JP2015170713A - Method for manufacturing wiring structure, wiring structure, and electronic equipment using the same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide technology of manufacturing a wiring structure that can prevent dielectric breakdown even in a fine wiring size and can maintain reliability.SOLUTION: A method for manufacturing a wiring structure is provided, which comprises: forming a seed layer for plating on an insulating film on a substrate; forming a resist pattern having an opening corresponding to a wiring pattern on the seed layer for plating; forming a wiring layer in the opening by electrolytic plating; subjecting the surface of the resist pattern to a water repellency imparting treatment; growing an electroless plating layer of a metal material different from the material of the wiring layer, after the water repellency imparting treatment, in a region excluding both ends in a cross-section along a width direction of the wiring layer; removing the resist pattern; and then removing by simultaneously etching an exposed corner of the wiring layer and an unnecessary part of the seed layer by using the electroless plating layer as a mask so as to form a wiring line having a barrel-shaped cross-section.

Description

  The present invention relates to a method for manufacturing a wiring structure, a wiring structure, and an electronic apparatus using the same.

  In recent years, along with demands for downsizing, higher performance, and lower prices for electronic devices, miniaturization of semiconductor chips and the increase in the number of terminals have been promoted. Along with the miniaturization of semiconductor chips and the increase in the number of terminals, miniaturization and multilayering of circuit boards on which semiconductor chips are mounted are required and the mounting density is increased. In recent years, the width of wiring used for circuit wiring has become less than 5 μm, and problems such as withstand voltage that have not existed in the past have emerged. In particular, when the interval between the wirings is reduced, electric charges are discharged due to electric field concentration at the corners of the wiring cross section, resulting in insulation failure.

  In general, a fine wiring having a wiring width of 1 to 10 μm is manufactured by a method called a semi-additive method (SAP) that can be made finer than the subtract method. In the semi-additive method, as shown in FIG. 1A, a copper (Cu) thin film 113 is formed on a base insulating film 111 on a substrate via an adhesion layer 112 such as titanium (Ti). A resist pattern 114 reflecting the wiring shape is formed on the stack. When a general resist is used, it melts from the top of the resist film during development, and in most cases, the upper end of the opening 125 of the resist pattern 114 is wide and the bottom is narrow. When a wiring material is formed in the opening 125 as shown in FIG. 1B, and then the resist pattern 114 and an unnecessary portion of the Cu thin film 113 are removed, as shown in FIG. The width of the upper surface is wider than the width of the bottom of the wiring 118. Even if an appropriate distance is maintained between the adjacent wirings at the lower part of the wiring 118, the distance between the adjacent wirings at the upper part of the wiring 118 is close. If there is a potential difference between adjacent wirings 118 in this state, the electric field concentrates on the corner C of the wiring 118 and causes dielectric breakdown at the upper part of the wiring.

  In order to prevent electric field concentration on the acute angle part of the wiring cross section, the wiring width at the center in the wiring height direction is made larger than the width of the bottom surface by a certain ratio in the wiring cross sectional shape, and the cross sectional shape at the top of the wiring Has been proposed (see, for example, Patent Document 1). In this method, when metal wiring is formed by electroplating, the top of the wiring is formed into an arc by adjusting the current density by appropriately adding brightener and smoothing agent, or by soft etching after wiring formation. An arc is formed.

JP 2006-196656 A

  Provided is a technique for manufacturing a wiring structure capable of preventing a dielectric breakdown and maintaining reliability even with a fine wiring size.

In one aspect, a method for manufacturing a wiring structure includes:
A plating seed layer is formed on the insulating film on the substrate,
On the seed layer for plating, a resist pattern having an opening corresponding to the wiring pattern is formed,
Forming a wiring layer in the opening by electrolytic plating;
The surface of the resist pattern is subjected to water repellency treatment,
After the water repellent treatment, an electroless plating layer made of a metal material different from the wiring layer is grown in a region excluding both ends in the cross section in the width direction of the wiring layer,
After removing the resist pattern, using the electroless plating layer as a mask, the exposed corners of the wiring layer and unnecessary portions of the seed layer are simultaneously etched away to form a wiring having a barrel-shaped cross section. .

  Even with a fine wiring size, it is possible to prevent dielectric breakdown and maintain reliability.

