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GB931943A - Production of carbon monoxide and hydrogen - Google Patents

Production of carbon monoxide and hydrogen

Info

Publication number
GB931943A
GB931943A GB26472/61A GB2647261A GB931943A GB 931943 A GB931943 A GB 931943A GB 26472/61 A GB26472/61 A GB 26472/61A GB 2647261 A GB2647261 A GB 2647261A GB 931943 A GB931943 A GB 931943A
Authority
GB
United Kingdom
Prior art keywords
steam
catalyst
oxygen
fluidized
fluidization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26472/61A
Inventor
Helmut Nonnemacher
Hermann Meyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB931943A publication Critical patent/GB931943A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/28—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles
    • C01B3/30—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles using the fluidised bed technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

A process for the flameless catalytic reaction of liquid sulphur-containing hydrocarbons, especially those containing non-vaporizable constituents, with amounts of oxygen insufficient for complete combustion, to form carbon monoxide and hydrogen, comprises spraying the initial material at a temperature of 800 DEG to 1200 DEG C.; preferably 900 DEG to 1100 DEG C., into a fluidized layer of a nickel catalyst and/or a sulphidic catalyst into which steam and/or CO2 necessary for the reaction is introduced as fluidization agent, and the gas rich in CO and H2 formed is reacted, for conversion of the hydrocarbons and carbon black contained therein, in a further fluidized layer in the presence of a nickel catalyst at a temperature at least 20 DEG C, and preferably at least 50 DEG C., below that of the first stage. Both the initial material and the fluidization agent may be preheated, e.g. to 300 DEG to 500 DEG C. and to 130 DEG to 600 DEG C. respectively. The oxygen and the steam and/or CO2 may be introduced separately, and 25% to 30% of the steam and/or CO2 may be introduced at the second stage. Pressures may be from normal to 50 atmospheres. In an example, a crude oil consisting of 85,6%C, 12,4%H, 2,6%S (per centages by weight) and a net calorific value of 9860 kg. cal. per kg. was sprayed into a fluidized catalyst of 0,2 mm. mean grain size containing 15% Ni and 10% Zr O2 (by weight) with oxygen and steam (preheated to 130 DEG C.) for gasification and fluidization at 1000 DEG C. The gas produced contained H2S, CH4, tar, atomized oil and carbon black, and was led into a second fluidized bed of the same catalyst and reacted with steam and CO2 at 930 DEG C. to form a gas comprising:-53,7% H2, 37,0% CO, 8,9% CO2, 0,1% CH4, 0,3% H2S.
GB26472/61A 1960-07-26 1961-07-21 Production of carbon monoxide and hydrogen Expired GB931943A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB58740A DE1129134B (en) 1960-07-26 1960-07-26 Process for the catalytic conversion of liquid, sulphurous hydrocarbons with insufficient amounts of oxygen for complete combustion to form carbon oxide and hydrogen using fluidized beds consisting of catalyst bodies

Publications (1)

Publication Number Publication Date
GB931943A true GB931943A (en) 1963-07-24

Family

ID=6972183

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26472/61A Expired GB931943A (en) 1960-07-26 1961-07-21 Production of carbon monoxide and hydrogen

Country Status (2)

Country Link
DE (1) DE1129134B (en)
GB (1) GB931943A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114044488A (en) * 2021-09-30 2022-02-15 万华化学集团股份有限公司 Resource utilization method for preparing acetylene and byproduct carbon black from natural gas and burner of gasification furnace

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4483691A (en) * 1982-09-30 1984-11-20 Engelhard Corporation Production of synthetic natural gas from coal gasification liquid by-products

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1023016B (en) * 1956-09-08 1958-01-23 Basf Ag Process for the conversion of oils with insufficient amounts of oxygen for complete combustion to carbon oxide and hydrogen

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114044488A (en) * 2021-09-30 2022-02-15 万华化学集团股份有限公司 Resource utilization method for preparing acetylene and byproduct carbon black from natural gas and burner of gasification furnace

Also Published As

Publication number Publication date
DE1129134B (en) 1962-05-10

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