JP2010130970A - Green juice powder with good dispersibility in hot water, and method for producing the same - Google Patents
Green juice powder with good dispersibility in hot water, and method for producing the same Download PDFInfo
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Abstract
Description
本発明は、湯分散性の良い青汁粉末及びその製造方法に関する。 The present invention relates to a green juice powder having good hot water dispersibility and a method for producing the same.
現代社会は食の欧米化により肉類の摂取量が大幅に増えると共に、野菜類の摂取量低下が顕著になってきている。2012年まで展開される国民健康づくり運動「健康日本21」の「栄養・食生活」分野では、「成人の1日あたりの野菜の平均摂取量の増加」を目標に掲げており、野菜を摂取することの重要性については改めて議論するまでもない。一方、野菜の摂取が健康維持に重要であることはわかっていても、なかなか取りづらいのが現状であり、このような状況を鑑み野菜を手軽に取れるよう開発されたものが青汁である。 In modern society, the intake of meat has increased significantly due to the westernization of food, and the decrease in the intake of vegetables has become prominent. In the “Nutrition and dietary life” field of “Health Japan 21”, a national health promotion campaign that will continue until 2012, the goal is to “increase the average daily intake of vegetables by adults”. There is no need to discuss the importance of doing it again. On the other hand, although it is known that the intake of vegetables is important for health maintenance, it is difficult to take vegetables at present, and green juice is developed to take vegetables easily in view of such a situation.
青汁のつくり方には様々な方法があるが、大きく分けると原料を丸ごと粉砕する方法と原料を搾汁する方法とに大別することができる。原料を丸ごと粉砕する方法は、丸ごと青汁に加工できるという利点があるが、一方で食物繊維などの不溶性成分が存在するため、飲食時にざらつきを感じたり、沈殿を生じやすいなどの欠点が存在する。この欠点を解消する方法として、不溶性の部分を取り除きながら青汁に加工する搾汁という方法がある。搾汁という方法を用いれば不溶性の繊維分などは搾汁粕として除去されるため、口当たりがよく滑らかで、沈殿を生じにくい青汁をつくることが可能である。 There are various methods for making green juice, but it can be roughly divided into a method of pulverizing the whole raw material and a method of squeezing the raw material. The method of crushing the whole raw material has the advantage that it can be processed into a green juice as a whole, but on the other hand, because there are insoluble components such as dietary fiber, there are disadvantages such as feeling rough and causing precipitation. . As a method for eliminating this disadvantage, there is a method called squeezing that is processed into green juice while removing insoluble portions. If the method of squeezing is used, the insoluble fiber content and the like are removed as squeezed koji, so that it is possible to produce a green juice that is smooth to the touch and hardly precipitates.
搾汁という方法によってつくられた青汁はそのまま飲用に供されるほか、保存性を高めるために冷凍処理や粉末化処理される。冷凍処理されたものは解凍した後飲用に供されるが、粉末化処理されたものは水等に溶かして飲用される。しかし粉末化された青汁をお湯などの温かいものに溶かした場合、多くは熱による凝集・沈殿を発生し、外観、口当たりとも不適なものとなってしまう。原因としては、青汁に含まれるタンパク質などの熱凝固性の物質がお湯の熱により凝集・沈殿を生成するためと考えられる。一方、青汁をホットで飲みたいというニーズは高く、粉末化された青汁をお湯などに溶かして飲むことができれば、温かい物が飲みたくなる冬場でも楽に飲用することができる上、各種加工食品の原料としても用途が広がり、利便性は飛躍的に向上する。 The green juice produced by the method of squeezing is used for drinking as it is, and is also subjected to freezing and pulverization in order to improve the storage stability. The frozen product is thawed and then used for drinking, while the powdered product is dissolved in water and used. However, when powdered green juice is dissolved in warm water such as hot water, many agglomerate and precipitate due to heat, and the appearance and mouthfeel are unsuitable. The cause is considered to be that a heat-coagulating substance such as protein contained in the green juice produces aggregation / precipitation due to the heat of hot water. On the other hand, there is a high need to drink Aojiru hot, and if powdered Aojiru can be dissolved in hot water, it can be drunk easily even in the winter when you want to drink hot foods, and various processed foods As a raw material, the use is expanded and the convenience is drastically improved.
