JP3252646B2 - Sinter production method - Google Patents
Sinter production methodInfo
- Publication number
- JP3252646B2 JP3252646B2 JP08563495A JP8563495A JP3252646B2 JP 3252646 B2 JP3252646 B2 JP 3252646B2 JP 08563495 A JP08563495 A JP 08563495A JP 8563495 A JP8563495 A JP 8563495A JP 3252646 B2 JP3252646 B2 JP 3252646B2
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- particles
- raw material
- mixer
- granulation
- pseudo
- Prior art date
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Description
【0001】[0001]
【産業上の利用分野】この発明は、良好な高温性状を有
する低SiO2 濃度の焼結鉱を高い歩留で製造できる焼結
鉱の製造方法に関する。この方法で製造される焼結鉱
は、焼結鉱の配合比率を高める高炉操業に好適である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a sintered ore having good high-temperature properties and a low SiO 2 concentration at a high yield. The sintered ore produced by this method is suitable for blast furnace operation in which the mixing ratio of the sintered ore is increased.
【0002】[0002]
【従来の技術】高炉に装入される焼結鉱の一般的な製造
工程は次のとおりである。即ち、まず鉄鉱石、粉コーク
ス、石灰石等の焼結原料に対し、混合造粒機内で適量の
水分を添加しつつ造粒する。こうして擬似粒子化された
焼結原料を焼結機のパレットに装入する。そして、焼結
原料充填層の上部から下部に向かって空気を吸引しつ
つ、充填層の上部に点火し、原料中の粉コークスを上部
から順次燃焼させて焼結原料を焼成する。焼成後はパレ
ットを傾転して焼成物(焼結ケーキと称する)を取り出
し、破砕、冷却した後、一定粒度以上の焼結鉱を高炉原
料として供する。一定粒度未満の焼成物は返鉱として再
び焼結原料に戻される。2. Description of the Related Art A general process for producing a sintered ore charged into a blast furnace is as follows. That is, first, a raw material such as iron ore, fine coke, and limestone is granulated while adding an appropriate amount of water in a mixing granulator. Thus charged sintering material which is pseudo particles of the pallet of the sintering machine. Then, while sucking air from the upper part to the lower part of the sintering raw material packed layer, the upper part of the packed bed is ignited, and the coke breeze in the raw material is sequentially burned from the upper part to burn the sintering raw material. After firing, the pallet is tilted to take out a fired product (called a sintered cake), crushed and cooled, and thereafter, a sintered ore having a predetermined grain size or more is provided as a blast furnace raw material. A fired product having a particle size smaller than a certain particle size is returned to the sintering raw material as returned ore.
【0003】近年、良質の塊鉱石が枯渇してきたため、
高炉装入原料に占める焼結鉱の比率(以下、「焼結比」
と言う)を高める操業方法が一般的になってきた。従来
の焼結鉱は主なスラグ成分としてSiO2 成分を 5.4質量
%前後、MgO 成分を 0.5質量%程度含有し、そのSiO2
濃度に応じて、CaO/SiO2 比が 1.6〜2 程度の一定値に
なるように高炉装入原料の配合を調整している。従っ
て、焼結鉱のSiO2 濃度を一定にしたまま焼結比を上昇
させると、CaO/SiO2 比を一定にするための CaO源の装
入量を多くしなければならず、単位出銑量当りの高炉ス
ラグ量(高炉スラグ比)の上昇、それに伴う単位出銑量
当りの燃料量(燃料比)の増加を招く。このような高炉
操業におよぼす悪影響を回避するために、SiO2 濃度が
低い焼結鉱が必要となる。In recent years, high quality lump ore has been depleted,
Ratio of sinter ore to blast furnace charge (hereinafter “sintering ratio”
Operating methods have been becoming more common. Conventional baked ore 5.4 wt% or so of the SiO 2 component as the main slag component, the MgO component containing about 0.5 wt%, the SiO 2
According to the concentration, the blending of the blast furnace raw material is adjusted so that the CaO / SiO 2 ratio becomes a constant value of about 1.6 to 2 . Therefore, if the sintering ratio is increased while the SiO 2 concentration of the sinter is kept constant, the amount of CaO source charged to keep the CaO / SiO 2 ratio must be increased, and the unit The blast furnace slag amount per unit amount (blast furnace slag ratio) increases, and the fuel amount per unit tapping amount (fuel ratio) increases accordingly. In order to avoid such adverse effects on the blast furnace operation, a sintered ore having a low SiO 2 concentration is required.
【0004】従来、低SiO2 焼結鉱は、SiO2 系副原料で
ある蛇紋岩の配合量を低減する方法と脈石成分の少ない
高品位鉄鉱石を用いる方法によって製造されていた。し
かし、蛇紋岩の配合量を低減する方法は、蛇紋岩が MgO
・SiO2 系副原料であるため、その配合量低減により焼
結鉱の MgO濃度も同時に低下する。このため、焼結鉱の
歩留低下、焼結鉱の高温性状の悪化による高炉内通気抵
抗の増加、さらにはスラグ粘度の増加による出滓作業の
支障などの問題が生じていた。また、高品位鉄鉱石を用
いる方法には原料コストの高騰が避けられないという欠
点がある。[0004] Conventionally, low SiO 2 sintered ore has been produced by a method of reducing the amount of serpentinite, which is an SiO 2 -based auxiliary material, and a method of using high-grade iron ore having a small gangue component. However, the only way to reduce the amount of serpentine is to use
・ Since it is an SiO 2 -based auxiliary material, the MgO concentration of the sintered ore decreases at the same time due to the reduction of the blending amount. For this reason, there have been problems such as a decrease in the yield of the sintered ore, an increase in the ventilation resistance in the blast furnace due to the deterioration of the high-temperature properties of the sintered ore, and a hindrance to the slagging operation due to an increase in the viscosity of the slag. In addition, the method using high-grade iron ore has a disadvantage that a rise in raw material costs is inevitable.
