[go: up one dir, main page]

EP2674475A1 - Composition détergente - Google Patents

Composition détergente Download PDF

Info

Publication number
EP2674475A1
EP2674475A1 EP12171551.0A EP12171551A EP2674475A1 EP 2674475 A1 EP2674475 A1 EP 2674475A1 EP 12171551 A EP12171551 A EP 12171551A EP 2674475 A1 EP2674475 A1 EP 2674475A1
Authority
EP
European Patent Office
Prior art keywords
mixtures
group
acid
enzyme
detergent composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12171551.0A
Other languages
German (de)
English (en)
Inventor
Steven George Patterson
Philip Frank Souter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=48570026&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2674475(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP12171551.0A priority Critical patent/EP2674475A1/fr
Priority to MX2014015172A priority patent/MX370587B/es
Priority to TR2018/09430T priority patent/TR201809430T4/tr
Priority to PCT/US2013/045070 priority patent/WO2013188331A1/fr
Priority to CN201380030796.9A priority patent/CN104364364A/zh
Priority to DK13171413.1T priority patent/DK2674476T4/da
Priority to HUE13171413A priority patent/HUE038095T2/hu
Priority to ES13171413T priority patent/ES2674940T5/es
Priority to JP2015516278A priority patent/JP2015528828A/ja
Priority to PL13171413T priority patent/PL2674476T5/pl
Priority to EP13171413.1A priority patent/EP2674476B2/fr
Priority to CN202010099823.XA priority patent/CN111205939A/zh
Priority to BR112014030417-3A priority patent/BR112014030417B1/pt
Priority to RU2014149582A priority patent/RU2612142C2/ru
Priority to IN10427DEN2014 priority patent/IN2014DN10427A/en
Publication of EP2674475A1 publication Critical patent/EP2674475A1/fr
Priority to ZA2014/08580A priority patent/ZA201408580B/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/046—Salts
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38672—Granulated or coated enzymes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents

