GB926282A - Improvements in or relating to organo-tin compounds for combating micro-organisms - Google Patents
Improvements in or relating to organo-tin compounds for combating micro-organismsInfo
- Publication number
- GB926282A GB926282A GB1657259A GB1657259A GB926282A GB 926282 A GB926282 A GB 926282A GB 1657259 A GB1657259 A GB 1657259A GB 1657259 A GB1657259 A GB 1657259A GB 926282 A GB926282 A GB 926282A
- Authority
- GB
- United Kingdom
- Prior art keywords
- triphenyl tin
- groups
- compounds
- radical
- carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 244000005700 microbiome Species 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 6
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical class C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 abstract 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 4
- NJLWREKTMWOSBL-UHFFFAOYSA-N C1(=CC=C(C=C1)S(=O)(=O)N)C.C1(=CC=CC=C1)[Sn](C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=C(C=C1)S(=O)(=O)N)C.C1(=CC=CC=C1)[Sn](C1=CC=CC=C1)C1=CC=CC=C1 NJLWREKTMWOSBL-UHFFFAOYSA-N 0.000 abstract 3
- BFWMWWXRWVJXSE-UHFFFAOYSA-M fentin hydroxide Chemical compound C=1C=CC=CC=1[Sn](C=1C=CC=CC=1)(O)C1=CC=CC=C1 BFWMWWXRWVJXSE-UHFFFAOYSA-M 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 abstract 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 abstract 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 2
- -1 aromatic dicarboxylic acids Chemical class 0.000 abstract 2
- 229940067597 azelate Drugs 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 2
- 229940116351 sebacate Drugs 0.000 abstract 2
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 abstract 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 abstract 2
- 229940095064 tartrate Drugs 0.000 abstract 2
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 abstract 1
- 150000003628 tricarboxylic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises compounds of the formula: [C6H3)5-SN]n-Q where n is 1, 2 or 3 and Q represents a radical containing 1 to 12 carbon atoms derived from a compound which contans 1 to 3 -COOH groups and may contain one or more hydroxyl groups provided that the said compound contains in total 2 to 4 -OH groups of which at least one and at the most three form part of -COOH groups, this radical (Q) being bound to tin by the oxygen atom(s) of one or more carboxyl groups; or n is 1 or 2 and Q represents the carbonate radical; or n is 1 and Q represents a para-toluenesulphonamido group. Compounds specified include triphenyl tin derivatives of carbonic acid, aliphatic and aromatic dicarboxylic acids and hydroxymonol, di- and tri-carboxylic acids, such as the acidic and neutral triphenyl tin carbonate, oxalate, malonate, succinate, adipate, azelate, sebacate, maleate, fumarate, phthalate, tartrate and citrate, triphenyl tin glycollate and lactate and in particular triphenyl tin p-toluenesulphonamide. They may be prepared by reacting triphenyl tin hydroxide, preferably in solution in say, ethanol, with the suitable carboxylic acid. Triphenyl tin carbonate may be prepared by reacting triphenyl tin hydroxide, preferably in solution for example in chloroform, with carbon dioxide. Triphenyl tin p-toluene-sulphonamide <FORM:0926282/IV(a)/1> may be prepared by reacting triphenyl tin hydroxide with p-toluenesulphonamide. The compounds of the invention may be used as fungicides (see Group VI). Specifications 734,119 and 797,073 are referred to.ALSO:Compounds of formula [(C6H5)3Sn]n-Q, where n is 1, 2 or 3 and Q represents a radical containing 1 to 12 carbon atoms derived from a compound which contains 1 to 3 -COOH groups and may contain one or more hydroxyl groups, provided that the said compound contains in total 2 to 4 -OH groups of which at least one and at the most three form part of -COOH groups, this radical (Q) being bound to the tin by the oxygen atoms(s) of one or/more carboxyl groups; or n is 1 or 2 and Q represents the carbonate radical; or n is 1 and Q represents a para-toluenesulphonamido group. Compounds specified include the acidic and neutral triphenyltin carbonate, oxalate, malonate, succinate, adipate, azelate, sebacate, maleate, fumarate, phthalate, tartrate, citrate, glycollate, lactate and triphenyltin - p - toluene - sulphonamide. The active compounds may be used in miscible oils together with emulsifiers, as aerosols, wettable powders, dusts or as seed-protecting compositions mixed with kaolin and an adhesive (spindle oil). Specifications 734,119 and 797,073 are referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL227870 | 1958-05-17 | ||
| NL227869 | 1958-05-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB926282A true GB926282A (en) | 1963-05-15 |
Family
ID=26641650
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1657259A Expired GB926282A (en) | 1958-05-17 | 1959-05-14 | Improvements in or relating to organo-tin compounds for combating micro-organisms |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE578745A (en) |
| CH (1) | CH414247A (en) |
| GB (1) | GB926282A (en) |
| NL (4) | NL103105C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3423443A (en) * | 1964-07-28 | 1969-01-21 | Fmc Corp | Fluoroalkyltin compounds |
-
0
- NL NL227869D patent/NL227869A/xx unknown
- NL NL99430D patent/NL99430C/xx active
- NL NL227870D patent/NL227870A/xx unknown
- NL NL103105D patent/NL103105C/xx active
- BE BE578745D patent/BE578745A/xx unknown
-
1959
- 1959-05-14 GB GB1657259A patent/GB926282A/en not_active Expired
- 1959-05-14 CH CH7323659A patent/CH414247A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3423443A (en) * | 1964-07-28 | 1969-01-21 | Fmc Corp | Fluoroalkyltin compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| NL227870A (en) | |
| NL103105C (en) | |
| CH414247A (en) | 1966-05-31 |
| BE578745A (en) | |
| NL99430C (en) | |
| NL227869A (en) |
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