ES2497115T3 - Procedimiento para la producción de composiciones de ABS con propiedades de tenacidad mejoradas - Google Patents
Procedimiento para la producción de composiciones de ABS con propiedades de tenacidad mejoradas Download PDFInfo
- Publication number
- ES2497115T3 ES2497115T3 ES03755102.5T ES03755102T ES2497115T3 ES 2497115 T3 ES2497115 T3 ES 2497115T3 ES 03755102 T ES03755102 T ES 03755102T ES 2497115 T3 ES2497115 T3 ES 2497115T3
- Authority
- ES
- Spain
- Prior art keywords
- rubber
- weight
- acrylonitrile
- styrene
- graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920001971 elastomer Polymers 0.000 abstract 10
- 239000005060 rubber Substances 0.000 abstract 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 9
- 229920000126 latex Polymers 0.000 abstract 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 5
- 239000002245 particle Substances 0.000 abstract 5
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 2
- 238000004898 kneading Methods 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 239000002952 polymeric resin Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 238000010526 radical polymerization reaction Methods 0.000 abstract 1
- 229920003002 synthetic resin Polymers 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 238000009757 thermoplastic moulding Methods 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Procedimiento para la producción de masas de moldeo termoplásticas del tipo ABS que contienen A) al menos un caucho de injerto obtenido mediante polimerización en emulsión de al menos dos monómeros seleccionados de estireno, a-metilestireno, acrilonitrilo, metacrilonitrilo, metacrilato de metilo, N- fenilmaleinimida en presencia de uno o varios látex de caucho, ascendiendo el diámetro de partícula medio d50 del látex de caucho o de los látex de caucho a <= 180 nm, B) al menos un caucho de injerto obtenido mediante polimerización en emulsión de al menos dos monómeros seleccionados de estireno, a-metilestireno, acrilonitrilo, metacrilonitrilo, metacrilato de metilo, N-fenilmaleinimida en presencia de uno o varios látex de caucho, ascendiendo el diámetro de partícula medio d50 del látex de caucho o de los látex de caucho a >= 220 nm, seleccionándose los látex de caucho de polibutadieno, copolímeros de butadieno/estireno con hasta el 20 % en peso de estireno incorporado y copolímeros de butadieno/acrilonitrilo con hasta el 15 % en peso de acrilonitrilo incorporado y C) al menos una resina polimérica termoplástica libre de caucho obtenida mediante polimerización por radicales de al menos dos monómeros seleccionados de estireno, a-metilestireno, acrilonitrilo, metacrilonitrilo, metacrilato de metilo, N-fenilmaleinimida, con el uso de un reactor amasador, caracterizado por que a) los componentes de caucho de injerto A) y B) se produjeron en reacciones de polimerización separadas, b) la porción en % en peso del caucho procedente del componente de caucho de injerto A) en la cantidad total de caucho en la masa de moldeo es al menos un 5 % en peso menor que la porción de caucho en % en peso, que procede del componente de caucho de injerto B) (en cada caso con respecto a 100 partes en peso de caucho de injerto) y c) el diámetro de partícula medio d50 de la totalidad de todas las partículas de caucho contenidas en la masa de moldeo presenta un valor de < 300 nm, determinándose los diámetros de partícula medios d50 mediante medición de ultracentrífuga.