Definitions

  • This invention relates to detergent compositions comprising more than one enzyme as well as methods of making and using such detergents.
  • IPCOM000200739D it is disclosed that uniform enzyme granule distribution can be improved by incorporating two or more enzymes combined in one co-granule.
  • Each enzyme will then be present in more granules securing a more uniform distribution of enzymes in the detergent. This also reduces the physical segregation of different enzymes due to different particle sizes.
  • interaction between enzymes in an enzyme cogranule can lead to loss of enzyme activity, in particular when one of the enzymes is protease. This problem is particularly acute in detergent compositions comprising low levels of typical strong builders i.e. zeolite and phosphate builders.
  • the present invention relates to a detergent composition
  • a detergent composition comprising (a) a multi-enzyme co-granule; (b) less than 10 wt% zeolite (anhydrous basis); and (c) less than 10 wt% phosphate salt (anhydrous basis), wherein said enzyme co-granule comprises from 10 to 98 wt% moisture sink component.
  • the invention also relates to a method of treating and/or cleaning a surface, preferably a fabric surface comprising the steps of (i) contacting said surface with the detergent composition as claimed and described herein in an aqueous wash liquor, (ii) rinsing and/or drying the surface.
  • aqueous wash liquor Preferably the temperature of the aqueous liquor is from 5 - 25°C and preferably the aqueous liquor comprises from 0.1g/l to 3g/l of surfactant.
  • detergent composition means consumer and institutional products, including but not limited to cleaning and/or treatment compositions, particularly cleaning compositions for laundry, dishwashing, and hard surface cleaning products, other cleaners, and cleaning systems all for the care and cleaning of inanimate surfaces, as well as fabric conditioner products and other products designed specifically for the care and maintenance of fabrics.
  • cleaning and/or treatment composition are generally intended to be used or consumed in the form in which they are sold.
  • Such products include laundry and rinse additive and/or care, hard surface cleaning and/or treatment including floor and toilet bowl cleaners.
  • the compositions of the invention are laundry or dish-washing detergents, most preferably laundry detergents.
  • the compositions of the invention are solid i.e.
  • a unit-dose detergent composition such as a tablet or pouch which may be single or multi-compartment. However, they may be liquid, gel or paste-form.
  • a pouch the composition of the invention will be present within a water-soluble film.
  • the pouch is multi-compartment, the composition of the invention will be present in one or more compartments. Further compositions, not in accordance with the invention may be provided in one or more further compartments of the multi-component pouch. All of such products which are applicable may be in standard, concentrated or even highly concentrated form even to the extent that such products may in certain aspect be non-aqueous.
  • the multi-enzyme co-granule comprises at least two enzymes, or at least three or four or more enzymes, preferably selected from the group consisting of first-wash lipases, cleaning cellulases, xyloglucanases, perhydrolases, peroxidases, lipoxygenases, laccases, hemicellulases, proteases, care cellulases, cellobiose dehydrogenases, xylanases, phospholipases, esterases, cutinases, pectinases, mannanases, pectate lyases, keratinases, reductases, oxidases, phenoloxidases, ligninases, pullulanases, tannases, pentosanases, lichenases glucanases, arabinosidases, hyaluronidase, chondroitinase, amylases, and mixtures thereof.
  • the co-granule comprises (a) one or more enzymes selected from the group consisting of first-wash lipases, cleaning cellulases, xyloglucanases, perhydrolases, peroxidases, lipoxygenases, laccases and mixtures thereof.
  • Preferred enzymes from group (a) are first wash lipases.
  • the co-granule preferably comprises (b) one or more enzymes selected from the group consisting of hemicellulases, proteases, care cellulases, cellobiose dehydrogenases, xylanases, phospholipases, esterases, cutinases, pectinases, mannanases, pectate lyases, keratinases, reductases, oxidases, phenoloxidases, ligninases, pullulanases, tannases, pentosanases, lichenases glucanases, arabinosidases, hyaluronidase, chondroitinase, amylases, and mixtures thereof.
  • the co-granule comprises a protease enzyme.
  • the co-granule may comprise for example at least two enzymes, for example including: (i) protease and amylase; (ii) portease and cellulase; (iii) protease and first wash lipase; (iv) cellulase an first wash lipase; (v) amylase and cellulase; or (vi) amylase and first wash lipase.
  • enzymes for example including: (i) protease and amylase; (ii) portease and cellulase; (iii) protease and first wash lipase; (iv) cellulase an first wash lipase; (v) amylase and cellulase; or (vi) amylase and first wash lipase.
  • the co-granule may comprise at least three enzymes, for example including (i) protease, first wash lipase and cellulase; (ii) protease, amylase and cellulase; (iii) protease, amylase and first wash lipase; (iv) first wash lipase, amylase and cellulase.
  • the co-granule may comprise at least four enzymes, for example including (i) protease, amylase, first wash lipase and cellulase; (ii) protease, amylase, first wash lipase and mannanase.
  • the amount of total active enzyme protein incorporated into the co-granule is typically delivers from 0.2 to 1.0wt% active enzyme in the detergent composition.
  • the moisture sink component is present in the co-granule in amounts of from 10 to 99 wt% of the co-granule.
  • the moisture sink material is herein understood a material that in its anhydrous form can take water to become hydrated and it can easily give up the hydration water when it is placed in a drier or warmer environment.
  • the moisture sink materials for use in the composition of the invention have a difference in density between the anhydrous and hydrated form of at least 0.8 g/cm3, more preferably at least 1 g/cm3 and especially at least 1.2 g/cm3.
  • This difference in densities provides a mechanism to break particle:particle crystal bridges that have formed as a result of water condensing as the powder temperature fell below the dew point associated with that powder.
  • the hydrated material forming a crystal bridge between particles reverts to the anhydrous (or less hydrated) form.
  • the higher crystal density associated with the anhydrous (or less hydrated) form provides a mechanism for breaking these crystal bridges due to the reduction in crystal volume. This allows that a period of low temperature does not negatively and permanently affect the structure of the powder and contributes to good handling properties of the composition.
  • the moisture sink component is present in amounts from 30, 50 or even 60 wt% of the co-granule, up to 90 or 95 wt% based on the co-granule.
  • suitable moisture sink components are capable of absorbing moisture.
  • Suitable moisture sink components are preferably selected from the group consisting of (a) hydratable salts, (b) dessicated clays, (c) bio-filler, and (d) mixtures thereof.
  • Useful as hydratable salts are typically sodium, calcium, magnesium salts, preferably sodium salts of carbonate, chloride, citrate and sulphate and mixtures thereof.
  • Anhydrous sodium carbonate may be preferred.
  • Light sodium carbonate may be preferred.
  • suitable clays are talc, calcite, kaolin, dolomite and bentonite.
  • Preferred dessicated clays have a moisture content of from 0.1 to 20 wt% free moisture, more preferably from 0.1 to 15 or even 0.1 to 10 or even 5 wt% free moisture;
  • Suitable as bio-filler is any water soluble or water insoluble agricultural by-product. Examples of water-insoluble agricultural by-products are described in WO2007/147698 .
  • Preferred bio-fillers have a moisture content of from 0.1 to 20 wt% free moisture, more preferably from 0.1 to 15 or even 0.1 to 10 wt% or even 5 wt% free moisture;
  • the particle size of the moisture sink component is preferably such that at least 90 wt% of the particles of moisture sink component have a diameter less than 700 or even less than 500 or 300 or 250 microns or even less than 100 microns.
  • the weight ratio of moisture sink component to active enzyme protein in the co-granule is preferably from 10: 1 or 20:1 or 50:1 or 10:1 up to 100:1 or 90:1 or 75:1.
  • Suitable enzyme co-granules for use herein include those formed according to any of the below technologies:
  • Preferred enzyme co-granules for use in the composition of the invention, have a core-shell structure.
  • the core comprises a central part, preferably free of enzymes, and a surrounding layer containing enzymes and the shell comprises a plurality of layers, the most outer layer being a protective layer.
  • the central part of the core and at least one of the layers of the shell comprise an moisture sink material.
  • the central part of the core represents from 1% to 60%, more preferably from 3% to 50% and especially from 5% to 40% by weight of the total particle.
  • the layer comprising the moisture sink material represents from 0.5% to 40%, more preferably from 1% to 30% and especially from 3% to 20% by weight of the total particle.
  • the most outer layer comprises polyvinyl alcohol, more preferably titanium oxide (for aesthetic reasons) and especially a combination thereof.
  • the protective layer represents from 0.05% to 20%, more preferably from 0.1 % to 15% and especially from 1% to 3% by weight of the total particle.
  • the enzyme granulate can also contain adjunct materials such as antioxidants, dyes, activators, solubilizers, binders, etc. Enzymes according to this embodiment can be made by a fluid bed layering process similar to that described in US 5,324,649 , US 6,602,841 B1 and US2008/0206830A1 .
  • Enzymes according to this embodiment can also be made by a combination of processes.
  • Such enzyme co-granules are built around a core that can be free of enzymes or contain enzymes (preferably comprising an moisture sink material, more preferably sodium sulphate) that can be made using a variety of processes including use of either a mixer granulator or an extruder.
  • the cores are then treated in a fluid bed process wherein the enzyme is sprayed onto the core.
  • the core is then coated by a layer, preferably comprising an moisture sink material, and more preferably sodium sulphate and finally is coated with a polymer selected from the group comprising hydroxpropylmethylcellulose and/or polyvinylalcohol and derivatives thereof, optionally also containing additional titanium dioxide, polyethylene glycol and/or kaolin or any mixtures thereof.
  • a layer preferably comprising an moisture sink material, and more preferably sodium sulphate
  • the granulate comprises from about 30% to about 75%, preferably from about 40 to about 50% by weight of the granulate of an moisture sink material, selected from the group comprising sodium sulphate, sodium citrate and mixtures thereof, preferably sodium sulphate.
