ES2046461T3 - Procedimiento para la polimerizacion de propileno. - Google Patents
Procedimiento para la polimerizacion de propileno.Info
- Publication number
- ES2046461T3 ES2046461T3 ES198989301132T ES89301132T ES2046461T3 ES 2046461 T3 ES2046461 T3 ES 2046461T3 ES 198989301132 T ES198989301132 T ES 198989301132T ES 89301132 T ES89301132 T ES 89301132T ES 2046461 T3 ES2046461 T3 ES 2046461T3
- Authority
- ES
- Spain
- Prior art keywords
- propylene
- ethylene
- halide
- mol
- absence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/906—Comminution of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
UN PROCESO DE ELEVADA EFICACIA PARA LA PRODUCCION DE COPOLIMEROS SUSTANCIALMENTE AMORFOS DE ETILENO - PROPILENO QUE SON UTILES COMO ADHESIVOS DE APLICACION POR FUSION, COMO COMPONENTES DE MEZCLA EN MATERIALES PARA TEJADOS Y COMO AGENTES LUBRICANTES PARA CABLES. EL PROCESO IMPLICA HACER REACCIONAR DESDE 70 A 96.5% EN PESO DE PROPILENO Y DESDE 3.5 A 30% EN PESO DE ETILENO A UNA TEMPERATURA ENTRE 55 Y 80 (GRADOS) C Y A UNA PRESION EN EL REACTOR SUFICIENTE PARA MANTENER EL PROPILENO EN FASE LIQUIDA, EN PRESENCIA DE ENTRE 0.7 Y 3.0 MOLES % DE H SOBRE LA BASE DE LA ALIMENTACION DE MONOMERO Y EMPLEANDO UN CATALIZADOR CUYA COMPOSICION Y PROCESO DE PREPARACION SE DAN DETALLADAMENTE Y QUE CONTIENE HALURO DE MG, TRIHALURO DE AL Y TETRAHALURO DE TI. SE OBTIENE UN COPOLIMERO DE ETILENO - PROPILENO ESTADISTICO SUSTANCIALMENTE AMORFO CON UN INDICE DE TACTICIDAD M/R EN LA GAMA DE 2.5 A 4 CUANDO SE DETERMINA MEDIANTE ESPECTRO RMN CON C13.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/156,047 US4847340A (en) | 1986-06-30 | 1988-02-16 | Novel propylene polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2046461T3 true ES2046461T3 (es) | 1994-02-01 |
Family
ID=22557850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198989301132T Expired - Lifetime ES2046461T3 (es) | 1988-02-16 | 1989-02-06 | Procedimiento para la polimerizacion de propileno. |
Country Status (10)
Country | Link |
---|---|
US (1) | US4847340A (es) |
EP (1) | EP0329319B1 (es) |
JP (1) | JP2703571B2 (es) |
KR (1) | KR0134777B1 (es) |
CN (1) | CN1035301A (es) |
AT (1) | ATE94567T1 (es) |
AU (1) | AU620333B2 (es) |
CA (1) | CA1309799C (es) |
DE (1) | DE68909066T2 (es) |
ES (1) | ES2046461T3 (es) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2647454B1 (fr) * | 1989-05-29 | 1993-01-22 | Solvay | Suspensions de particules contenant des composes de metaux de transition dans des huiles et procedes de polymerisation d'alpha-olefines effectues en presence de ces suspensions |
AU643315B2 (en) * | 1990-09-07 | 1993-11-11 | Huntsman Polymers Corporation | Amorphous elastomeric propylene homopolymers |
CA2049373A1 (en) * | 1990-09-07 | 1992-03-08 | Brian J. Pellon | Process for the production of amorphous elastomeric propylene homopolymers |
US5302380A (en) * | 1992-06-08 | 1994-04-12 | Revlon Consumer Products Corporation | Cosmetic compositions containing atactic polypropylenes and related methods |
US5302675A (en) * | 1992-09-08 | 1994-04-12 | Rexene Corporation | High tensile strength amorphous 1-butene/propylene copolymers |
US5681913A (en) * | 1992-09-08 | 1997-10-28 | Rexene Corporation | High tensile strength amorphous 1-butene/propylene and ethylene/propylene copolymers |
US6586536B1 (en) * | 1993-06-18 | 2003-07-01 | Joseph M. Kelley | High temperature process for the production of atactic, amorphous, tacky propylene homopolymers or copolymers |
IT1275857B1 (it) * | 1995-03-03 | 1997-10-24 | Spherilene Srl | Copolimeri atattici del propilene con l'etilene |