【0005】そこで、MgO 系副原料に MgO・SiO2 系副
原料である蛇紋岩だけを用いるのではなく、 MgO・CaO
系副原料である生ドロマイト、軽焼ドロマイトをも使用
し、焼結鉱の MgO濃度が 2〜4 質量%、SiO2 濃度が 5
〜6.5 質量%となるように調整して焼結鉱を製造する方
法が「特開昭53-30403号公報」に開示されている。ま
た、「特開昭58-39746号公報」と「特開昭58-39747号公
報」にはSiO2 系副原料を全く使用せず、 MgO・CaO 系
副原料を 2mmの分級点で篩分けした後、篩下を 0.5mm未
満に破砕し、SiO2 濃度が 4.6〜5.4 質量%の焼結鉱を
製造する方法が示されている。さらに「特開平2-170926
号公報」には、円柱形ロッドを内蔵したドラム型振動混
練機を使用し、軽焼ドロマイトを含む焼結原料の破砕と
混合を1台の装置によって行い、焼結鉱を製造する方法
が提案されている。Therefore, instead of using only the MgO.SiO 2 -based auxiliary material serpentine as the MgO-based auxiliary material, MgO.CaO
Raw dolomite is a system auxiliary material, also uses dolomitic, MgO concentration of sintered ore is 2-4% by weight, SiO 2 concentration of 5
Japanese Patent Application Laid-Open No. 53-30403 discloses a method for producing a sintered ore by adjusting the content to 6.5% by mass . Also, "JP 58-39746 discloses" and to "JP 58-39747 discloses" is not used at all the SiO 2 based auxiliary raw material, sieved MgO · CaO-based auxiliary raw material in classification point of 2mm After that, a method of producing a sintered ore having a SiO 2 concentration of 4.6 to 5.4 mass % by crushing the under sieve to less than 0.5 mm is disclosed. Further, `` Japanese Patent Laid-Open No. 2-170926
Publication No. 1) proposes a method of producing a sintered ore by using a drum-type vibrating kneader with a built-in cylindrical rod, and crushing and mixing sintering raw materials including light-burned dolomite with one device. Have been.
【0006】しかしながら、「特開昭53-30403号公報」
の方法で得られる焼結鉱成品はSiO2濃度が 5〜6.5 質量
%と高く、高炉における焼結比を高めることが困難であ
り、「特開昭58-39746号公報」と「特開昭58-39747号公
報」に開示の方法では原料を破砕する装置が別途必要と
なりコストの上昇が避けられない。そして、「特開平2-
170926号公報」の方法では粗粒の鉄鉱石までも破砕して
しまい、造粒過程で核粒子となる粗粒鉄鉱石の粒径低下
による造粒困難を招き、造粒後の焼結原料の粒径が低下
する。この造粒後の粒径低下は焼結パレット上の焼結原
料充填層の通気性を悪化させるため、焼結生産性が低下
し、生産性を確保しようとすると歩留低下が避けられな
い。However, Japanese Unexamined Patent Publication No. Sho 53-30403 discloses
The sintered mineral products obtained by the method described in (1) have a high SiO 2 concentration of 5 to 6.5% by mass, and it is difficult to increase the sintering ratio in a blast furnace. In the method disclosed in Japanese Patent Application Laid-Open No. 58-39747, an apparatus for crushing the raw material is separately required, and an increase in cost cannot be avoided. And, "Japanese Patent Laid-Open No. 2-
In the method of Japanese Patent No. 170926, even coarse iron ore is crushed, causing difficulty in granulation due to a decrease in the particle size of coarse iron ore that becomes core particles in the granulation process, and Particle size decreases. This reduction in particle size after granulation deteriorates the gas permeability of the sintering raw material-packed layer on the sintering pallet, so that the sintering productivity is reduced, and a reduction in yield is inevitable in order to ensure productivity.
【0007】[0007]
【発明が解決しようとする課題】前述のように、 MgO・
SiO2 系副原料である蛇紋岩の配合量だけを低減して製
造した低SiO2 焼結鉱は、焼結鉱成品の歩留低下、高炉
炉内での高温性状の悪化、さらに高炉スラグ粘度の増加
を招く欠点を有している。一方、 MgO・CaO 系副原料で
あるドロマイトと軽焼ドロマイトのいずれか一方または
両方を使用する方法では、原料混合の造粒時にドロマイ
トあるいは軽焼ドロマイトは分散性が悪いため、焼結鉱
中に未反応のまま MgO・CaO 系副原料が残留し、歩留お
よび高温性状の低下を招く。これを防止するには MgO・
CaO 系副原料の分散性を高める必要があるが、事前に篩
分けを行い篩下を 0.5mm未満まで破砕するというような
方法では原料を破砕する装置が別途必要でありコスト上
昇を招いてしまう。また、円柱形のロッドを内蔵したド
ラム型振動混練機を使用する方法は、粗粒の鉄鉱石まで
も破砕してしまい、結果として歩留の低下を引き起こす
欠点を有している。As described above, MgO.
Low SiO 2 sintered ore produced by reducing only the amount of serpentine, which is an SiO 2 auxiliary material, reduces the yield of sintered mineral products, deteriorates high-temperature properties in the blast furnace, and further increases the viscosity of the blast furnace slag. Has the drawback of causing an increase in On the other hand, in the method using either or both of dolomite and lightly fired dolomite, which are MgO / CaO-based auxiliary materials, dolomite or lightly fired dolomite has poor dispersibility during granulation of the raw material mixture, so MgO / CaO-based auxiliary raw materials remain unreacted, leading to a decrease in yield and high-temperature properties. To prevent this, MgO
Although it is necessary to enhance the dispersibility of CaO-based auxiliary materials, a method of sieving in advance and crushing under the sieve to less than 0.5 mm requires a separate device for crushing the raw materials, resulting in increased costs. . Further, the method using a drum-type vibrating kneader having a built-in cylindrical rod has the disadvantage that even coarse iron ore is crushed, resulting in a decrease in yield.
【0008】本発明の目的は、焼結原料中でのドロマイ
トあるいは軽焼ドロマイトの分散性を高め、しかも鉄鉱
石の過粉砕を防止して適正擬似粒子を形成させることに
より、高炉炉内での高温性状が良好であり、かつ高炉内
で生成するスラグ粘度を低くすることができる低SiO2
焼結鉱を高い歩留で製造する方法を提供することにあ
る。[0008] An object of the present invention is to improve the dispersibility of dolomite or lightly burned dolomite in a sintering raw material and prevent over-milling of iron ore so as to form appropriate pseudo-particles, thereby making it possible to form appropriate pseudo particles. Low SiO 2 with good high temperature properties and low slag viscosity generated in blast furnace
An object of the present invention is to provide a method for producing a sintered ore at a high yield.
【0009】[0009]
【課題を解決するための手段】本発明の要旨は、下記の
焼結鉱の製造方法にある。The gist of the present invention resides in the following method for producing a sintered ore.
【0010】『成品中のSiO2 濃度が 4.0〜4.8 質量%
で MgO濃度が 0.6質量%を超える焼結鉱を製造する方法
であって、ドロマイトと軽焼ドロマイトのいずれか一方
または両方を含む焼結原料を攪拌羽根を内蔵した混合機
で毎分 100〜 500回( 100〜500rpm )の回転速度で高
速攪拌混合した後に、上記混合原料を全使用原料の少な
くとも一部として使用することを特徴とする焼結鉱の製
造方法。』上記の攪拌羽根を内蔵した混合機で混合する
焼結原料は、粒径が 0.5mm以下の部分が30質量%以上(1
00%でもよい) が望ましい。[The SiO 2 concentration in the product is 4.0 to 4.8% by mass .