It is a figure which shows the problem of the fine wiring formed by the general SAP method. It is a manufacturing process figure of the wiring structure of an embodiment. It is a manufacturing process figure of the wiring structure of an embodiment. It is a figure which shows the wiring structure of embodiment. It is a figure which shows formation of the electroless-plating film | membrane after a water repellent process. It is a manufacturing process figure of the wiring structure by the modification 1 of an embodiment. It is a manufacturing process figure of the wiring structure by the modification 2 of an embodiment.

  2 and 3 are manufacturing process diagrams of the wiring structure of the embodiment. In the embodiment, even when a fine wiring pattern formed by a semi-additive method is used, a wiring structure manufacturing method capable of maintaining insulation resistance between adjacent wirings and a wiring structure manufactured by this method are provided. provide. In order to achieve this, an electroless plating film is formed in a self-aligned manner on the upper surface of the wiring of a good conductor such as copper (Cu) formed by electrolytic plating in a region excluding the edge or corner of the wiring, and wet etching is performed. The edge (corner) at the upper part of the wiring and the seed layer are dissolved in By this method, a barrel-shaped wiring having a metal film made of a material different from the wiring material on the bottom and top surfaces of the wiring and having a cross-sectional shape of the wiring having a larger width at the center than at the bottom and top ends of the wiring can be obtained. It is formed. Furthermore, the metal film on the upper part of the wiring has an arc-shaped cross-sectional shape with a central part rising in the width direction of the wiring. This configuration eliminates a corner portion where the electric field is concentrated, prevents proximity between adjacent wirings, and improves insulation resistance.

  First, as shown in FIG. 2A, a base insulating film 11 is formed on a substrate (not shown). The substrate is an arbitrary substrate on which a layer having a fine wiring pattern is formed, such as a core substrate on which a semiconductor chip is mounted, a wafer level package (WLP) substrate, a multi-chip package (MCP) substrate, and an interposer substrate. The base insulating film 11 is formed of a resin material such as polyimide having good heat resistance and chemical resistance, or an insulating material in which glass fibers or glass particles are mixed in a resin.

  Next, as illustrated in FIG. 2B, a seed layer 15 is formed over the base insulating film 11. The seed layer 15 is, for example, a stack of a base metal film 12 and a thin film 13 to be a plating electrode, and is formed by an arbitrary method such as sputtering, plating, or vapor deposition. The base metal film 12 is a film that ensures adhesion to the base insulating film 11, and is formed to a thickness of 5 to 30 nm by sputtering using a target such as Ti, Mo, Co, and Pd as an example. Subsequently, a thin film 13 having a thickness of 80 to 300 nm is formed using a highly conductive target such as copper (Cu), gold (Au), or silver (Ag) to form a stacked seed layer 15.

  Next, as shown in FIG. 2C, a plating resist pattern 14 is formed on the seed layer 15. The plating resist pattern 14 is formed, for example, by applying a positive photoresist on the seed layer 15, exposing the wiring pattern, and developing it. The resist pattern 14 has an opening 25 corresponding to the wiring pattern, but the width of the upper end of the opening 25 is wider than the width of the bottom because of the dissolution of the resist material by the developer. A part of the seed layer 15 is exposed in the opening 25.

  Next, as shown in FIG. 2D, a wiring layer 16 is grown in the opening 25 by electrolytic plating. When copper sulfate or the like is used for the electrolytic plating solution, the Cu layer 16 grows in the opening 25. The thickness of the growing Cu layer 16 is, for example, 2 to 5 μm.

  Next, as shown in FIG. 3A, the wafer surface is subjected to water repellency treatment. The water repellent treatment is performed by plasma irradiation with a fluorocarbon gas such as CF4, CHF3, C2HF5, for example. Plasma irradiation may be performed with a mixed gas of a fluorocarbon gas and an inert gas such as nitrogen or argon, or a mixed gas of a fluorocarbon gas and oxygen. In the resist pattern 14 formed of an organic resin material, the surface hydrogen groups and hydrocarbon groups are more easily replaced with fluorine (F) radicals and CF 3 radicals than the Cu layer 16, and the surface of the resist pattern 14 is preferential. Water repellent. The Cu layer 16 may be covered with a mask, and a water-repellent treatment may be performed by applying a gel-like water repellent to the surface of the resist pattern 14 and irradiating with ultraviolet rays, or may be performed with a chemical solution. When water repellent treatment is performed by plasma irradiation with fluorocarbon gas, for example, CF4 gas is supplied at a flow rate of 200 SCCM, and irradiation is performed for 30 seconds at a high frequency of 13.56 MHz, a power supply power of 500 W, and a pressure of 15 Pa.

