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EP2734610B1 - Flüssigwaschmittelzusammensetzung - Google Patents

Flüssigwaschmittelzusammensetzung Download PDF

Info

Publication number
EP2734610B1
EP2734610B1 EP12735572.5A EP12735572A EP2734610B1 EP 2734610 B1 EP2734610 B1 EP 2734610B1 EP 12735572 A EP12735572 A EP 12735572A EP 2734610 B1 EP2734610 B1 EP 2734610B1
Authority
EP
European Patent Office
Prior art keywords
liquid laundry
dyes
composition according
laundry composition
sulphonated aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP12735572.5A
Other languages
English (en)
French (fr)
Other versions
EP2734610A1 (de
Inventor
Stephen Norman Batchelor
Jayne Michelle Bird
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to EP12735572.5A priority Critical patent/EP2734610B1/de
Publication of EP2734610A1 publication Critical patent/EP2734610A1/de
Application granted granted Critical
Publication of EP2734610B1 publication Critical patent/EP2734610B1/de
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents

Definitions

  • top notes are defined by Poucher (Journal of the Society of Cosmetic Chemists 6(2):80 [1955 ]).
  • Preferred top-notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
  • Suitable lipases include those of bacterial or fungal origin. Chemically modified or protein engineered mutants are included. Examples of useful lipases include lipases from Humicola (synonym Thermomyces), e.g. from H. lanuginosa (T. lanuginosus) as described in EP 258 068 and EP 305 216 or from H. insolens as described in WO 96/13580 , a Pseudomonas lipase, e.g. from P. alcaligenes or P. pseudoalcaligenes ( EP 218 272 ), P. cepacia ( EP 331 376 ), P. stutzeri ( GB 1,372,034 ), P.
  • the enzyme and the shading dye may show some interaction and should be chosen such that this interaction is not negative. Some negative interactions may be avoided by encapsulation of one or other of enzyme or shading dye and/or other segregation within the product.
  • Any enzyme present in the composition may be stabilized using conventional stabilizing agents, e.g., a polyol such as propylene glycol or glycerol, a sugar or sugar alcohol, lactic acid, boric acid, or a boric acid derivative, e.g., an aromatic borate ester, or a phenyl boronic acid derivative such as 4-formylphenyl boronic acid, and the composition may be formulated as described in e.g. WO 92/19709 and WO 92/19708 .
  • a polyol such as propylene glycol or glycerol
  • a sugar or sugar alcohol lactic acid, boric acid, or a boric acid derivative, e.g., an aromatic borate ester, or a phenyl boronic acid derivative such as 4-formylphenyl boronic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Coloring (AREA)

Claims (13)

  1. Flüssigwaschmittelzusammensetzung, umfassend:
    (a) 0,0001 bis 0,01 Gew.-% eines blauen oder violetten Abtönungsfarbstoffes;
    (b) 1 bis 70 Gew.-% eines Tensids, wobei es sich beim Tensid um ein Gemisch aus anionischen mit nicht-ionischen waschaktiven Materialien handelt;
    (c) 0,1 bis 30 Gew.-% eines sulfonierten aromatischen Formaldehyd-Polykondensats; und
    (d) wobei es sich beim Rest der Zusammensetzung um Verdünnungsmittel und Zusatzstoffe ad 100 Gew.-% handelt.
  2. Flüssigwaschmittelzusammensetzung nach Anspruch 1, wobei es sich beim sulfonierten aromatischen Formaldehyd-Polykondensat um ein Naphthalinsulfonsäure-Formaldehyd-Polykondensat handelt.
  3. Flüssigwaschmittelzusammensetzung nach Anspruch 1 oder 2, wobei es sich beim sulfonierten aromatischen Formaldehyd-Polykondensat um ein ethoxyliertes sulfoniertes aromatisches Formaldehyd-Polykondensat handelt.
  4. Flüssigwaschmittelzusammensetzung nach einem der vorstehenden Ansprüche, wobei das sulfonierte aromatische Formaldehyd-Polykondensat durch eine oder mehrere Sulfonsäuregruppen substituiert ist.
  5. Flüssigwaschmittelzusammensetzung nach einem der vorstehenden Ansprüche, wobei das sulfonierte aromatische Formaldehyd-Polykondensat durch eine oder mehrere Sulfomethylgruppen substituiert ist.
  6. Flüssigwaschmittelzusammensetzung nach einem der vorstehenden Ansprüche 1, 3, 4 und 5, wobei das sulfonierte aromatische Formaldehyd-Polykondensat durch Kondensation einer Diphenylethersulfonsäure mit Formaldehyd erhältlich ist.
  7. Flüssigwaschmittelzusammensetzung nach einem der vorstehenden Ansprüche 1 bis 5, wobei das sulfonierte aromatische Formaldehyd-Polykondensat durch Kondensation von Toluolsulfonsäuren mit Formaldehyd erhältlich ist.
  8. Flüssigwaschmittelzusammensetzung nach Anspruch 4, wobei das sulfonierte aromatische Formaldehyd-Polykondensat durch Kondensation von Isopropylbenzolsulfonsäuren mit Formaldehyd erhältlich ist.
  9. Flüssigwaschmittelzusammensetzung nach Anspruch 4, wobei es sich beim sulfonierten aromatischen Formaldehyd-Polykondensat um das Kondensationsprodukt von Cresolsulfonsäuren mit Formaldehyd handelt.
  10. Flüssigwaschmittelzusammensetzung nach einem der Ansprüche 6 bis 9, wobei die Mindestkonzentration von restlichem Formaldehyd aus der Polykondensation 200 ppm beträgt.
  11. Flüssigwaschmittelzusammensetzung nach einem der vorstehenden Ansprüche, wobei die Abtönungsfarbstoffe ausgewählt sind aus Direktfarbstoffen, Säurefarbstoffen, hydrophoben Farbstoffen, kationischen Farbstoffen und reaktiven Farbstoffen.
  12. Flüssigwaschmittelzusammensetzung nach Anspruch 11, wobei das Abtönungsfarbstoff-Chromophor ausgewählt ist aus Monoazo-, Bisazo-, Triphenylmethan-, Triphenodioxazin-, Phthalocyanin-, Naphtholactam-, Azin- und Antrachinon-Chromophoren.
  13. Verfahren zum Behandeln eines Textilerzeugnisses zur Besserung der Vergrauung von Nylon-elastan, wobei das Textilerzeugnis Elastan umfasst, wobei das Verfahren die folgenden Stufen umfasst:
    (i) Aufbringen der Flüssigwaschmittelzusammensetzung auf ein Textilerzeugnis, wobei die Flüssigwaschmittelzusammensetzung der Definition in einem der Ansprüche 1 bis 12 entspricht;
    (ii) Spülen des Textilerzeugnisses mit Wasser; und
    (iii) gegebenenfalls Trocknen des Textilerzeugnisses.
EP12735572.5A 2011-07-21 2012-07-18 Flüssigwaschmittelzusammensetzung Not-in-force EP2734610B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12735572.5A EP2734610B1 (de) 2011-07-21 2012-07-18 Flüssigwaschmittelzusammensetzung