熱による凝集・沈殿を防止するために現在までに様々な検討が行われている。凝集・沈殿を防止する効果のある食品素材を添加する方法として、例えば特許文献1では、野菜汁と乳化水溶液とを混合して得られることを特徴とする、野菜ジュースを開示している。また、特許文献2では、可食性緑葉植物の葉及び茎の搾汁液の固形分及び環状デキストリンより成る安定な青汁粉末組成物を開示している。また、特許文献3では、発酵セルロース及びカルボキシメチルセルロースのアルカリ塩を含有する被加熱殺菌処理食品用の分散安定化組成物を開示している。しかし、凝集・沈殿を防止する効果のある食品素材を添加する方法は、乳化剤や環状デキストリンといった食品添加物を原料として使用することとなり、天然嗜好の消費者には受け入れられにくいという問題点が依然存在していた。 Various studies have been conducted so far to prevent heat aggregation and precipitation. As a method for adding a food material having an effect of preventing aggregation / precipitation, for example, Patent Document 1 discloses a vegetable juice characterized by being obtained by mixing vegetable juice and an emulsified aqueous solution. Patent Document 2 discloses a stable green juice powder composition comprising the solid content of squeezed juice of leaves and stems of edible green leaf plants and cyclic dextrin. Patent Document 3 discloses a dispersion-stabilized composition for heat-treated food that contains fermented cellulose and carboxymethylcellulose alkali salts. However, the method of adding food ingredients that have the effect of preventing aggregation and precipitation uses food additives such as emulsifiers and cyclic dextrins as raw materials, and there still remains a problem that it is difficult for consumers with natural tastes to accept them. Existed.
また、凝集・沈殿を防止する効果のある食品素材を添加せずに凝集・沈殿を防止する方法としては、例えば特許文献4では、豆乳、野菜、及び食塩を含有する調味料を基材として豆乳液状食品を得、得られた豆乳液状食品を105〜155℃で高温加熱し、該高温加熱と同時に、あるいは該高温加熱の後に均質化することを特徴とする、喫食時に於ける加熱の際に凝集物の発生しない豆乳液状食品の製造法を開示している。また、特許文献5では、パルプ質を含む人参汁を含有させた飲料を製造するに当たり、上記人参汁を50℃以上に加熱した後均質化処理することを特徴とする人参汁含有飲料の製造法を開示している。しかし、これらの製造方法を実現するには、別途特別に均質化させる装置が必要となる点が課題であった。 Moreover, as a method for preventing aggregation / precipitation without adding a food material having an effect of preventing aggregation / precipitation, for example, in Patent Document 4, soy milk, vegetables, and a seasoning containing salt are used as a base material. A liquid food is obtained, and the obtained soymilk liquid food is heated at a high temperature of 105 to 155 ° C., and is homogenized simultaneously with the high temperature heating or after the high temperature heating. Disclosed is a method for producing a soymilk liquid food product that does not generate aggregates. Moreover, in patent document 5, in manufacturing the drink containing the ginseng soup containing pulp quality, after heating the said ginseng soup to 50 degreeC or more, it homogenizes, The manufacturing method of the ginseng soup containing drink characterized by the above-mentioned. Is disclosed. However, in order to realize these manufacturing methods, there is a problem that a special homogenizing apparatus is required separately.
上記の通り、植物からの湯分散性の良い搾汁液を得るに際し、凝集・沈殿を防止する効果のある食品素材を添加する方法や、均質化処理を含む方法には不都合な課題が存在する。 As described above, when obtaining a squeezed juice having good water dispersibility from plants, there are disadvantageous problems in the method of adding a food material having an effect of preventing aggregation and precipitation and the method including a homogenization treatment.
そこで本発明は、凝集・沈殿を防止する効果のある食品素材の添加や、均質化処理を含まない、湯分散性の良い青汁粉末の製造方法を提供することを目的とする。 Accordingly, an object of the present invention is to provide a method for producing a green juice powder having good hot water dispersibility, which does not include addition of a food material having an effect of preventing aggregation / precipitation and homogenization treatment.
本発明者らは、上記課題を解決するため鋭意研究を重ねた結果、搾汁した青汁を乾燥処理後、再度溶解させてから特定の乾燥処理に供することにより、お湯に溶解させた際の分散性が飛躍的に向上した青汁粉末を製造できることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention, after drying the squeezed green juice, dissolving it again and then subjecting it to a specific drying process, when dissolved in hot water It has been found that a green juice powder having greatly improved dispersibility can be produced, and the present invention has been completed.