  Next, as shown in FIG. 3B, an electroless plating layer 17 is selectively formed on the Cu layer 16 by electroless plating. Since the resist pattern 14 has been subjected to water repellency in the process of FIG. 3A, the electroless plating solution hardly adheres to the vicinity of the boundary with the resist pattern 14 on the surface of the Cu layer 16, and there is no effect from the central portion. The electrolytic plating layer 17 grows. Due to the water repellency of the resist pattern 14, the surface of the Cu layer 16 becomes relatively hydrophilic, and the liquid around the electroless plating becomes better on the Cu layer 16. As a result, the electroless plating layer 17 grows in a self-aligned manner from a region away from the end of the Cu layer 16 (boundary with the resist pattern 14), and an arc-shaped cross section is obtained. As the electroless plating layer 17, for example, a film of NiP (nickel / phosphorus), CoP (cobalt / phosphorus), CoWP (cobalt / tungsten / phosphorus), CoWB (cobalt / tungsten / boron), or the like has a thickness of 20 nm to 100 nm. To form. As an example, the electroless plating layer 17 of NiP having a central portion thickness of 40 to 60 nm is formed.

  Next, as shown in FIG. 3C, the resist pattern 14 is removed. After the resist pattern 14 is removed, the upper edge of the Cu layer 16 in a region not covered with the electroless plating layer 17 is exposed to form an acute corner.

  Next, as shown in FIG. 3D, using the electroless plating layer 17 as a mask, the exposed upper edge of the Cu layer 16 and the unnecessary portion of the Cu thin film 13 are removed by etching. In this example, wet etching is performed using a copper etching solution as an etching solution. By this wet etching, the corners of the Cu layer 16 are removed, and the wiring layer 18 has a barrel-shaped cross section.

  Finally, as shown in FIG. 4, the adhesion layer 12 such as Ti is removed with an etching solution such as hydrofluoric acid to obtain a wiring structure 20. The wiring structure 20 has a Cu wiring 19 having a barrel-shaped cross section in which a part of the seed layer 15 and the wiring layer 18 are integrated, and the metal (adhesion) layer 12 is formed on the bottom of the Cu wiring 19. Has an electroless plating layer 17 having a circular arc cross section. Thereafter, an insulating film 22 is applied to the entire surface to complete a single wiring layer. The insulating film 22 is, for example, a resin insulating film or an insulating film containing glass fiber, like the base insulating film 11.

  FIG. 5 is a diagram showing the electroless plating layer 17 of the embodiment formed after the water repellent treatment in comparison with the electroless plating layer 117 formed without performing the water repellent treatment. In FIG. 5A, since the water repellent treatment is not performed, the electroless plating solution spreads uniformly on the surface of the Cu layer 16, or the film thickness is uniform on the surface of the Cu layer 16. 117 is formed.

  On the other hand, in FIG. 5B, the electroless plating solution does not easily flow around the Cu layer 16 near the boundary with the resist pattern 14 due to the water repellency of the resist pattern 14. As a result, the electroless plating layer 17 grows preferentially from the center portion of the Cu layer 16, and the arc-shaped electroless plating layer 17 is formed in a cross section along the wiring width direction. By performing wet etching using the electroless plating layer 17 as a mask, an edge (corner) portion of the Cu layer 16 and an unnecessary portion of the Cu thin film 13 in the seed layer 15 can be removed at a time. Further, since the electroless plating layer 17 itself has an arcuate cross-sectional shape and does not have corners, electric field concentration can be prevented in the entire wiring structure 20.

  FIG. 6 is a diagram illustrating a manufacturing method of the first modification of the embodiment. In the first modification, the etching rate of the Cu layer 16 is controlled to realize a wiring structure having a barrel-shaped cross section with high accuracy.

  The process of FIG. 3C, that is, the wafer surface is subjected to water repellency treatment to form the electroless plating layer 17 in a self-aligned manner on the surface region of the Cu layer 16 excluding the vicinity of the boundary with the resist pattern 14, and then the resist pattern Since the process up to removing 14 is the same as that of the above-described embodiment, the description thereof is omitted.

