FI111080B - Kantajalla olevia katalysaattoreita olefiinien polymerointiin - Google Patents
Kantajalla olevia katalysaattoreita olefiinien polymerointiin Download PDFInfo
- Publication number
- FI111080B FI111080B FI943238A FI943238A FI111080B FI 111080 B FI111080 B FI 111080B FI 943238 A FI943238 A FI 943238A FI 943238 A FI943238 A FI 943238A FI 111080 B FI111080 B FI 111080B
- Authority
- FI
- Finland
- Prior art keywords
- groups
- supported catalyst
- aluminum
- compound
- polymerization
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 124
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 60
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 24
- 229920000642 polymer Polymers 0.000 claims abstract description 55
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 40
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 20
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 18
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 12
- 150000003624 transition metals Chemical class 0.000 claims abstract description 12
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 11
- 239000003446 ligand Substances 0.000 claims abstract description 10
- 230000000737 periodic effect Effects 0.000 claims abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 sulfonamido, N-monosubstituted sulfonamido Chemical group 0.000 claims description 47
- 239000007787 solid Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 35
- 238000007334 copolymerization reaction Methods 0.000 claims description 27
- 239000000178 monomer Substances 0.000 claims description 24
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 13
- 125000001424 substituent group Chemical group 0.000 claims description 13
- 229910052726 zirconium Inorganic materials 0.000 claims description 13
- 229910052717 sulfur Chemical group 0.000 claims description 12
- 125000000524 functional group Chemical group 0.000 claims description 11
- 239000011593 sulfur Chemical group 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 229910052735 hafnium Inorganic materials 0.000 claims description 6
- 239000012442 inert solvent Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 238000011282 treatment Methods 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000003368 amide group Chemical group 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 150000003623 transition metal compounds Chemical class 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 150000002736 metal compounds Chemical class 0.000 claims description 3
- 125000002524 organometallic group Chemical group 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 1
- 239000012798 spherical particle Substances 0.000 abstract description 17
- 239000007788 liquid Substances 0.000 abstract description 16
- 239000007789 gas Substances 0.000 abstract description 10
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract description 5
- 150000002902 organometallic compounds Chemical class 0.000 abstract description 2
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 186
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 78
- 239000000243 solution Substances 0.000 description 74
- 239000000725 suspension Substances 0.000 description 50
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 49
- 239000005977 Ethylene Substances 0.000 description 49
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 48
- 239000000203 mixture Substances 0.000 description 45
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 37
- 238000002360 preparation method Methods 0.000 description 34
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 30
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 30
- 239000000047 product Substances 0.000 description 29
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 25
- 238000010992 reflux Methods 0.000 description 22
- 239000012153 distilled water Substances 0.000 description 20