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11174801 2011-07-21
PCT/EP2012/064120 WO2013011071A1 (en) 2011-07-21 2012-07-18 Liquid laundry composition
EP12735572.5A EP2734610B1 (de) 2011-07-21 2012-07-18 Flüssigwaschmittelzusammensetzung

Publications (2)

Publication Number Publication Date
EP2734610A1 EP2734610A1 (de) 2014-05-28
EP2734610B1 true EP2734610B1 (de) 2015-09-09

Family

ID=46514401

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12735572.5A Not-in-force EP2734610B1 (de) 2011-07-21 2012-07-18 Flüssigwaschmittelzusammensetzung

Country Status (8)

Country Link
EP (1) EP2734610B1 (de)
CN (1) CN103857781A (de)
AR (1) AR087267A1 (de)
BR (1) BR112014001378A2 (de)
ES (1) ES2550051T3 (de)
MX (1) MX337154B (de)
WO (1) WO2013011071A1 (de)
ZA (1) ZA201400467B (de)

Families Citing this family (9)

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DE102013021276A1 (de) * 2013-12-17 2015-06-18 Clariant International Ltd. Farbschützende Waschmittel
DE102013226152A1 (de) * 2013-12-17 2015-06-18 Henkel Ag & Co. Kgaa Vergrauungsinhibierende Waschmittel
DE102013226151A1 (de) * 2013-12-17 2015-06-18 Henkel Ag & Co. Kgaa Vergrauungsinhibierende Waschmittel
CN106715664B (zh) * 2014-09-18 2019-09-17 荷兰联合利华有限公司 液体增白组合物
BR112017005495B1 (pt) * 2014-09-18 2021-11-30 Unilever Ip Holdings B.V. Composição de detergente para lavagem de roupas e método doméstico de tratamento de um tecido
WO2016041679A1 (en) * 2014-09-18 2016-03-24 Unilever Plc Whitening composition
EP3194547A1 (de) * 2014-09-18 2017-07-26 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Bleichungszusammensetzung
BR112017004978B1 (pt) * 2014-09-18 2022-05-03 Unilever Ip Holdings B.V. Composição de detergente para lavagem de roupas e método doméstico de tratamento de um tecido
CN113166688B (zh) * 2018-12-13 2024-12-13 陶氏环球技术有限责任公司 液体衣物洗涤剂配制物

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Also Published As

Publication number Publication date
BR112014001378A2 (pt) 2017-03-01
EP2734610A1 (de) 2014-05-28
WO2013011071A1 (en) 2013-01-24
ZA201400467B (en) 2015-09-30
CN103857781A (zh) 2014-06-11
AR087267A1 (es) 2014-03-12
ES2550051T3 (es) 2015-11-04
MX337154B (es) 2016-02-15
MX2014000846A (es) 2014-10-24

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