  After removing the resist pattern 4, as shown in FIG. 6A, a positive charge is applied to the etching solution 26 and a negative charge is applied to the seed layer 15 to perform etching. By applying a positive charge to the etching solution 26, Cu 2+ ions are hardly dissolved from the Cu layer 16, and the etching rate can be controlled gently. As a result, the barrel-shaped Cu wiring 18 can be formed with high accuracy as shown in FIG. At the same time, unnecessary portions of the Cu thin film 13 of the seed layer 15 can be removed. Thereafter, unnecessary portions of the Ti adhesion layer 12 are removed with an etchant such as hydrofluoric acid, and the insulating film 22 is formed, thereby realizing the wiring structure 20 of FIG.

  FIG. 7 is a diagram illustrating a manufacturing method according to the second modification of the embodiment. In FIG. 7A, the water repellent treatment is performed on the wafer surface as in FIG. Thereby, the surface of the resist pattern 14 becomes water-repellent, and the surface of the Cu layer 16 becomes relatively hydrophilic with respect to the electroless plating solution.

  Next, in FIG. 7B, similarly to FIG. 3B, the electroless plating layer 17 is formed on the Cu layer 16 in a self-aligning manner in a region excluding the vicinity of the boundary with the resist pattern 14. Up to this point, it is the same as the above-described embodiment.

  Next, in FIG. 7C, after removing the resist pattern 14, oxygen plasma treatment is performed. By the oxygen plasma irradiation, the exposed Cu layer is oxidized to form copper oxide 31. Specifically, the corners of the Cu layer 16 not covered with the electroless plating layer 17 and the exposed portions of the Cu thin film 13 of the seed layer 15 become the copper oxide 31.

  Next, in FIG. 7D, the copper oxide 31 is removed by etching with dilute sulfuric acid. Also by this method, it is possible to accurately realize a barrel-shaped wiring having a cross-sectional shape in the width direction. Thereafter, unnecessary portions of the Ti adhesion layer 12 are removed with hydrofluoric acid. As a result, a wiring structure 20 having the Ti adhesion layer 12 at the bottom of the barrel-shaped Cu wiring 19 and the electroless plating layer 17 having an arc-shaped cross section on the upper surface is obtained. Thereafter, an insulating film 22 is formed on the entire surface with resin, glass cloth or the like.

  According to the method of the embodiment or the modification, it is possible to form a highly reliable wiring structure by reducing the dielectric breakdown even in the case of the wiring size that has conventionally caused the dielectric breakdown in the upper part of the wiring. Unlike the conventional structure, the elution (ion migration) of ions of the wiring material due to the electric field concentration at the corners (edges) of the wiring can be prevented, and the short circuit failure with the adjacent wiring can be reduced.

  Wiring reliability of a multilayer printed circuit board, LSI package board, wiring board such as WLP or MCP can be improved, and in particular, pressure resistance performance by a HAST (Highly Accelerated Temperature and Humidity Stress Test) test can be improved. In the conventional structure, the wiring density of about 3 μmL / S (wiring width: 3 μm, inter-wiring space: 3 μm) was the limit in terms of HAST resistance, but by adopting the structure and method of the present invention, the size of about 2 μmL / S is stable. Thus, a wiring that can withstand the HAST test can be manufactured. These wiring boards can be applied to electronic devices such as computers, servers, routers, optical communication devices, medical devices, and the reliability of products is improved.

