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GB888270A - A method of making synthetic resin/metal fibre articles - Google Patents

A method of making synthetic resin/metal fibre articles

Info

Publication number
GB888270A
GB888270A GB27154/58A GB2715458A GB888270A GB 888270 A GB888270 A GB 888270A GB 27154/58 A GB27154/58 A GB 27154/58A GB 2715458 A GB2715458 A GB 2715458A GB 888270 A GB888270 A GB 888270A
Authority
GB
United Kingdom
Prior art keywords
layers
resin
fibres
ribbons
bisphenol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27154/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB888270A publication Critical patent/GB888270A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

Articles having a surface layer composed of a formed, smooth, hard, uniform material are produced by (i) forming on a pattern a layer of a thermosetting epoxy resin or an unsaturated polyester resin, (ii) homogenously interspersing throughout said resin unwoven fibres or ribbons of heat-conductive metallic material, and (iii) curing said resin to a thermoset condition, said fibres or ribbons having a length between 0,8 and 13 mm. and a cross-sectional perimeter between 0,04 and 2,1 mm. and being present in an amount between 5 and 70% of the total volume of the resin and fibre or ribbon. A series of layers may be applied in this way; applied layers may or may not be cured before further layers are applied; and an applied layer may be compacted, e.g., with an impacting gun. If the layers are not impacted, they may be porous and may be rendered more so by the prior inclusion of blowing agents such as NaHCO3 or p-hydroxy phenylazide. The preferred method of process (ii) is to use a flocking technique as illustrated in the examples. Furthermore, the layers may be built up on a backing material, many being listed and the following being preferred: formed or foamable polyurethane, synthetic resin bonded glass fibre, a mixture of unwoven metal fibres and an epoxy resin, and wood. The use of the following materials under heading (i) is discussed: Epoxy resins: glycidyl ethers of polyhydric phenols (e.g. bisphenol A in the examples) hardened by 2-hydroxyethyl diethylenetriamine, a eutectic mixture of m-phenylenediamine, bisaniline F and bisphenol A, resorcinol, bisphenol A, maleic or phthalic anhydrides, ethylenediamine, diethylenetriamine, polyols, polythiols, trimethylamine, triethylamine, NaOH, KOH or BF3. Polyesters: derived from ethylene or diethylene glycol and fumaric acid or maleic anhydride with or without adipic acid or phthalic anhydride, inhibited by tertiary butyl catechol or hydroquinone, and cross-linked with styrene or diallylphthalate in the presence of azo compounds, benzoyl peroxide, tert. butyl perbenzoate or methyl ethyl ketone peroxide. The fibres or ribbons of (ii) may be of steel, Al Cu, Ag, Ni or brass, or of plastic or glass fibre coated with Ag, Al or Cu. Optional fillers include stainless steel flake, Fe or Al oxides, Fe, Al and silica. Uses: A wide variety of articles, especially dies, moulds, panels and checking fixtures, may be formed.ALSO:Articles having a surface layer composed of a formed, smooth, hard, uniform material are produced by (i) forming on a pattern a layer of a thermosetting epoxy resin or an unsaturated polyester resin, (ii) homogeneously interspersing throughout said resin unwoven fibres or ribbons of heat-conductive metallic material, and (iii) curing said resin to a thermoset condition, said fibres or ribbons having a length between 0,8 and 13 mm. and a cross-sectional perimeter between 0,04 and 2,1 mm. and being present in an amount between 5 and 70% of the total volume of the resin and fibre or ribbon. A series of layers may be applied in this way; applied layers may or may not be cured before further layers are applied; and an applied layer may be compacted, e.g. with an impacting gun. If the layers are not impacted, they may be porous and may be rendered more so by the prior inclusion of blowing agents such as NaHCO3 or p-hydroxy phenylazide. The preferred method of process (ii) is to use a flocking technique as illustrated in the examples. Furthermore, the layers may be built up on a backing material, many being listed and the following being preferred:- foamed or foamable polyurethane, synthetic resin bonded glass fibres, a mixture of unwoven metal fibres and an epoxy resin, and wood. The use of the following materials