- 239000000460 chlorine Substances 0.000 description 19
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- 229910052801 chlorine Inorganic materials 0.000 description 15
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 15
- 229920005989 resin Polymers 0.000 description 14
- 239000011347 resin Substances 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- 238000004458 analytical method Methods 0.000 description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 12
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 11
- 239000000969 carrier Substances 0.000 description 11
- 238000001816 cooling Methods 0.000 description 11
- 239000011521 glass Substances 0.000 description 11
- 239000004793 Polystyrene Substances 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 229920002223 polystyrene Polymers 0.000 description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 9
- 229910000831 Steel Inorganic materials 0.000 description 9
- 238000001914 filtration Methods 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 150000001993 dienes Chemical class 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 229920005990 polystyrene resin Polymers 0.000 description 8
- 239000002244 precipitate Substances 0.000 description 8
- 239000001294 propane Substances 0.000 description 8
- 238000001035 drying Methods 0.000 description 7
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 7
- 239000004711 α-olefin Substances 0.000 description 7
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 229920001198 elastomeric copolymer Polymers 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 5
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229920001038 ethylene copolymer Polymers 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 238000002309 gasification Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 150000004291 polyenes Chemical class 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 3
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 description 3
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000002329 infrared spectrum Methods 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000000877 morphologic effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000012265 solid product Substances 0.000 description 3
- 125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 3
- 230000001331 thermoregulatory effect Effects 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 2
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 2
- MYSXGUHRBSUOTM-UHFFFAOYSA-N 3-[2-(4,7-dimethyl-3h-inden-1-yl)ethyl]-4,7-dimethyl-1h-indene Chemical compound CC1=CC=C(C)C2=C1C(CCC=1C=3C(C)=CC=C(C=3CC=1)C)=CC2 MYSXGUHRBSUOTM-UHFFFAOYSA-N 0.000 description 2
- DKLQZDIAQKGVTA-UHFFFAOYSA-N 4,7-dimethyl-1h-indene Chemical compound CC1=CC=C(C)C2=C1CC=C2 DKLQZDIAQKGVTA-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 229910018965 MCl2 Inorganic materials 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910007926 ZrCl Inorganic materials 0.000 description 2
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 2
- 239000012346 acetyl chloride Substances 0.000 description 2
- 230000010933 acylation Effects 0.000 description 2
- 238000005917 acylation reaction Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 150000001925 cycloalkenes Chemical class 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 2
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
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- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
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- 239000012074 organic phase Substances 0.000 description 2
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- WCFQIFDACWBNJT-UHFFFAOYSA-N $l^{1}-alumanyloxy(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]O[Al] WCFQIFDACWBNJT-UHFFFAOYSA-N 0.000 description 1
