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ES2059107T3 - Copolimeros solubles y reticulables a base vinilesteres, vinilaromatos y acrilatos, procedimiento para su produccion asi como su utilizacion en medios de recubrimiento. - Google Patents

Copolimeros solubles y reticulables a base vinilesteres, vinilaromatos y acrilatos, procedimiento para su produccion asi como su utilizacion en medios de recubrimiento.

Info

Publication number
ES2059107T3
ES2059107T3 ES91900247T ES91900247T ES2059107T3 ES 2059107 T3 ES2059107 T3 ES 2059107T3 ES 91900247 T ES91900247 T ES 91900247T ES 91900247 T ES91900247 T ES 91900247T ES 2059107 T3 ES2059107 T3 ES 2059107T3
Authority
ES
Spain
Prior art keywords
weight
monomers
pct
amount
vinyl aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91900247T
Other languages
English (en)
Inventor
Werner Alfons Jung
Peter Hoffmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Farben und Fasern AG
Original Assignee
BASF Lacke und Farben AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Lacke und Farben AG filed Critical BASF Lacke und Farben AG
Application granted granted Critical
Publication of ES2059107T3 publication Critical patent/ES2059107T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)

Abstract

COPOLIMERIZADOS SOLUBLES RETICULABLES A BASE DE MONOMEROS DE ESTER DE VINILO, VINILAROMATICOS Y ACRILATO, PROCEDIMIENTO PARA SU PRODUCCION ASI COMO SU UTILIZACION EN MEDIOS DE RECUBRIMIENTO. LA INVENCION CONCIERNE A COPOLIMERIZADOS CON UN CONTENIDO DE 1,25 A 30 GRUPOS FUNCIONALES DE PROMEDIO POR CADA MOLECULA Y UN PESO MOLECULAR MEDIO DE 1500 A 6000, QUE SE PUEDEN PRODUCIR MEDIANTE POLIMERIZACION DE SOLUCIONES RADICAL A 130 HASTA 200 (GRADOS) C DE 5 A 25% EN PESO DE MONOMEROS FUNCIONALES DE ESTER DE VINILO, 10 A 50% EN PESO DE MONOMEROS VINILAROMATICOS, 10 A 40% EN PESO DE MONOMEROS FUNCIONALES Y, DADO EL CASO, OTROS MONOMEROS; COLOCANDO PRIMERO EL ESTER DE VINILO Y AÑADIENDO EL RESTO DE LOS MONOMEROS DENTRO DE UN PERIODO DE TIEMPO DE ADICION DE MONOMEROS DE IGUAL DURACION PARA TODOS ELLOS DE LA SIGUIENTE MANERA: LA CANTIDAD AÑADIDA POR UNIDAD DE TIEMPO DE LOS MONOMEROS DE ACRILATO PERMANECE CONSTANTE; LA CANTIDAD AÑADIDA DENTRO DEL PRIMER TERCIO DEL PERIODO DE ADICION DE MONOMEROS VINILAROMATICOS ES DEL 15 AL 30% EN PESO, DENTRO DEL SEGUNDO TERCIO DEL 25 A 40% EN PESO Y DENTRO DEL TERCER TERCIO DEL 35 AL 60% EN PESO, RESPECTIVAMENTE REFERIDOS A LA CANTIDAD TOTAL DE VINILAROMATICOS. EL COPOLIMERIZADO OBTENIDO SE REDUCE, DADO EL CASO, CON COMPUESTOS QUE CONTIENEN GRUPOS REACTIVOS FRENTE A LOS GRUPOS FUNCIONALES DEL COPOLIMERIZADO Y AL MENOS UN GRUPO RETICULABLE.
ES91900247T 1989-12-22 1990-12-07 Copolimeros solubles y reticulables a base vinilesteres, vinilaromatos y acrilatos, procedimiento para su produccion asi como su utilizacion en medios de recubrimiento. Expired - Lifetime ES2059107T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3942592A DE3942592A1 (de) 1989-12-22 1989-12-22 Loesliche vernetzbare copolymerisate auf der basis von vinylester-, vinyaromat- und acrylatmonomeren, verfahren zu ihrer herstellung sowie ihre verwendung in beschichtungsmitteln

Publications (1)

Publication Number Publication Date
ES2059107T3 true ES2059107T3 (es) 1994-11-01

Family

ID=6396216

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91900247T Expired - Lifetime ES2059107T3 (es) 1989-12-22 1990-12-07 Copolimeros solubles y reticulables a base vinilesteres, vinilaromatos y acrilatos, procedimiento para su produccion asi como su utilizacion en medios de recubrimiento.