すなわち本発明は、以下の特徴を包含する。
(1) 搾汁した青汁を乾燥処理後、再度溶媒に溶解させてから、(i)噴霧乾燥を含む処理に供するか、又は(ii)加熱処理と凍結乾燥処理とに供することにより、再度乾燥させることを含む、湯分散性の良い青汁粉末の製造方法。
(2) 加熱温度は70℃以上であることを特徴とする上記(1)記載の方法。
(3) 青汁の原料が大麦若葉であることを特徴とする、上記(1)又は(2)記載の方法。
(4) 上記(1)〜(3)のいずれか記載の方法により製造された湯分散性の良い青汁粉末。
That is, the present invention includes the following features.
(1) After the squeezed green juice is dried, it is dissolved again in the solvent, and then (i) subjected to treatment including spray drying, or (ii) subjected to heat treatment and lyophilization treatment, A method for producing green juice powder having good hot water dispersibility, including drying.
(2) The method according to (1) above, wherein the heating temperature is 70 ° C. or higher.
(3) The method according to (1) or (2) above, wherein the raw material of the green juice is barley young leaves.
(4) A green juice powder having good hot water dispersibility, produced by the method according to any one of (1) to (3) above.
本発明によれば、食品添加物を含まない、湯分散性の良い青汁粉末を簡便かつ安価に製造することができる。 According to the present invention, it is possible to easily and inexpensively produce a green juice powder that does not contain food additives and has good hot water dispersibility.
本発明は、湯分散性の良い青汁粉末を製造する方法(以下、単に本発明の方法という)。本明細書に記載する用語「湯分散性の良い」は、90℃以上の飲用溶媒に溶解させた際に、少なくとも5分間は青汁の均一な緑色を維持することをいう。 The present invention is a method for producing a green juice powder with good hot water dispersibility (hereinafter simply referred to as the method of the present invention). The term “good hot water dispersibility” described herein refers to maintaining a uniform green color of green juice for at least 5 minutes when dissolved in a drinking solvent at 90 ° C. or higher.
本発明の方法は、搾汁した青汁を乾燥処理後、再度溶解させてから、(i)噴霧乾燥を含む処理に供するか、又は(ii)加熱処理と凍結乾燥処理とに供することにより、再度乾燥させることを含んでいる。 In the method of the present invention, the squeezed green juice is dried and then dissolved again, and then subjected to (i) treatment including spray drying, or (ii) heat treatment and freeze-drying treatment. Includes drying again.
本発明において、出発原料からの搾汁処理及びその後の乾燥処理については特別な手法を使用する必要はなく、当業者に一般的な手法により行うことができる。 In the present invention, it is not necessary to use a special technique for the squeezing treatment from the starting material and the subsequent drying treatment, and can be carried out by a technique common to those skilled in the art.
本発明において、出発原料は青汁原料として使用することができるものであればどのような植物を用いてもよいが、ダイコン、ブロッコリー、カリフラワー、キャベツ、メキャベツ、白菜、かぶ、わさび、タイサイ、ミズナ、スグキナ、小松菜、からし菜、ケールなどのアブラナ科植物、大麦若葉、イネ、コムギ、カラスムギ、ライムギ、キビ、アワ、ヒエ、トウモロコシなどのイネ科植物、明日葉、セリ、ニンジン、セロリなどのセリ科植物、よもぎ、春菊などのキク科植物、ほうれん草、フダンソウなどのアカザ科植物、甘藷、ヨウサイなどのヒルガオ科植物、イグサなどのイグサ科植物などを使用することができる。青汁原料として大麦若葉を使用することが好ましい。 In the present invention, any starting material may be used as long as it can be used as a green juice raw material, but radish, broccoli, cauliflower, cabbage, cabbage, Chinese cabbage, turnip, wasabi, Taisai, Mizuna Cruciferous plants such as sugkina, komatsuna, mustard vegetable, kale, young barley, rice, wheat, oats, rye, millet, millet, millet, corn, etc., tomorrow, seri, carrot, celery, etc. Asteraceae plants, asteraceae plants such as mugwort and spring chrysanthemum, red crustaceae plants such as spinach and chard, convolvulaceae plants such as sweet potato and wild rhinoceros, and rush family plants such as rush. It is preferable to use barley young leaves as a green juice raw material.