  • an moisture sink material selected from the group comprising sodium sulphate, sodium citrate and mixtures thereof, preferably sodium sulphate.
  • the enzyme co-granules have a weight geometric mean particle size of from about 200 ⁇ m to about 1200 ⁇ m, more preferably from about 300 ⁇ m to about 1000 ⁇ m and especially from about 400 ⁇ m to about 600 ⁇ m.
  • compositions of the invention comprise less than 10 wt% zeolite (anhydrous basis), more preferably less than 7 or 5 or even below 3wt% zeolite. Zeolite may even be completely absent from the detergent compositions of the invention.
  • compositions of the invention comprise less than 10 wt% phosphate salt (anhydrous basis), more preferably less than 7 or 5 or even below 3wt% phosphate salt. Phosphate salts may even be completely absent from the detergent compositions of the invention.
  • the detergent composition additionally comprises a dye transfer inhibiting agent and/or a fabric hueing agents.
  • the detergent compositions of the invention may comprise one or more adjunct materials. These may enhance cleaning performance, for treatment of the substrate to be cleaned, or modify the aesthetics of the composition for example as is the case with perfumes, speckles, colorants, dyes or the like.
  • the levels of any such adjuncts incorporated in the composition of the invention any fabric and home care product are in addition to any materials previously recited for incorporation. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the consumer product and the nature of the cleaning operation for which it is to be used.
  • Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, fabric softeners, carriers, hydrotropes, processing aids, solvents and/or pigments. Examples of suitable adjuncts are described below. In addition to the disclosure below, suitable examples of such other adjuncts and levels of use are found in U.S. Patent Nos.
  • the composition may comprise a fabric hueing agent.
  • Suitable fabric hueing agents include dyes, dye-clay conjugates, and pigments.
  • Suitable dyes include small molecule dyes and polymeric dyes.
  • Suitable small molecule dyes include small molecule dyes selected from the group consisting of dyes falling into the Colour Index (C.I.) classifications of Direct Blue, Direct Red, Direct Violet, Acid Blue, Acid Red, Acid Violet, Basic Blue, Basic Violet and Basic Red, or mixtures thereof.
  • suitable small molecule dyes include small molecule dyes selected from the group consisting of Colour Index (Society of Dyers and Colourists, Bradford, UK ) numbers Direct Violet 9, Direct Violet 35, Direct Violet 48, Direct Violet 51, Direct Violet 66, Direct Violet 99, Direct Blue 1, Direct Blue 71, Direct Blue 80, Direct Blue 279, Acid Red 17, Acid Red 73, Acid Red 88, Acid Red 150, Acid Violet 15, Acid Violet 17, Acid Violet 24, Acid Violet 43, Acid Red 52, Acid Violet 49, Acid Blue 15, Acid Blue 17, Acid Blue 25, Acid Blue 29, Acid Blue 40, Acid Blue 45, Acid Blue 75, Acid Blue 80, Acid Blue 83, Acid Blue 90 and Acid Blue 113, Acid Black 1, Basic Violet 1, Basic Violet 3, Basic Violet 4, Basic Violet 10, Basic Violet 35, Basic Blue 3, Basic Blue 16, Basic Blue 22, Basic Blue 47, Basic Blue 66, Basic Blue 75, Basic Blue 159 and mixtures thereof.
  • Colour Index Society of Dyers and Colourists, Bradford, UK ) numbers Direct Violet 9, Direct Violet 35, Direct Violet 48, Direct Violet 51, Direct Violet 66, Direct Violet 99
  • suitable small molecule dyes include small molecule dyes selected from the group consisting of Colour Index (Society of Dyers and Colourists, Bradford, UK ) numbers Acid Violet 17, Acid Violet 43, Acid Red 52, Acid Red 73, Acid Red 88, Acid Red 150, Acid Blue 25, Acid Blue 29, Acid Blue 45, Acid Blue 113, Acid Black 1, Direct Blue 1, Direct Blue 71, Direct Violet 51 and mixtures thereof.
  • suitable small molecule dyes include small molecule dyes selected from the group consisting of Colour Index (Society of Dyers and Colourists, Bradford, UK ) numbers Acid Violet 17, Direct Blue 71, Direct Violet 51, Direct Blue 1, Acid Red 88, Acid Red 150, Acid Blue 29, Acid Blue 113 or mixtures thereof.
  • Suitable polymeric dyes include polymeric dyes selected from the group consisting of polymers containing conjugated chromogens (dye-polymer conjugates) and polymers with chromogens co-polymerized into the backbone of the polymer and mixtures thereof.
  • suitable polymeric dyes include polymeric dyes selected from the group consisting of fabric-substantive colorants sold under the name of Liquitint® (Milliken, Spartanburg, South Carolina, USA), dye-polymer conjugates formed from at least one reactive dye and a polymer selected from the group consisting of polymers comprising a moiety selected from the group consisting of a hydroxyl moiety, a primary amine moiety, a secondary amine moiety, a thiol moiety and mixtures thereof.
  • suitable polymeric dyes include polymeric dyes selected from the group consisting of Liquitint® (Milliken, Spartanburg, South Carolina, USA) Violet CT, carboxymethyl cellulose (CMC) conjugated with a reactive blue, reactive violet or reactive red dye such as CMC conjugated with C.I. Reactive Blue 19, sold by Megazyme, Wicklow, Ireland under the product name AZO-CM-CELLULOSE, product code S-ACMC, alkoxylated triphenyl-methane polymeric colourants, alkoxylated thiophene polymeric colourants, and mixtures thereof.
  • Liquitint® Moquitint®
  • CMC carboxymethyl cellulose
  • a reactive blue, reactive violet or reactive red dye such as CMC conjugated with C.I. Reactive Blue 19, sold by Megazyme, Wicklow, Ireland under the product name AZO-CM-CELLULOSE
  • product code S-ACMC alkoxylated triphenyl-methane polymeric colourants, alkoxylated
  • Suitable dye clay conjugates include dye clay conjugates selected from the group comprising at least one cationic/basic dye and a smectite clay, and mixtures thereof.
  • suitable dye clay conjugates include dye clay conjugates selected from the group consisting of one cationic/basic dye selected from the group consisting of C.I. Basic Yellow 1 through 108, C.I. Basic Orange 1 through 69, C.I. Basic Red 1 through 118, C.I. Basic Violet 1 through 51, C.I. Basic Blue 1 through 164, C.I. Basic Green 1 through 14, C.I. Basic Brown 1 through 23, CI Basic Black 1 through 11, and a clay selected from the group consisting of Montmorillonite clay, Hectorite clay, Saponite clay and mixtures thereof.
  • suitable dye clay conjugates include dye clay conjugates selected from the group consisting of: Montmorillonite Basic Blue B7 C.I. 42595 conjugate, Montmorillonite Basic Blue B9 C.I. 52015 conjugate, Montmorillonite Basic Violet V3 C.I. 42555 conjugate, Montmorillonite Basic Green G1 C.I. 42040 conjugate, Montmorillonite Basic Red R1 C.I. 45160 conjugate, Montmorillonite C.I. Basic Black 2 conjugate, Hectorite Basic Blue B7 C.I. 42595 conjugate, Hectorite Basic Blue B9 C.I. 52015 conjugate, Hectorite Basic Violet V3 C.I.
  • Suitable pigments include pigments selected from the group consisting of flavanthrone, indanthrone, chlorinated indanthrone containing from 1 to 4 chlorine atoms, pyranthrone, dichloropyranthrone, monobromodichloropyranthrone, dibromodichloropyranthrone, tetrabromopyranthrone, perylene-3,4,9,10-tetracarboxylic acid diimide, wherein the imide groups may be unsubstituted or substituted by C1-C3 -alkyl or a phenyl or heterocyclic radical, and wherein the phenyl and heterocyclic radicals may additionally carry substituents which do not confer solubility in water, anthrapyrimidinecarboxylic acid amides, violanthrone, isoviolanthrone, dioxazine pigments, copper phthalocyanine which may contain up to 2 chlorine atoms per molecule, polychloro
  • suitable pigments include pigments selected from the group consisting of Ultramarine Blue (C.I. Pigment Blue 29), Ultramarine Violet (C.I. Pigment Violet 15) and mixtures thereof.
  • the aforementioned fabric hueing agents can be used in combination (any mixture of fabric hueing agents can be used).
  • Suitable fabric hueing agents can be purchased from Aldrich, Milwaukee, Wisconsin, USA; Ciba Specialty Chemicals, Basel, Switzerland; BASF, Ludwigshafen, Germany; Dayglo Color Corporation, Mumbai, India; Organic Dyestuffs Corp., East Buffalo, Rhode Island, USA; Dystar, Frankfurt, Germany; Lanxess, Leverkusen, Germany; Megazyme, Wicklow, Ireland; Clariant, Muttenz, Switzerland; Avecia, Manchester, UK and/or made in accordance with the examples contained herein. Suitable hueing agents are described in more detail in US 7,208,459 B2 .
  • Encapsulates The composition may comprise an encapsulate.
  • an encapsulate comprising a core, a shell having an inner and outer surface, said shell encapsulating said core.
  • said core may comprise a material selected from the group consisting of perfumes; brighteners; dyes; insect repellants; silicones; waxes; flavors; vitamins; fabric softening agents; skin care agents in one aspect, paraffins; enzymes; antibacterial agents; bleaches; sensates; and mixtures thereof; and said shell may comprise a material selected from the group consisting of polyethylenes; polyamides; polystyrenes; polyisoprenes; polycarbonates; polyesters; polyacrylates; aminoplasts, in one aspect said aminoplast may comprise a polyureas, polyurethane, and/or polyureaurethane, in one aspect said polyurea may comprise polyoxymethyleneurea and/or melamine formaldehyde; polyolefins; polysaccharides, in one aspect said polysaccharide may comprise alginate and/or chitosan; gelatin; shellac; epoxy resins; vinyl polymers; water insoluble inorganics; silicone;
  • suitable encapsulates may comprise a core material and a shell, said shell at least partially surrounding said core material, is disclosed. At least 75%, 85% or even 90% of said encapsulates may have a fracture strength of from about 0.2 MPa to about 10 MPa, from about 0.4 MPa to about 5MPa, from about 0.6 MPa to about 3.5 MPa, or even from about 0.7 MPa to about 3MPa; and a benefit agent leakage of from 0% to about 30%, from 0% to about 20%, or even from 0% to about 5%.
  • At least 75%, 85% or even 90% of said encapsulates may have a particle size of from about 1 microns to about 80 microns, about 5 microns to 60 microns, from about 10 microns to about 50 microns, or even from about 15 microns to about 40 microns. In one aspect, at least 75%, 85% or even 90% of said encapsulates may have a particle wall thickness of from about 30 nm to about 250 nm, from about 80 nm to about 180 nm, or even from about 100 nm to about 160 nm.
  • said encapsulates' core material may comprise a material selected from the group consisting of a perfume raw material and/or optionally a material selected from the group consisting of vegetable oil, including neat and/or blended vegetable oils including caster oil, coconut oil, cottonseed oil, grape oil, rapeseed, soybean oil, corn oil, palm oil, linseed oil, safflower oil, olive oil, peanut oil, coconut oil, palm kernel oil, castor oil, lemon oil and mixtures thereof; esters of vegetable oils, esters, including dibutyl adipate, dibutyl phthalate, butyl benzyl adipate, benzyl octyl adipate, tricresyl phosphate, trioctyl phosphate and mixtures thereof; straight or branched chain hydrocarbons, including those straight or branched chain hydrocarbons having a boiling point of greater than about 80°C; partially hydrogenated terphenyls, dialkyl phthalates, alkyl
