FR2673184A1 - Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres. - Google Patents
Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres. Download PDFInfo
- Publication number
- FR2673184A1 FR2673184A1 FR9102076A FR9102076A FR2673184A1 FR 2673184 A1 FR2673184 A1 FR 2673184A1 FR 9102076 A FR9102076 A FR 9102076A FR 9102076 A FR9102076 A FR 9102076A FR 2673184 A1 FR2673184 A1 FR 2673184A1
- Authority
- FR
- France
- Prior art keywords
- process according
- soluble
- polymerization
- monomer
- organic phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 39
- 229920001577 copolymer Polymers 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims description 56
- 238000006116 polymerization reaction Methods 0.000 claims description 41
- 239000002904 solvent Substances 0.000 claims description 28
- 239000003999 initiator Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000012074 organic phase Substances 0.000 claims description 26
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 239000012429 reaction media Substances 0.000 claims description 17
- 239000008346 aqueous phase Substances 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- -1 alkyl sulphates Chemical class 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 230000000295 complement effect Effects 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 239000000375 suspending agent Substances 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
- 230000004913 activation Effects 0.000 claims description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001339 alkali metal compounds Chemical class 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 34
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 15
- 239000004926 polymethyl methacrylate Substances 0.000 description 15
- 238000001035 drying Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 239000002245 particle Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000012071 phase Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- ZXKXJHAOUFHNAS-UHFFFAOYSA-N fenfluramine hydrochloride Chemical compound [Cl-].CC[NH2+]C(C)CC1=CC=CC(C(F)(F)F)=C1 ZXKXJHAOUFHNAS-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 2
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 1
- 235000010263 potassium metabisulphite Nutrition 0.000 description 1
- 239000004297 potassium metabisulphite Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/32—Polymerisation in water-in-oil emulsions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyethers (AREA)
- Amplifiers (AREA)
- Treating Waste Gases (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102076A FR2673184A1 (fr) | 1991-02-21 | 1991-02-21 | Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres. |
| DK92400395.7T DK0500427T3 (da) | 1991-02-21 | 1992-02-13 | Fremgangsmåde til fremstilling af copolymerer, der er opløselige i deres comonomersammensætninger |
| AT92400395T ATE136554T1 (de) | 1991-02-21 | 1992-02-13 | Verfahren zur herstellung von in ihrer monomerischen zusammensetzungen lösbaren (co)- polymeren |
| DE69209697T DE69209697T2 (de) | 1991-02-21 | 1992-02-13 | Verfahren zur Herstellung von in ihrer monomerischen Zusammensetzungen lösbaren (Co)-Polymeren |
| EP92400395A EP0500427B1 (de) | 1991-02-21 | 1992-02-13 | Verfahren zur Herstellung von in ihrer monomerischen Zusammensetzungen lösbaren (Co)-Polymeren |
| ES92400395T ES2086092T3 (es) | 1991-02-21 | 1992-02-13 | Procedimiento de preparacion de (co)polimeros solubles en sus composiciones (co)monomeras. |
| NO920653A NO178970C (no) | 1991-02-21 | 1992-02-19 | Fremgangsmåte for fremstilling av (ko)polymerer som er opplöselige i sine (ko)monomerblandinger |
| IE920529A IE73640B1 (en) | 1991-02-21 | 1992-02-19 | Process for the preparation of (co)polymers soluble in their (co)monomer compositions |
| FI920740A FI920740L (fi) | 1991-02-21 | 1992-02-20 | Foerfaringsmetod av (sam)polymerer, som aer upploesliga i sina (sam)monomerkompositioner |
| CA002061585A CA2061585C (fr) | 1991-02-21 | 1992-02-20 | Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres |
| JP4035176A JP2518762B2 (ja) | 1991-02-21 | 1992-02-21 | その（コ）モノマ―組成物に可溶性である（コ）ポリマ―の製造方法 |
| CN92101104A CN1051772C (zh) | 1991-02-21 | 1992-02-21 | 制备可溶于其组成(共聚)单体的(共)聚合物的方法 |
