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ES2191962T3 - Procedimiento para la obtencion de metalocenos. - Google Patents

Procedimiento para la obtencion de metalocenos.

Info

Publication number
ES2191962T3
ES2191962T3 ES98942609T ES98942609T ES2191962T3 ES 2191962 T3 ES2191962 T3 ES 2191962T3 ES 98942609 T ES98942609 T ES 98942609T ES 98942609 T ES98942609 T ES 98942609T ES 2191962 T3 ES2191962 T3 ES 2191962T3
Authority
ES
Spain
Prior art keywords
metalocenes
procedure
obtaining
metallocenes
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES98942609T
Other languages
English (en)
Inventor
Andreas Winter
Carsten Bingel
Volker Fraaije
Frank Kueber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2191962T3 publication Critical patent/ES2191962T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La presente invención se refiere a un procedimiento de fabricación de metalocenos rac/meso, dichos metalocenos y la utilización de dichos metalocenos, para fabricar poliolefinas isotácticas.
ES98942609T 1997-07-28 1998-07-23 Procedimiento para la obtencion de metalocenos. Expired - Lifetime ES2191962T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19732366 1997-07-28

Publications (1)

Publication Number Publication Date
ES2191962T3 true ES2191962T3 (es) 2003-09-16

Family

ID=7837089

Family Applications (1)

Application Number Title Priority Date Filing Date
ES98942609T Expired - Lifetime ES2191962T3 (es) 1997-07-28 1998-07-23 Procedimiento para la obtencion de metalocenos.

Country Status (6)

Country Link
US (1) US6319874B1 (es)
EP (1) EP1003757B1 (es)
JP (1) JP4118507B2 (es)
DE (1) DE59807082D1 (es)
ES (1) ES2191962T3 (es)
WO (1) WO1999005153A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0953582A1 (en) * 1998-04-27 1999-11-03 Fina Research S.A. Polyolefin production
WO2000043331A2 (en) * 1999-01-21 2000-07-27 Boulder Scientific Company Synthesis and isomerization of 1,2-bis (indenyl) ethanes
GB9917851D0 (en) * 1999-07-29 1999-09-29 Borealis As Process
EP1254075B1 (en) 2000-01-21 2007-02-21 U.S. Borax Inc. Nonaborate compositions and their preparation
US7176158B2 (en) * 2002-10-25 2007-02-13 Exxonmobil Chemical Patents Inc. Polymerization catalyst composition
DE102004039877A1 (de) * 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
RU2529020C2 (ru) * 2012-10-17 2014-09-27 ЭлДжи КЕМ, ЛТД. Новое металлоценовое соединение, содержащая его каталитическая композиция и способ получения полимеров на основе олефинов с ее применением
JP7285286B2 (ja) * 2014-02-11 2023-06-01 ユニベーション・テクノロジーズ・エルエルシー ポリオレフィン生成物の生成
JP7212445B2 (ja) 2014-02-11 2023-01-25 ユニベーション・テクノロジーズ・エルエルシー ポリオレフィン生成物の生成
CN106062012B (zh) * 2014-09-05 2018-10-26 株式会社Lg化学 负载型混合催化剂及使用其制备基于烯烃的聚合物的方法
KR102097131B1 (ko) * 2015-12-22 2020-04-03 주식회사 엘지화학 올레핀 중합용 담지 촉매 및 이의 제조 방법

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443087A1 (de) 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
IL89525A0 (en) 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
EP0485821B1 (de) 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
ES2162953T3 (es) 1990-11-12 2002-01-16 Basell Polyolefine Gmbh Procedimiento para la obtencion de un polimero de olefina.
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5910464A (en) * 1992-06-18 1999-06-08 Montell Technology Company Bv Catalysts for the polymerization of olefins
DE19525178A1 (de) * 1995-07-11 1997-01-16 Basf Ag Verfahren zur Umwandlung der achiralen meso-Form eines ansa-Metallkomplexes in die chirale rac.-Form

Also Published As

Publication number Publication date
EP1003757A1 (de) 2000-05-31
WO1999005153A1 (de) 1999-02-04
DE59807082D1 (de) 2003-03-06
US6319874B1 (en) 2001-11-20
EP1003757B1 (de) 2003-01-29
JP2001510847A (ja) 2001-08-07
JP4118507B2 (ja) 2008-07-16

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