Description
11
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10223646 | 2002-05-28 | ||
| DE10223646A DE10223646A1 (de) | 2002-05-28 | 2002-05-28 | Verfahren zur Herstellung von ABS-Zusammensetzungen mit verbesserten Zähigkeitseigenschaften |
| PCT/EP2003/005104 WO2003099926A1 (de) | 2002-05-28 | 2003-05-15 | Verfahren zur herstellung von abs-zusammensetzungen mit verbesserten zähigkeitseigenschaften |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2497115T3 true ES2497115T3 (es) | 2014-09-22 |
Family
ID=29432373
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12190582T Expired - Lifetime ES2570141T3 (es) | 2002-05-28 | 2003-05-15 | Composición con propiedades de tenacidad mejoradas |
| ES03755102.5T Expired - Lifetime ES2497115T3 (es) | 2002-05-28 | 2003-05-15 | Procedimiento para la producción de composiciones de ABS con propiedades de tenacidad mejoradas |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12190582T Expired - Lifetime ES2570141T3 (es) | 2002-05-28 | 2003-05-15 | Composición con propiedades de tenacidad mejoradas |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20030225219A1 (es) |
| EP (2) | EP2584001B1 (es) |
| JP (1) | JP2005527680A (es) |
| KR (1) | KR100933619B1 (es) |
| CN (1) | CN100387650C (es) |
| AU (1) | AU2003232776A1 (es) |
| CA (1) | CA2487139A1 (es) |
| DE (1) | DE10223646A1 (es) |
| ES (2) | ES2570141T3 (es) |
| MX (1) | MXPA04011733A (es) |
| TW (1) | TWI297025B (es) |
| WO (1) | WO2003099926A1 (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1783170A1 (en) * | 2005-10-24 | 2007-05-09 | Basf Aktiengesellschaft | Thermoplastic molding composition comprising finely divided inert materials |
| DE102006056523A1 (de) * | 2006-11-30 | 2008-06-05 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Pfropfkautschuken, Pfropfkautschuke und thermoplastische Formmassen auf Basis dieser Pfropfkautschuke |
| CN101570588B (zh) * | 2008-04-30 | 2010-09-29 | 中国石油天然气股份有限公司 | 一种双峰分布abs的制备方法 |
| CN101667006B (zh) * | 2009-09-25 | 2011-05-25 | 武汉科技学院 | 新型光学全息记录材料及制备方法 |
| FR2969167B1 (fr) * | 2010-12-15 | 2013-01-11 | Arkema France | Composition thermoplastique modifiee choc amelioree |
| KR101533136B1 (ko) * | 2011-12-14 | 2015-07-01 | 주식회사 엘지화학 | 충격강도가 우수한 열가소성 ａｂｓ 수지 조성물 |
| JP6062450B2 (ja) * | 2012-10-15 | 2017-01-18 | 旭化成株式会社 | 熱可塑性樹脂組成物及びその成形体 |
| ES2658079T3 (es) * | 2013-07-11 | 2018-03-08 | Ineos Styrolution Group Gmbh | Procedimiento para la producción de masas de moldeo termoplásticas, así como masas de moldeo termoplásticas producidas según éste |
| ES2650265T3 (es) * | 2013-12-18 | 2018-01-17 | Ineos Styrolution Group Gmbh | Masas moldeables que se basan en copolímeros de compuesto aromático de vinilo para la impresión 3D |
| KR102477525B1 (ko) | 2015-05-18 | 2022-12-14 | 이네오스 스티롤루션 그룹 게엠베하 | 가공성과 표면 품질의 우수한 특성 조합을 갖는 abs 성형 화합물 |
| ES2860198T5 (es) | 2017-04-24 | 2024-04-26 | Ineos Styrolution Group Gmbh | Procedimiento mejorado para la preparación de copolímeros de injerto de ABS |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1379391A (en) | 1921-05-24 | Vtiiicanizing-pad | ||
