FI61855C - Foerfarande foer framstaellning av en jaernfri krom(iii)foerening - Google Patents
Foerfarande foer framstaellning av en jaernfri krom(iii)foerening Download PDFInfo
- Publication number
- FI61855C FI61855C FI802445A FI802445A FI61855C FI 61855 C FI61855 C FI 61855C FI 802445 A FI802445 A FI 802445A FI 802445 A FI802445 A FI 802445A FI 61855 C FI61855 C FI 61855C
- Authority
- FI
- Finland
- Prior art keywords
- chromium
- precipitation
- iron
- solution
- process according
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 67
- 239000011651 chromium Substances 0.000 claims description 45
- 239000000243 solution Substances 0.000 claims description 30
- 229910052742 iron Inorganic materials 0.000 claims description 29
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 28
- 229910052804 chromium Inorganic materials 0.000 claims description 28
- 238000001556 precipitation Methods 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 20
- 239000011701 zinc Substances 0.000 claims description 18
- 239000000654 additive Substances 0.000 claims description 16
- 229910052725 zinc Inorganic materials 0.000 claims description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 12
- 229910000604 Ferrochrome Inorganic materials 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- 238000004090 dissolution Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- -1 chromium (III) compound Chemical class 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- 230000001376 precipitating effect Effects 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 150000002506 iron compounds Chemical class 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 229910000423 chromium oxide Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229940117975 chromium trioxide Drugs 0.000 description 2
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052935 jarosite Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G37/00—Compounds of chromium
- C01G37/02—Oxides or hydrates thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Iron (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture Of Iron (AREA)
- Catalysts (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI802445A FI61855C (fi) | 1980-08-05 | 1980-08-05 | Foerfarande foer framstaellning av en jaernfri krom(iii)foerening |
| DE19813126681 DE3126681A1 (de) | 1980-08-05 | 1981-07-07 | Verfahren zur gewinnung eisenfreier chrom(iii)verbindung |
| FR8113873A FR2493297B1 (fr) | 1980-08-05 | 1981-07-16 | Procede pour la production d'un compose de chrome iii exempt de fer |
| US06/286,038 US4393029A (en) | 1980-08-05 | 1981-07-22 | Process for the production of an iron-free chronium (III) compound |
| NO812598A NO155960C (no) | 1980-08-05 | 1981-07-29 | Fremgangsmaate for fremstilling av jernfri crooh. |
| SE8104607A SE453490B (sv) | 1980-08-05 | 1981-07-30 | Forfarande for framstellning av en jernfri krom(iii)forening ur en sur vattenlosning innehallande jern och krom |
| GB8123484A GB2081696B (en) | 1980-08-05 | 1981-07-31 | Process for the production of an iron-free chromium (iii) compound |
| JP56121979A JPS57118030A (en) | 1980-08-05 | 1981-08-05 | Sedimentation of iron-free chromium(iii) compound |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI802445 | 1980-08-05 | ||
| FI802445A FI61855C (fi) | 1980-08-05 | 1980-08-05 | Foerfarande foer framstaellning av en jaernfri krom(iii)foerening |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI802445A FI802445A (fi) | 1982-02-06 |
| FI61855B FI61855B (fi) | 1982-06-30 |
| FI61855C true FI61855C (fi) | 1982-10-11 |
Family