Country Status (9)

Country Link
US (1) US5763546A (es)
EP (1) EP0506703B1 (es)
JP (1) JP2620446B2 (es)
AT (1) ATE106411T1 (es)
CA (1) CA2075903C (es)
DE (2) DE3942592A1 (es)
DK (1) DK0506703T3 (es)
ES (1) ES2059107T3 (es)
WO (1) WO1991009888A1 (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4337482A1 (de) * 1993-11-03 1995-05-04 Basf Ag Verfahren zur Herstellung von radikalisch vernetzbaren Copolymerisaten
DE4337481A1 (de) * 1993-11-03 1995-05-04 Basf Ag Radikalisch vernetzbare Copolymerisate
FR2748484B1 (fr) * 1996-05-13 1998-07-24 Atochem Elf Sa Polymerisation en presence d'un radical libre stable et d'un initiateur de radicaux libres
US5891950A (en) * 1996-05-28 1999-04-06 Eastman Chemical Company Use of stable amino-functional latexes in water-based inks
US6028155A (en) * 1997-05-21 2000-02-22 Eastman Chemical Company Surfactant-containing acetoacetoxy-functional and enamine-functional polymers
US5998543A (en) * 1996-05-28 1999-12-07 Eastman Chemical Company Stable amino-containing polymer latex blends
US6417267B1 (en) 1996-05-28 2002-07-09 Eastman Chemical Company Adhesive compositions containing stable amino-containing polymer latex blends
JP3727663B2 (ja) 1996-05-28 2005-12-14 イーストマン ケミカル カンパニー 界面活性剤含有アセトアセトキシ官能及びエナミン官能ポリマー
US5962556A (en) * 1996-10-22 1999-10-05 Eastman Chemical Company Functional latexes resistant to hydrolysis
EP0983306B1 (en) * 1997-05-21 2002-08-28 Eastman Chemical Company Process for preparing reactive latex blends which are chemically and physically stable until film formation
US6649679B1 (en) 1997-09-18 2003-11-18 Eastman Chemical Company Stable waterborne polymer compositions containing poly(alkylenimines)
US6228971B1 (en) * 1999-06-21 2001-05-08 Ppg Industries Ohio, Inc. Polymeric imine functional compositions and their use in film-forming compositions
US7230048B1 (en) * 2000-08-25 2007-06-12 Basf Corporation Process for continuous production of reactive polymers with in-line post-modification and products thereof
US8013068B2 (en) * 2003-01-02 2011-09-06 Rohm And Haas Company Michael addition compositions
JP4352788B2 (ja) * 2003-07-10 2009-10-28 富士ゼロックス株式会社 水酸基含有ポリマー粒子の製造方法
EP1640388B1 (en) * 2004-09-24 2015-02-25 Rohm and Haas Company Biomass based Michael addition composition
US20060079624A1 (en) * 2004-10-08 2006-04-13 Hildeberto Nava Crosslinkable polymer systems
US8349410B2 (en) * 2006-08-17 2013-01-08 University of Pittsburgh—of the Commonwealth System of Higher Education Modification of surfaces with polymers
US20090074709A1 (en) * 2007-09-14 2009-03-19 Koepsel Richard R Methods, devices and systems for biocidal surface activity
DE102007047837A1 (de) 2007-11-21 2009-05-28 Wacker Chemie Ag Herstellung von Lösungen von Vinylpolymeren in reaktiven Monomeren
DE102007055694A1 (de) 2007-12-03 2009-06-04 Wacker Chemie Ag Vernetzbare Vinylester-Copolymerisate und deren Verwendung als Low-Profile-Additive
KR101586763B1 (ko) * 2007-12-31 2016-01-20 바스프 코팅스 게엠베하 경화성 알콕시카르보닐아미노 조성물, 코팅, 및 방법
DE102008054482A1 (de) 2008-12-10 2010-06-17 Wacker Chemie Ag Pfropfcopolymere und deren Verwendung als Low-Profile-Additive
US8815971B2 (en) 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8173750B2 (en) 2009-04-23 2012-05-08 ATRP Solutions, Inc. Star macromolecules for personal and home care
WO2010123575A1 (en) 2009-04-23 2010-10-28 Atrp Solutions Inc Well defined stars with segmented arms
US8816001B2 (en) 2010-09-10 2014-08-26 Franklin And Marshall College Genetically encoded initiator for polymer growth from proteins