under heading (i) is discussed:-Epoxy resins: glycidyl ethers of polyhydricphenols (e.g. bisphenol A in the examples) hardened by 2-hydroxyethyl diethylenetriamine, a eutectic mixture of m-phenylenediamine, bisaniline F and bisphenol A, resorcinol, bisphenol A, maleic or phthalic anhydrides, ethylenediamine, diethylenetriamine, polyols, polythiols, trimethylamine, triethylamine, NaOH, KOH or BF3. Polyesters: derived from ethylene or diethylene glycol and fumaric acid or maleic anhydride with or without adipic acid or phthalic anhydride, inhibited by tertiary butyl catechol or hydroquinone, and cross-linked with styrene or diallylphthalate in the presence of azo compounds, benzoyl peroxide, tert. butyl perbenzoate or methyl ethyl ketone peroxide. The fibres or ribbons of (ii) may be of steel, Al, Cu, Ag, Ni or brass, or of plastic or glass fibre coated with Ag, Al or Cu. Optional fillers include stainless steel flake, Fe or Al oxides, Fe, Al and silica. Uses: A wide variety of articles, especially dies, moulds, panels and checking fixtures, may be formed.ALSO:Articles having a surface layer composed of a formed, smooth, hard, uniform material are produced by (i) forming on a pattern a layer of a thermosetting epoxy resin or an unsaturated polyester resin, (ii) homogeneously interspersing throughout said resin unwoven fibres or ribbons of heat-conductive metallic material, and (iii) curing said resin to a thermoset condition, said fibres or ribbons having a length between 0,8 and 13 mm. and a cross-sectional perimeter between 0,04 and 2,1 mm. and being present in an amount between 5 and 70% of the total volume of the resin and fibre or ribbon. A series of layers may be applied in this way; applied layers may or may not be cured before further layers are applied; and an applied layer may be compacted, e.g., with an impacting gun. If the layers are not impacted, they may be porous and may be rendered more so by the prior inclusion of blowing agents such as NaHCO3 or p-hydroxy phenylazide. The preferred method of process (ii) is to use a flocking technique as illustrated in the examples. Furthermore, the layers may be built up on a backing material, many being listed and the following being preferred:- foamed or foamable polyurethane, synthetic resin bonded glass fibres, a mixture of unwoven metal fibres and an epoxy resin, and wood. The use of the following materials under heading (i) is discussed:- Epoxy resins: glycidyl ethers of polyhydricphenols (e.g. bisphenol A in the examples) hardened by 2-hydroxyethyl diethylenetriamine a eutectic mixture of m-phenylenediamine, bisaniline F and bisphenol A, resorcinol, bisphenol A, maleic or phthalic anyhdrides, ethylenediamine, diethylenetriamine, polyols, polythiols, trimthylamine, triethylamine, NaOH, KOH or BF3. Polyesters: derived from ethylene or diethylene glycol and fumaric acid or maleic anhydride with or without adipic acid or phthalic anhydride, inhibited by tertiary butyl catechol or hydroquinone, and cross-linked with styrene or diallylphthalate in the presence of azo compounds, benzoyl peroxide, tert. butyl perbenzoate or methyl ethyl ketone peroxide. The fibres or ribbons of (ii) may be of steel, Al, Cu, Ag. Ni or brass, or of plastic or glass fibre coated with Ag, Al or Cu. Optional fillers include stainless steel flake, Fe or Al oxides, Fe, Al and silica. Uses: A wide variety of articles, especially dies, moulds, panels and checking fixtures, may be formed.
GB27154/58A 1957-08-26 1958-08-25 A method of making synthetic resin/metal fibre articles Expired GB888270A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US888270XA 1957-08-26 1957-08-26

Publications (1)

Publication Number Publication Date
GB888270A true GB888270A (en) 1962-01-31

Family

ID=22213734

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27154/58A Expired GB888270A (en) 1957-08-26 1958-08-25 A method of making synthetic resin/metal fibre articles

Country Status (1)

Country Link
GB (1) GB888270A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2117388A (en) * 1982-03-19 1983-10-12 Hepworth Plastics Ltd Moulding compounds
GB2232629A (en) * 1989-05-26 1990-12-19 Stom Holdings Sink tops

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2117388A (en) * 1982-03-19 1983-10-12 Hepworth Plastics Ltd Moulding compounds
GB2232629A (en) * 1989-05-26 1990-12-19 Stom Holdings Sink tops

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