[go: up one dir, main page]

ES2130297T3 - Procedimiento para producir metacroleina y acido metacrilico. - Google Patents

Procedimiento para producir metacroleina y acido metacrilico.

Info

Publication number
ES2130297T3
ES2130297T3 ES94103673T ES94103673T ES2130297T3 ES 2130297 T3 ES2130297 T3 ES 2130297T3 ES 94103673 T ES94103673 T ES 94103673T ES 94103673 T ES94103673 T ES 94103673T ES 2130297 T3 ES2130297 T3 ES 2130297T3
Authority
ES
Spain
Prior art keywords
alpha
selected element
representa
general formula
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94103673T
Other languages
English (en)
Inventor
Hideo Onodera
Shigeru Ohno
Ikuo Kurimoto
Yukio Aoki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP1315163A external-priority patent/JP2934267B2/ja
Priority claimed from JP1338471A external-priority patent/JP2756160B2/ja
Priority claimed from JP2007200A external-priority patent/JP2638241B2/ja
Priority claimed from JP2014815A external-priority patent/JP2659839B2/ja
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Application granted granted Critical
Publication of ES2130297T3 publication Critical patent/ES2130297T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8873—Zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8875—Germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

LA PRESENTE INVENCION PROPORCIONA UN PROCESO PARA PRODUCIR METACROLEINA Y ACIDO METACRILICO, SOMETIENDO AL MENOS UN MATERIAL SELECCIONADO DE ISOBUTILENO, T-BUTANOL Y ETER DE METIL T MOLECULAR O UN GAS QUE CONTENGA OXIGENO MOLECULAR, USANDO UN REACTOR MULTITUBULAR DE LECHO FIJO. EL PROCESO SE CARACTERIZA POR LAS SIGUIENTES ((ALFA)), ((BETA)) Y ((TAU)). ((ALFA)) SE USAN COMO CATALIZADORES, OXIDOS COMPUESTOS REPRESENTADOS POR LA SIGUIENTE FORMULA GENERAL: MOA WB BIC FED AE BF CG DH EI OX (EN LA FORMULA, MO REPRESENTA MOLIBDENO, W REPRESENTA TUNGSTENO, BI REPRESENTA BISMUTO, FE REPRESENTA HIERRO, A REPRESENTA AL MENOS UN ELEMENTO SELECCIONADO DE NIQUEL Y COBALTO, BE REPRESENTA AL MENOS UN ELEMENTO SELECCIONADO DE METALES ALCALINOS Y TALIO, C REPRESENTA AL MENOS UN ELEMENTO SELECCIONADO DE METALES ALCALINOTERREOS, D REPRESENTA AL MENOS UN ELEMENTO SELECCIONADO DE FOSFORO, TELURIO, ANTIMONIO, ESTAÑO, CERIO, PLOMO, NIOBIO, MANGANESO, ARSENICO Y CINZ, E REPRESENTA AL MENOS UN ELEMENTO SELECCIONADODE SILICIO, ALUMINIO, TITANIO Y CIRCONIO, Y O REPRESENTA OXIGENO; A, B, C, D, E, F, G, H, I Y X REPRESENTAN LOS NUMEROS DE ATOMOS DE MO, W, BI, FE, A, B, C, D, E Y O, RESPECTIVAMENTE; CUANDO A ES 12, B = 0 F = 0 DETERMINADO POR LOS ESTADOS DE OXIDACION DE ELEMENTOS INDIVIDUALES). ((BETA)) CADA TUBO DE REACCION TIENE UNA PLURALIDAD DE ZONAS DE REACCION FORMADAS DIVIDIENDO LA CAPA CATALIZADORA EN EL TUBO DE REACCION EN DOS O MAS PORCIONES, EN LA DIRECCION AXIAL DEL TUBO. ((TAU)) LA PLURALIDAD DE ZONAS DE REACCION SE LLENA CON CATALIZADORES REPRESENTADOS EN LA ANTERIOR ((ALFA)) TENIENDO DIFERENTES ACTIVIDADES, PREPARADAS MEDIANTE LA VARIACION DE TIPOS Y/O CANTIDADES DE LOS ELEMENTOS CONSTITUYENTES DE LOS GRUPOS A, B, C, D Y E EN LA FORMULA GENERAL (I) Y/O CON CATALIZADORES REPRESENTADOS EN LA ANTERIOR ((ALFA)), TENIENDO DIFERENTES ACTIVIDADES, PREPARADAS VARIANDO LA CANTIDAD DE, AL MENOS, UN ELEMENTO DE W, BI Y FE EN LA FORMULA GENERAL (I), EN TAL FORMA QUE LA ACTIVIDAD DEL CATALIZADOR LLENO SE HACE SUPERIOR A MEDIDA QUE UN GAS MATERIAL AVANZA DESDE LA ENTRADA A LA SALIDA.
ES94103673T 1989-12-06 1990-12-06 Procedimiento para producir metacroleina y acido metacrilico. Expired - Lifetime ES2130297T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP1315163A JP2934267B2 (ja) 1989-12-06 1989-12-06 メタクロレインおよびメタクリル酸の製造方法
JP1338471A JP2756160B2 (ja) 1989-12-28 1989-12-28 メタクロレインおよびメタクリル酸の製造方法
JP2007200A JP2638241B2 (ja) 1990-01-18 1990-01-18 メタクロレインおよびメタクリル酸の製造方法
JP2014815A JP2659839B2 (ja) 1990-01-26 1990-01-26 メタクロレインおよびメタクリル酸の製造方法