  • said encapsulates' wall material may comprise a suitable resin including the reaction product of an aldehyde and an amine
  • suitable aldehydes include, formaldehyde.
  • suitable amines include melamine, urea, benzoguanamine, glycoluril, and mixtures thereof.
  • Suitable melamines include, methylol melamine, methylated methylol melamine, imino melamine and mixtures thereof.
  • Suitable ureas include, dimethylol urea, methylated dimethylol urea, urea-resorcinol, and mixtures thereof.
  • suitable formaldehyde scavengers may be employed with the encapsulates, for example, in a capsule slurry and/or added to a consumer product before, during or after the encapsulates are added to such consumer product.
  • Suitable capsules that can be made by following the teaching of USPA 2008/0305982 A1 ; and/or USPA 2009/0247449 A1 .
  • suitable capsules can be purchased from Appleton Papers Inc. of Appleton, Wisconsin USA.
  • the materials for making the aforementioned encapsulates can be obtained from Solutia Inc. (St Louis, Missouri U.S.A.), Cytec Industries (West Paterson, New Jersey U.S.A.), sigma-Aldrich (St. Louis, Missouri U.S.A.), CP Kelco Corp. of San Diego, California, USA; BASF AG of Ludwigshafen, Germany; Rhodia Corp. of Cranbury, New Jersey, USA; Hercules Corp. of Wilmington, Delaware, USA; Agrium Inc.
  • the consumer product may comprise one or more polymers. Examples are carboxymethylcellulose, poly(vinyl-pyrrolidone), poly (ethylene glycol), poly(vinyl alcohol), poly(vinylpyridine-N-oxide), poly(vinylimidazole), polycarboxylates such as polyacrylates, maleic/acrylic acid copolymers and lauryl methacrylate/acrylic acid co-polymers.
  • the consumer product may comprise amphiphilic alkoxylated grease cleaning polymers which have balanced hydrophilic and hydrophobic properties such that they remove grease particles from fabrics and surfaces.
  • amphiphilic alkoxylated grease cleaning polymers of the present invention comprise a core structure and a plurality of alkoxylate groups attached to that core structure. These may comprise alkoxylated polyalkylenimines, preferably having an inner polyethylene oxide block and an outer polypropylene oxide block.
  • Carboxylate polymer - The detergent composition of the present invention may also include one or more carboxylate polymers such as a maleate/acrylate random copolymer or polyacrylate homopolymer.
  • the carboxylate polymer is a polyacrylate homopolymer having a molecular weight of from 4,000 Da to 9,000 Da, or from 6,000 Da to 9,000 Da.
  • Soil release polymer - The detergent composition of the present invention may also include one or more soil release polymers having a structure as defined by one of the following structures (I), (II) or (III): (I) -[(OCHR 1 -CHR 2 ) a -O-OC-Ar-CO-] d (II) -[(OCHR 3 -CHR 4 ) b -O-OC-sAr-CO-] e (III) -[(OCHR 5 -CHR 6 ) c -OR 7 ] f wherein:
  • Suitable soil release polymers are polyester soil release polymers such as Repel-o-tex polymers, including Repel-o-tex SF, SF-2 and SRP6 supplied by Rhodia.
  • Other suitable soil release polymers include Texcare polymers, including Texcare SRA100, SRA300, SRN100, SRN170, SRN240, SRN300 and SRN325 supplied by Clariant.
  • Other suitable soil release polymers are Marloquest polymers, such as Marloquest SL supplied by Sasol.
  • Cellulosic polymer - The detergent composition of the present invention may also include one or more cellulosic polymers including those selected from alkyl cellulose, alkyl alkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose.
  • the cellulosic polymers are selected from the group comprising carboxymethyl cellulose, methyl cellulose, methyl hydroxyethyl cellulose, methyl carboxymethyl cellulose, and mixures thereof.
  • the carboxymethyl cellulose has a degree of carboxymethyl substitution from 0.5 to 0.9 and a molecular weight from 100,000 Da to 300,000 Da.
  • the detergent composition may comprise one or more additional enzymes which provide cleaning performance and/or fabric care benefits.
  • suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, mannanases, pectate lyases, keratinases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, ß-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof.
  • a typical combination is an enzyme cocktail that may comprise, for example, a protease and lipase in conjunction with amylase.
  • the aforementioned additional enzymes may be present at levels from about 0.00001 % to about 2%, from about 0.0001 % to about 1% or even from about 0.001 % to about 0.5% enzyme protein by weight of the consumer product.
  • the detailed information given below relates to enzymes suitable for incorporation into the co-granule or the detergent composition more generally other than via the co-granule.
  • Suitable proteases include metalloproteases and serine proteases, including neutral or alkaline microbial serine proteases, such as subtilisins (EC 3.4.21.62).
  • Suitable proteases include those of animal, vegetable or microbial origin. In one aspect, such suitable protease may be of microbial origin.
  • the suitable proteases include chemically or genetically modified mutants of the aforementioned suitable proteases.
  • the suitable protease may be a serine protease, such as an alkaline microbial protease or/and a trypsin-type protease.
  • suitable neutral or alkaline proteases include:
  • Preferred proteases include those derived from Bacillus gibsonii or Bacillus Lentus.
  • Suitable commercially available protease enzymes include those sold under the trade names Alcalase®, Savinase®, Primase®, Durazym®, Polarzyme®, Kannase®, Liquanase®, Liquanase Ultra®, Savinase Ultra®, Ovozyme®, Neutrase®, Everlase® and Esperase® by Novozymes A/S (Denmark), those sold under the tradename Maxatase®, Maxacal®, Maxapem®, Properase®, Purafect®, Purafect Prime®, Purafect Ox®, FN3®, FN4®, Excellase® and Purafect OXP® by Genencor International, those sold under the tradename Opticlean® and Optimase® by Solvay Enzymes, those available from Henkel/ Kemira, namely BLAP (sequence shown in Figure 29 of US 5,352,604 with the following mutations S99D + S101 R + S103A
  • Suitable alpha-amylases include those of bacterial or fungal origin. Chemically or genetically modified mutants (variants) are included.
  • a preferred alkaline alpha-amylase is derived from a strain of Bacillus, such as Bacillus licheniformis, Bacillus amyloliquefaciens, Bacillus stearothermophilus, Bacillus subtilis, or other Bacillus sp., such as Bacillus sp. NCIB 12289, NCIB 12512, NCIB 12513, DSM 9375 ( USP 7,153,818 ) DSM 12368, DSMZ no. 12649, KSM AP1378 ( WO 97/00324 ), KSM K36 or KSM K38 ( EP 1,022,334 ).
  • Preferred amylases include:
  • Suitable commercially available alpha-amylases include DURAMYL®, LIQUEZYME®, TERMAMYL®, TERMAMYL ULTRA®, NATALASE®, SUPRAMYL®, STAINZYME®, STAINZYME PLUS@, FUNGAMYL® and BAN® (Novozymes A/S, Bagsvaerd, Denmark), KEMZYM® AT 9000 Biozym Biotech Trading GmbH Wehlistrasse 27b A-1200 Wien Austria, RAPIDASE®, PURASTAR®, ENZYSIZE®, OPTISIZE HT PLUS® and PURASTAR OXAM® (Genencor International Inc., Palo Alto, California) and KAM® (Kao, 14-10 Nihonbashi Kayabacho, 1-chome, Chuo-ku Tokyo 103-8210, Japan).
  • suitable amylases include NATALASE®, STAINZYME® and STAINZYME PLUS® and mixtures thereof.
  • such enzymes may be selected from the group consisting of: lipases, including "first wash lipases” such as those described in U.S. Patent 6,939,702 B1 and US PA 2009/0217464 .
  • the lipase is a first-wash lipase, preferably a variant of the wild-type lipase from Thermomyces lanuginosus comprising T231R and N233R mutations.
  • the wild-type sequence is the 269 amino acids (amino acids 23 - 291) of the Swissprot accession number Swiss-Prot 059952 (derived from Thermomyces lanuginosus (Humicola lanuginosa)).
  • Preferred lipases would include those sold under the tradenames Lipex® and Lipolex®.
  • other preferred enzymes include microbial-derived endoglucanases exhibiting endo-beta-1,4-glucanase activity (E.C. 3.2.1.4), including a bacterial polypeptide endogenous to a member of the genus Bacillus which has a sequence of at least 90%, 94%, 97% and even 99% identity to the amino acid sequence SEQ ID NO:2 in 7,141,403B2) and mixtures thereof.
  • Suitable endoglucanases are sold under the tradenames Celluclean® and Whitezyme® (Novozymes A/S, Bagsvaerd, Denmark).
  • the detergent composition of the present invention may comprise one or more bleaching agents.
  • Suitable bleaching agents other than bleaching catalysts include photobleaches, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, pre-formed peracids and mixtures thereof.
  • the detergent composition of the present invention may comprise from about 0.1 % to about 50% or even from about 0.1% to about 25% bleaching agent by weight of the subject consumer product.
  • suitable bleaching agents include:
  • the pre-formed peroxyacid or salt thereof can also be a peroxysulphonic acid or salt thereof, typically having a chemical structure corresponding to the following chemical formula: wherein: R 15 is selected from alkyl, aralkyl, cycloalkyl, aryl or heterocyclic groups; the R 15 group can be linear or branched, substituted or unsubstituted; and Z is any suitable counter-ion that achieves electric charge neutrality, preferably Z is selected from hydrogen, sodium or potassium.
  • R 15 is a linear or branched, substituted or unsubstituted C 6-9 alkyl.
  • such bleach components may be present in the compositions of the invention in an amount from 0.01 to 50%, most preferably from 0.1 % to 20%;
  • the peracid and/or bleach activator is generally present in the consumer product in an amount of from about 0.1 to about 60 wt%, from about 0.5 to about 40 wt % or even from about 0.6 to about 10 wt% based on the fabric and home care product.
  • One or more hydrophobic peracids or precursors thereof may be used in combination with one or more hydrophilic peracid or precursor thereof.
  • the amounts of hydrogen peroxide source and peracid or bleach activator may be selected such that the molar ratio of available oxygen (from the peroxide source) to peracid is from 1:1 to 35:1, or even 2:1 to 10:1.
  • the bleach catalyst has a structure corresponding to general formula below: wherein R 13 is selected from the group consisting of 2-ethylhexyl, 2-propylheptyl, 2-butyloctyl, 2-pentylnonyl, 2-hexyldecyl, n-dodecyl, n-tetradecyl, n-hexadecyl, n-octadecyl, isononyl, iso-decyl, iso-tridecyl and iso-pentadecyl;
  • Suitable anionic detersive surfactants include sulphate and sulphonate detersive surfactants.
  • Suitable sulphonate detersive surfactants include alkyl benzene sulphonate, in one aspect, C 10-13 alkyl benzene sulphonate.
  • Suitable alkyl benzene sulphonate (LAS) may be obtained, by sulphonating commercially available linear alkyl benzene (LAB); suitable LAB includes low 2-phenyl LAB, such as those supplied by Sasol under the tradename Isochem® or those supplied by Petresa under the tradename Petrelab®, other suitable LAB include high 2-phenyl LAB, such as those supplied by Sasol under the tradename Hyblene®.