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
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- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
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- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
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- CTWJQOQFTNPBCX-UHFFFAOYSA-N 1-[2-(1h-inden-1-yl)ethyl]-1h-indene Chemical compound C1=CC2=CC=CC=C2C1CCC1C2=CC=CC=C2C=C1 CTWJQOQFTNPBCX-UHFFFAOYSA-N 0.000 description 1
- 229940106006 1-eicosene Drugs 0.000 description 1
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- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 description 1
- KUFDSEQTHICIIF-UHFFFAOYSA-N 6-methylhepta-1,5-diene Chemical compound CC(C)=CCCC=C KUFDSEQTHICIIF-UHFFFAOYSA-N 0.000 description 1
- 101001124623 Burkholderia pyrrocinia Non-heme chloroperoxidase Proteins 0.000 description 1
- ADAYMABSBWWNDN-UHFFFAOYSA-N CC1=CC=C(C)C2=C1C([Li])C=C2 Chemical compound CC1=CC=C(C)C2=C1C([Li])C=C2 ADAYMABSBWWNDN-UHFFFAOYSA-N 0.000 description 1
- 101000715514 Lactiplantibacillus plantarum (strain ATCC BAA-793 / NCIMB 8826 / WCFS1) Carbamoyl-phosphate synthase pyrimidine-specific small chain Proteins 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- DTAFLBZLAZYRDX-UHFFFAOYSA-N OOOOOO Chemical compound OOOOOO DTAFLBZLAZYRDX-UHFFFAOYSA-N 0.000 description 1
- MOMWFXLCFJOAFX-UHFFFAOYSA-N OOOOOOOO Chemical compound OOOOOOOO MOMWFXLCFJOAFX-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 101000621511 Potato virus M (strain German) RNA silencing suppressor Proteins 0.000 description 1
- 229910007932 ZrCl4 Inorganic materials 0.000 description 1
- QSZGOMRHQRFORD-UHFFFAOYSA-L [Cl-].[Cl-].C=C.C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C=C.C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 QSZGOMRHQRFORD-UHFFFAOYSA-L 0.000 description 1
- VCOKPLHNHKEXIO-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC=C(C)C2=C1C=CC2[Zr+2] Chemical compound [Cl-].[Cl-].CC1=CC=C(C)C2=C1C=CC2[Zr+2] VCOKPLHNHKEXIO-UHFFFAOYSA-L 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DXHPZXWIPWDXHJ-UHFFFAOYSA-N carbon monosulfide Chemical compound [S+]#[C-] DXHPZXWIPWDXHJ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- LKRBKNPREDAJJQ-UHFFFAOYSA-M chloro-di(propan-2-yl)alumane Chemical compound [Cl-].CC(C)[Al+]C(C)C LKRBKNPREDAJJQ-UHFFFAOYSA-M 0.000 description 1
- 238000007265 chloromethylation reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 1
- IVTQDRJBWSBJQM-UHFFFAOYSA-L dichlorozirconium;indene Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)C1C2=CC=CC=C2C=C1 IVTQDRJBWSBJQM-UHFFFAOYSA-L 0.000 description 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- DBSDMAPJGHBWAL-UHFFFAOYSA-N penta-1,4-dien-3-ylbenzene Chemical compound C=CC(C=C)C1=CC=CC=C1 DBSDMAPJGHBWAL-UHFFFAOYSA-N 0.000 description 1
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 229940002612 prodrug Drugs 0.000 description 1
- 239000000651 prodrug Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI931467 | 1993-07-07 | ||
| IT93MI001467A IT1264680B1 (it) | 1993-07-07 | 1993-07-07 | Catalizzatori supportati per la polimerizzazione delle olefine |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI943238A0 FI943238A0 (fi) | 1994-07-06 |
| FI943238L FI943238L (fi) | 1995-01-08 |
| FI111080B true FI111080B (fi) | 2003-05-30 |
Family
ID=11366547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI943238A FI111080B (fi) | 1993-07-07 | 1994-07-06 | Kantajalla olevia katalysaattoreita olefiinien polymerointiin |
Country Status (17)
| Country | Link |
|---|---|
| US (3) | US6423660B1 (xx) |
| EP (1) | EP0633272B2 (xx) |
| JP (1) | JP3573494B2 (xx) |
| KR (1) | KR100335805B1 (xx) |
| CN (1) | CN1033860C (xx) |
| AT (1) | ATE158309T1 (xx) |
| AU (1) | AU675711B2 (xx) |
| BR (1) | BR9402237A (xx) |
| CA (1) | CA2127601A1 (xx) |
| DE (1) | DE69405658T3 (xx) |
