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FI111458B - Förfarande för framställning av 1,4-butandiol - Google Patents

Förfarande för framställning av 1,4-butandiol Download PDF

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Publication number
FI111458B
FI111458B FI960429A FI960429A FI111458B FI 111458 B FI111458 B FI 111458B FI 960429 A FI960429 A FI 960429A FI 960429 A FI960429 A FI 960429A FI 111458 B FI111458 B FI 111458B
Authority
FI
Finland
Prior art keywords
hydrogenation catalyst
process according
dihydrofuran
catalyst
butanediol
Prior art date
Application number
FI960429A
Other languages
English (en)
Finnish (fi)
Other versions
FI960429L (sv
FI960429A0 (sv
Inventor
Rolf Pinkos
Boris Breitscheidel
Peter Polanek
Rolf Harthmuth Fischer
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of FI960429L publication Critical patent/FI960429L/sv
Publication of FI960429A0 publication Critical patent/FI960429A0/sv
Application granted granted Critical
Publication of FI111458B publication Critical patent/FI111458B/sv

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/20—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/28—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Claims (11)

1. Förfarande för framställning av 1,4-butandiol, kannet ecknat av att man later 2,5-dihydrofuran reage- 5 ra i ett steg i närvaro av vatten och väte vid en tempera-tur av 20 - 300 °C och vid ett tryck av 1 - 3 00 bar och i närvaro av en hydreringskatalyt.
2. Förfarande enligt patentkrav 1, känneteck-nat av att man använder en hydreringskatalyt, som inne- 10 häller ätminstone ett grundämne frän grupp Ib, VIb, Vllb eller VIIIb i grundämnenas periodiska system.
3. Förfarande enligt patentkrav 1 och 2, kanne-tecknat av att man använder en heterogen hydreringskatalyt . 15
4. Förfarande enligt patentkrav 1 - 3, kanne - tecknat av att man använder en hydreringskatalyt, vars katalytiskt aktiva komponent är applicerad pä en bärare.
5. Förfarande enligt patentkrav 1 - 4, kanne -tecknat av att man använder en hydreringskatalyt, som 20 innehäller en eller flera komponenter som fungerar som Brönsted- eller Lewis-syra.
6. Förfarande enligt patentkrav 1 - 5, kanne-tecknat av att man använder en hydreringskatalyt, som innehäller renium. 25
7. Förfarande enligt patentkrav 1 - 5, kanne - tecknat av att man använder en hydreringskatalyt, som innehäller koppar.
8. Förfarande enligt patentkrav 1 - 5, känne-tecknat av att man använder en hydreringskatalyt, som 30 innehäller nickel eller kobolt.
9. Förfarande enligt patentkrav 1 - 5, kanne -tecknat av att man använder en hydreringskatalyt, som innehäller en platinametall. 111458
10. Förfarande enligt patentkrav 1-9, känne-tecknat av att man använder en hydreringskatalyt, vars katalytiskt aktiva komponent är applicerad pä ett bärarma-terial, som innehäller aluminiumoxid, lerjordar, kiseldi- 5 oxid, zirkoniumdioxid, titandioxid, zeolit och/eller ak-tivt koi.
11. Förfarande enligt patentkrav 1 och 2, kän-netecknat av att man använder en homogen hydreringskatalyt, som innehäller ett grundämne frän grupp VHIb i 10 grundämnenas periodiska system.
FI960429A 1993-07-31 1996-01-30 Förfarande för framställning av 1,4-butandiol FI111458B (sv)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE4325753A DE4325753A1 (de) 1993-07-31 1993-07-31 Verfahren zur Herstellung von 1,4-Butandiol
DE4325753 1993-07-31
PCT/EP1994/002232 WO1995004023A1 (de) 1993-07-31 1994-07-07 Verfahren zur herstellung von 1,4-butandiol
EP9402232 1994-07-07

Publications (3)

Publication Number Publication Date
FI960429L FI960429L (sv) 1996-01-30
FI960429A0 FI960429A0 (sv) 1996-01-30
FI111458B true FI111458B (sv) 2003-07-31

Family

ID=6494169

Family Applications (1)

Application Number Title Priority Date Filing Date
FI960429A FI111458B (sv) 1993-07-31 1996-01-30 Förfarande för framställning av 1,4-butandiol

Country Status (13)