  • a suitable anionic detersive surfactant is alkyl benzene sulphonate that is obtained by DETAL catalyzed process, although other synthesis routes, such as HF, may also be suitable.
  • Suitable sulphate detersive surfactants include alkyl sulphate, in one aspect, C 8-10 alkyl sulphate, or predominantly C 12 alkyl sulphate.
  • alkyl alkoxylated sulphate in one aspect, alkyl ethoxylated sulphate, in one aspect, a C 8-18 alkyl alkoxylated sulphate, in another aspect, a C 8-18 alkyl ethoxylated sulphate, typically the alkyl alkoxylated sulphate has an average degree of alkoxylation of from 0.5 to 20, or from 0.5 to 10, typically the alkyl alkoxylated sulphate is a C 8-18 alkyl ethoxylated sulphate having an average degree of ethoxylation of from 0.5 to 10, from 0.5 to 7, from 0.5 to 5 or even from 0.5 to 3.
  • the alkyl sulphate, alkyl alkoxylated sulphate and alkyl benzene sulphonates may be linear or branched, substituted or unsubstituted.
  • the detersive surfactant may be a mid-chain branched detersive surfactant, in one aspect, a mid-chain branched anionic detersive surfactant, in one aspect, a mid-chain branched alkyl sulphate and/or a mid-chain branched alkyl benzene sulphonate, for example a mid-chain branched alkyl sulphate.
  • the mid-chain branches are C 1-4 alkyl groups, typically methyl and/or ethyl groups.
  • Suitable non-ionic detersive surfactants are selected from the group consisting of: C 8 -C 18 alkyl ethoxylates, such as, NEODOL® non-ionic surfactants from Shell; C 6 -C 12 alkyl phenol alkoxylates wherein the alkoxylate units may be ethyleneoxy units, propyleneoxy units or a mixture thereof; C 12 -C 18 alcohol and C 6 -C 12 alkyl phenol condensates with ethylene oxide/propylene oxide block polymers such as Pluronic® from BASF; C 14 -C 22 mid-chain branched alcohols; C 14 -C 22 mid-chain branched alkyl alkoxylates, typically having an average degree of alkoxylation of from 1 to 30; alkylpolysaccharides, in one aspect, alkylpolyglycosides; polyhydroxy fatty acid amides; ether capped poly(oxyalkylated) alcohol surfactants; and mixtures thereof.
  • non-ionic detersive surfactants include alkyl polyglucoside and/or an alkyl alkoxylated alcohol.
  • non-ionic detersive surfactants include alkyl alkoxylated alcohols, in one aspect C 8-18 alkyl alkoxylated alcohol, for example a C 8-18 alkyl ethoxylated alcohol, the alkyl alkoxylated alcohol may have an average degree of alkoxylation of from 1 to 50, from 1 to 30, from 1 to 20, or from 1 to 10.
  • the alkyl alkoxylated alcohol may be a C 8-18 alkyl ethoxylated alcohol having an average degree of ethoxylation of from 1 to 10, from 1 to 7, more from 1 to 5 or from 3 to 7.
  • the alkyl alkoxylated alcohol can be linear or branched, and substituted or un-substituted.
  • Suitable cationic detersive surfactants include alkyl pyridinium compounds, alkyl quaternary ammonium compounds, alkyl quaternary phosphonium compounds, alkyl ternary sulphonium compounds, and mixtures thereof.
  • Suitable cationic detersive surfactants are quaternary ammonium compounds having the general formula: (R)(R 1 )(R 2 )(R 3 )N + X - wherein, R is a linear or branched, substituted or unsubstituted C 6-18 alkyl or alkenyl moiety, R 1 and R 2 are independently selected from methyl or ethyl moieties, R 3 is a hydroxyl, hydroxymethyl or a hydroxyethyl moiety, X is an anion which provides charge neutrality, suitable anions include: halides, for example chloride; sulphate; and sulphonate.
  • Suitable cationic detersive surfactants are mono-C 6-18 alkyl mono-hydroxyethyl di-methyl quaternary ammonium chlorides. Highly suitable cationic detersive surfactants are mono-C 8-10 alkyl mono-hydroxyethyl di-methyl quaternary ammonium chloride, mono-C 10-12 alkyl mono-hydroxyethyl di-methyl quaternary ammonium chloride and mono-C 10 alkyl mono-hydroxyethyl di-methyl quaternary ammonium chloride.
  • Chelating Agents The detergent composition herein may contain a chelating agent. Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof.
  • the subject consumer product may comprise from about 0.005% to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject consumer product.
  • Suitable chelants include DTPA (Diethylene triamine pentaacetic acid), HEDP (Hydroxyethane diphosphonic acid), DTPMP (Diethylene triamine penta(methylene phosphonic acid)), 1,2-Dihydroxybenzene-3,5-disulfonic acid disodium salt hydrate, ethylenediamine, diethylene triamine, ethylenediaminedisuccinic acid (EDDS), N-hydroxyethylethylenediaminetri-acetic acid (HEDTA), triethylenetetraaminehexaacetic acid (TTHA), N-hydroxyethyliminodiacetic acid (HEIDA), dihydroxyethylglycine (DHEG), ethylenediaminetetrapropionic acid (EDTP) and derivatives thereof.
  • DTPA Diethylene triamine pentaacetic acid
  • the detergent composition of the present invention may also include one or more dye transfer inhibiting agents.
  • Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
  • the dye transfer inhibiting agents may be present at levels from about 0.0001 % to about 10%, from about 0.01 % to about 5% or even from about 0.1 % to about 3% by weight of the consumer product.
  • Brighteners The detergent composition of the present invention can also contain additional components that may tint articles being cleaned, such as fluorescent brighteners.
  • composition may comprise C.I. fluorescent brightener 260 in alpha-crystalline form having the following structure:
  • the brightener is a cold water soluble brightener, such as the C.I. fluorescent brightener 260 in alpha-crystalline form.
  • the brightener is predominantly in alpha-crystalline form, which means that typically at least 50wt%, at least 75wt%, at least 90wt%, at least 99wt%, or even substantially all, of the C.I. fluorescent brightener 260 is in alpha-crystalline form.
  • the brightener is typically in micronized particulate form, having a weight average primary particle size of from 3 to 30 micrometers, from 3 micrometers to 20 micrometers, or from 3 to 10 micrometers.
  • the composition may comprise C.I. fluorescent brightener 260 in beta-crystalline form, and the weight ratio of: (i) C.I. fluorescent brightener 260 in alpha-crystalline form, to (ii) C.I. fluorescent brightener 260 in beta-crystalline form may be at least 0.1, or at least 0.6.
  • BE680847 relates to a process for making C.I fluorescent brightener 260 in alpha-crystalline form.
  • Suitable fluorescent brightener levels include lower levels of from about 0.01, from about 0.05, from about 0.1 or even from about 0.2 wt % to upper levels of 0.5 or even 0.75 wt %.
  • Silicate salts - The detergent composition of the present invention can also contain silicate salts, such as sodium or potassium silicate.
  • the composition may comprise from 0wt% to less than 10wt% silicate salt, to 9wt%, or to 8wt%, or to 7wt%, or to 6wt%, or to 5wt%, or to 4wt%, or to 3wt%, or even to 2wt%, and preferably from above 0wt%, or from 0.5wt%, or even from 1wt% silicate salt.
  • a suitable silicate salt is sodium silicate.
  • Dispersants - The detergent composition of the present invention can also contain dispersants.
  • Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.
  • Enzyme Stabilizers - Enzymes for use in the detergent composition can be stabilized by various techniques.
  • the enzymes employed herein can be stabilized by the presence of water-soluble sources of calcium and/or magnesium ions in the finished fabric and home care products that provide such ions to the enzymes.
  • a reversible protease inhibitor such as a boron compound, or compounds such as calcium formate, sodium formate and 1,2-propane diol can be added to further improve stability.
  • Solvents - Suitable solvents include water and other solvents such as lipophilic fluids.
  • suitable lipophilic fluids include siloxanes, other silicones, hydrocarbons, glycol ethers, glycerine derivatives such as glycerine ethers, perfluorinated amines, perfluorinated and hydrofluoroether solvents, low-volatility nonfluorinated organic solvents, diol solvents, other environmentally- friendly solvents and mixtures thereof.
  • the detergent composition of the present invention are preferably in granular form, optionally the granules being incorporated into a unit dose detergent composition as described above.
  • the present invention includes a method of treating and/or cleaning a surface, preferably a fabric surface comprising the steps of (i) contacting said surface with a composition according to any of claims 1 to 11 in an aqueous wash liquor, (ii) rinsing and/or drying the surface, preferably the temperature of the aqueous liquor is from 5 - 25°C and preferably the aqueous liquor comprises from 0.1g/l to 3g/l of surfactant.
  • Enzyme co-granules are prepared according to the process described in US2008/0206830A1 , however the granules each comprising the enzymes as outlined in the formulation examples below.
  • Granular laundry detergent compositions designed for hand washing or top-loading washing machines. 1 (wt%) 2 (wt%) 3 (wt %) 4 (wt%) 5 (wt%) 6 (wt %) 7 (wt%) Linear alkylbenzenesulfonate 18 20 22 20 15 20 20 C 12-14 Dimethylhydroxyethyl ammonium chloride 0.5 0.7 0.2 1 0.6 0.0 0 AE3S 1.0 0.9 1 0.9 0.0 0.5 0.9 AE7 2.0 0.0 0.0 0.0 1 0.0 3 Sodium tripolyphosphate 5 5 0.0 4 9 2 0.0 Zeolite A 0 0.0 1 0.0 1 4 1 1.6R Silicate (SiO 2 :Na 2 O at ratio 1.6:1) 6 7 5 2 3 3 5 Sodium carbonate 26 25 20 25 17 18 19 Polyacrylate MW 4500 1 1 0.6 1 1 1.5 1 Random graft copolymer 1 0.1 0.1 0.2 0.0 0.0 0.0 0.0 0.0 0.0 Carboxymethyl cellulose 0.7
  • Granular laundry detergent compositions designed for front-loading automatic washing machines 8 (wt%) 9 (wt%) 10 (wt%) 11 (wt%) 12 (wt%) 13 (wt%) Linear alkylbenzenesulfonate 8 7.1 7 6.5 7.5 7.5 AE3S 0 4.8 0 5.2 4 4 C12-14 Alkylsulfate 1 0 1 0 0 0 AE7 2.2 0 3.2 0 0 0 C 10-12 Dimethyl hydroxyethylammonium chloride 0.75 0.94 0.98 0.98 0 0 Crystalline layered silicate ( ⁇ -Na 2 Si 2 O 5 ) 4.1 0 4.8 0 0 0 0 Zeolite A 5 0 5 0 2 2 Citric Acid 3 5 3 4 2.5 3 Sodium Carbonate 15 20 14 20 23 23 Silicate 2R (SiO 2 :Na 2 O at ratio 2:1) 0.08 0 0.11 0 0 0 0 Soil release agent 0.75 0.72 0.71 0.72
  • any of the above compositions is used to launder fabrics at a concentration of 7000 to 10000 ppm in water, 20-90 °C, and a 5:1 water:cloth ratio.
  • the typical pH is about 10.
  • the fabrics are then dried.
  • the fabrics are actively dried using a dryer.
  • the fabrics are actively dried using an iron.
  • the fabrics are merely allowed to dry on a line wherein they are exposed to air and optionally sunlight.
  • Random graft copolymer is a polyvinyl acetate grafted polyethylene oxide copolymer having a polyethylene oxide backbone and multiple polyvinyl acetate side chains (m wt about 6000, weight ratio of the polyethylene oxide to polyvinyl acetateabout 40 to 60).
  • Polyethyleneimine (MW 600) with 20 ethoxylate groups per -NH. * Remark: all enzyme levels expressed as % enzyme raw material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
  • Enzymes And Modification Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
EP12171551.0A 2012-06-11 2012-06-11 Composition détergente Withdrawn EP2674475A1 (fr)