| DK (1) | DK0633272T3 (xx) |
| ES (1) | ES2108339T5 (xx) |
| FI (1) | FI111080B (xx) |
| IL (1) | IL110219A (xx) |
| IT (1) | IT1264680B1 (xx) |
| MY (1) | MY110923A (xx) |
| RU (1) | RU2116316C1 (xx) |
Families Citing this family (105)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
| IT1270253B (it) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
| IT1273662B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
| IT1273661B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
| US6143686A (en) * | 1994-08-03 | 2000-11-07 | Exxon Chemical Patents, Inc. | Supported ionic catalyst compositions |
| IT1276752B1 (it) | 1995-06-20 | 1997-11-03 | Spherilene S P A Ora Montell I | Catalizzatori e procedimenti per la polimerizzazione di olefine |
| CA2181413A1 (en) * | 1995-07-18 | 1998-01-18 | Edwar S. Shamshoum | Process for the syndiotactic propagation of olefins |
| US6166153A (en) * | 1995-07-18 | 2000-12-26 | Fina Technology, Inc. | Process for the syndiotactic propagation of olefins |
| US6150483A (en) * | 1995-08-21 | 2000-11-21 | Dsm N.V. | Catalyst system for the preparation of a rubbery copolymer |
| NL1001014C2 (nl) * | 1995-08-21 | 1997-02-25 | Dsm Nv | Katalysatorsysteem voor het bereiden van een rubberachtig copolymeer. |
| NO306549B1 (no) * | 1995-12-15 | 1999-11-22 | Norsk Hydro As | Fremgangsmåte ved baking eller kalsinering av formede kull-legemer i en kalsineringsovn samt pakkmateriale for bruk i samme |
| US5914289A (en) * | 1996-02-19 | 1999-06-22 | Fina Research, S.A. | Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution |
| DE19621969A1 (de) * | 1996-05-31 | 1997-12-04 | Basf Ag | Verfahren zur Herstellung von kristallinen Polymerisaten durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen |
| EP0839835B1 (en) * | 1996-10-30 | 2000-02-16 | Repsol Quimica S.A. | Organometallic catalysts for the polymerisation and copolymerisation of alpha-olefins |
| EP0839834B1 (en) | 1996-10-30 | 2001-06-13 | Repsol Quimica S.A. | Catalyst systems for the polymerization and copolymerization of alpha-olefins |
| JP3955140B2 (ja) | 1996-10-31 | 2007-08-08 | レプソル・ケミカ・ソシエダ・アノニマ | アルフアオレフインの重合及び共重合用触媒系 |
| CN1074771C (zh) * | 1996-12-30 | 2001-11-14 | 中国科学院长春应用化学研究所 | 聚合物载体茂金属催化剂的制备 |
| US6228795B1 (en) | 1997-06-05 | 2001-05-08 | Exxon Chemical Patents, Inc. | Polymeric supported catalysts |
| US6100214A (en) * | 1997-06-05 | 2000-08-08 | Exxon Chemical Patents Inc. | Polymeric supported catalysts for olefin polymerization |
| JPH11292913A (ja) * | 1998-04-06 | 1999-10-26 | Sumitomo Chem Co Ltd | オレフィン重合用固体触媒成分、オレフィン重合用触媒、オレフィン系重合体の製造方法、並びにオレフィン重合用固体触媒成分の製造方法 |
| JP2002505713A (ja) | 1998-04-21 | 2002-02-19 | モンテル テクノロジー カンパニー ビーブイ | α−オレフィンとのエチレンコポリマーの製造方法 |
| DE69914012T2 (de) | 1998-04-27 | 2004-12-09 | Repsol Quimica S.A. | Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen |
| KR20010023361A (ko) * | 1998-06-27 | 2001-03-26 | 간디 지오프레이 에이치. | 올레핀 중합용 촉매 성분 및 이로부터 수득된 촉매 |
| BR9910387A (pt) | 1998-07-02 | 2006-08-15 | Montell Technology Company Bv | processo para preparação de polìmeros alfa-olefinos substancialmente amorfos e composições contendo ele e processo para preparação de ligações em ponte, filme e artigos obtidos da composição |
| BE1012364A3 (fr) * | 1998-12-22 | 2000-10-03 | Solvay | Procede pour la preparation d'une composition catalytique pour la polymerisation des alpha-olefines, composition catalytique obtenue et procede de polymerisation utilisant une telle composition catalytique |
| US6544921B1 (en) * | 1999-09-28 | 2003-04-08 | Sumitomo Chemical Comapny, Limited | Solid catalyst component and catalyst for olefin polymerization, process for producing olefin polymer and process for producing solid catalyst component for olefin polymerization |
| JP2001163912A (ja) * | 1999-09-28 | 2001-06-19 | Sumitomo Chem Co Ltd | オレフィン重合用固体触媒成分、オレフィン重合用触媒、オレフィン重合体の製造方法、並びにオレフィン重合用固体触媒成分の製造方法 |
