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ES2156153T3 - Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina. - Google Patents

Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.

Info

Publication number
ES2156153T3
ES2156153T3 ES94917804T ES94917804T ES2156153T3 ES 2156153 T3 ES2156153 T3 ES 2156153T3 ES 94917804 T ES94917804 T ES 94917804T ES 94917804 T ES94917804 T ES 94917804T ES 2156153 T3 ES2156153 T3 ES 2156153T3
Authority
ES
Spain
Prior art keywords
catalyst
polymerization
molecular weight
olefin polymer
olefine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94917804T
Other languages
English (en)
Inventor
Syoji Naganuma
Masami Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=15340962&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2156153(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Application granted granted Critical
Publication of ES2156153T3 publication Critical patent/ES2156153T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

SE EXPONEN UN CATALIZADOR PARA LA POLIMERIZACION DE UN OLEFIN, QEU INCLUYE (A) UN COMPUESTO COMPLEJO DE UN METAL DE TRANSICION REPRESENTADO POR LA FORMULA GENERAL (I) DONDE LOS SIMBOLOS RESPECTIVOS SON COMO DEFINIDOS EN LA ESPECIFICACION, (B) UN ACIDO LEWIS O UN COMPUESTO IONICO CAPAZ DE REACCIONAR CON EL COMPUESTO COMPLEJO DE METAL DE TRANSICION DEL COMPONENTE (A) O SU DERIVADO PARA FORMAR UN COMPLEJO IONICO, Y (C) UN COMPUESTO DE ALUMINIO ORGANICO, Y UN PROCESO PARA PREPARAR UN POLIMERO DE OLEFIN EN LA PRESENCIA DE UN CATALIZADOR. EL CATALIZADOR DE LA PRESENTE INVENCION ES INEXPRESIVO Y TIENE UNA ALTA ACTIVIDAD Y, DE ACUERDO CON LA INVENCION, EL DETERIORO DE LA ACTIVIDAD PUEDE SER INHIBIDO Y, EL PESO MOLECULAR DEL POLIMERO OBTENIDO, FACILMENTE AJUSTADO, DE TAL MODO QUE EL POLIMERO DE OLEFIN PUEDE SER PREPARADO EFICAZMENTE CON UN PESO MOLECULAR OPCIONAL Y PUEDE POSEER UNA DISTRIBUCION DE PESO MOLECULAR CON PORCIONES DE BAJOS Y ALTOS PESOS MOLECULARES DISMINUIDAS.
ES94917804T 1993-06-15 1994-06-14 Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina. Expired - Lifetime ES2156153T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14353393 1993-06-15

Publications (1)

Publication Number Publication Date
ES2156153T3 true ES2156153T3 (es) 2001-06-16

Family

ID=15340962

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94917804T Expired - Lifetime ES2156153T3 (es) 1993-06-15 1994-06-14 Procedimiento de produccion de polimero olefinico, y catalizador para la polimerizacion de una olefina.

Country Status (6)

Country Link
US (1) US6462154B1 (es)
EP (1) EP0705849B2 (es)
CA (1) CA2164968A1 (es)
DE (2) DE69426648T3 (es)
ES (1) ES2156153T3 (es)
WO (1) WO1994029356A1 (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69333327T2 (de) * 1992-06-23 2004-09-09 The Dow Chemical Company, Midland Verfahren zur Herstellung Tetrakisfluorphenylborat
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
WO1997007141A1 (de) * 1995-08-18 1997-02-27 Targor Gmbh Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren
WO1997023191A1 (fr) * 1995-12-22 1997-07-03 Tokuyama Corporation Composition d'agent de decapage dentaire et catalyseur de polymerisation
ID16442A (id) * 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah
ID17196A (id) 1996-03-14 1997-12-11 Dow Chemical Co Bahan-bahan perekat yang mengandung polimer-polimer olefin
IL127069A0 (en) * 1996-05-17 1999-09-22 Dow Chemical Co Polyolefin composition with molecular weight maximum occuring in that part of the composition that has the highest comonomer content
JPH09309926A (ja) 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
ES2160289T3 (es) † 1996-08-13 2001-11-01 Basell Polyolefine Gmbh Sistema catalizador soportado, un procedimiento para su obtencion y su empleo para la polimerizacion de olefinas.
US6894131B2 (en) 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
EP1640386A3 (en) * 1998-08-21 2006-04-12 Univation Technologies, LLC Polymerization process using an improved bulky ligand metallocene-type catalyst-system
US6632901B2 (en) * 1998-08-21 2003-10-14 Univation Technologies, Llc Polymerization process using an improved bulky ligand metallocene-type catalyst system
CN1174805C (zh) 1999-01-21 2004-11-10 出光石油化学株式会社 α-烯烃制造用催化剂和α-烯烃制造方法
US6303718B1 (en) * 1999-09-17 2001-10-16 Bayer Aktiengesellschaft Composition based on fluorine-containing metal complexes
US6875828B2 (en) 2002-09-04 2005-04-05 Univation Technologies, Llc Bimodal polyolefin production process and films therefrom
US6884748B2 (en) 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
ES2257710T5 (es) * 2002-10-02 2011-11-22 Dow Global Technologies Llc Polímeros de etileno de bajo peso molecular líquidos y de tipo gel.
DE60322410D1 (de) 2002-10-17 2008-09-04 Dow Global Technologies Inc Hochgefüllte polymerzusammensetzungen
US6869903B2 (en) 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
US6890876B2 (en) 2002-11-26 2005-05-10 Univation Technologies, Llc Processes for producing fluorided catalysts from nitrogenous metallocenes
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
US7759489B2 (en) * 2006-01-27 2010-07-20 Idemitsu Kosan Co., Ltd. Transition metal complex compound and organic electroluminescence device using the compound
US8455415B2 (en) * 2009-10-23 2013-06-04 Exxonmobil Research And Engineering Company Poly(alpha-olefin/alkylene glycol) copolymer, process for making, and a lubricant formulation therefor