Priority Applications (16)

Application Number Priority Date Filing Date Title
EP12171551.0A EP2674475A1 (fr) 2012-06-11 2012-06-11 Composition détergente
IN10427DEN2014 IN2014DN10427A (fr) 2012-06-11 2013-06-11
JP2015516278A JP2015528828A (ja) 2012-06-11 2013-06-11 洗剤組成物
EP13171413.1A EP2674476B2 (fr) 2012-06-11 2013-06-11 Composition détergente
PCT/US2013/045070 WO2013188331A1 (fr) 2012-06-11 2013-06-11 Composition de détergent
CN201380030796.9A CN104364364A (zh) 2012-06-11 2013-06-11 洗涤剂组合物
DK13171413.1T DK2674476T4 (da) 2012-06-11 2013-06-11 Detergentsammensætning
HUE13171413A HUE038095T2 (hu) 2012-06-11 2013-06-11 Mosószerkészítmény
ES13171413T ES2674940T5 (es) 2012-06-11 2013-06-11 Composición detergente
MX2014015172A MX370587B (es) 2012-06-11 2013-06-11 Composicion detergente.
PL13171413T PL2674476T5 (pl) 2012-06-11 2013-06-11 Kompozycja detergentowa
TR2018/09430T TR201809430T4 (tr) 2012-06-11 2013-06-11 Deterjan bileşimi.
CN202010099823.XA CN111205939A (zh) 2012-06-11 2013-06-11 洗涤剂组合物
BR112014030417-3A BR112014030417B1 (pt) 2012-06-11 2013-06-11 Composição detergente
RU2014149582A RU2612142C2 (ru) 2012-06-11 2013-06-11 Моющий состав
ZA2014/08580A ZA201408580B (en) 2012-06-11 2014-11-21 Detergent composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12171551.0A EP2674475A1 (fr) 2012-06-11 2012-06-11 Composition détergente