Publications (1)

Publication Number Publication Date
ES2130297T3 true ES2130297T3 (es) 1999-07-01

Family

ID=27454664

Family Applications (2)

Application Number Title Priority Date Filing Date
ES94103673T Expired - Lifetime ES2130297T3 (es) 1989-12-06 1990-12-06 Procedimiento para producir metacroleina y acido metacrilico.
ES91900057T Expired - Lifetime ES2092557T3 (es) 1989-12-06 1990-12-06 Procedimiento para producir metalocreina y acido metacrilico.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES91900057T Expired - Lifetime ES2092557T3 (es) 1989-12-06 1990-12-06 Procedimiento para producir metalocreina y acido metacrilico.

Country Status (7)

Country Link
US (1) US5276178A (es)
EP (2) EP0608917B1 (es)
KR (1) KR950006522B1 (es)
DE (2) DE69028843T2 (es)
ES (2) ES2130297T3 (es)
SG (1) SG50687A1 (es)
WO (1) WO1991008185A1 (es)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3272745B2 (ja) * 1991-06-06 2002-04-08 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JP2974826B2 (ja) * 1991-07-17 1999-11-10 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸製造用触媒の調製法
CN1062550C (zh) * 1993-06-25 2001-02-28 住友化学工业株式会社 不饱和醛和不饱和羧酸的制备方法
TW309513B (es) * 1994-05-31 1997-07-01 Nippon Catalytic Chem Ind
EP0767161B1 (en) * 1994-06-22 1999-11-03 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing methacrolein
US6136998A (en) * 1996-10-15 2000-10-24 Mitsubishi Rayon Co., Ltd. Retention of activity of molybdenum-containing metallic oxide catalyst
JP3775872B2 (ja) * 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
US5864051A (en) * 1997-11-10 1999-01-26 Uop Selective oxidation catalyst process for preparing the catalyst and process using the catalyst
JP4045693B2 (ja) * 1999-04-27 2008-02-13 住友化学株式会社 メタクリル酸の製造方法
KR100569632B1 (ko) * 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
JP4185217B2 (ja) * 1999-05-25 2008-11-26 株式会社日本触媒 複合酸化物触媒、並びに（メタ）アクロレインおよび（メタ）アクリル酸の製造方法
JP3943291B2 (ja) * 1999-08-04 2007-07-11 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
JP3943311B2 (ja) * 2000-05-19 2007-07-11 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸の製造方法
DE10046957A1 (de) * 2000-09-21 2002-04-11 Basf Ag Verfahren zur Herstellung eines Multimetalloxid-Katalysators, Verfahren zur Herstellung ungesättigter Aldehyde und/oder Carbonsäuren und Bandcalziniervorrichtung
DE10063162A1 (de) * 2000-12-18 2002-06-20 Basf Ag Verfahren zur Herstellung einer Mo, Bi, Fe sowie Ni und/oder Co enthaltenden Multimetalloxidativmasse
TW572885B (en) * 2001-05-30 2004-01-21 Mitsubishi Rayon Co Method for producing (meth)acrolein and/or (meth)acrylic acid
CN1572772A (zh) * 2001-12-27 2005-02-02 三菱化学株式会社 （甲基）丙烯醛或（甲基）丙烯酸的制造方法
EP1466883A4 (en) * 2001-12-28 2006-09-06 Mitsubishi Chem Corp CATALYTIC OXIDATION PROCESS IN STEAM PHASE
JP3884967B2 (ja) * 2002-02-07 2007-02-21 住友化学株式会社 メタクリル酸の製造方法
US6960684B2 (en) * 2002-03-29 2005-11-01 Nippon Shokubai Co., Ltd. Production process for unsaturated aldehyde
US7045657B2 (en) * 2002-04-03 2006-05-16 Nippon Shokubai Co., Ltd. Catalytic gas phase oxidation process
US6946422B2 (en) * 2002-12-12 2005-09-20 Saudi Basic Industries Corporation Preparation of mixed metal oxide catalysts for catalytic oxidation of olefins to unsaturated aldehydes
US7232788B2 (en) * 2003-03-31 2007-06-19 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7361791B2 (en) * 2003-03-31 2008-04-22 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US20040192973A1 (en) * 2003-03-31 2004-09-30 Saudi Basic Industries Corporation Mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US7161044B2 (en) * 2003-10-22 2007-01-09 Nippon Shokubai Co., Ltd. Catalytic gas phase oxidation reaction
WO2005054166A1 (ja) * 2003-12-03 2005-06-16 Mitsubishi Chemical Corporation 不飽和アルデヒド及び不飽和カルボン酸の製造方法
US7229945B2 (en) * 2003-12-19 2007-06-12 Saudi Basic Industrics Corporation Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP2005213179A (ja) * 2004-01-29 2005-08-11 Mitsubishi Rayon Co Ltd 触媒層およびその形成方法、固定床管型反応器、メタクロレインまたはメタクリル酸の製造方法