例えば搾汁処理は、青汁原料を洗浄後、必要に応じて細断又は粉砕処理を施した後、一般的に使用される搾汁機を使用して行うことができる。搾汁機としては、これに限定されるものではないが、例えばスクリュープレス、フィルタープレス、パルパー、デカンターなど、飲食品分野で搾汁に通常用いられているものを適宜組合せて使用することができる。 For example, the squeezing treatment can be performed using a squeezing machine that is generally used after washing the green juice raw material, and performing shredding or pulverization treatment as necessary. The squeezer is not limited to this, but for example, a screw press, a filter press, a pulper, a decanter, etc., which are usually used for squeezing in the food and beverage field can be used in appropriate combination. .
また乾燥処理は、熱風乾燥、凍結乾燥、噴霧乾燥など当業者が通常用いる任意の方法を用いることができる。特に噴霧乾燥は、熱による変質が熱風乾燥に比べて小さく、また凍結乾燥に比べて乾燥処理時間が短いため、上記のように搾汁された搾汁液の乾燥方法として好ましい。 The drying treatment can be any method commonly used by those skilled in the art, such as hot air drying, freeze drying, and spray drying. In particular, spray drying is preferable as a method for drying a squeezed juice squeezed as described above, because alteration due to heat is smaller than that of hot air drying and drying time is shorter than that of freeze drying.
また、乾燥前に殺菌処理を行ってもよい。例えば加熱殺菌、高圧殺菌など、当業者が通常用いる任意の方法を用いることができる。 Moreover, you may sterilize before drying. For example, any method usually used by those skilled in the art, such as heat sterilization and high-pressure sterilization, can be used.
本発明の方法において、上記のようにして乾燥された青汁粉末を再度溶媒に溶解させる。青汁粉末を溶解させる溶媒としては、次工程である乾燥工程に悪影響を及ぼさないものであればどのような溶媒でも構わないが、好ましくは水、又は水とアルコールの混合液などである。水の重量に対する乾燥された青汁粉末の投入量については特に制限はなく、均一に溶解できる条件であればどのような割合でもよい。また、溶解させる方法についても特に制限はなく、均一に溶解できる方法であればどのような方法でもよい。 In the method of the present invention, the green juice powder dried as described above is dissolved again in a solvent. The solvent for dissolving the green juice powder may be any solvent as long as it does not adversely affect the subsequent drying step, and is preferably water or a mixture of water and alcohol. There is no restriction | limiting in particular about the input amount of the dried green juice powder with respect to the weight of water, What kind of ratio may be sufficient as long as it is the conditions which can melt | dissolve uniformly. Moreover, there is no restriction | limiting in particular about the method to melt | dissolve, What kind of method may be sufficient if it is a method which can melt | dissolve uniformly.
続いて上記のようにして再溶解された青汁を、上記(i)又は(ii)に規定される第2の乾燥処理に供する。
上記(i)の乾燥処理は、噴霧乾燥を含む処理である。「噴霧乾燥を含む処理」とは、噴霧乾燥以外の乾燥処理や、加熱処理などと適宜組合せた処理を含む意図である。加熱処理と組合せて噴霧乾燥を行う場合は、噴霧乾燥前に加熱処理を行うものとする。加熱処理の温度、加熱時間は特に制限されず、例えばそれぞれ50〜130℃、1秒〜30分の範囲で行うことができる。ここで使用する噴霧乾燥処理は、当業者に一般的な手法により行えばよく、例えば常法の噴霧乾燥処理が可能なスプレードライヤー(例えば株式会社山陽社製のもの)によって行えばよい。
Subsequently, the green juice redissolved as described above is subjected to the second drying treatment defined in (i) or (ii) above.
The drying process (i) is a process including spray drying. “Processing including spray drying” is intended to include processing appropriately combined with drying processing other than spray drying, heat treatment, and the like. When spray drying is performed in combination with heat treatment, the heat treatment is performed before spray drying. The temperature and heating time of the heat treatment are not particularly limited, and can be performed, for example, in the range of 50 to 130 ° C. and 1 second to 30 minutes, respectively. The spray-drying process used here may be performed by a method generally used by those skilled in the art. For example, it may be performed by a spray dryer (for example, manufactured by Sanyo Co., Ltd.) capable of performing a conventional spray-drying process.