WO2012091965A1 (en) 2010-12-17 2012-07-05 Carnegie Mellon University Electrochemically mediated atom transfer radical polymerization
EP2747753B1 (en) 2011-08-22 2023-03-29 Carnegie Mellon University Atom transfer radical polymerization under biologically compatible conditions
US9790305B2 (en) 2011-09-09 2017-10-17 Franklin And Marshall College Site specifically incorporated initiator for growth of polymers from proteins
WO2013126745A2 (en) 2012-02-23 2013-08-29 Carnegie Mellon University Ligands designed to provide highly active catalyst complexes
US8975346B2 (en) 2012-05-18 2015-03-10 Sabic Global Technologies B.V. Polycarbonate copolymers via controlled radical polymerization
WO2014116672A1 (en) 2013-01-22 2014-07-31 Carnegie Mellon University Lignin-containing polymers and compositions including lignin-containing polymers
US9982070B2 (en) 2015-01-12 2018-05-29 Carnegie Mellon University Aqueous ATRP in the presence of an activator regenerator
US10934383B2 (en) 2016-01-25 2021-03-02 Carnegie Mellon University Composite compositions and modification of inorganic particles for use in composite compositions
US10982266B2 (en) 2016-11-03 2021-04-20 Carnegie Mellon University Nucleic acid-polymer conjugates for bright fluorescent tags
WO2018132696A2 (en) 2017-01-12 2018-07-19 Russell Alan J Stomach acid-stable and mucin-binding protein-polymer conjugates
WO2018132582A1 (en) 2017-01-12 2018-07-19 Carnegie Mellon University Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes
US11472894B2 (en) 2018-07-23 2022-10-18 Carnegie Mellon University Enzyme-assisted ATRP procedures
US12053529B2 (en) 2018-08-01 2024-08-06 Carnegie Mellon University Amino-reactive positively charged ATRP initiators that maintain their positive charge during synthesis of biomacro-initiators
CN114514256A (zh) 2019-10-16 2022-05-17 巴斯夫涂料有限公司 超高端受控自由基聚合
CN115819645B (zh) * 2022-09-09 2024-07-23 浙江国能科技有限公司 一种多反应性紫外光固化导电胶树脂基体的制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3492369A (en) * 1965-05-24 1970-01-27 Phillips Petroleum Co Graft polymerizing by first lithiating in the presence of polar compounds
US3546323A (en) * 1967-11-07 1970-12-08 Stauffer Chemical Co Graft polymers of vinyl halide monomers and mercapto-functional diene polymers
GB1249390A (en) * 1969-07-03 1971-10-13 Shell Int Research Copolymers of vinylesters
US4512775A (en) * 1983-10-03 1985-04-23 Ethyl Corporation Cold flow improver
FR2589866B1 (fr) * 1985-11-07 1988-07-15 Inst Francais Du Petrole Compositions de copolymeres, utilisables comme additifs pour huiles lubrifiantes
DE3710431A1 (de) * 1987-03-28 1988-10-06 Basf Lacke & Farben Haertbare zusammensetzung auf basis eines michael-additionsproduktes, verfahren zu seiner herstellung sowie seine verwendung
DE3823005A1 (de) * 1988-07-07 1990-01-11 Basf Lacke & Farben Hydroxylgruppenhaltie copolymerisate auf der basis von vinylester-,vinylaromat- und hydroxylalkylester-monomeren, verfahren zur ihrer herstellung sowie ihre verwendung in beschichtungsmitteln
DE3827587A1 (de) * 1988-08-13 1990-03-01 Basf Lacke & Farben Aminogruppenhaltige copolymerisate, verfahren zu ihrer herstellung sowie ihre verwendung in beschichtungsmitteln

Also Published As

Publication number Publication date
US5763546A (en) 1998-06-09
DK0506703T3 (da) 1994-09-26
ATE106411T1 (de) 1994-06-15
DE59005968D1 (de) 1994-07-07
WO1991009888A1 (de) 1991-07-11
JPH04506373A (ja) 1992-11-05
CA2075903C (en) 1997-09-02
EP0506703A1 (de) 1992-10-07
JP2620446B2 (ja) 1997-06-11
DE3942592A1 (de) 1991-06-27
CA2075903A1 (en) 1991-06-23
EP0506703B1 (de) 1994-06-01

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