KR101237662B1 (ko) 2004-05-07 2013-02-26 바스프 에스이 촉매 튜브 다발의 촉매 튜브를 구조화된 방식으로 충진하는방법
JP4572573B2 (ja) * 2004-05-13 2010-11-04 三菱化学株式会社 （メタ）アクロレイン又は（メタ）アクリル酸の製造方法
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
DE102007017080A1 (de) 2007-04-10 2008-10-16 Basf Se Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres
EP1995232B1 (en) 2007-05-25 2018-01-03 Evonik Röhm GmbH Use of feed compositions in preparation of methacrylic acid by oxidation
DE102007025869A1 (de) 2007-06-01 2008-07-03 Basf Se Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett
DE102007028332A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst
EP2085376B1 (en) 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
KR101072177B1 (ko) * 2009-06-08 2011-10-10 주식회사 엘지화학 탄화수소 수증기 열분해용 촉매, 그의 제조방법 및 이를 이용한 올레핀의 제조방법
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
WO2013163806A1 (en) 2012-05-03 2013-11-07 Evonik Industries Ag Process for preparation of highly pure, non-yellowing methacrylic acid
JP2016516732A (ja) 2013-03-18 2016-06-09 エボニック レーム ゲゼルシャフト ミット ベシュレンクテル ハフツングＥｖｏｎｉｋ Ｒｏｅｈｍ ＧｍｂＨ メタクリル酸及びメタクリル酸エステルの製造方法
KR101776796B1 (ko) * 2013-05-09 2017-09-08 닛뽄 가야쿠 가부시키가이샤 불포화 알데히드 및/또는 불포화 카본산 제조용 촉매, 그의 제조 방법 및 불포화 알데히드 및/또는 불포화 카본산의 제조 방법
RU2016104764A (ru) 2013-07-18 2017-08-21 Ниппон Каяку Кабусики Кайся Способ получения ненасыщенного альдегида и/или ненасыщенной карбоновой кислоты
CN104649872B (zh) * 2013-11-19 2016-08-17 中国石油天然气股份有限公司 一种低碳烯烃选择性氧化的方法
CN105801394B (zh) * 2014-12-31 2018-10-02 上海华谊新材料有限公司 由叔丁醇制备甲基丙烯醛的方法
EP3321247B1 (en) * 2015-07-10 2019-11-20 Nippon Kayaku Kabushiki Kaisha Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
CN115260015A (zh) * 2021-04-29 2022-11-01 中国石油化工股份有限公司 制备甲基丙烯醛和甲基丙烯酸的方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2056614C3 (de) * 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Acrylsäure aus Propylen
JPS5541213B2 (es) * 1972-07-21 1980-10-22
JPS5761011B2 (es) * 1973-12-28 1982-12-22 Nippon Shokubai Kagaku Kogyo Kk
US4001317A (en) * 1974-07-22 1977-01-04 Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
IN142430B (es) * 1975-04-21 1977-07-09 Standard Oil Co
US4323520A (en) * 1976-08-02 1982-04-06 The Standard Oil Co. Preparation of methacrylic derivatives from tertiary-butyl-containing compounds
JPS543008A (en) * 1977-06-09 1979-01-11 Japan Synthetic Rubber Co Ltd Preparation of methacrylic acid
US4148757A (en) * 1977-08-10 1979-04-10 The Standard Oil Company Process for forming multi-component oxide complex catalysts
JPS5547144A (en) * 1977-08-10 1980-04-03 Standard Oil Co Multiple component oxide complex catalyst forming technique
US4267386A (en) * 1978-11-13 1981-05-12 Celanese Corporation Olefin oxidation catalyst
JPS55113730A (en) * 1979-02-26 1980-09-02 Mitsubishi Petrochem Co Ltd Preparation of acrolein and acrylic acid
JPS5673041A (en) * 1979-11-19 1981-06-17 Mitsubishi Petrochem Co Ltd Preparation of acrylic acid
JPS5687530A (en) * 1979-12-19 1981-07-16 Asahi Chem Ind Co Ltd Dehydrating method of gas containing unsaturated aldehyde
JPS56166140A (en) * 1980-05-24 1981-12-21 Asahi Chem Ind Co Ltd Preparation of methacrolein
JPS58119346A (ja) * 1982-01-06 1983-07-15 Nippon Shokubai Kagaku Kogyo Co Ltd プロピレン酸化用触媒
JPS58143843A (ja) * 1982-02-17 1983-08-26 ザ・スタンダ−ド・オイル・カンパニー オレフインの酸化またはアンモ酸化に有用な触媒
JPS5946132A (ja) * 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE3308625A1 (de) * 1983-03-11 1984-09-13 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure
JPS6122040A (ja) * 1984-07-10 1986-01-30 Mitsubishi Rayon Co Ltd メタクロレイン及びメタクリル酸の製造法
JPH0625085B2 (ja) * 1984-07-24 1994-04-06 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
EP0168826B1 (en) * 1984-07-18 1988-05-04 Mitsubishi Rayon Co., Ltd. Process for producing methacrolein and methacrylic acid
US5208371A (en) * 1986-11-11 1993-05-04 Mitsubishi Rayon Co., Ltd. Process for production of methacrolein and methacrylic acid

