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FR2755971B1 - Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation - Google Patents

Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation

Info

Publication number
FR2755971B1
FR2755971B1 FR9614058A FR9614058A FR2755971B1 FR 2755971 B1 FR2755971 B1 FR 2755971B1 FR 9614058 A FR9614058 A FR 9614058A FR 9614058 A FR9614058 A FR 9614058A FR 2755971 B1 FR2755971 B1 FR 2755971B1
Authority
FR
France
Prior art keywords
preparation
rare earth
coloring pigment
beta form
earth sulfide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9614058A
Other languages
English (en)
French (fr)
Other versions
FR2755971A1 (fr
Inventor
Sylvain Busnot
Pierre Macaudier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9614058A priority Critical patent/FR2755971B1/fr
Application filed by Rhodia Chimie SAS filed Critical Rhodia Chimie SAS
Priority to PCT/FR1997/002018 priority patent/WO1998022391A1/fr
Priority to CN97181084A priority patent/CN1087273C/zh
Priority to CA002272459A priority patent/CA2272459A1/fr
Priority to EP97945900A priority patent/EP0948459A1/fr
Priority to JP10519770A priority patent/JP2000505039A/ja
Priority to KR1019990704400A priority patent/KR20000057133A/ko
Priority to AU51236/98A priority patent/AU729959B2/en
Publication of FR2755971A1 publication Critical patent/FR2755971A1/fr
Application granted granted Critical
Publication of FR2755971B1 publication Critical patent/FR2755971B1/fr
Priority to US09/864,956 priority patent/US20010038815A1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/10—Preparation or treatment, e.g. separation or purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/288—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/60—Compounds characterised by their crystallite size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/62—L* (lightness axis)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/63—Optical properties, e.g. expressed in CIELAB-values a* (red-green axis)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/65—Chroma (C*)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009—Sulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Nanotechnology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Paints Or Removers (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Paper (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cosmetics (AREA)
FR9614058A 1996-11-19 1996-11-19 Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation Expired - Fee Related FR2755971B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR9614058A FR2755971B1 (fr) 1996-11-19 1996-11-19 Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation
CN97181084A CN1087273C (zh) 1996-11-19 1997-11-10 β－型稀土金属硫化物的制备方法
CA002272459A CA2272459A1 (fr) 1996-11-19 1997-11-10 Procede de preparation d'un sulfure de terre rare de forme beta utilisable comme pigment colorant
EP97945900A EP0948459A1 (fr) 1996-11-19 1997-11-10 Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation
PCT/FR1997/002018 WO1998022391A1 (fr) 1996-11-19 1997-11-10 Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation
JP10519770A JP2000505039A (ja) 1996-11-19 1997-11-10 β型希土類金属硫化物の着色顔料としての使用及びその製造方法
KR1019990704400A KR20000057133A (ko) 1996-11-19 1997-11-10 베타 희토류 황화물의 착색 안료로서의 용도 및 그의 제조 방법
AU51236/98A AU729959B2 (en) 1996-11-19 1997-11-10 Sulphide of beta form and its use as a colouring pigment
US09/864,956 US20010038815A1 (en) 1996-11-19 2001-05-24 Process for the preparation of a rare-earth metal sulphide of beta form, the rare-earth metal being lanthanum, cerium, praseodymium, samarium or neodymium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9614058A FR2755971B1 (fr) 1996-11-19 1996-11-19 Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation

Publications (2)

Publication Number Publication Date
FR2755971A1 FR2755971A1 (fr) 1998-05-22
FR2755971B1 true FR2755971B1 (fr) 1999-03-05

Family

ID=9497740

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9614058A Expired - Fee Related FR2755971B1 (fr) 1996-11-19 1996-11-19 Utilisation comme pigment colorant d'un sulfure de terre rare de forme beta et son procede de preparation

Country Status (8)