Is a method of producing a sintered ore having an MgO concentration of more than 0.6% by mass, wherein a sintering raw material containing one or both of dolomite and lightly burned dolomite is mixed at a rate of 100 to 500 / min with a mixer having a built-in stirring blade. A method for producing sinter, characterized in that the mixed raw material is used as at least a part of all raw materials after high-speed stirring and mixing at a rotation speed of 100 to 500 rpm . ] In the sintering raw materials mixed by the above-mentioned mixer with a built-in stirring blade, the part having a particle size of 0.5 mm or less is 30% by mass or more (1
00%).
【0011】本発明方法において使用する攪拌羽根を内
蔵した混合機とは、円筒形パン内に攪拌を目的とする羽
根が設置され、パンと羽根の双方が回転運動する混合機
であり、代表例としてはアイリッヒミキサー(商品名)
と呼ばれるものがある。このタイプの混合機は羽根の回
転速度が毎分1回(1rpm)以上で、圧密作用がないため
に十分な均一混合が可能である。従って、この型の混合
機で攪拌混合を行えば、焼結原料中においてドロマイト
および/または軽焼ドロマイトの分散性を改善し、焼結
後の成品に未反応のまま残留する MgO・CaO 系副原料を
低減することができる。A mixer having a built-in stirring blade used in the method of the present invention is a mixer in which a blade for stirring is installed in a cylindrical pan and both the pan and the blade rotate. As Eirich mixer (trade name)
There is something called. This type of mixer has a blade rotation speed of at least once per minute (1 rpm) or more, and does not have a compaction action, so that sufficient uniform mixing is possible. Therefore, by performing stirring and mixing with this type of mixer, the dispersibility of dolomite and / or lightly fired dolomite in the sintering raw material is improved, and the MgO / CaO-based auxiliary remaining unreacted in the sintered product is improved. Raw materials can be reduced.
【0012】上記のような攪拌羽根を内蔵した混合機で
焼結原料を混合した後に、更に転動型造粒機を使用して
造粒を行ってもよい。After mixing the sintering raw materials with the mixer having the stirring blades as described above, granulation may be further performed using a rolling granulator.
【0013】本発明方法において焼結鉱成品中のSiO2
濃度を 4.0〜4.8 質量%としたのは、SiO2 濃度が 4.0
質量%未満ではSiO2 濃度が低すぎ、焼結化反応におい
て十分な量の融液生成が見込めないためである。一方、
SiO2 濃度が 4.8質量%を超える焼結鉱ではSiO2 濃度の
低い焼結鉱とはいえず、この焼結鉱を大量に高炉に装入
した場合、高炉スラグ比が上昇し高炉操業に支障をきた
してしまう。また、焼結鉱成品中のMgO 濃度を 0.6質量
%を超えることとしたのは、MgO 濃度が 0.6質量%以下
の低SiO2 焼結鉱では、高炉炉内での高温性状の悪化と
高炉内で生成するスラグ粘度の増加を招くからである。
この MgO濃度の上限は、高炉スラグ量の上昇を抑えるた
めに3質量%程度が適当である。[0013] In the method of the present invention, SiO 2 in the sintered mineralized product
The concentration is used as a 4.0-4.8% by mass, SiO 2 concentration of 4.0
Is less than mass% SiO 2 concentration is too low, because that are not expected to be a sufficient amount of melt produced in the baked Yuika reaction. on the other hand,
The sintered ore that SiO 2 concentration exceeds 4.8 wt% not be said to be low sinter the SiO 2 concentration, when charged with the sintered ore in large quantities blast furnace, it hinders the blast furnace operation blast furnace slag ratio increased Will cause. In addition, the reason why the MgO concentration in the sintered ore was set to exceed 0.6% by mass was that, for low SiO 2 sintered ore with a MgO concentration of 0.6% by mass or less, deterioration of high-temperature properties in the blast furnace and blast furnace This leads to an increase in the viscosity of the slag generated in the above.
The upper limit of the MgO concentration is appropriately about 3% by mass in order to suppress an increase in the amount of blast furnace slag.
【0014】本発明方法において、粒子の大きさを表す
「mm」は、篩目の代表径を意味し、例えば粒径 0.5mm以
下の粒子とは篩目が 0.5mmの篩の篩下を、また、粒径 2
〜1mmの粒子とは篩目が 2mmの篩の篩下であって、1 mm
の篩上に残る粒子を意味する。また、前記の「粒径0.5
mm以下の粒子を30質量%以上含み」とは、原料を配合し
た時点で、その原料中に粒径 0.5mm以下の粒子が30質量
%以上含まれていることを意味する。In the method of the present invention, “mm” representing the size of a particle means a representative diameter of a sieve, for example, particles having a particle diameter of 0.5 mm or less are measured under a sieve having a sieve of 0.5 mm. In addition, particle size 2
Particles of ~ 1 mm are under a 2 mm sieve and 1 mm
Means particles remaining on the sieve. In addition, the aforementioned “particle size 0.5
The mm particles below contains more than 30 wt% ", when blended with the raw material, which means that the particle size 0.5mm or smaller particles are contained more than 30 wt% in its raw material.
【0015】[0015]
【作用】以下、本発明方法について詳細に説明する。な
お、「%」は「質量%」を意味する。Hereinafter, the method of the present invention will be described in detail. In addition, "%" means "% by mass ".
【0016】図1は、装入原料の全部を本発明方法で処
理する一例の概略工程図で、1は焼結原料(副原料を含
む)を容れた原料槽、2は原料槽1から所定の配合にな
るように切り出された粉鉄鉱石、粉コークス、石灰石、
ドロマイト、軽焼ドロマイト等に水分を添加して、原料
を混合、造粒するアイリッヒミキサーである。FIG. 1 is a schematic process diagram of an example in which all of the charged raw materials are treated by the method of the present invention. Reference numeral 1 denotes a raw material tank containing sintering raw materials (including auxiliary raw materials); Iron ore, coke breeze, limestone,
It is an Erich mixer that mixes and granulates raw materials by adding water to dolomite, lightly-burned dolomite, and the like.
【0017】図2は、装入原料の全部を本発明方法で処
理する他の例の概略工程図で、図1に示したアイリッヒ
ミキサー2の後段でドラムミキサー3を使用する例であ
る。FIG. 2 is a schematic process diagram of another example of treating the whole charged material by the method of the present invention, in which a drum mixer 3 is used at a stage subsequent to the Eirich mixer 2 shown in FIG.
