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FR2426666A1 - Catalyseur d'hydrogenation menagee de l'acetophenone, son obtention et son application - Google Patents

Catalyseur d'hydrogenation menagee de l'acetophenone, son obtention et son application

Info

Publication number
FR2426666A1
FR2426666A1 FR7913031A FR7913031A FR2426666A1 FR 2426666 A1 FR2426666 A1 FR 2426666A1 FR 7913031 A FR7913031 A FR 7913031A FR 7913031 A FR7913031 A FR 7913031A FR 2426666 A1 FR2426666 A1 FR 2426666A1
Authority
FR
France
Prior art keywords
weight
acetophenone
catalyst
household
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7913031A
Other languages
English (en)
Other versions
FR2426666B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon Research and Development Corp
Original Assignee
Halcon Research and Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halcon Research and Development Corp filed Critical Halcon Research and Development Corp
Publication of FR2426666A1 publication Critical patent/FR2426666A1/fr
Application granted granted Critical
Publication of FR2426666B1 publication Critical patent/FR2426666B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
    • Y10S502/52—Suppressed side reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne l'obtention et l'utilisation d'un catalyseur pour l'hydrogénation, en phase liquide, de l'acétophénone en phényl-méthyl-carbinol. Exprimée en oxydes, la composition du catalyseur consiste essentiellement en a. un chromite de cuivre-baryum contenant 30-55 % en poids de CuO, 30-57 % en poids de Cr2 O3 et jusqu'à 16 % en poids de BaO, et b. 1 à 13 % en poids de ZnO et éventuellement aussi 0,15 à 1,7 % en poids de MgO (pour 100 % en poids du chromite). Le catalyseur a une meilleure résistance à l'écrasement et une grande sélectivité. Pastillé, il peut constituer un lit fixe d'un réacteur d'hydrogénation. La déshydratation du phényl-méthyl-carbinol donne du styrène, qui est un intermédiaire de synthèse.
FR7913031A 1978-05-23 1979-05-22 Catalyseur d'hydrogenation menagee de l'acetophenone, son obtention et son application Granted FR2426666A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/908,610 US4160746A (en) 1978-05-23 1978-05-23 Catalyst for hydrogenation of acetophenone

Publications (2)

Publication Number Publication Date
FR2426666A1 true FR2426666A1 (fr) 1979-12-21
FR2426666B1 FR2426666B1 (fr) 1984-02-10

Family

ID=25426037

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7913031A Granted FR2426666A1 (fr) 1978-05-23 1979-05-22 Catalyseur d'hydrogenation menagee de l'acetophenone, son obtention et son application

Country Status (10)

Country Link
US (1) US4160746A (fr)
JP (2) JPS5927216B2 (fr)
BE (1) BE876448A (fr)
BR (1) BR7903178A (fr)
DE (1) DE2920996B2 (fr)
ES (2) ES480766A1 (fr)
FR (1) FR2426666A1 (fr)
GB (3) GB2105211B (fr)
IT (1) IT1117219B (fr)
NL (1) NL184061C (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4160746A (en) * 1978-05-23 1979-07-10 Malcon Research & Development Corporation Catalyst for hydrogenation of acetophenone
US4789502A (en) * 1986-11-24 1988-12-06 Shell Oil Company Carboxylic acid production
US5663458A (en) * 1994-12-02 1997-09-02 Sumitomo Chemical Company, Limited. Process for producing α-phenylethyl alcohol
SG66476A1 (en) * 1997-07-14 1999-07-20 Sumitomo Chemical Co Process for producing alpha-phenylethyl alcohol
US7037877B1 (en) * 1999-02-12 2006-05-02 Council Of Scientific And Industrial Research Process for the preparation of copper chromite catalyst
SG98016A1 (en) * 2000-01-12 2003-08-20 Sumitomo Chemical Co Process for producing alpha-phenylethyl alcohol
JP3899764B2 (ja) 2000-01-19 2007-03-28 住友化学株式会社 α−フェニルエチルアルコールの製造方法
DE10108842A1 (de) * 2001-02-23 2002-10-02 Degussa Geformter Kupfer-Katalysator
RU2335486C2 (ru) * 2003-03-28 2008-10-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ гидрирования алкиларилкетонов
JP5163097B2 (ja) * 2007-12-20 2013-03-13 Ｔｄｋ株式会社 バリスタ
WO2013015702A1 (fr) * 2011-07-26 2013-01-31 Закрытое Акционерное Общество "Алмаз Фарм" Conjugué de nano-diamant et de glycine et procédé de sa fabrication
WO2013015704A1 (fr) * 2011-07-26 2013-01-31 Закрытое Акционерное Общество "Алмаз Фарм" Système pour l'administration d'additifs bioactifs dans le corps et procédé de sa fabrication

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2275152A (en) * 1932-01-02 1942-03-03 Du Pont Process for hydrogenating aliphatic carboxylic acid anhydrides

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2137407A (en) * 1931-05-11 1938-11-22 Du Pont Catalytic hydrogenation process
US2125412A (en) * 1936-08-26 1938-08-02 Du Pont Process for hydrogenating polynuclear aromatic ketones
JPS4935510B1 (fr) * 1962-04-24 1974-09-24
US4160746A (en) * 1978-05-23 1979-07-10 Malcon Research & Development Corporation Catalyst for hydrogenation of acetophenone

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2275152A (en) * 1932-01-02 1942-03-03 Du Pont Process for hydrogenating aliphatic carboxylic acid anhydrides

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/32 *

Also Published As

Publication number Publication date
IT1117219B (it) 1986-02-17
NL184061B (nl) 1988-11-01
JPH0125730B2 (fr) 1989-05-19
DE2920996C3 (fr) 1982-06-09
DE2920996A1 (de) 1979-11-29
NL184061C (nl) 1989-04-03
JPS5927216B2 (ja) 1984-07-04
ES480766A1 (es) 1980-08-16
BR7903178A (pt) 1979-12-11
FR2426666B1 (fr) 1984-02-10
GB2105211B (en) 1983-07-13
JPS54153793A (en) 1979-12-04
JPS59130228A (ja) 1984-07-26
BE876448A (fr) 1979-11-22
GB2021966A (en) 1979-12-12
GB2021966B (en) 1983-04-07
DE2920996B2 (de) 1981-08-06
GB2104404A (en) 1983-03-09
GB2104404B (en) 1983-07-13
NL7903805A (nl) 1979-11-27
ES8102081A1 (es) 1980-12-16
GB2105211A (en) 1983-03-23
ES488080A0 (es) 1980-12-16
US4160746A (en) 1979-07-10
IT7949092A0 (it) 1979-05-18

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Legal Events

Date Code Title Description
TP Transmission of property
ST Notification of lapse