| US07/846,248 US5272228A (en) | 1991-02-21 | 1992-02-21 | Preparation of (co)polymers soluble in their (co)monomer compositions |
| GR960401388T GR3020025T3 (en) | 1991-02-21 | 1996-05-23 | Process for preparing (co)-polymers soluble in their monomeric compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102076A FR2673184A1 (fr) | 1991-02-21 | 1991-02-21 | Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| FR2673184A1 true FR2673184A1 (fr) | 1992-08-28 |
Family
ID=9409954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9102076A Pending FR2673184A1 (fr) | 1991-02-21 | 1991-02-21 | Procede de preparation de (co)polymeres solubles dans leurs compositions (co)monomeres. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5272228A (de) |
| EP (1) | EP0500427B1 (de) |
| JP (1) | JP2518762B2 (de) |
| CN (1) | CN1051772C (de) |
| AT (1) | ATE136554T1 (de) |
| CA (1) | CA2061585C (de) |
| DE (1) | DE69209697T2 (de) |
| DK (1) | DK0500427T3 (de) |
| ES (1) | ES2086092T3 (de) |
| FI (1) | FI920740L (de) |
| FR (1) | FR2673184A1 (de) |
| GR (1) | GR3020025T3 (de) |
| IE (1) | IE73640B1 (de) |
| NO (1) | NO178970C (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5686518A (en) * | 1993-10-12 | 1997-11-11 | Georgia Tech | Miniemulsion polymerization process using polymeric co-surfactant |
| CN102775615B (zh) * | 2011-05-13 | 2014-02-19 | 中国石油化工股份有限公司 | 一种制备聚苯乙烯塑料小球的方法和其制备的产品及应用 |
| CN103387681B (zh) * | 2012-05-07 | 2015-09-09 | 中国石油化工股份有限公司 | 聚苯乙烯塑料小球的制备方法及其应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB962702A (en) * | 1960-06-09 | 1964-07-01 | Bayer Ag | Process for the production of polymers |
| DE1645659A1 (de) * | 1965-07-29 | 1970-09-17 | Will Dr Guenther | Verfahren zum Herstellen von Perlpolymerisaten |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85100403A (zh) * | 1985-04-01 | 1986-07-09 | 湘潭大学 | 生产丙苯建筑乳胶新方法 |
| JPH0796580B2 (ja) * | 1985-06-03 | 1995-10-18 | 三井東圧化学株式会社 | 透明耐熱性スチレン系共重合体 |
| FR2612520A1 (fr) * | 1987-03-17 | 1988-09-23 | Atochem | Procede de preparation en emulsion suspendue de polymeres et copolymeres insolubles dans leurs compositions monomeres ou comonomeres |
-
1991
- 1991-02-21 FR FR9102076A patent/FR2673184A1/fr active Pending
-
1992
- 1992-02-13 DK DK92400395.7T patent/DK0500427T3/da active
- 1992-02-13 AT AT92400395T patent/ATE136554T1/de not_active IP Right Cessation
- 1992-02-13 DE DE69209697T patent/DE69209697T2/de not_active Expired - Fee Related
- 1992-02-13 EP EP92400395A patent/EP0500427B1/de not_active Expired - Lifetime
- 1992-02-13 ES ES92400395T patent/ES2086092T3/es not_active Expired - Lifetime
- 1992-02-19 IE IE920529A patent/IE73640B1/en not_active IP Right Cessation
- 1992-02-19 NO NO920653A patent/NO178970C/no unknown
- 1992-02-20 CA CA002061585A patent/CA2061585C/fr not_active Expired - Fee Related
- 1992-02-20 FI FI920740A patent/FI920740L/fi unknown
- 1992-02-21 CN CN92101104A patent/CN1051772C/zh not_active Expired - Fee Related
- 1992-02-21 US US07/846,248 patent/US5272228A/en not_active Expired - Fee Related
- 1992-02-21 JP JP4035176A patent/JP2518762B2/ja not_active Expired - Fee Related
-
1996
- 1996-05-23 GR GR960401388T patent/GR3020025T3/el unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB962702A (en) * | 1960-06-09 | 1964-07-01 | Bayer Ag | Process for the production of polymers |
| DE1645659A1 (de) * | 1965-07-29 | 1970-09-17 | Will Dr Guenther | Verfahren zum Herstellen von Perlpolymerisaten |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2518762B2 (ja) | 1996-07-31 |
| CA2061585A1 (fr) | 1992-08-22 |
| ATE136554T1 (de) | 1996-04-15 |
| US5272228A (en) | 1993-12-21 |
| NO178970C (no) | 1996-07-10 |
| EP0500427B1 (de) | 1996-04-10 |
| FI920740L (fi) | 1992-08-22 |
| NO920653D0 (no) | 1992-02-19 |
| CN1051772C (zh) | 2000-04-26 |
| IE920529A1 (en) | 1992-08-26 |
| FI920740A0 (fi) | 1992-02-20 |
| GR3020025T3 (en) | 1996-08-31 |
| DK0500427T3 (da) | 1996-08-05 |
| EP0500427A1 (de) | 1992-08-26 |
| JPH0578408A (ja) | 1993-03-30 |
| CA2061585C (fr) | 2000-08-01 |
| ES2086092T3 (es) | 1996-06-16 |
| NO178970B (no) | 1996-04-01 |
| CN1064280A (zh) | 1992-09-09 |
| DE69209697D1 (de) | 1996-05-15 |
| NO920653L (no) | 1992-08-24 |
| DE69209697T2 (de) | 1996-11-07 |
| IE73640B1 (en) | 1997-06-18 |
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