Also Published As

Publication number Publication date
US5276178A (en) 1994-01-04
EP0456837A1 (en) 1991-11-21
EP0608917A1 (en) 1994-08-03
EP0608917B1 (en) 1999-04-21
EP0456837A4 (en) 1992-01-15
ES2092557T3 (es) 1996-12-01
DE69033068D1 (de) 1999-05-27
KR920701099A (ko) 1992-08-11
DE69028843T2 (de) 1997-02-27
EP0456837B1 (en) 1996-10-09
SG50687A1 (en) 1998-07-20
DE69033068T2 (de) 1999-08-19
KR950006522B1 (ko) 1995-06-16
DE69028843D1 (de) 1996-11-14
WO1991008185A1 (en) 1991-06-13

Similar Documents

Publication Publication Date Title
ES2130297T3 (es) Procedimiento para producir metacroleina y acido metacrilico.
KR840003037A (ko) 프로필렌 산화용 촉매
US3865873A (en) Process for preparing acrylic acid and or methacrylic acid from acrolein or methacrolein
Sournia Circadian periodicities in natural populations of marine phytoplankton
Bornstein et al. The anniversary reaction.
US6069271A (en) Production method of acrylic acid
MX9701682A (es) Proceso para la elaboarcion de acido acrilico.
DE3001911A1 (de) Verfahren zur herstellung von methacrolein und methacrylsaeure
ES438560A1 (es) Procedimiento mejorado para preparar acido acrilico o acido metacrilico.
ES450761A1 (es) Mejoras introducidas en el procedimiento para preparar acidoacrilico y acido metacrilico.
MX171566B (es) Metodo para la produccion de acido acrilico
FR2361450A1 (fr) Matiere de revetement durcissable
ES2148885T3 (es) Procedimiento para la produccion de acido acrilico.
DE2513405A1 (de) Verfahren zur herstellung von acrylsaeure durch oxidation von propylen mit sauerstoff enthaltenden gasen in zwei getrennten katalysatorstufen, die in einem roehrenreaktor hintereinander angeordnet sind
EP0881206B1 (de) Verfahren zur kontinuierlichen technischen Herstellung ungesättigter aliphatischer Aldehyde in einem Rohrbündelreaktor
FI875549A0 (fi) Ammoniakin hapetuskatalysaattoripakkaus ja menetelmä typpioksidin valmistamiseksi
IT1024675B (it) Perfezionamenti nella catalisi e relativi ad essa
GB1415468A (en) Preparation of aromatic nitriles
CS224605B2 (en) Method for producing methacryl acid
ES8205575A1 (es) Un procedimiento para mejorar el comportamiento catalitico de un catalizador complejo de oxido que contiene antimonio
JPS6456634A (en) Production of methacrolein and methacrylic acid from methyl tertiary butyl ether
GB1412059A (en) Process for production of acrylic acid
BE848836R (fr) Application d'un compose d'heteropolyanion contenant du tungstene combine a de l'antimoine a titre d'agent antiviral,
DE19530454A1 (de) Verfahren zur Gewinnung von Propen durch Umsetzung von Propan mit Sauerstoff an Katalysatoren
GB1423911A (en) Production of optically active alcohols

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 608917

Country of ref document: ES