[go: up one dir, main page]

ES2135958T3 - Procedimiento para la obtencion de soportes de catalizadores y catalizadores de poliolefinas soportados asi como su empleo para la obtencion de poliolefinas. - Google Patents

Procedimiento para la obtencion de soportes de catalizadores y catalizadores de poliolefinas soportados asi como su empleo para la obtencion de poliolefinas.

Info

Publication number
ES2135958T3
ES2135958T3 ES97100880T ES97100880T ES2135958T3 ES 2135958 T3 ES2135958 T3 ES 2135958T3 ES 97100880 T ES97100880 T ES 97100880T ES 97100880 T ES97100880 T ES 97100880T ES 2135958 T3 ES2135958 T3 ES 2135958T3
Authority
ES
Spain
Prior art keywords
obtaining
polyolefin
catalysts
procedure
supported
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97100880T
Other languages
English (en)
Inventor
Eberhard Ernst
Jens Reubetaner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis AG
Original Assignee
Borealis AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis AG filed Critical Borealis AG
Application granted granted Critical
Publication of ES2135958T3 publication Critical patent/ES2135958T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Working-Up Tar And Pitch (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE UN SOPORTE DE CATALIZADOR, QUE CONSISTE EN SECAR UN OXIDO INORGANICO HIDROFILICO DE UN ELEMENTO DE LOS GRUPOS PRINCIPALES II A IV O DEL GRUPO SECUNDARIO IV DEL SISTEMA PERIODICO O SUS MEZCLAS U OXIDOS MEZCLADOS DE 110 A 800 C, A CONTINUACION SE PUEDE HACER REACCIONAR CON ALUMINOXANOS O CON ALQUILENO DE AL, Y SEGUIDAMENTE SE HACE REACCIONAR SIMULTANEAMENTE CON ALUMINOXANOS Y RETICULANTES ORGANICOS POLIFUNCIONALES. EN EL SIGUIENTE PASO SE PUEDE PONER EN CONTACTO EL SOPORTE DEL CATALIZADOR CON UN CATALIZADOR DE POLIOLEFINA, OBTENIENDOSE UN CATALIZADOR SOPORTADO DE POLIOLEFINA, QUE SE PUEDE UTILIZAR EN PARTICULAR PARA LA POLIMERIZACION DE OLEFINAS.
ES97100880T 1996-02-02 1997-01-21 Procedimiento para la obtencion de soportes de catalizadores y catalizadores de poliolefinas soportados asi como su empleo para la obtencion de poliolefinas. Expired - Lifetime ES2135958T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT0018896A AT403919B (de) 1996-02-02 1996-02-02 Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
DE19608804A DE19608804A1 (de) 1996-02-02 1996-03-07 Verfahren zur Herstellung von Katalysatorträgern und geträgerter Polyolefin-Katalysatoren sowie deren Verwendung für die Herstellung von Polyolefinen

Publications (1)

Publication Number Publication Date
ES2135958T3 true ES2135958T3 (es) 1999-11-01

Family

ID=25591783

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97100880T Expired - Lifetime ES2135958T3 (es) 1996-02-02 1997-01-21 Procedimiento para la obtencion de soportes de catalizadores y catalizadores de poliolefinas soportados asi como su empleo para la obtencion de poliolefinas.

Country Status (14)