| AU783097B2 (en) | 1999-12-28 | 2005-09-22 | Basell Technology Company B.V. | Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers |
| AU3538601A (en) | 1999-12-28 | 2001-07-09 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers |
| AU3016401A (en) | 1999-12-28 | 2001-07-09 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers |
| RU2278124C2 (ru) * | 2000-05-12 | 2006-06-20 | Базелль Полиолефин Италия С.П.А. | Форполимеризованный катализатор для полимеризации этилена |
| KR20020012346A (ko) * | 2000-08-07 | 2002-02-16 | 유현식 | 신디오탁틱 폴리스티렌을 고수율로 제조하고 반응기부착물을 감소시키는 담지촉매 |
| NO20013880L (no) | 2000-08-22 | 2002-02-25 | Rohm & Haas | Matriks og fremgangsmåte for fremstilling av polyolefiner |
| GB0021301D0 (en) | 2000-08-30 | 2000-10-18 | Borealis Tech Oy | Supported catalyst |
| US7202315B2 (en) | 2000-09-25 | 2007-04-10 | Basell Polyolefine Gmbh | Process for the preparation of ethylene polymers |
| GB0023662D0 (en) | 2000-09-27 | 2000-11-08 | Borealis Tech Oy | Supported catalyst |
| US7074736B2 (en) | 2000-10-31 | 2006-07-11 | Rohm And Haas Company | Hydrozirconated matrix and process for polyolefin production |
| US6720396B2 (en) * | 2000-11-30 | 2004-04-13 | Univation Technologies, Llc | Polymerization process |
| US20020137861A1 (en) * | 2000-12-04 | 2002-09-26 | Woo Min Song | Polymerization process |
| DE60233961D1 (de) | 2001-06-12 | 2009-11-19 | Basell Polyolefine Gmbh | Verfahren zur Polymerisation von Buten-1 |
| US7459511B2 (en) | 2001-06-12 | 2008-12-02 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| EP1397371B1 (en) | 2001-06-22 | 2006-03-22 | Basell Polyolefine GmbH | Metallocenes and their use in catalyst systems for producing olefin polymers |
| DE60218059T2 (de) | 2001-11-12 | 2007-08-30 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von 1-buten und 1-buten polymeren |
| WO2003045964A1 (en) | 2001-11-30 | 2003-06-05 | Basell Polyolefine Gmbh | Metallocene compounds and process for the preparation of propylene polymers |
| EP1492825A1 (en) | 2002-02-25 | 2005-01-05 | Basell Polyolefine GmbH | Process for the copolymerization of ethylene |
| US7005487B2 (en) | 2002-07-02 | 2006-02-28 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
| ATE445651T1 (de) | 2002-09-06 | 2009-10-15 | Basell Polyolefine Gmbh | Verfahren zur copolymerisation von ethylen |
| US7569647B2 (en) | 2002-10-10 | 2009-08-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| EP1569968B1 (en) * | 2002-11-04 | 2010-03-17 | Basell Polyolefine GmbH | Preparation of catalyst compositions having improved activity |
| DE10251491A1 (de) * | 2002-11-04 | 2004-05-13 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Katalysatorzusammensetzungen mit verbesserter Aktivität |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| JP4771938B2 (ja) | 2003-05-12 | 2011-09-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| BRPI0411942B1 (pt) | 2003-07-04 | 2019-12-03 | Basell Polyolefine Gmbh | processo para a polimerização de olefinas |
| US8178636B2 (en) | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
| JP2008528339A (ja) | 2005-02-03 | 2008-07-31 | バーゼル・ポリオレフィン・ゲーエムベーハー | 熱成形品を製造する方法 |
| US7175444B2 (en) * | 2005-02-23 | 2007-02-13 | Molex Incorporated | Plug connector and construction therefor |
| US7842764B2 (en) | 2005-03-18 | 2010-11-30 | Basell Poliolefine Italia S.R.L. | Metallocene compounds |
| EP1858934B1 (en) | 2005-03-18 | 2013-04-24 | Basell Polyolefine GmbH | Metallocene compounds |
| US7799880B2 (en) | 2005-03-23 | 2010-09-21 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| JP5294842B2 (ja) | 2005-03-23 | 2013-09-18 | バーゼル・ポリオレフィン・ゲーエムベーハー | オレフィンの重合プロセス |
| US7964679B2 (en) | 2005-05-03 | 2011-06-21 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of alpha olefins |
| WO2006120177A2 (en) | 2005-05-11 | 2006-11-16 | Basell Poliolefine Itatia S.R.L. | Polymerization process for preparing polyolefin blends |