ID=8513669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI802445A FI61855C (fi) | 1980-08-05 | 1980-08-05 | Foerfarande foer framstaellning av en jaernfri krom(iii)foerening |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4393029A (no) |
| JP (1) | JPS57118030A (no) |
| DE (1) | DE3126681A1 (no) |
| FI (1) | FI61855C (no) |
| FR (1) | FR2493297B1 (no) |
| GB (1) | GB2081696B (no) |
| NO (1) | NO155960C (no) |
| SE (1) | SE453490B (no) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2118559B (en) * | 1982-02-02 | 1985-07-31 | Giuliano Guardini | Process for extracting protein and chromium from chrome tanned hide wastes |
| EP0433748B1 (de) * | 1989-12-16 | 1993-12-01 | Bayer Ag | Verfahren zur Herstellung von Chromsäure |
| EP0433750B1 (de) * | 1989-12-16 | 1993-12-01 | Bayer Ag | Verfahren zur Herstellung von Chromsäure |
| AU2003227163A1 (en) * | 2003-03-19 | 2004-10-11 | Institute Of Process Engineering Chinese Academy Of Sciences | Method for production of alkali metal chromates |
| CN115928108B (zh) * | 2022-12-23 | 2023-08-01 | 中国科学院青海盐湖研究所 | 电化学氧化铬铁直接制备三价铬化合物的方法 |
| CN115976535B (zh) * | 2022-12-23 | 2023-08-18 | 中国科学院青海盐湖研究所 | 酸性体系中铬铁电化学氧化制备三价铬盐的方法及装置 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB204886A (en) * | 1922-09-22 | 1923-10-11 | Griesheim Elektron Chem Fab | Process for the production of chromium oxide from chrome iron ore |
| CH181527A (de) * | 1934-08-14 | 1935-12-31 | Wydler Ernst | Verfahren zur Gewinnung von reinem Chromihydroxyd aus unreinen Chromisulfatlösungen. |
| JPS4717697U (no) * | 1971-03-30 | 1972-10-30 | ||
| US3896209A (en) * | 1973-01-22 | 1975-07-22 | Du Pont | Reduction of hexavalent chromium |
| US3961029A (en) * | 1973-05-21 | 1976-06-01 | Tokico Ltd. | Process for recovering chromic acid solution from a waste liquor containing chromic ions |
| US4108596A (en) * | 1975-07-11 | 1978-08-22 | Revere Copper And Brass, Incorporated | Recovery of chromium values from waste streams by the use of alkaline magnesium compounds |
| DE2710175C2 (de) * | 1977-03-09 | 1986-08-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Chromgerbstoff und Glaubersalz |
| US4086150A (en) * | 1977-06-27 | 1978-04-25 | Huron Chemicals Limited | Chromate removal by precipitation |
| FI60381C (fi) * | 1979-02-06 | 1982-01-11 | Outokumpu Oy | Foerfarande foer framstaellning av en jaernfri krom(iii)foerening |
| US4207295A (en) * | 1979-02-13 | 1980-06-10 | Union Carbide Corporation | Processing of chromium ore |
| US4259297A (en) * | 1979-09-04 | 1981-03-31 | Olin Corporation | Chromate removal from concentrated chlorate solution by chemical precipitation |
-
1980
- 1980-08-05 FI FI802445A patent/FI61855C/fi not_active IP Right Cessation
-
1981
- 1981-07-07 DE DE19813126681 patent/DE3126681A1/de not_active Ceased
- 1981-07-16 FR FR8113873A patent/FR2493297B1/fr not_active Expired
- 1981-07-22 US US06/286,038 patent/US4393029A/en not_active Expired - Fee Related
- 1981-07-29 NO NO812598A patent/NO155960C/no unknown
- 1981-07-30 SE SE8104607A patent/SE453490B/sv not_active IP Right Cessation
- 1981-07-31 GB GB8123484A patent/GB2081696B/en not_active Expired
- 1981-08-05 JP JP56121979A patent/JPS57118030A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| NO812598L (no) | 1982-02-08 |
| JPS57118030A (en) | 1982-07-22 |
| GB2081696B (en) | 1984-06-27 |
| GB2081696A (en) | 1982-02-24 |
| FR2493297B1 (fr) | 1985-11-22 |
| NO155960B (no) | 1987-03-23 |
| SE453490B (sv) | 1988-02-08 |
| US4393029A (en) | 1983-07-12 |
| SE8104607L (sv) | 1982-02-06 |
| FR2493297A1 (fr) | 1982-05-07 |
| DE3126681A1 (de) | 1982-03-18 |
| NO155960C (no) | 1987-07-01 |
| JPH0116777B2 (no) | 1989-03-27 |
| FI802445A (fi) | 1982-02-06 |
| FI61855B (fi) | 1982-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed |
Owner name: OUTOKUMPU OY |