Publications (1)

Publication Number Publication Date
EP2674475A1 true EP2674475A1 (fr) 2013-12-18

Family

ID=48570026

Family Applications (2)

Application Number Title Priority Date Filing Date
EP12171551.0A Withdrawn EP2674475A1 (fr) 2012-06-11 2012-06-11 Composition détergente
EP13171413.1A Active EP2674476B2 (fr) 2012-06-11 2013-06-11 Composition détergente

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP13171413.1A Active EP2674476B2 (fr) 2012-06-11 2013-06-11 Composition détergente

Country Status (14)

Country Link
EP (2) EP2674475A1 (fr)
JP (1) JP2015528828A (fr)
CN (2) CN104364364A (fr)
BR (1) BR112014030417B1 (fr)
DK (1) DK2674476T4 (fr)
ES (1) ES2674940T5 (fr)
HU (1) HUE038095T2 (fr)
IN (1) IN2014DN10427A (fr)
MX (1) MX370587B (fr)
PL (1) PL2674476T5 (fr)
RU (1) RU2612142C2 (fr)
TR (1) TR201809430T4 (fr)
WO (1) WO2013188331A1 (fr)
ZA (1) ZA201408580B (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014068109A3 (fr) * 2012-11-05 2014-08-28 Novozymes A/S Compositions d'enzyme permettant la réutilisation d'eau dans une lessive
WO2015057619A1 (fr) * 2013-10-15 2015-04-23 Danisco Us Inc. Granulé d'argile
EP3037512A1 (fr) * 2014-12-22 2016-06-29 The Procter and Gamble Company Procédé pour le recyclage de sachets de détergent
WO2017037097A1 (fr) * 2015-09-01 2017-03-09 Novozymes A/S Procédé de lessive
GB2544470A (en) * 2015-11-16 2017-05-24 Reckitt Benckiser Vanish Bv Composition
WO2018083093A1 (fr) * 2016-11-01 2018-05-11 Novozymes A/S Granules à noyaux multiples

