JP2013514490A - 排気ガス後処理デバイス内の還元剤バッファ・レベルをコントロールするための方法 - Google Patents
排気ガス後処理デバイス内の還元剤バッファ・レベルをコントロールするための方法 Download PDFInfo
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- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 94
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000002347 injection Methods 0.000 claims abstract description 150
- 239000007924 injection Substances 0.000 claims abstract description 150
- 238000006243 chemical reaction Methods 0.000 claims abstract description 75
- 238000011156 evaluation Methods 0.000 claims abstract description 25
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 14
- 238000002485 combustion reaction Methods 0.000 claims abstract description 5
- 239000004202 carbamide Substances 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 230000032683 aging Effects 0.000 claims description 5
- 238000004590 computer program Methods 0.000 claims description 5
- 230000003247 decreasing effect Effects 0.000 claims description 5
- 230000004044 response Effects 0.000 claims description 3
- 238000005259 measurement Methods 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 167
- 239000003054 catalyst Substances 0.000 description 48
- 238000002474 experimental method Methods 0.000 description 36
- 239000007789 gas Substances 0.000 description 34
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 28
- 229910021529 ammonia Inorganic materials 0.000 description 12
- 230000007423 decrease Effects 0.000 description 10
- 230000008901 benefit Effects 0.000 description 8
- 230000001276 controlling effect Effects 0.000 description 5
- 230000002950 deficient Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical group N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 238000007726 management method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000003044 adaptive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
- F01N3/208—Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
- F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
- F01N2560/026—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting NOx
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/18—Ammonia
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
【選択図】なし
Description
4NH3+5O2=>4NO+6H2O
102 第1のNOxセンサ
104 第2のNOxセンサ
106 SCR触媒
110 取入れ口
112 吐き出し口
200 先行技術の排気ガス後処理システム
202 第1のNOxセンサ
204 第2のNOxセンサ
206 SCR触媒
208 クリーンアップ触媒
210 取入れ口
212 吐き出し口
310 正常動作、公称動作
320 還元剤噴射開ループ実験
330 実験結果の評価
340 充填ステップ
350 抜き取りステップ
400 曲線
402 ピーク
Claims (19)
- 内燃エンジンの下流に接続可能な排気ガス後処理デバイス内における還元剤バッファ・レベルをコントロールするための方法であって、
a. 前記排気ガス後処理デバイスの上流において第1の量の第1の還元剤噴射を実行するステップと、
b. 前記排気ガス後処理デバイスの上流において第2の量の第2の還元剤噴射を実行するステップであって、前記第2の量が前記第1の量とは異なるものとするステップとを包含し、それにおいて前記方法が、さらに、
c. 前記第1および第2の還元剤噴射から結果としてもたらされるNOx変換を、前記排気ガス後処理デバイスの下流において評価し、第1および第2の結果を獲得するステップと、
d. 前記第1および第2のNOx変換の評価から得られた前記第1および第2の結果に応じてその後に続く還元剤噴射をコントロールするステップとを包含することを特徴とする方法。 - 前記第1の噴射量は、前記第2の噴射量より小さいとする、請求項1に記載の方法。
- 前記第2のNOx変換の評価から得られた前記第2の結果が前記第1のNOx変換の評価から得られた前記第1の結果より高い場合には、前記評価するステップの後に続く噴射量が前記第1の噴射または公称噴射との比較において増加される、請求項2に記載の方法。
- 前記第2のNOx変換の評価から得られた前記第2の結果が前記第1のNOx変換の評価から得られた前記第1の結果と本質的に同一であるか、またはそれより低い場合には、前記評価するステップの後に続く噴射量が前記第1の噴射または公称噴射との比較において減少される、請求項2に記載の方法。
- 前記第1の還元剤噴射は、噴射モデルによる前記公称噴射に等しい、請求項1に記載の方法。
- 前記NOx変換の前記評価は、
− 前記排気ガス後処理デバイスの上流に提供される第1のNOxセンサを用いて前記排気ガスのNOx含有量を測定するステップと、