上記(ii)の乾燥処理は、加熱処理と凍結乾燥処理とからなる処理である。加熱処理と凍結乾燥処理の順序は、加熱処理、凍結乾燥処理の順であるものとする。この乾燥処理における加熱温度は、70℃以上、好ましくは90℃以上である。加熱温度の上限は、製造物を高温にさらすことによる品質低下や加熱機等の機械的制約がない限り、特に制限されない。また加熱時間は、製造物を長時間の加熱条件下にさらすことによる品質低下や加熱機等の機械的制約がない限り特に制限されないが、例えば1秒〜30分とすることができる。ここで使用する凍結乾燥処理は、当業者に一般的な手法により行えばよく、例えば常法の凍結乾燥処理が可能なフリーズドライヤー(例えばタイテック社製)によって行えばよい。 The drying process (ii) is a process including a heating process and a freeze-drying process. The order of the heat treatment and the freeze-drying process is the order of the heat treatment and the freeze-drying process. The heating temperature in this drying treatment is 70 ° C. or higher, preferably 90 ° C. or higher. The upper limit of the heating temperature is not particularly limited as long as there is no deterioration in quality due to exposure of the product to a high temperature or mechanical restrictions such as a heater. The heating time is not particularly limited as long as there is no deterioration in quality due to exposure of the product to long-time heating conditions or mechanical restrictions such as a heater, but it can be set to, for example, 1 second to 30 minutes. The freeze-drying process used here may be performed by a method generally used by those skilled in the art. For example, it may be performed by a freeze dryer (for example, manufactured by Tytec Co., Ltd.) capable of a conventional freeze-drying process.
また、上記(i)又は(ii)の乾燥処理前に殺菌処理を行ってもよい。殺菌処理としては、例えば加熱殺菌、高圧殺菌など、業者が通常用いる任意の方法を用いることができる。 Further, a sterilization treatment may be performed before the drying treatment (i) or (ii). As the sterilization treatment, any method usually used by a trader, such as heat sterilization and high-pressure sterilization, can be used.
上記のようにして製造された青汁粉末は、湯分散性が良く、ホットでの飲用や各種加工食品の原料として広く利用することができる。また本発明の方法で製造された青汁粉末は、乳化剤、環状デキストリン、アラビアガム、グアガム、ローカストビーンガム、タラガム、ペクチン、発酵セルロース、カルボキシメチルセルロースなどの食品添加物を含まない点で特徴付けることができる。 The green juice powder produced as described above has good hot water dispersibility, and can be widely used as a raw material for hot drinking and various processed foods. The green juice powder produced by the method of the present invention may be characterized in that it does not contain food additives such as emulsifier, cyclic dextrin, gum arabic, guar gum, locust bean gum, tara gum, pectin, fermented cellulose, carboxymethylcellulose and the like. it can.
以下、実施例を用いて本発明を具体的に説明するが、本発明はこれら実施例等に限定されるものではない。 EXAMPLES Hereinafter, although this invention is demonstrated concretely using an Example, this invention is not limited to these Examples.
[実施例1] 再度溶解させてから乾燥させた湯分散性の良い青汁の調製
大麦若葉を水で洗浄し粉砕、搾汁した後、搾汁液を濃縮し噴霧乾燥した。得られた粉末を水に再溶解した後、130℃に加熱し、再度噴霧乾燥した。
(青汁の湯分散性の評価)
得られた粉末4gを沸騰させた熱湯100mlで溶解させ、100mlメスシリンダーに移した後、5分間静置し状態を観察した。その結果を表1に示す。なお、湯分散状態の評価基準は以下の通りであった。
<湯分散性評価基準>
◎;全体的に均一に分散して液は緑色、○;一部沈殿・凝集があるが液は緑色
△;沈殿・凝集はあるが液は緑色、×;緑色の沈殿・凝集と褐色の液に分離
[Example 1] Preparation of green juice with good hot water dispersibility which was dissolved again and dried Barley young leaves were washed with water, ground and squeezed, and then the juice was concentrated and spray-dried. The obtained powder was redissolved in water, heated to 130 ° C. and spray-dried again.
(Evaluation of hot water dispersibility of green juice)
4 g of the obtained powder was dissolved in 100 ml of boiling hot water, transferred to a 100 ml graduated cylinder, and allowed to stand for 5 minutes to observe the state. The results are shown in Table 1. In addition, the evaluation criteria of the hot water dispersion state were as follows.