| WO2007003528A2 (en) * | 2005-06-30 | 2007-01-11 | Basell Polyolefine Gmbh | Metallocene compounds |
| EP1940944B1 (en) | 2005-10-21 | 2017-03-15 | Basell Polyolefine GmbH | Polypropylene for injection molding |
| JP5379480B2 (ja) | 2005-10-21 | 2013-12-25 | バーゼル・ポリオレフィン・ゲーエムベーハー | プロピレンポリマー |
| DE602006014708D1 (de) * | 2005-10-21 | 2010-07-15 | Basell Polyolefine Gmbh | Statistische polypropylencopolymere mit hohen schmelzflussraten für spritzguss- und schmelzblasanwendungen |
| HUP0800699A2 (en) * | 2006-02-02 | 2009-08-28 | Basell Polyolefine Gmbh | Blasted resin made by propylene fusion, and pile and non woven products made by it and process for production of these |
| ATE461244T1 (de) | 2006-02-23 | 2010-04-15 | Basell Poliolefine Srl | Propylenpolymere für spritzgiessanwendungen |
| US7858717B2 (en) | 2006-03-17 | 2010-12-28 | Basell Polyolefine Gmbh | Metallocene compounds |
| WO2007116034A1 (en) | 2006-04-12 | 2007-10-18 | Basell Polyolefine Gmbh | Metallocene compounds |
| EP2010579A1 (en) | 2006-04-21 | 2009-01-07 | Basell Polyolefine GmbH | Process for the preparation of ethylene propylene copolymers |
| EP2010580B1 (en) | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Process for the preparation of ethylene copolymers |
| CN101274968B (zh) * | 2007-03-28 | 2012-11-21 | 中国石油化工股份有限公司 | 一种用于生产宽分子量分布的聚乙烯的复合催化剂 |
| ATE485318T1 (de) * | 2007-06-25 | 2010-11-15 | Basell Polyolefine Gmbh | 1-butenethylencopolymere |
| EP2202246B1 (en) | 2007-10-16 | 2016-06-15 | Sinopec Yangzi Petrochemical Company Ltd. | Non-metallocene catalyst supported on magnesium compound and its preparation method |
| JP5480147B2 (ja) | 2007-10-16 | 2014-04-23 | 中国石化揚子石油化工有限公司 | 担持非メタロセン触媒およびその製造方法 |
| US20100249346A1 (en) * | 2007-10-19 | 2010-09-30 | Basell Polyolefine Gmbh | Metallocene compounds based on ethanediyl-bridged indene and cyclopentadithiophene ligands |
| ATE524498T1 (de) | 2007-12-20 | 2011-09-15 | Basell Polyolefine Gmbh | Verfahren zur gewinnung von polymeren aus ethylen und zykloolefinen |
| WO2009115402A1 (en) * | 2008-03-20 | 2009-09-24 | Basell Poliolefine Italia S.R.L. | 1-butene terpolymers |
| WO2009115395A1 (en) * | 2008-03-20 | 2009-09-24 | Basell Polyolefine Italia S.R.L. | 1-butene copolymers |
| BRPI0908965A2 (pt) * | 2008-03-20 | 2016-04-26 | Basell Poliolefine Srl | copolímeros de 1-buteno |
| ATE543870T1 (de) * | 2008-03-20 | 2012-02-15 | Basell Poliolefine Srl | Zusammensetzungen aus polymeren auf 1-buten-basis |
| US8344086B2 (en) * | 2008-04-22 | 2013-01-01 | Basell Poliolefine Italia S.R.L. | 1-butene terpolymers |
| KR100976666B1 (ko) * | 2008-07-21 | 2010-08-18 | 대림산업 주식회사 | 올레핀 중합 촉매 및 이를 이용한 폴리올레핀 중합체의제조방법 |
| CN102257060A (zh) | 2008-12-19 | 2011-11-23 | 巴塞尔聚烯烃意大利有限责任公司 | 聚烯烃纤维 |
| EP2379609B1 (en) | 2009-01-13 | 2012-10-24 | Basell Polyolefine GmbH | Polyethylene copolymers |
| KR20110104031A (ko) | 2009-01-13 | 2011-09-21 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 중합체 조성물 |
| US20100273964A1 (en) * | 2009-04-22 | 2010-10-28 | Stewart Lewis | Heterogeneous lewis acid catalysts for cationic polymerizations |
| SG10201907833WA (en) | 2009-06-16 | 2019-10-30 | Chevron Phillips Chemical Co Lp | Oligomerization of alpha olefins using metallocene-ssa catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends |
| WO2011044150A1 (en) * | 2009-10-06 | 2011-04-14 | Chevron Phillips Chemical Company Lp | Oligomerization of olefin waxes using metallocene-based catalyst systems |
| JP5670460B2 (ja) | 2009-10-26 | 2015-02-18 | 中国石油化工股▲ふん▼有限公司 | 担持型非メタロセン触媒、その製造方法およびその使用 |
| WO2011050566A1 (zh) | 2009-10-26 | 2011-05-05 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| WO2011057469A1 (zh) | 2009-11-13 | 2011-05-19 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| US8957169B2 (en) | 2009-11-13 | 2015-02-17 | China Petroleum & Chemical Corp. | Supported nonmetallocene catalyst, preparation and use thereof |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| RU2637316C2 (ru) | 2011-01-14 | 2017-12-04 | В.Р.Грейс Энд Ко.-Конн. | Способ получения модифицированного металлоценового катализатора, полученный катализатор и его применение |
