GB878139A - Improvements in or relating to aqueous emulsions of epoxy resins - Google Patents
Improvements in or relating to aqueous emulsions of epoxy resinsInfo
- Publication number
- GB878139A GB878139A GB10655/60A GB1065560A GB878139A GB 878139 A GB878139 A GB 878139A GB 10655/60 A GB10655/60 A GB 10655/60A GB 1065560 A GB1065560 A GB 1065560A GB 878139 A GB878139 A GB 878139A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- drying
- epoxy resin
- resin
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003822 epoxy resin Substances 0.000 title abstract 4
- 229920000647 polyepoxide Polymers 0.000 title abstract 4
- 239000000839 emulsion Substances 0.000 title abstract 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 title 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 abstract 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- 238000007605 air drying Methods 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 abstract 1
- UHYPYGJEEGLRJD-UHFFFAOYSA-N cadmium(2+);selenium(2-) Chemical compound [Se-2].[Cd+2] UHYPYGJEEGLRJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 239000004359 castor oil Substances 0.000 abstract 1
- 235000019438 castor oil Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 abstract 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 abstract 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 150000002780 morpholines Chemical class 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000003352 sequestering agent Substances 0.000 abstract 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- 235000015096 spirit Nutrition 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 229960004418 trolamine Drugs 0.000 abstract 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/22—Amides or hydrazides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/027—Dispersing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Epoxy Resins (AREA)
Abstract
An aqueous emulsion of an epoxy resin contains as an emulsifying agent a mixture of mono-, di- or tri-ethanolamine and an unsaturated fatty acid having at least two ethylenically unsaturated groups in the molecule (e.g. the fatty acids of linseed oil, soyabean oil, tall oil, dehydrated castor oil or wood-resin). The epoxy resin is preferably a glycidyl polyether and may be modified by a phenol, an amine or a fatty acid of a drying or semi-drying oil. The epoxy resin is generally emulsified while dissolved in an organic solvent (e.g. xylene or white spirits). The emulsions may be used as air-drying or stoving coating compositions and may also contain (a) an alkyd resin or a phenol-, urea- or melamine-formaldehyde resin; (b) a pigment, e.g. iron oxide, barytes, titanium dioxide, chromium oxide, cadmium sulphide, cadmium selenide, carbon black, sienna, umber or a mixture of red iron oxide and barytes; (c) a drier, e.g. lead or cobalt naphthenate; (d) a sequestering agent, e.g. citric acid or sodium hexametaphosphate; (e) a curing agent, e.g. the morpholine salt of toluene sulphonic acid; or (f) a thickening agent.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB10655/60A GB878139A (en) | 1960-03-25 | 1960-03-25 | Improvements in or relating to aqueous emulsions of epoxy resins |
NL262774D NL262774A (en) | 1960-03-25 | 1960-03-25 | |
BE601704D BE601704A (en) | 1960-03-25 | 1961-03-23 | |
FR856734A FR1284905A (en) | 1960-03-25 | 1961-03-24 | Emulsion production |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB10655/60A GB878139A (en) | 1960-03-25 | 1960-03-25 | Improvements in or relating to aqueous emulsions of epoxy resins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB878139A true GB878139A (en) | 1961-09-27 |
Family
ID=29585764
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB10655/60A Expired GB878139A (en) | 1960-03-25 | 1960-03-25 | Improvements in or relating to aqueous emulsions of epoxy resins |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE601704A (en) |
FR (1) | FR1284905A (en) |
GB (1) | GB878139A (en) |
NL (1) | NL262774A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1980000447A1 (en) * | 1978-08-21 | 1980-03-20 | Grow Group Inc | Aqueous dispersion coating composition and application to molded articles |
US4263352A (en) * | 1978-08-21 | 1981-04-21 | Grow Group, Inc. | Aqueous dispersion coating composition and application to molded articles |
CN104178000A (en) * | 2013-05-23 | 2014-12-03 | 海安县国力化工有限公司 | Emulsion paint |
CN112409558A (en) * | 2020-11-06 | 2021-02-26 | 常州大学 | Epoxy emulsifier with high-branching degree hydrophilic chain and preparation method thereof |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3525254C1 (en) * | 1985-07-15 | 1987-04-02 | Wiederhold Hermann Gmbh | Process for the reprocessing of paint waste and use of the aqueous dispersions obtained in the process |
GB2331993B (en) | 1997-12-04 | 2002-06-05 | Rhone Poulenc Chemicals | Dispersed resins for use in coating compositions |
-
1960
- 1960-03-25 NL NL262774D patent/NL262774A/xx unknown
- 1960-03-25 GB GB10655/60A patent/GB878139A/en not_active Expired
-
1961
- 1961-03-23 BE BE601704D patent/BE601704A/nl unknown
- 1961-03-24 FR FR856734A patent/FR1284905A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1980000447A1 (en) * | 1978-08-21 | 1980-03-20 | Grow Group Inc | Aqueous dispersion coating composition and application to molded articles |
US4263352A (en) * | 1978-08-21 | 1981-04-21 | Grow Group, Inc. | Aqueous dispersion coating composition and application to molded articles |
CN104178000A (en) * | 2013-05-23 | 2014-12-03 | 海安县国力化工有限公司 | Emulsion paint |
CN112409558A (en) * | 2020-11-06 | 2021-02-26 | 常州大学 | Epoxy emulsifier with high-branching degree hydrophilic chain and preparation method thereof |
CN112409558B (en) * | 2020-11-06 | 2022-04-08 | 常州大学 | Epoxy emulsifier with high-branching degree hydrophilic chain and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
FR1284905A (en) | 1962-02-16 |
BE601704A (en) | 1961-09-25 |
NL262774A (en) | 1964-05-25 |
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