivalent view) which shows other embodiment of the absorber in the absorbent article of this invention. It is a schematic diagram (figure 1 equivalent view) which shows other embodiment of the absorber in the absorbent article of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Absorbent body 2 Web 2a High fiber amount area | region 2b Low fiber amount area | region 3 High absorbent polymer 4 Pulp fiber layer 5 Fiber sheet

Claims (6)

An absorbent article comprising a web comprising crimped long fibers oriented in one direction and a superabsorbent polymer embedded and supported in the web,
The web has a high fiber amount region and a low fiber amount region respectively extending in the orientation direction of the long fibers, and these regions are alternately arranged in parallel in a direction perpendicular to the orientation direction of the long fibers. Absorbent article.   The absorbent article according to claim 1, wherein the basis weight of the superabsorbent polymer is substantially uniform in a direction orthogonal to the orientation direction of the long fibers.   The absorbent article according to claim 1 or 2, wherein the superabsorbent polymer is biased and buried in the web on the non-skin facing side of the web.   The absorbent article according to any one of claims 1 to 3, wherein the continuous fibers have a crimp rate of 10 to 90%.   The absorbent article according to any one of claims 1 to 4, wherein the absorbent body has a structure in which the web is overlaid on a fiber stack layer of a pulp containing or not containing a superabsorbent polymer. The absorbent article according to any one of claims 1 to 5, wherein the web is coated with a sheet of fiber material.

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