<Evaluation criteria for hot water dispersibility>
◎: The solution is uniformly dispersed as a whole and the liquid is green. ○: The liquid is green with some precipitation / aggregation. △; The liquid is green with precipitation / aggregation. ×: Green precipitation / aggregation and brown liquid Isolated on
[実施例2] 再溶解後の加熱条件の検討
大麦若葉を水で洗浄し粉砕、搾汁した後、搾汁液を濃縮し噴霧乾燥した。得られた粉末を水に再溶解した後、50℃加熱、70℃加熱、90℃加熱、130℃加熱処理若しくは非加熱処理し、噴霧乾燥を行った。また、得られた粉末を水に再溶解した後、70℃加熱、90℃加熱処理し、凍結乾燥処理を行った。得られた粉末4gを沸騰させた熱湯100mlで溶解させ、100mlメスシリンダーに移した後、5分間静置し状態を観察した。その結果を表2に示す。なお、湯分散状態の評価基準は実施例1と同様である。
[Example 2] Examination of heating conditions after re-dissolution After washing barley young leaves with water, pulverizing and squeezing them, the juice was concentrated and spray-dried. After the obtained powder was redissolved in water, it was spray-dried by heating at 50 ° C., heating at 70 ° C., heating at 90 ° C., heating at 130 ° C. or non-heating. Moreover, after redissolving the obtained powder in water, 70 degreeC heating and 90 degreeC heat processing were performed, and the freeze-drying process was performed. 4 g of the obtained powder was dissolved in 100 ml of boiling hot water, transferred to a 100 ml graduated cylinder, and allowed to stand for 5 minutes to observe the state. The results are shown in Table 2. The evaluation criteria for the hot water dispersion state are the same as in Example 1.
[比較例]
1.再度溶解させてから乾燥させる処理を行わない青汁の試作
大麦若葉を水で洗浄し粉砕、搾汁した後、搾汁液を濃縮し噴霧乾燥した。得られた粉末4gを沸騰させた熱湯100mlで溶解させ、100mlメスシリンダーに移した後、5分間静置し状態を観察した。
2.再度溶解させてから非加熱処理又は50℃で加熱処理し、凍結乾燥処理した青汁の試作
大麦若葉を水で洗浄し粉砕、搾汁した後、搾汁液を濃縮し噴霧乾燥した。得られた粉末を水に再溶解した後、50℃加熱若しくは非加熱処理し、凍結乾燥処理を行った。得られた粉末4gを沸騰させた熱湯100mlで溶解させ、100mlメスシリンダーに移した後、5分間静置し状態を観察した。
上記結果を表1及び2に示す。
[Comparative example]
1. Trial manufacture of green juice which does not perform the process of drying after dissolving again Barley young leaves were washed with water, ground and squeezed, then the juice was concentrated and spray-dried. 4 g of the obtained powder was dissolved in 100 ml of boiling hot water, transferred to a 100 ml graduated cylinder, and allowed to stand for 5 minutes to observe the state.
2. Trial manufacture of green juice which was dissolved again and then heat-treated or heat-treated at 50 ° C. and freeze-dried. Barley young leaves were washed with water, ground and squeezed, and then the juice was concentrated and spray-dried. The obtained powder was redissolved in water, and then heated or non-heated at 50 ° C. and lyophilized. 4 g of the obtained powder was dissolved in 100 ml of boiling hot water, transferred to a 100 ml graduated cylinder, and allowed to stand for 5 minutes to observe the state.
The results are shown in Tables 1 and 2.
Claims (4)
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Citations (4)
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JPH04341153A (en) * | 1991-05-17 | 1992-11-27 | Yoshihide Hagiwara | Blue juice or its dried powder and production thereof |
JPH057471A (en) * | 1991-07-03 | 1993-01-19 | Yoshihide Hagiwara | Blue juice or dried powder thereof |
JP2006042805A (en) * | 2004-07-07 | 2006-02-16 | Toyo Shinyaku:Kk | Granulated products containing processed wheat leaves |
JP2006320224A (en) * | 2005-05-17 | 2006-11-30 | House Foods Corp | Beverage and dry powder |
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JPH04341153A (en) * | 1991-05-17 | 1992-11-27 | Yoshihide Hagiwara | Blue juice or its dried powder and production thereof |
JPH057471A (en) * | 1991-07-03 | 1993-01-19 | Yoshihide Hagiwara | Blue juice or dried powder thereof |
JP2006042805A (en) * | 2004-07-07 | 2006-02-16 | Toyo Shinyaku:Kk | Granulated products containing processed wheat leaves |
JP2006320224A (en) * | 2005-05-17 | 2006-11-30 | House Foods Corp | Beverage and dry powder |
Cited By (1)
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WO2011155626A1 (en) | 2010-06-08 | 2011-12-15 | Hitachi Koki Co., Ltd. | Power tool |
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