【0018】図3は、装入原料の一部を本発明方法で処
理する一例の概略工程図で、原料槽1から切り出された
A系焼結原料(装入原料の一部で MgO・CaO 系副原料を
一括混合した原料)は、アイリッヒミキサー2、次いで
ドラムミキサー3Aを通過して混合、造粒される(図2の
本発明方法の工程)。一方、B系焼結原料(装入原料の
残部)は、水分を添加して別に設けたドラムミキサー3
B内で混合、造粒される。そして、A系およびB系焼結
原料の混合・造粒物は、混合されて焼結パレットへ装入
される。FIG. 3 is a schematic process diagram of an example of treating a part of the charged raw material by the method of the present invention. The A-based sintered raw material cut out from the raw material tank 1 (a part of the charged raw material is MgO.CaO The raw material obtained by batch-mixing the system auxiliary raw materials) is mixed and granulated by passing through the Erich mixer 2 and then the drum mixer 3A (step of the method of the present invention in FIG. 2). On the other hand, the B-based sintering raw material (the remaining portion of the charged raw material) is obtained by adding a moisture to a separately provided drum mixer 3.
It is mixed and granulated in B. Then, the mixed and granulated materials of the A-based and B-based sintering raw materials are mixed and charged into a sintering pallet.
【0019】図4は、装入原料の一部を本発明方法で処
理する他の例の概略工程図である。FIG . 4 is a schematic flow chart of another example of treating a part of the charged material by the method of the present invention.
【0020】即ち、図2の本発明方法の工程で、A系焼
結原料を混合、造粒し、その混合・造粒物とB系焼結原
料をドラムミキサー3C内で混合、造粒して焼結パレッ
トへ装入する。That is, in the step of the method of the present invention shown in FIG. 2, the A-based sintering raw material is mixed and granulated, and the mixed and granulated material and the B-based sintering raw material are mixed and granulated in the drum mixer 3C. Into the sintering pallet.
【0021】前記の焼結原料を攪拌羽根を内蔵した混合
機(例えばアイリッヒミキサー)で攪拌混合するのは、
以下の理由によるものである。The above-mentioned sintering raw materials are stirred and mixed by a mixer (for example, an Erich mixer) having a stirring blade built therein.
This is for the following reason.
【0022】MgO・CaO 系副原料であるドロマイトある
いは軽焼ドロマイトの分散性および反応性を改善して、
未反応のまま残留する MgO・CaO 系副原料を低減すれば
焼結鉱の高温性状が改善され歩留が上がる。しかし、焼
結鉱原料の大部分を占める鉄鉱石を過度に破砕せずに、
MgO・CaO 系副原料の分散性を高める技術が知られてい
なかった。[0022] to improve the dispersibility and the reactivity of dolomite or light sintered dolomite is MgO · CaO-based auxiliary raw material,
If the unreacted MgO / CaO-based auxiliary material is reduced, the high-temperature properties of the sinter are improved and the yield increases. However, without excessively crushing iron ore, which accounts for the majority of sinter raw material,
A technique for improving the dispersibility of MgO / CaO-based auxiliary materials has not been known.
【0023】本発明者らはドロマイトと軽焼ドロマイト
のいずれか一方または両方を含み、さらに粗粒の鉄鉱石
を含む焼結原料を、過度に破砕することなく、しかもド
ロマイトあるいは軽焼ドロマイトの分散性および反応性
を向上させる方法について検討を重ねた。その結果、下
記の〜が有効であることを見いだした。The inventors of the present invention disperse a sintering raw material containing one or both of dolomite and lightly burned dolomite and further containing coarse iron ore without excessively crushing the dolomite or lightly burned dolomite. The method of improving the reactivity and reactivity was repeated. As a result, the following was found to be effective.
【0024】 ドロマイトと軽焼ドロマイトのいずれ
か一方または両方を他の焼結原料と均一に混合する。One or both of dolomite and lightly burnt dolomite are uniformly mixed with other sintering raw materials.
【0025】一般に、ドロマイトあるいは軽焼ドロマイ
トなどの MgO・CaO 系副原料は粘着性が高く分散性が悪
いため、強力な混合力を加えて混合しないと、粒子単位
まで分離することは困難である。従って、MgO 濃度が
0.6%を超えるような焼結鉱の場合、他の焼結原料との
混合が不均一になって MgO・CaO 系副原料の粒子同志が
凝集し、実質的に高 MgO・高CaO 成分の粗粒が存在する
状態と同等になり、 MgO・CaO 系副原料の反応性が低下
することになる。In general, MgO.CaO-based auxiliary materials such as dolomite and lightly burnt dolomite have high tackiness and poor dispersibility, and it is difficult to separate them into particles unless they are mixed by applying a strong mixing force. . Therefore, the MgO concentration
In the case of a sintered ore exceeding 0.6%, the mixing with other sintering raw materials becomes uneven and the particles of the MgO / CaO-based auxiliary raw material aggregate, and the coarseness of the high MgO / high CaO component is substantially increased. This is equivalent to the state in which grains are present, and the reactivity of the MgO / CaO-based auxiliary material is reduced.
【0026】 造粒後の原料(以下「擬似粒子」と言
う)における粒子間の結合力を向上させる。The bonding force between particles in the raw material after granulation (hereinafter referred to as “pseudo particles”) is improved.
【0027】粒子間の結合力の弱い擬似粒子は乾燥によ
る付着粉の剥離量が多い。これは焼結化反応時の急激昇
温(急激乾燥)により擬似粒子から付着粉が剥離するこ
とを意味し、焼結粒子同志が固相反応する際に粒子間の
接触状態の悪化を招く。この粒子間の接触状態の悪化が
ドロマイトあるいは軽焼ドロマイトの反応性を損なうこ
とになる。The pseudo particles having a weak bonding force between the particles have a large amount of peeling off of the adhered powder due to drying. This means that the adhered powder is separated from the pseudo particles due to a rapid temperature rise (rapid drying) during the sintering reaction, and the contact state between the particles is deteriorated when the sintered particles undergo a solid phase reaction. This deterioration of the contact state between the particles impairs the reactivity of dolomite or lightly burned dolomite.
【0028】 造粒の際に核粒子にも付着粉にもなら
ない、つまり造粒に関与しない粒子の存在量を減少させ
る。During granulation, the amount of particles that do not become core particles or adhered powder, that is, do not participate in granulation, is reduced.
【0029】造粒に関与しない粒子とは、主として粒径
が0.25〜2 mmの、言わば、中間粒径を有する粒子である
(製銑研究(1976)No. 288,10頁)。このような粒子は造
粒後においても他の粒子との接触状態が悪いので、当
然、反応面積が小さくなる。従って、このような粒子が
多量に存在すると反応性が低下することになる。The particles not involved in granulation are mainly particles having a particle size of 0.25 to 2 mm, that is, particles having an intermediate particle size (Italy Research (1976) No. 288, p. 10). Such particles have a poor contact state with other particles even after granulation, so that the reaction area naturally becomes small. Therefore, if such particles are present in a large amount, the reactivity will decrease.