− 前記排気ガス後処理デバイスの下流に提供される第2のNOxセンサを用いて前記排気ガスのNOx含有量を測定するステップと、
− 前記第1および第2のNOxセンサからの測定値を比較するステップとを包含する、請求項1に記載の方法。 - 前記排気ガス後処理デバイス内に直接前記還元剤を噴射するステップをさらに包含する、請求項1に記載の方法。
- 前記還元剤は尿素である、請求項1に記載の方法。
- 前記増加されるか、または減少されたその後に続く還元剤噴射を、次に示すパラメータ、すなわち、あらかじめ決定済みのレベルのNOx変換が達成されること、あらかじめ決定済みの数の噴射が実行されること、またはあらかじめ決定済みの時間期間が経過することのうちの少なくとも1つが充足されるまで継続するステップをさらに包含する、請求項3または4に記載の方法。
- 検出されたNOx変換レベルと、見積もられたNOx変換レベルを比較するステップと、
前記検出されたNOx変換と前記見積もられたNOx変換の間に偏差が存在する場合には請求項1に記載のステップ(a)を起動するステップとをさらに包含する、請求項1に記載の方法。 - 前記第1の噴射量は、前記第2の噴射量より大きい、請求項1に記載の方法。
- 前記評価するステップの後に続く噴射は、前記第2のNOx変換の評価から得られた前記第2の結果が前記第1のNOx変換の評価から得られた前記第1の結果より高い場合に、前記第1の噴射または公称噴射との比較において減少される、請求項11に記載の方法。
- 前記第2のNOx変換の評価から得られた前記第2の結果が前記第1のNOx変換の評価から得られた前記第1の結果と本質的に同一であるか、またはそれより低い場合には、前記評価するステップの後に続く噴射量が前記第1の噴射または公称噴射との比較において増加される、請求項11に記載の方法。
- 前記増加されるか、または減少されたその後に続く噴射を、次に示すパラメータ、すなわち、あらかじめ決定済みのレベルのNOx変換が達成されること、あらかじめ決定済みの数の噴射が実行されること、またはあらかじめ決定済みの時間期間が経過することのうちの少なくとも1つが充足されるまで継続するステップをさらに包含する、請求項12または13に記載の方法。
- 前記第1および第2のNOx変換の評価から得られた前記第1および第2の結果に応じて前記排気ガス後処理デバイスの老化を見積もるステップをさらに包含する、請求項1に記載の方法。
- 前記第1および第2のNOx変換の評価から得られた前記第1および第2の結果に応じて閉ループにおいて前記公称還元剤噴射を調整するステップをさらに包含する、請求項5に記載の方法。
- a.−d.までのステップと還元剤の公称噴射の閉ループ・コントロールを組み合わせるステップをさらに包含する、請求項1に記載の方法。
- コンピュータ・プログラムであって、コンピュータ上において前記プログラムが実行されるときに請求項1乃至17のいずれか一項に記載のすべてのステップを実行するためのプログラム・コード手段を包含するコンピュータ・プログラム。
- コンピュータ・プログラム・プロダクトであって、コンピュータ上において前記プログラム・プロダクトが実行されるときに請求項1乃至17のいずれか一項に記載のすべてのステップを実行するためのコンピュータ可読媒体上にストアされたプログラム・コード手段を包含するコンピュータ・プログラム・プロダクト。
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PCT/SE2009/000530 WO2011075015A1 (en) | 2009-12-18 | 2009-12-18 | Method for controlling the reductant buffer level in an exhaust gas aftertreatment device |
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JP2015044781A Division JP2015135117A (ja) | 2015-03-06 | 2015-03-06 | 排気ガス後処理デバイス内の還元剤貯蔵・レベルをコントロールするための方法 |
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US (2) | US9243535B2 (ja) |
EP (1) | EP2513439B1 (ja) |
JP (1) | JP5759476B2 (ja) |
CN (1) | CN102713180B (ja) |
BR (1) | BR112012014614B1 (ja) |
RU (1) | RU2532463C2 (ja) |
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- 2009-12-18 RU RU2012130157/06A patent/RU2532463C2/ru active
- 2009-12-18 WO PCT/SE2009/000530 patent/WO2011075015A1/en active Application Filing
- 2009-12-18 JP JP2012544426A patent/JP5759476B2/ja active Active
- 2009-12-18 US US13/516,246 patent/US9243535B2/en active Active
- 2009-12-18 CN CN200980163020.8A patent/CN102713180B/zh active Active
- 2009-12-18 BR BR112012014614-9A patent/BR112012014614B1/pt not_active IP Right Cessation
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2015
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Also Published As
Publication number | Publication date |
---|---|
BR112012014614B1 (pt) | 2020-12-08 |
EP2513439A1 (en) | 2012-10-24 |
US20130186067A1 (en) | 2013-07-25 |
EP2513439B1 (en) | 2018-05-02 |
BR112012014614A8 (pt) | 2016-05-17 |
BR112012014614A2 (pt) | 2016-04-12 |
RU2532463C2 (ru) | 2014-11-10 |
US9243535B2 (en) | 2016-01-26 |
EP2513439A4 (en) | 2016-06-15 |
RU2012130157A (ru) | 2014-01-27 |
WO2011075015A1 (en) | 2011-06-23 |
JP5759476B2 (ja) | 2015-08-05 |
CN102713180B (zh) | 2015-09-16 |
US20160003121A1 (en) | 2016-01-07 |
CN102713180A (zh) | 2012-10-03 |
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