| DE1495626B1 (de) | 1960-03-30 | 1971-06-09 | Bayer Ag | Verfahren zum herstellen von polyestern |
| NL269409A (es) | 1960-09-20 | |||
| FR1580834A (es) | 1968-01-04 | 1969-09-12 | ||
| CA953838A (en) | 1970-01-14 | 1974-08-27 | Donald A. Bennett | Preparation of graft copolymers |
| CA942446A (en) * | 1970-07-30 | 1974-02-19 | Walter Laber | Incorporating rubber into thermoplastics |
| DE2232877B2 (de) | 1972-07-05 | 1980-04-10 | Werner & Pfleiderer, 7000 Stuttgart | Verfahren zur Herstellung von Polyestern |
| CH578138A5 (es) | 1973-02-28 | 1976-07-30 | Jylland Gummivarefabriken As | |
| DE2407776A1 (de) | 1974-02-19 | 1975-09-04 | Licentia Gmbh | Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers |
| DE2420358B2 (de) | 1974-04-26 | 1980-02-07 | Bayer Ag, 5090 Leverkusen | Formmassen |
| JPS5292295A (en) | 1976-01-29 | 1977-08-03 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester |
| IT1116721B (it) | 1976-04-02 | 1986-02-10 | Allied Chem | Copolimero bisfenolo a tereftalato carbonato lavorabili in massa fusa |
| DE2715932A1 (de) | 1977-04-09 | 1978-10-19 | Bayer Ag | Schnellkristallisierende poly(aethylen/alkylen)-terephthalate |
| DE2724360C3 (de) | 1977-05-28 | 1988-03-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von thermoplastischen Formmassen auf Basis von Vinylpolymerisaten |
| BR7904871A (pt) | 1978-07-31 | 1980-05-06 | Monsanto Co | Processo para preparar latices estaveis de grandes particulas de borracha de dieno enxertadas |
| DE2842005A1 (de) | 1978-09-27 | 1980-04-10 | Bayer Ag | Polycarbonate mit alkylphenyl-endgruppen, ihre herstellung und ihre verwendung |
| JPS5594930A (en) | 1979-01-10 | 1980-07-18 | Sumitomo Chem Co Ltd | Preparation of aromatic polyester by improved bulk polymerization process |
| DD144415A1 (de) | 1979-06-20 | 1980-10-15 | Frans Steffers | Verfahren zum agglomerieren von butadien-copolymerisatlatices |
| IT1127266B (it) | 1979-11-27 | 1986-05-21 | Montedison Spa | Procedimento per agglomerare lattici di gomme |
| DE3506472A1 (de) | 1985-02-23 | 1986-08-28 | Bayer Ag, 5090 Leverkusen | Neue polydiorganosiloxan-polycarbonat-blockcopolymere |
| DE3639904A1 (de) | 1986-11-22 | 1988-06-01 | Bayer Ag | Bifunktionelle emulgatoren auf basis von perhydrobisphenolen und carbonsaeureanhydriden |
| JPH0618618B2 (ja) | 1987-03-20 | 1994-03-16 | 三菱重工業株式会社 | 撹拌装置 |
| DE3844633A1 (de) | 1988-08-12 | 1990-04-19 | Bayer Ag | Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten |
| DE3913509A1 (de) | 1989-04-25 | 1990-10-31 | Bayer Ag | Neue emulgatoren und verfahren zur herstellung grobteiliger homodisperser polymerdispersionen unter verwendung dieser emulgatoren |
| DE4018069A1 (de) | 1990-06-06 | 1991-12-12 | Bayer Ag | Selbstreinigender reaktor/mischer mit grossem nutzvolumen |
| DE4118884A1 (de) | 1991-06-07 | 1992-12-10 | List Ag | Mischkneter |
| DE4126425A1 (de) | 1991-08-09 | 1993-02-11 | Bayer Ag | Vollstaendig selbstreinigender reaktor/mischer mit grossem nutzvolumen |
| DE4131872A1 (de) | 1991-09-25 | 1993-04-08 | Basf Ag | Verfahren zur herstellung schlagzaehmodifizierter thermoplaste |