【0030】本発明者らは、上記〜を達成する方策
について検討した結果、攪拌羽根を内蔵した混合機で焼
結原料を攪拌混合するのが有効であることを確認した。
攪拌羽根を内蔵した混合機とは、前記のように円筒形パ
ン内に羽根が設置され、パンと羽根の双方が回転運動す
るタイプの混合機で、アイリッヒミキサーが代表的なも
のであるが、ドラムミキサー内に回転する攪拌羽根を設
置した混合機も使用可能である。[0030] The present inventors have found that was investigated ways to achieve the above Symbol ~, to mixing and stirring the sintered material in a mixer with a built-in stirring blade was confirmed to be effective.
A mixer having a built-in stirring blade is a type of mixer in which the blade is installed in a cylindrical pan as described above, and both the pan and the blade rotate, and an Erich mixer is typical. Alternatively, a mixer provided with a rotating stirring blade in a drum mixer can be used.
【0031】攪拌羽根を内蔵した混合機を使用して攪拌
すると、その強力な混合力によって、粘着性が高く分散
性が悪い MgO・CaO 系副原料であっても、凝集状態から
粒子単位にまで分離されて焼結原料内に均一に混合し、
MgO・CaO 系副原料の偏在が無くなる。つまり、これに
よって前記の条件を満たすことができる。When stirring is performed using a mixer having a built-in stirring blade, the strong mixing force causes even the MgO / CaO-based auxiliary material having high tackiness and poor dispersibility to be converted from the agglomerated state to the particle unit. Separated and uniformly mixed in the sintering raw material,
The uneven distribution of MgO / CaO-based auxiliary material is eliminated. That is, the above condition can be satisfied.
【0032】攪拌羽根を内蔵した混合機の強力な混合力
によって、混合の際に添加した水分を原料全体に浸透さ
せ、焼結原料の粒子径に関係なく全ての粒子の表面にお
いて水膜が形成され、粒子の可塑性が向上する。その結
果、造粒の際に付着粉として機能する微粉の付着力が高
められて、擬似粒子を構成する粒子間の結合力が上昇す
る。これにより前記の条件も満たされる。By the strong mixing force of the mixer having a built-in stirring blade, the water added at the time of mixing permeates the entire raw material, and a water film is formed on the surface of all the particles regardless of the particle diameter of the sintering raw material. And the plasticity of the particles is improved. As a result, the adhesion of the fine powder functioning as the adhesion powder during granulation is increased, and the bonding force between the particles constituting the pseudo particles is increased. This satisfies the above condition.
【0033】また、強力な混合力により水滴が微細化さ
れ、その水滴は焼結原料の粒子表面において、水膜の形
成を容易にする。従って、通常の造粒法(例えばドラム
ミキサーの使用)では造粒に関与しにくい粒径0.25〜2
mmの粒子が可塑化されて他の粒子に付着し、造粒に関与
するようになる。これにより前記の条件も満たされ
る。Further, water droplets are made fine by strong mixing force, and the water droplets facilitate the formation of a water film on the particle surface of the sintering raw material. Therefore, a particle size of 0.25 to 2 which is hardly involved in granulation by a normal granulation method (for example, using a drum mixer).
mm particles are plasticized and adhere to other particles and become involved in granulation. This satisfies the above condition.
【0034】上記の効果が得られる強力混合力を確保す
るため、攪拌羽根の回転速度は、毎分 100回(100rpm)
以上とする。また、回転速度の上限は毎分 500回(500r
pm)とするのが適切である。なお、攪拌羽根を内蔵した
混合機は圧密作用がないため、鉄鉱石の粒子自体が破砕
されることはない。従って擬似粒子の核となる粗粒鉄鉱
石が過粉砕されて細粒化し、核粒子減少による擬似粒子
の形成不良を生ずるようなことはない。In order to secure a strong mixing force for obtaining the above effects, the rotation speed of the stirring blade is set to 100 times per minute (100 rpm).
Above. The upper limit of the rotation speed is 500 times per minute (500r
pm) is appropriate . In addition, since the mixer incorporating the stirring blade has no compaction action, the iron ore particles themselves are not crushed. Therefore, the coarse iron ore serving as the nucleus of the pseudo particles is not excessively pulverized into fine particles, and the formation of pseudo particles due to the reduction of the core particles does not occur.
【0035】なお、羽根だけでなくパン (またはドラ
ム) も回転させてよい。その回転方向や回転速度には特
に制約はない。Note that not only the blades but also the pan (or drum) may be rotated. There is no particular limitation on the rotation direction and rotation speed.
【0036】攪拌羽根を内蔵した混合機の後段に転動型
造粒機を使用する場合には、攪拌羽根を内蔵した混合機
を使用する段階において大部分の水分を添加することが
望ましい。これは強力な混合条件下で、水分を添加する
と粒子の可塑性が向上し、擬似粒子の粒子間結合力を強
める効果が得られるからである。When a tumbling type granulator is used after a mixer having a stirring blade built therein, it is desirable to add most of the water at the stage of using the mixer having the stirring blade built therein. This is because the addition of moisture under strong mixing conditions improves the plasticity of the particles and has the effect of increasing the interparticle bonding force of the pseudo particles.
【0037】上記の高速攪拌羽根を内蔵した混合機で混
合される焼結原料は、粒径0.5 mm以下の部分が30%以上
であることが望ましい。微粒子が多くなれば、前述した
ように粗粒鉄鉱石が粉砕されることなく核粒子となる粒
径のままで原料内に混合分散され、付着粉となる粒径の
粒子が多くなるので、強固な擬似粒子を安定して形成す
ることができる。このため攪拌羽根を内蔵した混合機に
よる分散および造粒の効果がさらに向上する。In the sintering raw material mixed by the mixer having the high-speed stirring blade therein, it is desirable that the portion having a particle size of 0.5 mm or less is 30% or more. As described above, the coarse iron ore is mixed and dispersed in the raw material without being crushed as described above, and the number of particles having a particle diameter serving as adhered powder increases. Quasi-particles can be formed stably. For this reason, the effect of dispersion and granulation by the mixer incorporating the stirring blade is further improved.
【0038】[0038]
【実施例1】攪拌羽根を内蔵した混合機を使用して、本
発明方法により焼結原料の造粒を行い、擬似粒子の乾燥
による崩壊の抑制効果および造粒に関与しない粒子の存
在量を減少させる効果、すなわち中間粒径粒子を造粒に
関与させる効果について調査した。Example 1 A sintering raw material was granulated by the method of the present invention using a mixer having a built-in stirring blade, and the effect of suppressing the collapse of the pseudo particles by drying and the amount of particles not involved in the granulation were determined. The effect of reducing, that is, the effect of involving intermediate-size particles in granulation was investigated.
