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FR2862302A1 - Procede pour l'oxydation catalytique d'olefines en enols, olefine-cetones et epoxydes - Google Patents

Procede pour l'oxydation catalytique d'olefines en enols, olefine-cetones et epoxydes Download PDF

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Publication number
FR2862302A1
FR2862302A1 FR0452664A FR0452664A FR2862302A1 FR 2862302 A1 FR2862302 A1 FR 2862302A1 FR 0452664 A FR0452664 A FR 0452664A FR 0452664 A FR0452664 A FR 0452664A FR 2862302 A1 FR2862302 A1 FR 2862302A1
Authority
FR
France
Prior art keywords
porphyrins
catalyst
olefins
reaction
general formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR0452664A
Other languages
English (en)
French (fr)
Inventor
Cancheng Guo
Wen Liu
Jinyong Ma
Yanli Mao
Qiang Liu
Xutao Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Hunan University
Original Assignee
China Petroleum and Chemical Corp
Hunan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Hunan University filed Critical China Petroleum and Chemical Corp
Publication of FR2862302A1 publication Critical patent/FR2862302A1/fr
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
FR0452664A 2003-11-18 2004-11-17 Procede pour l'oxydation catalytique d'olefines en enols, olefine-cetones et epoxydes Pending FR2862302A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2003101105337A CN1283602C (zh) 2003-11-18 2003-11-18 催化氧化烯烃成烯醇、烯酮和环氧化合物的方法

Publications (1)

Publication Number Publication Date
FR2862302A1 true FR2862302A1 (fr) 2005-05-20

Family

ID=34335647

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0452664A Pending FR2862302A1 (fr) 2003-11-18 2004-11-17 Procede pour l'oxydation catalytique d'olefines en enols, olefine-cetones et epoxydes

Country Status (3)

Country Link
CN (1) CN1283602C (zh)
FR (1) FR2862302A1 (zh)
NL (1) NL1027537C2 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1943237A2 (en) * 2005-10-25 2008-07-16 University Of Kansas Process for selective oxidation of olefins to epoxides
US8080677B2 (en) 2005-10-25 2011-12-20 University Of Kansas Process for selective oxidation of olefins to epoxides

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101899022B (zh) * 2010-07-27 2012-01-18 中山大学 一种仿生催化丙烯环氧化制备环氧丙烷的方法
CN102050711B (zh) * 2010-12-21 2013-02-06 中山大学 一种丙烯醛的制备方法
CN102206146B (zh) * 2011-03-23 2014-04-16 中山大学 一种香兰素的制备方法
CN105001183B (zh) * 2015-07-29 2017-12-19 中山大学惠州研究院 一种联产环氧丙烷和糠酸的方法
CN105669598B (zh) * 2016-01-12 2018-06-29 中国林业科学研究院林产化学工业研究所 一种α-蒎烯烯丙位选择性氧化方法及其产品
CN105585541B (zh) * 2016-03-10 2018-04-06 中山大学惠州研究院 一种环氧环己烷的制备方法
CN111039902B (zh) * 2019-10-25 2023-06-02 中山大学惠州研究院 一种环氧环己烷的制备方法
CN112341407A (zh) * 2020-10-23 2021-02-09 如皋市丹凤纺织有限公司 一种纱线浸渍助剂合成方法
CN119192101A (zh) * 2024-11-29 2024-12-27 山东华安新材料有限公司 一种环氧环己烷的制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4822899A (en) * 1985-04-12 1989-04-18 The University Of Michigan Metallic porphyrin complexes as catalysts in epoxidation reactions
US4900871A (en) * 1987-01-02 1990-02-13 Sun Refining And Marketing Company Hydrocarbon oxidations catalyzed by iron coordination complexes containing a halogenated ligand
JPH03232534A (ja) * 1990-02-08 1991-10-16 Mitsui Toatsu Chem Inc ポルフィリン錯体によるオレフィンの酸素酸化法
JPH03246238A (ja) * 1990-02-26 1991-11-01 Mitsui Toatsu Chem Inc ハロゲン化ポルフィリン錯体触媒によるオレフィンの酸素酸化法
EP0527623A2 (en) * 1991-08-12 1993-02-17 SUN COMPANY, INC. (R&M) Allylic oxidation of olefins
EP0532327A2 (en) * 1991-09-12 1993-03-17 SUN COMPANY, INC. (R&M) Cyano- and polycyanometalloporphyrins as catalysts for alkane oxidation
WO1998004538A1 (en) * 1996-07-26 1998-02-05 Princeton University Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4822899A (en) * 1985-04-12 1989-04-18 The University Of Michigan Metallic porphyrin complexes as catalysts in epoxidation reactions
US4900871A (en) * 1987-01-02 1990-02-13 Sun Refining And Marketing Company Hydrocarbon oxidations catalyzed by iron coordination complexes containing a halogenated ligand
JPH03232534A (ja) * 1990-02-08 1991-10-16 Mitsui Toatsu Chem Inc ポルフィリン錯体によるオレフィンの酸素酸化法
JPH03246238A (ja) * 1990-02-26 1991-11-01 Mitsui Toatsu Chem Inc ハロゲン化ポルフィリン錯体触媒によるオレフィンの酸素酸化法
EP0527623A2 (en) * 1991-08-12 1993-02-17 SUN COMPANY, INC. (R&M) Allylic oxidation of olefins
EP0532327A2 (en) * 1991-09-12 1993-03-17 SUN COMPANY, INC. (R&M) Cyano- and polycyanometalloporphyrins as catalysts for alkane oxidation
WO1998004538A1 (en) * 1996-07-26 1998-02-05 Princeton University Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 1991, 16 October 1991 Derwent World Patents Index; AN 1991-349039, XP002366134 *
LI Z ET AL: "Epoxidation of olefins catalyzed by manganese(III) porphyrin in a room temperature ionic liquid", TETRAHEDRON LETTERS, ELSEVIER, AMSTERDAM, NL, vol. 44, no. 10, 3 March 2003 (2003-03-03), pages 2069 - 2071, XP004410073, ISSN: 0040-4039 *
LONG G S ET AL: "TRANSITION METAL PHTHALOCYANINE AND PORPHYRIN COMPLEXES A CATALYSTSFOR THE POLYMERIZATION OF OLEFINS", POLYMER PREPRINTS, AMERICAN CHEMICAL SOCIETY, US, vol. 40, no. 2, 1999, pages 843 - 844, XP000994565, ISSN: 0032-3934 *
PATENT ABSTRACTS OF JAPAN *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1943237A2 (en) * 2005-10-25 2008-07-16 University Of Kansas Process for selective oxidation of olefins to epoxides
EP1943237A4 (en) * 2005-10-25 2009-10-21 Univ Kansas PROCESS FOR SELECTIVE OXIDATION OF OLEFINS INTO EPOXY RESINS
US7649101B2 (en) 2005-10-25 2010-01-19 University Of Kansas Process for selective oxidation of olefins to epoxides
US8080677B2 (en) 2005-10-25 2011-12-20 University Of Kansas Process for selective oxidation of olefins to epoxides

Also Published As

Publication number Publication date
NL1027537C2 (nl) 2005-09-13
NL1027537A1 (nl) 2005-05-23
CN1283602C (zh) 2006-11-08
CN1544404A (zh) 2004-11-10

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