In the above-described example, the Cu wiring has been described as an example. However, a highly conductive wiring such as Ni or Au may be formed by electrolytic plating. Also in this case, the electroless-plated wafer can be subjected to water repellent treatment, and the electroless plating layer 17 can be grown in a self-aligning manner in the region excluding the edge on the upper surface of the wiring layer 16. Using the electroless plating layer 17 as a mask, the edge (corner portion) of the wiring layer 16 can be removed by etching, and unnecessary portions of the thin film that becomes the seed layer can be removed, so that a barrel-shaped wiring can be formed efficiently. . The barrel-shaped cross-sectional shape can prevent electric field concentration, and can maintain an appropriate interval between adjacent wirings.
The following notes are presented for the following explanation.
(Appendix 1)
A plating seed layer is formed on the insulating film on the substrate,
On the seed layer for plating, a resist pattern having an opening corresponding to the wiring pattern is formed,
Forming a wiring layer in the opening by electrolytic plating;
The surface of the resist pattern is subjected to water repellency treatment,
After the water repellent treatment, an electroless plating layer made of a metal material different from the wiring layer is grown in a region excluding both ends in the cross section in the width direction of the wiring layer,
After removing the resist pattern, using the electroless plating layer as a mask, the exposed corners of the wiring layer and unnecessary portions of the seed layer are simultaneously etched away to form a wiring having a barrel-shaped cross section. ,
A manufacturing method of a wiring structure characterized by the above.
(Appendix 2)
The method for producing a wiring structure according to claim 1, wherein the etching removal is wet etching, and a positive charge is applied to the etching solution, and a negative charge is applied to the seed layer to control the etching rate. .
(Appendix 3)
After removing the resist pattern, using the electroless plating layer as a mask, the exposed corners of the wiring layer and unnecessary portions of the seed layer are oxidized to form a metal oxide, and the metal oxide is wet etched The method for manufacturing a wiring structure according to appendix 1, wherein the wiring structure is removed by the step of (1).
(Appendix 4)
4. The electroless plating layer according to any one of appendices 1 to 3, wherein a cross-section swelled at a central portion in the width direction of the upper surface of the wiring layer is formed in an arc shape by the water repellent treatment. Of manufacturing the wiring structure.
(Appendix 5)
The method for manufacturing a wiring structure according to any one of appendices 1 to 4, wherein the water repellent treatment is plasma irradiation with a fluorocarbon gas.
(Appendix 6)
The method of manufacturing a wiring structure according to any one of appendices 1 to 5, wherein the wiring layer is a copper wiring layer, and the electroless plating layer is selected from NiP, CoP, CoWP, and CoWB. .
(Appendix 7)
A cross-sectional shape in the width direction is a barrel-shaped wiring layer,
A first metal layer located on an upper surface of the wiring layer, formed of a metal material different from the wiring layer, and having an arc-shaped cross-sectional shape in the width direction;
A wiring structure characterized by comprising:
(Appendix 8)
The wiring structure according to appendix 7, wherein the wiring layer is a copper wiring layer, and the first metal layer is selected from NiP, CoP, CoWP, and CoWB.
(Appendix 9)
The wiring structure according to appendix 7, wherein the wiring structure is located at the bottom of the wiring layer and has a second metal layer made of a metal material different from that of the wiring layer.
(Appendix 10)
A substrate having the wiring structure according to any one of appendices 7 to 9,
Electronic components mounted on the substrate;
Electronic equipment having

11 Underlying insulating film 12 Adhesion layer 13 Metal thin film 14 Resist pattern 15 Seed layer 16 Wiring layer 17 Electroless plating layer (first metal layer)
18 Wiring layer after etching 19 Wiring 25 Opening 26 Etching solution

Claims (6)

A plating seed layer is formed on the insulating film on the substrate,
On the seed layer for plating, a resist pattern having an opening corresponding to the wiring pattern is formed,
Forming a wiring layer in the opening by electrolytic plating;
The surface of the resist pattern is subjected to water repellency treatment,
After the water repellent treatment, an electroless plating layer made of a metal material different from the wiring layer is grown in a region excluding both ends in the cross section in the width direction of the wiring layer,
After removing the resist pattern, using the electroless plating layer as a mask, the exposed corners of the wiring layer and unnecessary portions of the seed layer are simultaneously etched away to form a wiring having a barrel-shaped cross section. ,
A manufacturing method of a wiring structure characterized by the above.   The wiring structure according to claim 1, wherein the etching removal is wet etching, and a positive charge is applied to an etching solution and a negative charge is applied to the seed layer to control an etching rate. Method.   After removing the resist pattern, using the electroless plating layer as a mask, the exposed corners of the wiring layer and unnecessary portions of the seed layer are oxidized to form a metal oxide, and the metal oxide is wet etched The method for producing a wiring structure according to claim 1, wherein the wiring structure is removed at a step.   4. The electroless plating layer according to claim 1, wherein a cross-section swelled at a central portion in the width direction of the upper surface of the wiring layer is formed in an arc shape by the water repellent treatment. The manufacturing method of the wiring structure as described in a term. A cross-sectional shape in the width direction is a barrel-shaped wiring layer,
A first metal layer located on an upper surface of the wiring layer, formed of a metal material different from the wiring layer, and having an arc-shaped cross-sectional shape in the width direction;
A wiring structure characterized by comprising: A substrate having the wiring structure according to claim 5;
Electronic components mounted on the substrate;
Electronic equipment having

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