Country Link
EP (1) EP0711267B1 (sv)
JP (1) JP3616642B2 (sv)
KR (1) KR100307255B1 (sv)
CN (1) CN1066702C (sv)
AT (1) ATE159237T1 (sv)
AU (1) AU7384794A (sv)
CA (1) CA2168458C (sv)
DE (2) DE4325753A1 (sv)
ES (1) ES2107852T3 (sv)
FI (1) FI111458B (sv)
RU (1) RU2119905C1 (sv)
TW (1) TW328947B (sv)
WO (1) WO1995004023A1 (sv)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4422051A1 (de) * 1994-06-27 1996-01-04 Basf Ag Verfahren zur Herstellung von 1,4-Butandiol
DE4443529A1 (de) * 1994-12-07 1996-06-13 Basf Ag Katalysator zur Durchführung lewissäurekatalysierter Reaktionen
DE19749201A1 (de) 1997-11-07 1999-08-12 Degussa Verfahren zur intermolekularen Veretherung und zur Etherspaltung
DE19929396B4 (de) * 1999-06-26 2013-08-22 Basf Se Vakuumisolationseinheiten enthaltend ein Sorptionsmittel
DE19935828A1 (de) * 1999-07-29 2001-02-01 Basf Ag Herstellung von Pentandiolen aus Alkoxydihydropyranen
CN103102246B (zh) * 2011-11-10 2014-10-22 中国科学院大连化学物理研究所 一种制备1,3-二元醇的方法
EP2674552B1 (en) 2012-06-12 2017-01-11 iLOQ Oy Electromechanical lock
CN104341269A (zh) * 2013-08-02 2015-02-11 胡小军 1,4-丁二醇溶液的制备方法
CN105618051B (zh) * 2014-10-27 2018-01-26 中国科学院大连化学物理研究所 一种用于co加氢合成高碳醇联产石脑油和柴油的催化剂及其制备方法及应用
CN107001203A (zh) * 2014-12-18 2017-08-01 国际壳牌研究有限公司 由呋喃生产正丁醇和1,4‑丁二醇的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1248669B (de) * 1965-01-07 1968-03-14 Badische Anilin &. Soda-Fabrik Aktien gesellschaft, 6700 Ludwigshafen Verfahren zur Herstellung von 2 3-Dihydrofuranen
DE2519817A1 (de) * 1975-05-03 1976-11-11 Hoechst Ag Verfahren zur herstellung von butandiol-(1.4)
US4091041A (en) * 1977-06-13 1978-05-23 General Electric Company Preparation of 1,4-diols by hydrolysis-hydrogenation of 2-alkoxytetrahydrofurans
US4476332A (en) * 1983-12-21 1984-10-09 Ethyl Corporation Preparation of alkanediols
US4475004A (en) * 1983-12-21 1984-10-02 Ethyl Corporation Preparation of alkanediols
US4879420A (en) * 1988-05-06 1989-11-07 E.I. Du Pont De Nemours And Company Preparation of mixtures of butanediols
US4859801A (en) * 1988-05-26 1989-08-22 E. I. Du Pont De Nemours And Company Synthesis of mixtures of butanediols
DE3909485A1 (de) * 1989-03-22 1990-09-27 Basf Ag Verfahren zur herstellung von butandiol-1,4 und tetrahydrofuran
US5254701A (en) * 1991-05-20 1993-10-19 Eastman Kodak Company Process for the production of mixtures of 2-hydroxytetrahydrofuran and 4-hydroxybutanal

Also Published As

Publication number Publication date
KR960703835A (ko) 1996-08-31
EP0711267A1 (de) 1996-05-15
RU2119905C1 (ru) 1998-10-10
JP3616642B2 (ja) 2005-02-02
AU7384794A (en) 1995-02-28
DE4325753A1 (de) 1995-02-02
ATE159237T1 (de) 1997-11-15
CA2168458A1 (en) 1995-02-09
DE59404358D1 (de) 1997-11-20
KR100307255B1 (ko) 2001-11-30
TW328947B (en) 1998-04-01
EP0711267B1 (de) 1997-10-15
CN1066702C (zh) 2001-06-06
WO1995004023A1 (de) 1995-02-09
FI960429L (sv) 1996-01-30
FI960429A0 (sv) 1996-01-30
ES2107852T3 (es) 1997-12-01
CN1128017A (zh) 1996-07-31
CA2168458C (en) 2004-05-25
JPH09500877A (ja) 1997-01-28

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