【0039】表1に原料条件および造粒方法を示し、表
2に使用した造粒機の仕様 (運転条件) を示す。なお、
表1および後述の表における粒径を表わす−0.5 mmは、
粒径0.5 mm以下の粒子を意味する。Table 1 shows the raw material conditions and the granulation method, and Table 2 shows the specifications (operating conditions) of the granulator used. In addition,
-0.5 mm representing the particle size in Table 1 and the table below is
It means particles having a particle size of 0.5 mm or less.
【0040】(イ)擬似粒子の乾燥による崩壊 下記の擬似粒度分布調査bにおける粒径 2mm以下の質量
比率と、同じく下記の擬似粒度分布調査aにおける粒径
2mm以下の質量比率との差分(以下「乾燥崩壊量(質量
%)」と言う)により評価した。この差分の小さい方が
擬似粒子の乾燥による崩壊が少なく、焼結時の原料充填
層の通気性が向上する。(A) Disintegration of pseudo particles by drying The mass ratio of particle size of 2 mm or less in the following pseudo particle size distribution survey b and the particle size in the following pseudo particle size distribution survey a
Evaluation was made based on the difference from the mass ratio of 2 mm or less (hereinafter, referred to as “dry disintegration amount (% by mass )”). The smaller the difference, the less the pseudo-particles collapse due to drying, and the better the permeability of the raw material packed layer during sintering.
【0041】〔擬似粒度分布調査a〕 造粒後の原料を450g〜500g単位まで分割した後、湿潤状
態のまま手篩いで篩分ける。[Pseudo-grain size distribution investigation a] The raw material after granulation is divided into units of 450 g to 500 g and then sieved with a hand sieve in a wet state.
【0042】〔擬似粒度分布調査b〕 擬似粒度分布調査aの後の原料を 110℃において 2時間
乾燥処理した後、篩分ける。[Pseudo-grain size distribution survey b] The raw material after the pseudo-grain size distribution survey a is dried at 110 ° C for 2 hours and then sieved.
【0043】(ロ)中間粒径粒子の造粒への関与 下記の擬似粒子を構成する粒子の粒径分布調査(擬似粒
度別、即ち、粒径の異なる擬似粒子別)の結果から、粒
径 2〜1 mm、1 〜0.5 mmおよび 0.5〜0.25mmの粒子が、
それぞれどの粒径の擬似粒子中にどの程度ふくまれてい
たのか、即ち、擬似粒子中における分布状態を解析し、
これらの粒径粒子の造粒への関与を評価した。(B) Involvement of Intermediate Particle Size Particles in Granulation From the results of the following particle size distribution investigation of the particles constituting the pseudo particles (by pseudo particle size, that is, by pseudo particles having different particle sizes), 2-1 mm, 1-0.5 mm and 0.5-0.25 mm particles
Analyzing how much each particle contained in the pseudo particle, that is, the distribution state in the pseudo particle,
The contribution of these particles to granulation was evaluated.
【0044】〔擬似粒子を構成する粒子の粒径分布調査
(擬似粒度別)〕 擬似粒度分布調査bを行った後の擬似粒度別原料を、そ
れぞれ水洗によって構成粒子単位まで分解し篩分ける。[Survey of Particle Size Distribution of Particles Constituting Pseudo Particles (Pseudo Particle Size Distribution)] The pseudo particle size raw materials after the pseudo particle size distribution survey b are performed are decomposed into constituent particle units by washing with water and sieved.
【0045】図5は、擬似粒子の乾燥崩壊についての調
査結果であり、本発明例のアイリッヒミキサーを使用し
たケース1およびアイリッヒミキサーの後段にドラムミ
キサーを設けたケース2は、いずれもドラムミキサーだ
けを使用する比較例に比べて乾燥崩壊量がほぼ半減して
いる。この結果から、本発明方法により粒子間結合力の
強い擬似粒子が形成されることがわかる。FIG. 5 shows the results of a study on the drying and disintegration of the pseudo particles. The case 1 using the Erich mixer of the present invention and the case 2 provided with a drum mixer at the subsequent stage of the Erich mixer were both drums. The amount of dry disintegration is almost halved compared to the comparative example using only the mixer. From this result, it is understood that pseudo particles having a strong interparticle bonding force are formed by the method of the present invention.
【0046】図6は、中間粒径粒子の造粒への関与につ
いての調査結果で、粒径0.25〜0.5mm、0.5 〜1 mmおよ
び 1〜2 mmの中間粒径粒子(ここでは、「構成粒子」と
言う)について、それぞれの構成粒子の擬似粒子中にお
ける分布状態を示す図である。横軸は擬似粒子の粒径範
囲で、例えば、左側の図(構成粒子の粒径範囲が0.25〜
0.5 mm)において、「0.5 −1 」は造粒後原料を湿潤状
態のまま手篩いで篩分け、次いで 110℃で乾燥処理した
後再度篩分けたその中の粒径 0.5〜1 mmの擬似粒子を表
わす。また、縦軸の構成粒子の存在比は、その粒径 0.5
〜1 mmの擬似粒子を水洗によって構成粒子単位まで分解
し、篩分けたその中の粒径0.25〜0.5 mmの粒子の存在比
を意味する。FIG. 6 shows the results of an investigation on the involvement of intermediate-size particles in granulation. The results show that intermediate-size particles having a particle size of 0.25 to 0.5 mm, 0.5 to 1 mm, and 1 to 2 mm (here, FIG. 4 is a diagram showing the distribution of constituent particles in pseudo particles. The horizontal axis represents the particle size range of the pseudo-particles.
(0.5 mm), "0.5 -1" means that the raw material after granulation was sieved with a hand sieve in a wet state, then dried at 110 ° C, and then sieved again. Represents The abundance ratio of the constituent particles on the vertical axis is 0.5
This means the abundance ratio of particles having a particle size of 0.25 to 0.5 mm in which 擬 似 1 mm pseudo particles are decomposed into constituent particle units by washing with water and sieved.