| CN102516437B (zh) * | 2011-12-14 | 2014-05-21 | 浙江大学宁波理工学院 | 一种聚苯乙烯系功能微球的制备方法 |
| EP2606970A1 (en) | 2011-12-19 | 2013-06-26 | Basell Polyolefine GmbH | Monocyclopentadienyl binuclear complexes, ligands used in their preparaion, catalyst systems comprising them and olefin polymerisation process |
| EP2676972A1 (en) | 2012-06-19 | 2013-12-25 | Basell Polyolefine GmbH | Process for the obtainment of a polyolefin composition |
| EP2743000A1 (en) | 2012-12-13 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Catalyst system for the preparation of polyolefins |
| EP2767542A1 (en) | 2013-02-18 | 2014-08-20 | Basell Polyolefine GmbH | Oligomerization catalyst |
| US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
| KR20220012646A (ko) | 2020-07-23 | 2022-02-04 | 한국항공우주연구원 | 가스켓 제거 도구 |
| US20250059362A1 (en) | 2021-12-23 | 2025-02-20 | Basell Poliolefine Italia S.R.L. | Soft polyolefin composition |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4224415A (en) | 1958-07-18 | 1980-09-23 | Rohm And Haas Company | Polymerization processes and products therefrom |
| US4147664A (en) * | 1975-10-24 | 1979-04-03 | Pomogailo Anatoly D | Catalyst of polymerization, copolymerization and oligomerization of olefins and drolefins |
| DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US4426318A (en) | 1982-12-01 | 1984-01-17 | Northern Petrochemical Company | Supported polyethylene polymerization catalysts utilizing substituted polystyrene resins |
| US4564647A (en) | 1983-11-14 | 1986-01-14 | Idemitsu Kosan Company Limited | Process for the production of polyethylene compositions |
| US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| CA1268754A (en) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
| US4632912A (en) | 1985-12-10 | 1986-12-30 | The Dow Chemical Company | Polymer supported Ziegler-Natta catalysts |
| DE3609862A1 (de) * | 1986-03-22 | 1987-10-01 | Boge Gmbh | Regelbarer stossdaempfer |
| GB8609803D0 (en) | 1986-04-22 | 1986-05-29 | Bp Chem Int Ltd | Silicone surfactants |
| EP0279863B1 (en) | 1986-08-26 | 1992-10-14 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing alpha-olefin and polymerization process |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US4921825A (en) | 1986-12-30 | 1990-05-01 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and processes for its production |
| JP2538595B2 (ja) | 1987-05-13 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒 |
| JPH072798B2 (ja) | 1987-10-28 | 1995-01-18 | 住友化学工業株式会社 | オレフィン重合用固体触媒成分 |
| US5118648A (en) | 1988-10-05 | 1992-06-02 | Mobil Oil Corporation | Particulate polymer-supported olefin polymerization catalyst |
| KR950001285B1 (ko) | 1989-03-23 | 1995-02-15 | 가부시끼가이샤 닛뽄 쇼꾸바이 | 가교구상 미립자를 함유하는 도료조성물 |
| JP2826362B2 (ja) * | 1990-02-13 | 1998-11-18 | 三井化学株式会社 | オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法 |
| US5290912A (en) | 1990-05-11 | 1994-03-01 | Asahi Glass Company Ltd. | Process for producing a polyoxyalkylene compound |
| KR0179033B1 (ko) | 1990-05-22 | 1999-05-15 | 에토 다케토시 | 프로필렌 공중합체의 제조방법 |
| US5242955A (en) | 1990-10-30 | 1993-09-07 | Daicel Chemical Industries, Ltd. | Composition comprising polyether compounds, a process for the preparation thereof and a curable resin composition |
| EP0496405A1 (en) * | 1991-01-25 | 1992-07-29 | Mitsubishi Kasei Corporation | Porous resin and process for its production |
| DE4119343A1 (de) | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| CA2082678C (en) * | 1991-11-12 | 1996-07-30 | Naoki Kataoka | Catalyst components for polymerization of olefins |