Country Link
EP (1) EP0948459A1 (zh)
JP (1) JP2000505039A (zh)
KR (1) KR20000057133A (zh)
CN (1) CN1087273C (zh)
AU (1) AU729959B2 (zh)
CA (1) CA2272459A1 (zh)
FR (1) FR2755971B1 (zh)
WO (1) WO1998022391A1 (zh)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19810317A1 (de) * 1998-03-11 1999-09-16 Merck Patent Gmbh Seltene Erdmetallsulfidpigmente und Yttriumsulfidpigmente
CN1120804C (zh) * 2000-01-31 2003-09-10 李波 稀土硫化物的制备方法
FR2807023B1 (fr) * 2000-03-30 2002-12-20 Rhodia Terres Rares Composition a base d'un sulfure de terre rare a stabilite chimique amelioree, son procede de preparation et son utilisation comme pigment
JP2002194208A (ja) * 2000-12-27 2002-07-10 Daicel Degussa Ltd 赤系色に着色されたポリアミド系樹脂組成物
CN102127317B (zh) * 2011-01-20 2013-04-17 中国科学院长春应用化学研究所 稀土着色剂及其制备方法
CN103011241B (zh) * 2012-12-31 2015-03-18 江西理工大学 一种稀土镨片状晶体及其制备方法
CN103819934A (zh) * 2014-02-25 2014-05-28 内蒙古大学 一种包覆型稀土硫化物颜料的制备方法
CN103965522B (zh) * 2014-04-15 2016-08-17 包头市宏博科技有限责任公司 一种稀土硫化物橡胶助剂及其制备方法
WO2018025866A1 (ja) * 2016-08-04 2018-02-08 国立大学法人名古屋大学 一硫化サマリウムの製造方法、体積変化材料、体積制御部材、負熱膨張材料、および化合物材料
CN106517295B (zh) * 2016-10-18 2018-02-23 西北工业大学 一种合成高稳定性γ‑Pr2S3粉体的方法
CN107151461B (zh) 2017-06-29 2019-04-26 包头中科世纪科技有限责任公司 着色剂及其制备方法
CN108084736B (zh) * 2017-12-19 2020-07-24 包头中科世纪科技有限责任公司 一种简单无污染处理稀土硫化物颜料的工艺
CN109929269A (zh) * 2017-12-19 2019-06-25 包头中科世纪科技有限责任公司 一种可连续化规模化生产稀土硫化物着色剂的方法
CN109651846B (zh) * 2017-12-28 2021-01-05 包头市宏博特科技有限责任公司 一种稀土硫化物的后处理方法
CN108715549B (zh) * 2018-06-05 2021-04-02 西北工业大学 一种制备稀土硫化物γ-Ln2S3透明陶瓷的方法
CN116143160A (zh) * 2023-02-08 2023-05-23 包头市宏博特科技有限责任公司 具有吸波特性的稀土硫化物及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2100551B1 (zh) * 1970-05-27 1973-11-23 Raffinage Cie Francaise
JPS5120437B2 (zh) * 1973-11-14 1976-06-24
FR2657599B1 (fr) * 1990-01-30 1992-04-03 Loire Atlantique Procedes Chim Procede d'elaboration de composes binaires du soufre.
FR2703999B1 (fr) * 1993-04-16 1995-05-24 Rhone Poulenc Chimie Nouveaux pigments minéraux colorés à base de sulfures de terres rares, procédé de synthèse et utilisations.
FR2706476B1 (fr) * 1993-06-09 1995-09-15 Rhone Poulenc Chimie Procédé de traitement de pigments à base de sulfures de terres, rares, nouveaux pigments ainsi obtenus et leurs utilisations.
FR2719576B1 (fr) * 1994-05-06 1996-07-12 Rhone Poulenc Chimie Composition à base d'un sulfure de terre rare comprenant au moins un élément alcalin, son procédé de préparation et son utilisation comme pigment coloré.
FR2732005B1 (fr) * 1995-03-22 1997-06-13 Rhone Poulenc Chimie Procede de preparation de sulfures de terres rares a partir d'halogenures

Also Published As

Publication number Publication date
CN1241987A (zh) 2000-01-19
FR2755971A1 (fr) 1998-05-22
EP0948459A1 (fr) 1999-10-13
CN1087273C (zh) 2002-07-10
CA2272459A1 (fr) 1998-05-28
AU5123698A (en) 1998-06-10
KR20000057133A (ko) 2000-09-15
WO1998022391A1 (fr) 1998-05-28
AU729959B2 (en) 2001-02-15
JP2000505039A (ja) 2000-04-25

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