GB1123551A - Method of freeing carbon monoxide-containing gas mixtures from oxygen - Google Patents
Method of freeing carbon monoxide-containing gas mixtures from oxygenInfo
- Publication number
- GB1123551A GB1123551A GB17977/66A GB1797766A GB1123551A GB 1123551 A GB1123551 A GB 1123551A GB 17977/66 A GB17977/66 A GB 17977/66A GB 1797766 A GB1797766 A GB 1797766A GB 1123551 A GB1123551 A GB 1123551A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxygen
- hydrogen
- carbon monoxide
- removal
- gas mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 7
- 239000001301 oxygen Substances 0.000 title abstract 7
- 229910052760 oxygen Inorganic materials 0.000 title abstract 7
- 239000000203 mixture Substances 0.000 title abstract 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title abstract 3
- 229910002091 carbon monoxide Inorganic materials 0.000 title abstract 3
- 239000007789 gas Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 239000000741 silica gel Substances 0.000 abstract 2
- 229910002027 silica gel Inorganic materials 0.000 abstract 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000010304 firing Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
Abstract
Oxygen is removed from gas mixtures containing carbon monoxide by reacting the oxygen with hydrogen, provided in stoichiometric excess, in the presence of a metallic copper catalyst supported on a carrier. A catalyst containing 10% copper, based on the weight of the silica gel carrier, may be prepared by impregnating dried silica gel with an aqueous copper nitrate solution, drying for 2-3 hours at 100-120 DEG C. and firing at 400 DEG C. until the evolution of nitrogen oxides ceases followed by reduction at 200-250 DEG C. for 4-8 hours with hydrogen or with the gas mixture to be treated. The oxygen removal process may be carried out at 150-220 DEG C. with a pressure of 100-300 atm. using a space velocity of 1000-6000 by volume per hour or at 190-250 DEG C. at atmospheric pressure using a space velocity of 1000-3000. The removal of oxygen from carbon monoxide/hydrogen mixtures is exemplified and compared with the removal of oxygen from otherwise pure hydrogen containing 0.2% by volume of oxygen using the same catalyst.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB17977/66A GB1123551A (en) | 1966-04-25 | 1966-04-25 | Method of freeing carbon monoxide-containing gas mixtures from oxygen |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB17977/66A GB1123551A (en) | 1966-04-25 | 1966-04-25 | Method of freeing carbon monoxide-containing gas mixtures from oxygen |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1123551A true GB1123551A (en) | 1968-08-14 |
Family
ID=10104516
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17977/66A Expired GB1123551A (en) | 1966-04-25 | 1966-04-25 | Method of freeing carbon monoxide-containing gas mixtures from oxygen |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1123551A (en) |
-
1966
- 1966-04-25 GB GB17977/66A patent/GB1123551A/en not_active Expired
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