Country Link
US (2) US5932514A (es)
EP (1) EP0787746B1 (es)
JP (1) JPH09216909A (es)
CN (1) CN1117101C (es)
AT (2) AT403919B (es)
BR (1) BR9700826A (es)
CA (1) CA2196509A1 (es)
CZ (1) CZ19597A3 (es)
DE (2) DE19608804A1 (es)
DK (1) DK0787746T3 (es)
ES (1) ES2135958T3 (es)
HU (1) HU218966B (es)
NO (1) NO970421L (es)
SK (1) SK13497A3 (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
DE19821370A1 (de) * 1998-04-28 1999-11-18 Borealis Polymere Holding Gmbh Verfahren zur Herstellung von Katalysatorträgern und geträgerten Polyolefinkatalysatoren
AT406868B (de) * 1998-04-28 2000-10-25 Borealis Ag Verfahren zur herstellung von katalysatorträgern und geträgerten polyolefinkatalysatoren
US6165929A (en) * 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
EP1218423B1 (en) 1999-10-02 2005-03-16 Borealis Technology Oy Modified supported catalysts for the polymerization of olefins
GB0220681D0 (en) 2002-09-05 2002-10-16 Borealis Tech Oy Process
MX382405B (es) 2010-07-02 2025-03-13 The Procter & Gamble Company Método para suministrar un agente activo.
BR112013000101A2 (pt) 2010-07-02 2016-05-17 Procter & Gamble filamentos compreendendo mantas de não tecido com agente ativo e métodos de fabricação dos mesmos
EP3533908A1 (en) 2010-07-02 2019-09-04 The Procter & Gamble Company Nonwoven web comprising one or more active agents
CA2815336C (en) 2010-11-22 2019-06-18 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
US9701770B2 (en) 2012-04-19 2017-07-11 Ineos Europe Ag Catalyst for the polymerisation of olefins, process for its production and use
US11896693B2 (en) 2019-12-01 2024-02-13 The Procter & Gamble Company Hair conditioner compositions with a preservative system containing sodium benzoate and glycols and/or glyceryl esters
EP3134184B1 (en) 2014-04-22 2024-04-10 The Procter & Gamble Company Compositions in the form of dissolvable solid structures
EP3573593B1 (en) 2017-01-27 2023-08-30 The Procter & Gamble Company Compositions in the form of dissolvable solid structures
EP3573722B1 (en) 2017-01-27 2022-02-23 The Procter & Gamble Company Compositions in the form of dissolvable solid structures comprising effervescent agglomerated particles
WO2018213003A1 (en) 2017-05-16 2018-11-22 The Procter & Gamble Company Conditioning hair care compositions in the form of dissolvable solid structures
JP1629688S (es) 2018-07-16 2019-04-15
US11666514B2 (en) 2018-09-21 2023-06-06 The Procter & Gamble Company Fibrous structures containing polymer matrix particles with perfume ingredients
CN109438596B (zh) * 2018-12-13 2020-09-11 芜湖万隆新材料有限公司 催化剂、制备方法、以聚合物多孔微球为载体的催化剂体系及使用方法
WO2020264574A1 (en) 2019-06-28 2020-12-30 The Procter & Gamble Company Dissolvable solid fibrous articles containing anionic surfactants
WO2021003492A1 (en) 2019-07-03 2021-01-07 The Procter & Gamble Company Fibrous structures containing cationic surfactants and soluble acids
USD939359S1 (en) 2019-10-01 2021-12-28 The Procter And Gamble Plaza Packaging for a single dose personal care product
CN114555483B (zh) 2019-10-14 2024-04-26 宝洁公司 含有固体制品的可生物降解的和/或家庭可堆肥的小袋
CA3157576A1 (en) 2019-11-20 2021-05-27 The Procter & Gamble Company Porous dissolvable solid structure
USD941051S1 (en) 2020-03-20 2022-01-18 The Procter And Gamble Company Shower hanger
USD962050S1 (en) 2020-03-20 2022-08-30 The Procter And Gamble Company Primary package for a solid, single dose beauty care composition
USD965440S1 (en) 2020-06-29 2022-10-04 The Procter And Gamble Company Package
US11925698B2 (en) 2020-07-31 2024-03-12 The Procter & Gamble Company Water-soluble fibrous pouch containing prills for hair care
WO2022036352A1 (en) 2020-08-11 2022-02-17 The Procter & Gamble Company Clean rinse hair conditioner compositions containing brassicyl valinate esylate
WO2022036354A1 (en) 2020-08-11 2022-02-17 The Procter & Gamble Company Low viscosity hair conditioner compositions containing brassicyl valinate esylate
CN116018123A (zh) 2020-08-11 2023-04-25 宝洁公司 含有芸苔油醇缬氨酸酯乙磺酸盐的保湿毛发调理剂组合物
EP4255384A1 (en) 2020-12-01 2023-10-11 The Procter & Gamble Company Aqueous hair conditioner compositions containing solubilized anti-dandruff actives
USD1045064S1 (en) 2020-12-17 2024-10-01 The Procter & Gamble Company Single-dose dissolvable personal care unit