US6586543B1 (en) * | 1999-09-01 | 2003-07-01 | Degussa Ag | Process for the preparation of substantially amorphous poly-α-olefins |
CA2508216A1 (en) * | 2005-04-14 | 2006-10-14 | Sercel, Inc. | Solid flooding compound for marine seismic cable |
EP3936164A1 (en) * | 2013-05-29 | 2022-01-12 | H.B. Fuller Company | Elastic attachment adhesive composition |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US9593179B2 (en) | 2014-02-07 | 2017-03-14 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
WO2016176821A1 (en) | 2015-05-05 | 2016-11-10 | Dow Global Technologies Llc | Functionalized, halogenated olefin-based adhesive, articles containing and process for using thereof |
US10752815B2 (en) | 2016-04-12 | 2020-08-25 | Rextac Llc | Low molecular weight butene-1-co-hexene-1 amorphous poly alpha olefins for hot-melt adhesives with enhanced properties |
US20170292047A1 (en) | 2016-04-12 | 2017-10-12 | Rextac Llc | Hexene-1 Containing Amorphous Polyalphaolefins For Improved Hot Melt Adhesives |
EP3493780A1 (en) | 2016-08-03 | 2019-06-12 | H.B. Fuller Company | An elastic attachment hot melt adhesive composition and a disposable absorbent article made with the same |
KR102352173B1 (ko) * | 2020-02-13 | 2022-01-19 | 대한유화(주) | 내구성과 저온유연성이 동시에 우수한 비결정성 폴리프로필렌 공중합체 및 이의 제조방법 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL163523C (nl) * | 1970-07-31 | 1983-11-16 | Montedison Spa | Werkwijze om een polymerisatiekatalysator te bereiden. |
NL7113778A (es) * | 1970-10-13 | 1972-04-17 | ||
US4234710A (en) * | 1976-07-08 | 1980-11-18 | Phillips Petroleum Company | Catalyst and a polymerization process employing the catalyst |
US4175171A (en) * | 1976-08-02 | 1979-11-20 | Mitsui Toatsu Chemicals, Inc. | Catalyst for polymerizing α-olefins |
JPS6042805B2 (ja) * | 1979-02-27 | 1985-09-25 | 日石三菱株式会社 | 共重合体の製法 |
JPS62157960A (ja) * | 1985-12-28 | 1987-07-13 | Casio Comput Co Ltd | 小型電子式計算機 |
ES2022355B3 (es) * | 1986-06-30 | 1991-12-01 | Rexene Products Company (A Delaware Corporation) | Polimeros de propileno y su preparacion. |
US4736002A (en) | 1986-06-30 | 1988-04-05 | El Paso Products Company | Novel propylene polymerization process |
CA1282546C (en) * | 1986-06-30 | 1991-04-02 | Brian Jay Pellon | Propylene polymers |
-
1988
- 1988-02-16 US US07/156,047 patent/US4847340A/en not_active Expired - Lifetime
- 1988-07-04 AU AU18666/88A patent/AU620333B2/en not_active Ceased
- 1988-07-07 CA CA000571364A patent/CA1309799C/en not_active Expired - Lifetime
- 1988-09-21 JP JP63235109A patent/JP2703571B2/ja not_active Expired - Lifetime
- 1988-10-11 CN CN88109162A patent/CN1035301A/zh active Pending
-
1989
- 1989-02-04 KR KR1019890001354A patent/KR0134777B1/ko not_active IP Right Cessation
- 1989-02-06 ES ES198989301132T patent/ES2046461T3/es not_active Expired - Lifetime
- 1989-02-06 DE DE89301132T patent/DE68909066T2/de not_active Expired - Lifetime
- 1989-02-06 EP EP89301132A patent/EP0329319B1/en not_active Expired - Lifetime
- 1989-02-06 AT AT89301132T patent/ATE94567T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE68909066T2 (de) | 1994-05-05 |
AU620333B2 (en) | 1992-02-20 |
KR890013065A (ko) | 1989-09-21 |
JPH01210407A (ja) | 1989-08-24 |
EP0329319A1 (en) | 1989-08-23 |
EP0329319B1 (en) | 1993-09-15 |
ATE94567T1 (de) | 1993-10-15 |
JP2703571B2 (ja) | 1998-01-26 |
CA1309799C (en) | 1992-11-03 |
KR0134777B1 (ko) | 1998-04-20 |
AU1866688A (en) | 1989-09-21 |
US4847340A (en) | 1989-07-11 |
DE68909066D1 (de) | 1993-10-21 |
CN1035301A (zh) | 1989-09-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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