【0047】図6中の実線は、本発明例のケース2、破
線は従来例であり、□および■印は構成粒子の粒径が擬
似粒子の粒径と合致する場合の比率で、構成粒子は単独
で存在し、造粒には関与していない場合、△および▲印
は、構成粒子が、それよりも1ランク径の大きい擬似粒
子中に存在する比率で、構成粒子が造粒における核粒子
として機能している場合、○および●印は、構成粒子が
それよりも2ランク以上径の大きい擬似粒子中に存在す
る比率で、構成粒子は造粒における付着粉として機能し
ている場合である。In FIG. 6, the solid line is Case 2 of the present invention, the broken line is the conventional example, and □ and Δ are the ratios when the particle size of the constituent particles matches the particle size of the pseudo particles. Are present alone and are not involved in the granulation, the symbols △ and ▲ indicate the ratio of the constituent particles in the pseudo-particles having a rank larger than that of the constituent particles. In the case of functioning as particles, ○ and ● marks indicate the ratio of the constituent particles present in pseudo particles having a diameter of at least two ranks larger than that of the case where the constituent particles function as adhered powder in granulation. is there.
【0048】図6の結果からアイリッヒミキサーを使用
した場合(本発明例ケース2)は、使用しない場合(比
較例)に比べて、構成粒子のままで存在する比率が著し
く減少し(□印と■印との比較)、構成粒子が0.25〜0.
5 mmの場合は付着粉として機能するものが増え、0.5 〜
1 mmおよび 1〜2 mmの場合は核粒子として機能するもの
が増えていることがわかる。この結果から、本発明方法
により、従来法では造粒に関与しないとされている粒径
0.25〜2 mmの原料粒子を造粒に寄与させることができ、
擬似粒子が安定して形成されることがわかる。As can be seen from the results shown in FIG. 6, when the Erich mixer was used (Example 2 of the present invention), the ratio of the constituent particles as they were was significantly reduced as compared with the case where the Erich mixer was not used (Comparative Example). And the symbol ■), the constituent particles are 0.25 to 0.
In the case of 5 mm, the one that functions as an adhering powder increases,
In the case of 1 mm and 1 to 2 mm, it can be seen that those that function as nuclear particles are increasing. From these results, it can be seen that the method of the present invention has a particle size that is not considered to be involved in granulation in the conventional method.
Raw material particles of 0.25 to 2 mm can contribute to granulation,
It can be seen that pseudo particles are formed stably.
【0049】[0049]
【表1】 [Table 1]
【0050】[0050]
【表2】 [Table 2]
【0051】[0051]
【実施例2】表3に示すA−1、A−2、BおよびCの
配合の焼結原料について、本発明方法を適用して焼結鍋
試験を行い、焼結鉱の成品歩留および高温性状の改善効
果を調査した。Example 2 A sintering pot test was performed on the sintering raw materials having the composition of A-1, A-2, B and C shown in Table 3 by applying the method of the present invention, and the product yield of sinter ore and The improvement effect of high temperature properties was investigated.
【0052】使用した造粒機は前記表2に示す実施例1
の場合と同じで、造粒方法は表4に示す通りである。ま
た、表5に配合原料と造粒方法の組合せを示す。The granulator used was Example 1 shown in Table 2 above.
The granulation method is the same as shown in Table 4 below. Table 5 shows combinations of the raw materials and the granulation method.
【0053】焼成は造粒後の原料を直径 300mmの円筒形
のポットに装入し、層高 500mm、空塔風速 15.0 Nm3 /m
2 min 一定の条件にて行った。空塔風速を一定とした理
由は、焼結鉱品質に与える影響が大きい焼成時間を一定
とするためである。つまり、焼結のヒートパターンを一
定条件として、焼結鉱の歩留、品質を評価した。なお、
点火条件はLPG 90 リットル/分で2分間とし、焼成
終了はBTP(Burn through point 、排ガス温度最高到
達点)後 90 秒とした。In the firing, the raw material after granulation is charged into a cylindrical pot having a diameter of 300 mm, the bed height is 500 mm, and the superficial air velocity is 15.0 Nm 3 / m
The test was performed under constant conditions for 2 min. The reason why the air tower wind speed is constant is that the firing time, which has a large effect on the sinter quality, is constant. That is, the yield and quality of the sintered ore were evaluated with the heat pattern of sintering being a constant condition. In addition,
The ignition conditions were LPG 90 liters / minute for 2 minutes, and the firing was completed 90 seconds after BTP (Burn through point, maximum point of exhaust gas temperature).
【0054】焼結鉱の荷重軟化試験は 0〜 9.8×10-2kg
f/mm2 の荷重で、CO/N2 =0 〜1の混合ガス雰囲気内
で昇温し、昇温過程時の試料の収縮率と圧損を測定し
た。そして、この圧損の積算値で高温性状を評価した。
一般に装入物が高炉内で荷下り軟化溶融を開始する際、
軟化溶融温度が高いほど、また、軟化開始温度と溶け落
ち温度の温度幅が狭いほど、その装入物の性状が良好と
されている。従って、圧損の積算値が低いほど高温性状
が良好と評価される。The load softening test of the sintered ore is 0 to 9.8 × 10-2 kg
At a load of f / mm 2, the temperature was raised in a mixed gas atmosphere of CO / N 2 = 0 to 1, and the shrinkage ratio and pressure loss of the sample during the heating process were measured. Then, high-temperature properties were evaluated based on the integrated value of the pressure loss.
Generally, when the charge begins to unload and soften in the blast furnace,
It is considered that the higher the softening / melting temperature and the narrower the temperature range between the softening start temperature and the burn-through temperature, the better the properties of the charge. Therefore, the lower the integrated value of the pressure loss, the better the high-temperature property is evaluated.
【0055】調査結果を図7に示す。図示のとおり、造
粒e法のようにドラムミキサーだけを用い、粘着性が高
く、分散性、反応性が悪いドロマイト、軽焼ドロマイト
を配合して低SiO2 焼結鉱を製造すると、成品歩留は70
%以下と低く、圧損積算値も550 mH2 O以上で高温性状
も良くない(従来例ケース13,14 )。FIG. 7 shows the results of the investigation. As shown in the figure, when only a drum mixer is used as in the case of the granulation e method and dolomite having high adhesiveness, poor dispersibility and low reactivity, and dolomite lightly burned are mixed to produce a low SiO 2 sintered ore, Stay 70
%, The pressure drop integrated value is 550 mH 2 O or more, and the high temperature properties are not good (conventional cases 13, 14).
【0056】これに対して、本発明方法を適用した例で
は、いずれも成品歩留は85%以上、圧損積算値は500 mH
2 O以下で、歩留、高温性状がともに改善されている。
特に、アイリッヒミキサーとドラムミキサーを併用した
造粒b法の本発明例2のケース7、8では、その改善効
果が高くなっている。また、A系原料中に MgO・CaO系
副原料を一括混合し、A系原料はアイリッヒミキサーと
ドラムミキサーを併用し、B系原料はドラムミキサーだ
けを使用して造粒した本発明例3、4(造粒c法、d
法)でも十分な改善効果が得られている。アイリッヒミ
キサー単独使用の本発明例1(造粒a法)でも効果が得
られていることから、アイリッヒミキサーで MgO・CaO
系副原料の分散性、反応性が改善され、粒子間結合の強
い擬似粒子が安定して形成されたと考えられる。On the other hand, in each of the examples to which the method of the present invention was applied, the product yield was 85% or more, and the pressure loss integrated value was 500 mH.