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE870242C (de) * 1941-09-26 1953-03-12 Degussa Verfahren zum Verdicken von Fluessigkeiten
DE952891C (de) * 1954-01-23 1956-11-22 Degussa Verfahren zur Herstellung von feinverteilten Metalloxyden und deren Gemischen
US4452914A (en) * 1982-08-13 1984-06-05 The Dow Chemical Company Titanium complexes and catalysts prepared therefrom
US4435519A (en) * 1982-11-24 1984-03-06 Cities Service Co. Novel catalyst composition
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4874880A (en) 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
JPH0791327B2 (ja) * 1988-03-24 1995-10-04 出光興産株式会社 スチレン系重合体の製造方法とその触媒
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
KR100197327B1 (ko) 1988-07-15 1999-06-15 치어즈 엠. 노우드 신디오택틱 폴리프로필렌
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
JPH05502906A (ja) 1990-01-02 1993-05-20 エクソン・ケミカル・パテンツ・インク オレフィン重合用の担持イオン性メタロセン触媒
US5142006A (en) * 1990-01-29 1992-08-25 Shell Oil Company Polymerization of cyclic olefins
ES2091273T3 (es) 1990-11-12 1996-11-01 Hoechst Ag Procedimiento para la preparacion de un polimero olefinico de alto peso molecular.
TW300901B (es) * 1991-08-26 1997-03-21 Hoechst Ag
DE4139262A1 (de) * 1991-11-29 1993-06-03 Basf Ag Getraegerte katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
FI112233B (fi) 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
EP0578838A1 (en) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
DE69224184T2 (de) 1992-06-13 1999-06-02 Targor GmbH, 55116 Mainz Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl
US5258344A (en) * 1992-06-30 1993-11-02 Phillips Petroleum Company Transition metal catalyst, method of producing the catalyst, polymerization process employing the catalyst, and polymer produced by the polymerization process
DE4228711A1 (de) * 1992-08-28 1994-03-03 Degussa Silicium-Aluminium-Mischoxid
US5278305A (en) * 1992-12-31 1994-01-11 Shell Oil Company Catalysts for ring-opening, metathesis polymerization of cyclic olefins
DK0685494T3 (da) * 1994-06-03 1999-02-15 Pcd Polymere Ag Katalysatorbærere, understøttede metallocenkatalysatorer og deres anvendelse til fremstilling af polyolefiner
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
JP3357186B2 (ja) * 1994-07-14 2002-12-16 三菱化学株式会社 プロピレンブロック共重合体の製造法
US5625015A (en) * 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
EP0754706B1 (en) * 1995-07-08 1998-08-05 PCD-Polymere Gesellschaft m.b.H. Supported polymerization-catalyst and its use for olefin polymerization
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
AT403919B (de) * 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen

Also Published As

Publication number Publication date
CN1162601A (zh) 1997-10-22
HUP9700315A2 (hu) 1998-03-02
DE59700318D1 (de) 1999-09-16
SK13497A3 (en) 1998-10-07
AT403919B (de) 1998-06-25
BR9700826A (pt) 1998-08-25
DK0787746T3 (da) 1999-12-06
DE19608804A1 (de) 1997-09-18
HU218966B (hu) 2001-01-29
EP0787746B1 (de) 1999-08-11
JPH09216909A (ja) 1997-08-19
US5932514A (en) 1999-08-03
ATA18896A (de) 1997-11-15
HUP9700315A3 (en) 1998-03-30
US6225252B1 (en) 2001-05-01
NO970421D0 (no) 1997-01-31
EP0787746A1 (de) 1997-08-06
CA2196509A1 (en) 1997-08-03
NO970421L (no) 1997-08-04
CZ19597A3 (en) 1997-08-13
HU9700315D0 (en) 1997-03-28
MX9700669A (es) 1998-06-28
CN1117101C (zh) 2003-08-06
ATE183207T1 (de) 1999-08-15

Similar Documents

Publication Publication Date Title
ES2135958T3 (es) Procedimiento para la obtencion de soportes de catalizadores y catalizadores de poliolefinas soportados asi como su empleo para la obtencion de poliolefinas.
AR025163A1 (es) Un procedimiento para preparar olefinas, un sistema catalizador soportado, el uso de un compuesto catalizador del grupo 15 que contiene hafnio y el uso deun sistema catalizador que comprende un compuesto catalizador
BR9810857A (pt) Composto quìmico, processos para a preparação do mesmo, e para a preparação de uma poliolefina, sistema catalisador, e, uso do mesmo
ES2194924T3 (es) Sistemas cataliticos de polimerizacion, su produccion y uso.
ATE263973T1 (de) Biochemisches und immunochemisches testgerät
ES2168444T3 (es) Fabricacion de tiras de prueba.
ES2191184T3 (es) Sistemas cataliticos de metales de transicion ultimos soportados.
AR026302A1 (es) Un metodo para estabilizar solventes siliconados para la limpieza en seco, un adsorbente y un proceso de limpieza en seco.
ES2104575T3 (es) 3-amino-pirazolo-heterociclos, su utilizacion para la determinacion de peroxido de hidrogeno, sistemas que forman peroxido de hidrogeno, peroxidasas, sustancias activas como peroxidantes o compuestos aromaticos ricos en electrones, procedimientos correspondientes y agentes
ES2135771T3 (es) Sistemas cataliticos de polimerizacion, su produccion y su uso.
DE3762867D1 (de) Mesomorpher polymerwirkstoff, verwendungsfaehig zur nichtlinearoptik.
ES2052610T3 (es) Un metodo de determinacion de anfetamina y/o metanfetamina en una muestra de ensayo.
ATE78193T1 (de) Verfahren zur reduktion eines raffinierungskatalysators vor seiner anwendung.
SE9700768D0 (sv) Förfarande för att introducera funktionalitet
BR9800515A (pt) Processo para a preparação de um sistema catalisador de metaloceno
ES8704750A1 (es) Procedimiento para la eliminacion selectiva de oxidos de nitrogeno a partir de gases de escape
ES2008699B3 (es) Procedimiento de reformacion catalitica.
IT1075554B (it) Procedimento per la purificazione di acque contenenti prodotti organici,mediante estrazione dei detti prodotti organici per mezzo di un solvente immobilizzato
JPS57105203A (en) Selective permeable membrane
DE69424474D1 (de) Hydrierungsverfahren zur Reinigung einer Mischung von Wasser und Caprolactam
ES2050959T3 (es) Limpieza de un sistema de conversion de hidrocarburos para hacer posible su uso con un catalizador sensible a sustancias contaminantes.
ES2102858T3 (es) Procedimiento que utiliza electroquimioluminiscencia.
MX172707B (es) Soluciones absorbentes con diaminoeter y su uso en un proceso para eliminar h2s de corrientes gaseosas
ES2054884T3 (es) Soporte para la reaccion enzimatica, o quimica y enzimatica de acidos nucleicos o fragmentos de acidos nucleicos en presencia de bases solidas.
DE3766671D1 (de) Vernetzte polymerisate mit carbonatestergruppen und verfahren zu ihrer herstellung.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 787746

Country of ref document: ES