| US5817266A (en) * | 1994-01-27 | 1998-10-06 | Basf Aktiengesellschaft | Dewatering of water-moist graft rubber |
| DE4402394B4 (de) | 1994-01-27 | 2005-02-10 | Basf Ag | Verfahren zur Entwässerung von wasserfeuchtem Pfropfkautschuk |
| DE59600080D1 (de) * | 1995-03-27 | 1998-02-26 | Basf Ag | Verfahren zur Herstellung von Thermoplasten |
| ES2117890T3 (es) | 1995-03-27 | 1998-08-16 | Basf Ag | Procedimiento para la obtencion de termoplasticos. |
| ES2104481T3 (es) * | 1995-03-27 | 1997-10-01 | Basf Ag | Procedimiento para la obtencion de termoplasticos. |
| EP0735077B1 (de) | 1995-03-27 | 1998-07-29 | BASF Aktiengesellschaft | Verfahren zur Herstellung von Thermoplasten |
| DE19639592A1 (de) | 1996-09-26 | 1998-04-02 | Basf Ag | Thermoplastische Formmassen |
| DE19649255A1 (de) * | 1996-11-28 | 1998-06-04 | Bayer Ag | Thermoplastische Hochglanz-Formmassen vom ABS-Typ |
| DE19713039A1 (de) * | 1997-03-27 | 1998-10-01 | Bayer Ag | Verfahren zur Herstellung von elastomermodifizierten Thermoplasten |
| TWI230727B (en) * | 1999-03-25 | 2005-04-11 | Bayer Ag | Compositions containing polycarbonate and grafted rubber having improved low-temperature toughness |
| US6528583B1 (en) | 2000-03-30 | 2003-03-04 | Bayer Corporation | Thermoplastic molding composition having improved dimensional stability and low gloss |
-
2002
- 2002-05-28 DE DE10223646A patent/DE10223646A1/de not_active Withdrawn
-
2003
- 2003-05-15 AU AU2003232776A patent/AU2003232776A1/en not_active Abandoned
- 2003-05-15 CA CA002487139A patent/CA2487139A1/en not_active Abandoned
- 2003-05-15 WO PCT/EP2003/005104 patent/WO2003099926A1/de active Application Filing
- 2003-05-15 JP JP2004508173A patent/JP2005527680A/ja not_active Withdrawn
- 2003-05-15 EP EP12190582.2A patent/EP2584001B1/de not_active Expired - Lifetime
- 2003-05-15 ES ES12190582T patent/ES2570141T3/es not_active Expired - Lifetime
- 2003-05-15 EP EP03755102.5A patent/EP1511807B1/de not_active Expired - Lifetime
- 2003-05-15 KR KR1020047019169A patent/KR100933619B1/ko not_active Expired - Lifetime
- 2003-05-15 ES ES03755102.5T patent/ES2497115T3/es not_active Expired - Lifetime
- 2003-05-15 MX MXPA04011733A patent/MXPA04011733A/es active IP Right Grant
- 2003-05-15 CN CNB038171228A patent/CN100387650C/zh not_active Expired - Fee Related
- 2003-05-21 US US10/442,459 patent/US20030225219A1/en not_active Abandoned
- 2003-05-27 TW TW092114201A patent/TWI297025B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP2584001B1 (de) | 2016-03-16 |
| KR100933619B1 (ko) | 2009-12-23 |
| US20030225219A1 (en) | 2003-12-04 |
| ES2570141T3 (es) | 2016-05-17 |
| WO2003099926A1 (de) | 2003-12-04 |
| MXPA04011733A (es) | 2005-07-14 |
| JP2005527680A (ja) | 2005-09-15 |
| EP2584001A1 (de) | 2013-04-24 |
| TWI297025B (en) | 2008-05-21 |
| DE10223646A1 (de) | 2003-12-11 |
| AU2003232776A1 (en) | 2003-12-12 |
| EP1511807A1 (de) | 2005-03-09 |
| EP1511807B1 (de) | 2014-06-25 |
| TW200412360A (en) | 2004-07-16 |
| CA2487139A1 (en) | 2003-12-04 |
| KR20050014840A (ko) | 2005-02-07 |
| CN100387650C (zh) | 2008-05-14 |
| CN1668694A (zh) | 2005-09-14 |
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