| US5461017A (en) | 1991-12-13 | 1995-10-24 | Mobil Oil Corporation | Olefin polymerization catalysts |
| US5362824A (en) * | 1991-12-13 | 1994-11-08 | Mobil Oil Corporation | Olefin polymerization catalysts |
| US5198399A (en) * | 1992-01-17 | 1993-03-30 | Quantum Chemical Corporation | Polymerization catalyst and method |
| FI112233B (fi) † | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| EP0598543B1 (en) † | 1992-11-10 | 1997-01-15 | Mitsubishi Chemical Corporation | Method for producing Alpha-olefin polymers |
| US5646332A (en) | 1992-12-17 | 1997-07-08 | Exxon Chemical Patents Inc. | Batch Koch carbonylation process |
| US5455214A (en) | 1993-09-09 | 1995-10-03 | Mobil Oil Corporation | Metallocenes supported on ion exchange resins |
| EP0719291B1 (en) | 1993-09-17 | 1998-05-20 | Exxon Research And Engineering Company | Novel functionalized isoolefin/para-alkylstyrene copolymers |
| US5670557A (en) | 1994-01-28 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Polymerized microemulsion pressure sensitive adhesive compositions and methods of preparing and using same |
| AU694765B2 (en) * | 1994-03-01 | 1998-07-30 | Mobil Oil Corporation | Olefin polymerization catalysts |
| BR9508269A (pt) | 1994-07-11 | 1999-06-01 | Exxon Chemical Patents Inc | Dispersante solúvel em óleo processo para a produção do mesmo uso do dispersante e composição oleaginosa |
-
1993
- 1993-07-07 IT IT93MI001467A patent/IT1264680B1/it active IP Right Grant
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1994
- 1994-06-30 AT AT94110168T patent/ATE158309T1/de not_active IP Right Cessation
- 1994-06-30 DK DK94110168.5T patent/DK0633272T3/da active
- 1994-06-30 ES ES94110168T patent/ES2108339T5/es not_active Expired - Lifetime
- 1994-06-30 EP EP94110168A patent/EP0633272B2/en not_active Expired - Lifetime
- 1994-06-30 DE DE69405658T patent/DE69405658T3/de not_active Expired - Fee Related
- 1994-07-02 MY MYPI94001730A patent/MY110923A/en unknown
- 1994-07-05 AU AU66181/94A patent/AU675711B2/en not_active Ceased
- 1994-07-05 IL IL11021994A patent/IL110219A/xx not_active IP Right Cessation
- 1994-07-05 RU RU94023242A patent/RU2116316C1/ru not_active IP Right Cessation
- 1994-07-06 FI FI943238A patent/FI111080B/fi not_active IP Right Cessation
- 1994-07-06 BR BR9402237-2A patent/BR9402237A/pt not_active IP Right Cessation
- 1994-07-07 JP JP15611694A patent/JP3573494B2/ja not_active Expired - Lifetime
- 1994-07-07 CA CA002127601A patent/CA2127601A1/en not_active Abandoned
- 1994-07-07 CN CN94109180A patent/CN1033860C/zh not_active Expired - Fee Related
- 1994-07-07 KR KR1019940016366A patent/KR100335805B1/ko not_active IP Right Cessation
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| EP0633272A1 (en) | 1995-01-11 |
| MY110923A (en) | 1999-06-30 |
| CN1033860C (zh) | 1997-01-22 |
| ES2108339T5 (es) | 2005-07-16 |
| CN1103069A (zh) | 1995-05-31 |
| IL110219A (en) | 1999-10-28 |
| EP0633272B1 (en) | 1997-09-17 |
| EP0633272B2 (en) | 2005-01-12 |
| RU2116316C1 (ru) | 1998-07-27 |
| KR100335805B1 (ko) | 2002-10-09 |
| CA2127601A1 (en) | 1995-01-08 |
| AU675711B2 (en) | 1997-02-13 |
| ES2108339T3 (es) | 1997-12-16 |
| KR960014162A (ko) | 1996-05-22 |
| FI943238A0 (fi) | 1994-07-06 |
| FI943238L (fi) | 1995-01-08 |
| RU94023242A (ru) | 1996-05-27 |
| DE69405658T2 (de) | 1998-02-12 |
| US20030134993A1 (en) | 2003-07-17 |
| US6774194B2 (en) | 2004-08-10 |
| BR9402237A (pt) | 1996-03-19 |
| ATE158309T1 (de) | 1997-10-15 |
| JPH0753623A (ja) | 1995-02-28 |
| US6444604B1 (en) | 2002-09-03 |
| IT1264680B1 (it) | 1996-10-04 |
| DE69405658D1 (de) | 1997-10-23 |
| ITMI931467A0 (it) | 1993-07-07 |
| DK0633272T3 (da) | 1997-10-13 |
| DE69405658T3 (de) | 2005-12-29 |
| ITMI931467A1 (it) | 1995-01-07 |
| US6423660B1 (en) | 2002-07-23 |
| JP3573494B2 (ja) | 2004-10-06 |
| AU6618194A (en) | 1995-01-19 |
| IL110219A0 (en) | 1994-10-21 |
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