At 2 O or less, both the yield and high temperature properties are improved.
In particular, in the cases 7 and 8 of Example 2 of the present invention of the granulation b method using the Erich mixer and the drum mixer together, the improvement effect is high. In addition, Example 3 of the present invention was prepared by mixing MgO / CaO-based auxiliary raw materials in the A-based raw materials at one time, using the Erich-mixer and the drum mixer together for the A-based raw materials, and granulating the B-based raw materials using only the drum mixer. , 4 (granulation c method, d
Method), a sufficient improvement effect has been obtained. Since the effect was also obtained in Example 1 of the present invention (granulation a method) using the Erich mixer alone, MgO / CaO
It is considered that the dispersibility and reactivity of the system auxiliary material were improved, and pseudo particles having strong inter-particle bonds were stably formed.
【0057】上述の結果から、本発明方法によって、高
温性状が良好な低SiO2 濃度の焼結鉱を高い歩留で製造
できることがわかる。From the above results, it can be seen that the method of the present invention enables the production of sintered ores with good low-temperature properties and high SiO 2 concentration at a high yield.
【0058】[0058]
【表3】 [Table 3]
【0059】[0059]
【表4】 [Table 4]
【0060】[0060]
【表5】 [Table 5]
【0061】[0061]
【発明の効果】本発明方法によれば、高炉炉内での高温
性状が良好で、かつ高炉内で生成するスラグ粘度を低く
することができる低SiO2 焼結鉱を高い歩留で製造する
ことができる。本発明方法に得られる低SiO2 焼結鉱を
用いれば、焼結鉱の配合比を高めても高炉の安定操業が
可能となり、良質塊鉱原料の枯渇に十分に対応できる。According to the method of the present invention, a low SiO 2 sintered ore having a good high-temperature property in a blast furnace and a low slag viscosity generated in the blast furnace can be produced at a high yield. be able to. By using the low SiO 2 sintered ore obtained in the method of the present invention, a stable operation of the blast furnace becomes possible even if the mixing ratio of the sintered ore is increased, and it is possible to sufficiently cope with the depletion of the raw material of the high quality lump ore.
【図1】装入原料の全部を本発明方法で処理する一例の
概略工程を示す図である。FIG. 1 is a diagram showing an example of a schematic process for treating all of a charged material by a method of the present invention.
【図2】装入原料の全部を本発明方法で処理する他の例
の概略工程を示す図である。FIG. 2 is a diagram showing schematic steps of another example in which all of the charged materials are treated by the method of the present invention.
【図3】装入原料の一部を本発明方法で処理する一例の
概略工程を示す図である。FIG. 3 is a schematic view showing an example of a schematic process of treating a part of a charged material by the method of the present invention.
【図4】装入原料の一部を本発明方法で処理する他の例
の概略工程を示す図である。FIG. 4 is a diagram showing schematic steps of another example of treating a part of the charged material by the method of the present invention.
【図5】擬似粒子の乾燥崩壊に対する本発明方法の抑制
効果を示す図である。FIG. 5 is a graph showing the effect of the method of the present invention for suppressing dry disintegration of pseudo particles.
【図6】中間粒粒径粒子の造粒への関与に対する本発明
方法の効果を示す図である。FIG. 6 is a diagram showing the effect of the method of the present invention on the involvement of intermediate-size particles in granulation.
【図7】焼結鉱の成品歩留、高温性状に対する本発明方
法の効果を示す図である。FIG. 7 is a diagram showing the effects of the method of the present invention on the product yield and high-temperature properties of sintered ore.
1:原料層、 2:アイリッヒミキサー、 3,3A,3B,3
C :ドラムミキサー1: raw material layer, 2: Erich mixer, 3,3A, 3B, 3
C: Drum mixer
フロントページの続き (58)調査した分野(Int.Cl.7,DB名) C22B 1/00 - 61/00 Continuation of front page (58) Field surveyed (Int. Cl. 7 , DB name) C22B 1/00-61/00
Claims (2)
MgO濃度が 0.6質量%を超える焼結鉱を製造する方法で
あって、ドロマイトと軽焼ドロマイトのいずれか一方ま
たは両方を含む焼結原料を攪拌羽根を内蔵した混合機で
毎分 100〜 500回の回転速度で高速攪拌混合した後に、
上記混合原料を全使用原料の少なくとも一部として使用
することを特徴とする焼結鉱の製造方法。(1) When the SiO 2 concentration in the product is 4.0 to 4.8% by mass .
A method for producing sintered ore with an MgO concentration of more than 0.6% by mass. A sintering raw material containing one or both of dolomite and lightly burned dolomite is mixed by a mixer with a built-in stirring blade.
After high-speed stirring and mixing at a rotation speed of 100 to 500 times per minute ,
A method for producing a sintered ore, wherein the mixed raw material is used as at least a part of all raw materials used.
原料が、粒径 0.5mm以下の部分が30質量%以上のもので
あることを特徴とする請求項1の焼結鉱の製造方法。2. The production of sintered ore according to claim 1, wherein the sintering raw material to be mixed by the mixer having a stirring blade is 30 mass % or more in a portion having a particle diameter of 0.5 mm or less. Method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP08563495A JP3252646B2 (en) | 1995-04-11 | 1995-04-11 | Sinter production method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP08563495A JP3252646B2 (en) | 1995-04-11 | 1995-04-11 | Sinter production method |
Publications (2)
Publication Number | Publication Date |
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JPH08283876A JPH08283876A (en) | 1996-10-29 |
JP3252646B2 true JP3252646B2 (en) | 2002-02-04 |
Family
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JP08563495A Expired - Lifetime JP3252646B2 (en) | 1995-04-11 | 1995-04-11 | Sinter production method |
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JP5074043B2 (en) * | 2007-01-11 | 2012-11-14 | 株式会社神戸製鋼所 | Method for producing sintered ore |
JP5126580B2 (en) * | 2007-08-10 | 2013-01-23 | 新日鐵住金株式会社 | Method for producing sintered ore |
JP6380762B2 (en) * | 2015-08-11 | 2018-08-29 | Jfeスチール株式会社 | Method for producing sintered ore |
JP6493305B2 (en) * | 2016-05-27 | 2019-04-03 | Jfeスチール株式会社 | Method for producing sintered ore |
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1995
- 1995-04-11 JP JP08563495A patent/JP3252646B2/en not_active Expired - Lifetime
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