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0699519B2 (ja) 1984-05-28 1994-12-07 出光興産株式会社 エチレン共重合体の製造方法
ATE177759T1 (de) † 1986-09-24 1999-04-15 Mitsui Chemicals Inc Verfahren zur olefinpolymerisation
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5041584A (en) † 1988-12-02 1991-08-20 Texas Alkyls, Inc. Modified methylaluminoxane
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
NZ235032A (en) † 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5420217A (en) * 1989-09-13 1995-05-30 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
EP0427697B1 (en) * 1989-10-10 1996-05-08 Fina Technology, Inc. Metallocene catalysts with Lewis acids and aluminum alkyls
DE69122275T3 (de) 1990-06-22 2002-10-31 Exxon Chemical Patents Inc., Linden Aluminiumfreie Monocyclopentadienyl-Metallocenkatalysatoren für Olefinpolymerisation
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
EP0500944B1 (en) † 1990-07-24 1998-10-07 Mitsui Chemicals, Inc. Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith
US5369196A (en) 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers
DE69222700T2 (de) * 1991-07-11 1998-03-26 Idemitsu Kosan Co Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren
US5278272A (en) † 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
JP2816766B2 (ja) 1991-12-23 1998-10-27 エクソン・ケミカル・パテンツ・インク オレフィン重合用改質モノシクロペンタジエニル遷移金属／アルモキサン触媒系
US5453410A (en) * 1992-01-06 1995-09-26 The Dow Chemical Company Catalyst composition
JP3194438B2 (ja) 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
BE1005957A5 (fr) * 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
JP3153000B2 (ja) 1992-06-11 2001-04-03 三菱化学株式会社 α‐オレフィン重合体の製造法
JPH061803A (ja) * 1992-06-18 1994-01-11 Mitsubishi Petrochem Co Ltd オレフィンの重合法
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JP3202349B2 (ja) * 1992-09-22 2001-08-27 三菱化学株式会社 触媒組成物およびそれを用いるオレフィンの重合法
CA2146012A1 (en) † 1992-10-02 1994-04-14 Brian W. S. Kolthammer Supported homogenous catalyst complexes for olefin polymerization
JP3370331B2 (ja) * 1992-10-05 2003-01-27 エクソンモービル・ケミカル・パテンツ・インク 改善された生産性の触媒系及びその重合プロセスにおける使用
JP3188092B2 (ja) 1994-02-25 2001-07-16 三菱重工業株式会社 脱水シューブレード

Also Published As

Publication number Publication date
WO1994029356A1 (fr) 1994-12-22
DE69426648T4 (de) 2002-06-13
EP0705849A4 (en) 1996-10-23
EP0705849B2 (en) 2004-06-16
EP0705849B1 (en) 2001-01-31
EP0705849A1 (en) 1996-04-10
US6462154B1 (en) 2002-10-08
DE69426648T3 (de) 2005-02-03
DE69426648D1 (de) 2001-03-08
CA2164968A1 (en) 1994-12-22
DE69426648T2 (de) 2001-05-31

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