Families Citing this family (173)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9834740B2 (en) * 2014-01-24 2017-12-05 The Procter & Gamble Company Photoactivators
WO2015121134A1 (fr) * 2014-02-11 2015-08-20 Novozymes A/S Composition détergente, procédé et utilisation de celle-ci
CN106164236B (zh) 2014-04-11 2021-02-02 诺维信公司 洗涤剂组合物
EP3280800A1 (fr) 2015-04-10 2018-02-14 Novozymes A/S Composition détergente
CN107567489A (zh) 2015-04-10 2018-01-09 诺维信公司 衣物洗涤方法，dna酶和洗涤剂组合物的用途
US20180171271A1 (en) 2015-06-30 2018-06-21 Novozymes A/S Laundry detergent composition, method for washing and use of composition
AU2016323412B2 (en) 2015-09-17 2021-04-01 Henkel Ag & Co. Kgaa Detergent compositions comprising polypeptides having xanthan degrading activity
CA2991114A1 (fr) 2015-09-17 2017-03-23 Novozymes A/S Polypeptides presentant une activite de degradation de xylanase et polynucleotides codant pour ceux-ci
CN116064474A (zh) 2015-10-07 2023-05-05 诺维信公司 多肽
EP3362556B1 (fr) 2015-10-14 2024-07-10 Novozymes A/S Variants polypeptidiques
EP3417050A1 (fr) 2016-02-15 2018-12-26 Novozymes A/S Culture microbienne, composition, utilisation et procédé
CN109072133B (zh) 2016-03-23 2021-06-15 诺维信公司 具有dna酶活性的多肽用于处理织物的用途
JP6959259B2 (ja) 2016-04-29 2021-11-02 ノボザイムス アクティーゼルスカブ 洗剤組成物およびその使用
PL3249037T3 (pl) * 2016-05-23 2020-08-24 The Procter & Gamble Company Kompozycja detergentowa zawierająca kapsułkowany enzym
MX2018013875A (es) 2016-05-24 2019-09-04 Novozymes As Composiciones que comprenden polipeptidos que tienen actividad galactanasa y polipeptidos que tienen actividad beta-galactosidasa.
AU2017270231A1 (en) 2016-05-24 2018-11-15 Novozymes A/S Compositions comprising polypeptides having galactanase activity and polypeptides having beta-galactosidase activity
AU2017269498A1 (en) 2016-05-24 2018-11-08 Novozymes A/S Polypeptides having alpha-galactosidase activity and polynucleotides encoding same
EP3462904B1 (fr) 2016-05-24 2024-12-18 Novozymes A/S Polypeptides gastriques stables ayant une activité alpha-galactosidase et polynucléotides codant pour ceux-ci
CN107486239A (zh) * 2016-06-10 2017-12-19 国立大学法人信州大学 动物组织加工物、金属纳米粒子催化剂、它们的制造方法
WO2018002261A1 (fr) 2016-07-01 2018-01-04 Novozymes A/S Compositions détergentes
MX2019000133A (es) 2016-07-05 2019-04-22 Novozymes As Variantes de pectato liasa y polinucleotidos que las codifican.
BR112019000089A2 (pt) 2016-07-08 2019-07-09 Novozymes As variante de xilanase, composição, grânulo, aditivo de ração animal, formulação líquida, ração animal, métodos para aprimorar um ou mais parâmetros de desempenho de um animal, para solubilizar xilana a partir do material à base de planta, para liberar amido do material à base de planta, para aprimorar o valor nutricional de uma ração animal, para preparar uma massa ou um produto assado preparado a partir da massa, de produção de uma variante de xilanase e para obter uma variante de xilanase, uso de uma variante de xilanase, processo de produção de um produto de fermentação, polinucleotídeo isolado, construto de ácido nucleico ou vetor de expressão, e, célula hospedeira recombinante.
WO2018007573A1 (fr) 2016-07-08 2018-01-11 Novozymes A/S Compositions détergentes contenant de la galactanase
AU2017294066A1 (en) 2016-07-08 2019-01-17 Novozymes A/S Polypeptides having xylanase activity and polynucleotides encoding same
EP3950941A3 (fr) 2016-07-13 2022-04-20 Novozymes A/S Variants polypeptidiques de la dnase
CN106191882B (zh) * 2016-08-17 2018-09-21 安徽红桥金属制造有限公司 一种无磷脱脂剂及其制备方法
US20200140786A1 (en) 2016-09-29 2020-05-07 Novozymes A/S Use of enzyme for washing, method for washing and warewashing composition
EP3532592A1 (fr) 2016-10-25 2019-09-04 Novozymes A/S Compositions détergentes
CA3044415C (fr) * 2016-12-02 2022-06-07 The Procter & Gamble Company Compositions de nettoyage comprenant des enzymes
US11149233B2 (en) 2017-03-31 2021-10-19 Novozymes A/S Polypeptides having RNase activity
US11208639B2 (en) 2017-03-31 2021-12-28 Novozymes A/S Polypeptides having DNase activity
US11053483B2 (en) 2017-03-31 2021-07-06 Novozymes A/S Polypeptides having DNase activity
EP3607040A1 (fr) 2017-04-04 2020-02-12 Novozymes A/S Compositions de poypeptides et utilisations associées
CN110651029B (zh) 2017-04-04 2022-02-15 诺维信公司 糖基水解酶
US20200109354A1 (en) 2017-04-04 2020-04-09 Novozymes A/S Polypeptides
EP3607044B1 (fr) 2017-04-06 2024-11-13 Novozymes A/S Compositions détergentes et leurs utilisations
WO2018185267A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
US11499121B2 (en) 2017-04-06 2022-11-15 Novozymes A/S Detergent compositions and uses thereof
JP7032430B2 (ja) 2017-04-06 2022-03-08 ノボザイムス アクティーゼルスカブ クリーニング組成物及びその使用
US20200190438A1 (en) 2017-04-06 2020-06-18 Novozymes A/S Cleaning compositions and uses thereof
WO2018184818A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
US20200032170A1 (en) 2017-04-06 2020-01-30 Novozymes A/S Cleaning compositions and uses thereof
EP3607037A1 (fr) 2017-04-06 2020-02-12 Novozymes A/S Compositions de nettoyage et leurs utilisations
CN107151459A (zh) * 2017-06-08 2017-09-12 巢湖市天宇渔具有限公司 一种废旧渔网的处理方法
EP3642339A1 (fr) 2017-06-22 2020-04-29 Novozymes A/S Variants de xylanase et polynucléotides codant pour ceux-ci
BR112020001577B1 (pt) 2017-09-01 2023-12-26 Novozymes A/S Aditivo de ração animal, formulação líquida, ração animal, métodos para melhoria de um ou mais parâmetros de desempenho de um animal, para preparação de uma ração animal, para o tratamento de proteínas, para aumento da digestibilidade e/ou solubilidade da proteína, para melhoria do valor nutricional de uma ração animal e para produção de um polipeptídeo, e, uso do aditivo de ração animal
WO2019043191A1 (fr) 2017-09-01 2019-03-07 Novozymes A/S Additifs alimentaires pour animaux comprenant un polypeptide ayant une activité de protéase et leurs utilisations
US11414814B2 (en) 2017-09-22 2022-08-16 Novozymes A/S Polypeptides
EP3692148A1 (fr) 2017-10-02 2020-08-12 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
EP3692147A1 (fr) 2017-10-02 2020-08-12 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
WO2019076800A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2019081515A1 (fr) 2017-10-24 2019-05-02 Novozymes A/S Compositions comprenant des polypeptides présentant une activité mannanase
EP3701017A1 (fr) 2017-10-27 2020-09-02 Novozymes A/S Variants de dnase
ES2910120T3 (es) 2017-10-27 2022-05-11 Procter & Gamble Composiciones detergentes que comprenden variantes polipeptídicas
DE102017125558A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine i enthalten
DE102017125560A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine iii enthalten
WO2019086530A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
BR112020008711A2 (pt) 2017-11-01 2020-11-10 Novozymes A/S polipeptídeos e composições que compreendem tais polipeptídeos
CN111491519A (zh) 2017-12-20 2020-08-04 帝斯曼知识产权资产管理有限公司 包含胞壁质酶的动物饲料组合物及其用途
EP3728578A1 (fr) 2017-12-20 2020-10-28 DSM IP Assets B.V. Compositions d'aliments pour animaux et leurs utilisations
EP3728543A1 (fr) * 2017-12-21 2020-10-28 Danisco US Inc. Granulés thermofusibles contenant des enzymes, comprenant un déshydratant thermotolérant
EP3737769A1 (fr) 2018-01-11 2020-11-18 Novozymes A/S Compositions d'aliment pour animaux et leurs utilisations
CN112262207B (zh) 2018-04-17 2024-01-23 诺维信公司 洗涤剂组合物中包含碳水化合物结合活性的多肽及其在减少纺织品或织物中的褶皱的用途
JP6633123B2 (ja) * 2018-04-24 2020-01-22 花王株式会社 衣料用粉末洗浄剤組成物
BR112020021365A2 (pt) 2018-04-25 2021-01-19 Novozymes A/S Ração animal, método para melhoria do fator de eficiência de produção europeu, ganho de peso corporal e/ou razão de conversão de ração de um animal monogástrico, uso de pelo menos um probiótico em combinação com um polipeptídeo tendo atividade de muramidase em uma composição de ração, e, composição de ração ou uma composição de pré-mistura, ou um aditivo de ração para animais.
EP3814472A1 (fr) 2018-06-28 2021-05-05 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020002608A1 (fr) 2018-06-29 2020-01-02 Novozymes A/S Compositions détergentes et leurs utilisations
EP3818139A1 (fr) 2018-07-02 2021-05-12 Novozymes A/S Compositions de nettoyage et leurs utilisations
US20210301223A1 (en) 2018-07-03 2021-09-30 Novozymes A/S Cleaning compositions and uses thereof
WO2020008024A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020008043A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3848444A1 (fr) * 2018-08-14 2021-07-14 The Procter & Gamble Company Compositions liquides pour le traitement de tissus comprenant un agent de blanchiment
EP3611247B1 (fr) 2018-08-14 2021-03-10 The Procter & Gamble Company Compositions de traitement de tissus comprenant des capsules d'agent traitant
EP3848442A1 (fr) 2018-08-14 2021-07-14 The Procter & Gamble Company Compositions de traitement de tissus comprenant des capsules d'agent traitant
WO2020043836A1 (fr) 2018-08-31 2020-03-05 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides les codant
AU2019341519A1 (en) 2018-09-17 2021-03-18 Dsm Ip Assets B.V. Animal feed compositions and uses thereof
EP4581938A2 (fr) 2018-09-17 2025-07-09 DSM IP Assets B.V. Compositions d'aliments pour animaux et leurs utilisations
MX2021003074A (es) 2018-09-17 2021-06-23 Dsm Ip Assets Bv Composiciones de alimento animal y usos de las mismas.
WO2020058226A1 (fr) 2018-09-17 2020-03-26 Dsm Ip Assets B.V. Compositions d'aliments pour animaux et leurs utilisations
US20210340466A1 (en) 2018-10-01 2021-11-04 Novozymes A/S Detergent compositions and uses thereof
US20230287306A1 (en) 2018-10-02 2023-09-14 Novozymes A/S Cleaning Composition
WO2020070014A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage comprenant un tensioactif anionique et un polypeptide ayant une activité rnase
WO2020070209A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage
EP3861008A1 (fr) 2018-10-03 2021-08-11 Novozymes A/S Polypeptides ayant une activité de dégradation de l'alpha-mannane et polynucléotides codant pour ceux-ci
WO2020070249A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Compositions de nettoyage
EP3864123A1 (fr) 2018-10-09 2021-08-18 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3864122A1 (fr) 2018-10-09 2021-08-18 Novozymes A/S Compositions de nettoyage et leurs utilisations
US20220033739A1 (en) 2018-10-11 2022-02-03 Novozymes A/S Cleaning compositions and uses thereof
ES2981999T3 (es) 2018-10-31 2024-10-14 Henkel Ag & Co Kgaa Composiciones limpiadoras que contienen dispersinas V
EP3647397A1 (fr) 2018-10-31 2020-05-06 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersions iv
WO2020127796A2 (fr) 2018-12-21 2020-06-25 Novozymes A/S Polypeptides ayant une activité de dégradation de peptidoglycane et polynucléotides codant pour ceux-ci
EP3702452A1 (fr) 2019-03-01 2020-09-02 Novozymes A/S Compositions détergentes comprenant deux protéases
CA3122942A1 (fr) 2019-03-21 2020-09-24 Novozymes A/S Variants d'alpha-amylase et polynucleotides codant pour ceux-ci
US12247237B2 (en) 2019-04-10 2025-03-11 Novozymes A/S Polypeptide variants
EP3997202A1 (fr) * 2019-07-12 2022-05-18 Novozymes A/S Émulsions enzymatiques pour détergents
CN114787329A (zh) 2019-08-27 2022-07-22 诺维信公司 洗涤剂组合物
CA3152952A1 (fr) 2019-09-16 2021-03-25 Novozymes A/S Polypeptides dotes d'une activite beta-glucanase et polynucleotides codant pour ces polypeptides
EP4031644A1 (fr) 2019-09-19 2022-07-27 Novozymes A/S Composition détergente
WO2021064068A1 (fr) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprenant au moins deux domaines de liaison aux hydrates de carbone
EP3805346B1 (fr) * 2019-10-08 2024-08-14 The Procter & Gamble Company Procédé de lavage de tissu
WO2021078839A1 (fr) 2019-10-22 2021-04-29 Novozymes A/S Composition d'aliment pour animaux
WO2021097601A1 (fr) * 2019-11-18 2021-05-27 Solvay Sa Particules de blanchiment solides
KR20220119608A (ko) 2019-12-20 2022-08-30 헨켈 아게 운트 코. 카게아아 디스페르신 viii을 포함하는 세정 조성물
CN114829562A (zh) 2019-12-20 2022-07-29 汉高股份有限及两合公司 包含分散蛋白vi的清洁组合物
KR20220119607A (ko) 2019-12-20 2022-08-30 헨켈 아게 운트 코. 카게아아 디스페르신 ix를 포함하는 세정 조성물
EP4077656A2 (fr) 2019-12-20 2022-10-26 Novozymes A/S Polypeptides présentant une activité protéolytique et leur utilisation
AU2020410142A1 (en) 2019-12-20 2022-08-18 Henkel Ag & Co. Kgaa Cleaning composition coprising a dispersin and a carbohydrase
US20240228913A1 (en) 2019-12-23 2024-07-11 Novozymes A/S Enzyme compositions and uses thereof
WO2021148364A1 (fr) 2020-01-23 2021-07-29 Novozymes A/S Compositions enzymatiques et leurs utilisations
US20250002888A1 (en) 2020-01-31 2025-01-02 Novozymes A/S Mannanase variants and polynucleotides encoding same
JP2023511739A (ja) 2020-01-31 2023-03-22 ノボザイムス アクティーゼルスカブ マンナナーゼバリアント及びそれをコードするポリヌクレオチド
WO2021163030A2 (fr) 2020-02-10 2021-08-19 Novozymes A/S Polypeptides ayant une activité alpha-amylase et polynucléotides codant pour ces derniers
DE102020001458A1 (de) * 2020-03-06 2021-09-09 WeylChem Performance Products GmbH Wasch- und Reinigungsmittel, Verfahren zum Desinfizieren und deren Verwendung
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
EP4139431A1 (fr) 2020-04-21 2023-03-01 Novozymes A/S Compositions de nettoyage comprenant des polypeptides ayant une activité de dégradation de fructane
EP4152946A1 (fr) 2020-05-18 2023-03-29 DSM IP Assets B.V. Compositions d'aliments pour animaux
US20230276828A1 (en) 2020-05-18 2023-09-07 Dsm Ip Assets B.V. Animal feed compositions
EP4172298A1 (fr) 2020-06-24 2023-05-03 Novozymes A/S Utilisation de cellulases pour retirer d'un textile les acariens de la poussière
EP3936593A1 (fr) 2020-07-08 2022-01-12 Henkel AG & Co. KGaA Compositions de nettoyage et leurs utilisations
EP4204551A2 (fr) 2020-08-25 2023-07-05 Novozymes A/S Variants de xyloglucanase de la famille 44
WO2022074037A2 (fr) 2020-10-07 2022-04-14 Novozymes A/S Variants d'alpha-amylase
EP4232539A2 (fr) 2020-10-20 2023-08-30 Novozymes A/S Utilisation de polypeptides ayant une activité de dnase
US20230399588A1 (en) 2020-10-28 2023-12-14 Novozymes A/S Use of lipoxygenase
EP4237555A1 (fr) 2020-11-02 2023-09-06 Novozymes A/S Variants de glucoamylase et polynucléotides codant pour ceux-ci
WO2022106404A1 (fr) 2020-11-18 2022-05-27 Novozymes A/S Combinaison de protéases
WO2022106400A1 (fr) 2020-11-18 2022-05-27 Novozymes A/S Combinaison de protéases immunochimiquement différentes
WO2023288294A1 (fr) 2021-07-16 2023-01-19 Novozymes A/S Compositions et procédés pour améliorer la résistance à la pluie de protéines sur des surfaces de plantes
CN116829709A (zh) 2021-02-12 2023-09-29 诺维信公司 α-淀粉酶变体
EP4305146A1 (fr) 2021-03-12 2024-01-17 Novozymes A/S Variants polypeptidiques
WO2022194673A1 (fr) 2021-03-15 2022-09-22 Novozymes A/S Variants de la dnase
EP4060036A1 (fr) 2021-03-15 2022-09-21 Novozymes A/S Variantes de polypeptides
EP4312537A1 (fr) 2021-04-01 2024-02-07 Sterilex LLC Désinfectant/agent d'assainissement pulvérulents sans matière quaternaire
WO2022268885A1 (fr) 2021-06-23 2022-12-29 Novozymes A/S Polypeptides d'alpha-amylase
EP4469545A1 (fr) 2022-01-28 2024-12-04 Unilever IP Holdings B.V. Composition de lessive
WO2023144071A1 (fr) 2022-01-28 2023-08-03 Unilever Ip Holdings B.V. Composition de lessive
WO2023165507A1 (fr) 2022-03-02 2023-09-07 Novozymes A/S Utilisation de xyloglucanase pour l'amélioration de la durabilité de détergents
CN118786210A (zh) 2022-03-04 2024-10-15 诺维信公司 Dna酶变体和组合物
US20250215412A1 (en) 2022-03-08 2025-07-03 Novozymes A/S Fusion Polypeptides with Deamidase Inhibitor and Deamidase Domains
EP4242303A1 (fr) 2022-03-08 2023-09-13 Novozymes A/S Polypeptides de fusion avec inhibiteur de désamidase et domaines de désamidase
CN118974228A (zh) 2022-04-08 2024-11-15 诺维信公司 氨基己糖苷酶变体和组合物
AU2023272468A1 (en) 2022-05-14 2024-11-14 Novonesis Plant Biosolutions A/S Compositions and methods for preventing, treating, supressing and/or eliminating phytopathogenic infestations and infections
EP4544036A1 (fr) 2022-06-21 2025-04-30 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
EP4544015A2 (fr) 2022-06-24 2025-04-30 Novozymes A/S Variants de lipase et compositions comprenant de tels variants de lipase
CN119451664A (zh) 2022-06-30 2025-02-14 诺维信公司 变聚糖酶和包含变聚糖酶的口腔护理组合物
WO2024012912A1 (fr) 2022-07-15 2024-01-18 Novozymes A/S Polypeptides ayant une activité inhibitrice de désamidase
AU2023388516A1 (en) 2022-12-05 2025-04-10 Novozymes A/S Protease variants and polynucleotides encoding same
AU2023389271A1 (en) 2022-12-08 2025-05-22 Novozymes A/S Polypeptide having lysozyme activity and polynucleotides encoding same
WO2024126483A1 (fr) 2022-12-14 2024-06-20 Novozymes A/S Variants de lipase gcl1 améliorés
WO2024137246A1 (fr) 2022-12-19 2024-06-27 Novozymes A/S Polypeptides de la famille 1 d'estérase de glucide (ce1) présentant une activité d'estérase d'acide férulique et/ou d'estérase d'acétyl xylane et polynucléotides codant pour ceux-ci
WO2024137250A1 (fr) 2022-12-19 2024-06-27 Novozymes A/S Polypeptides de la famille 3 de gludice estérase (ce3) présentant une activité acétyl xylane estérase et polynucléotides codant pour ceux-ci
WO2024133497A1 (fr) 2022-12-21 2024-06-27 Novozymes A/S Protéase recombinante pour détachement cellulaire
WO2024133495A1 (fr) 2022-12-21 2024-06-27 Novozymes A/S Protéases microbiennes pour le détachement cellulaire
EP4389865A1 (fr) 2022-12-21 2024-06-26 Novozymes A/S Protéase recombinante pour le détachement cellulaire
WO2024131880A2 (fr) 2022-12-23 2024-06-27 Novozymes A/S Composition détergente comprenant une catalase et une amylase
WO2024156628A1 (fr) 2023-01-23 2024-08-02 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2024175631A1 (fr) 2023-02-22 2024-08-29 Novozymes A/S Composition de soins buccodentaires comprenant une invertase
WO2024213513A1 (fr) 2023-04-12 2024-10-17 Novozymes A/S Compositions comprenant des polypeptides ayant une activité de phosphatase alcaline
WO2024226828A2 (fr) 2023-04-26 2024-10-31 Novozymes A/S Composition de nettoyage et procédé de nettoyage
EP4461795A1 (fr) 2023-05-10 2024-11-13 Novozymes A/S Composition detergente comprenant une laccase
EP4461796A1 (fr) 2023-05-10 2024-11-13 Novozymes A/S Composition detergente comprenant une laccase
WO2025036987A1 (fr) 2023-08-15 2025-02-20 Novozymes A/S Polypeptides ayant une activité phosphatase alcaline pour l'alimentation animale
WO2025045955A1 (fr) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Composition à lessive solide
WO2025045982A1 (fr) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Composition solide pour lessive
WO2025045923A1 (fr) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Composition lessivielle solide
WO2025045968A1 (fr) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Composition lessivielle solide
WO2025045870A1 (fr) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Composition de lessive solide
WO2025045942A1 (fr) 2023-08-30 2025-03-06 Unilever Ip Holdings B.V. Composition de lessive solide
WO2025088003A1 (fr) 2023-10-24 2025-05-01 Novozymes A/S Utilisation de xyloglucanase pour remplacer un azurant optique
WO2025103765A1 (fr) 2023-11-17 2025-05-22 Novozymes A/S Monooxygénases polysaccharidiques lytiques et leur utilisation dans un détergent
WO2025111274A2 (fr) 2023-11-20 2025-05-30 Novozymes A/S Variants d'épimérase et polynucléotides les codant
WO2025113371A2 (fr) 2023-11-30 2025-06-05 Novozymes A/S Composition de soins bucco-dentaires comprenant une peptidase ou une lactonase
WO2025114053A1 (fr) 2023-11-30 2025-06-05 Novozymes A/S Biopolymères destinés à être utilisés dans un détergent
WO2025128568A1 (fr) 2023-12-11 2025-06-19 Novozymes A/S Composition et son utilisation pour augmenter la solubilisation de fibres hémicellulosiques

Citations (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE680847A (fr) 1963-05-27 1966-11-14
US3451935A (en) * 1966-04-25 1969-06-24 Procter & Gamble Granular enzyme-containing laundry composition
US4016040A (en) 1969-12-10 1977-04-05 Colgate-Palmolive Company Preparation of enzyme-containing beads
US4106991A (en) 1976-07-07 1978-08-15 Novo Industri A/S Enzyme granulate composition and process for forming enzyme granulates
US4430243A (en) 1981-08-08 1984-02-07 The Procter & Gamble Company Bleach catalyst compositions and use thereof in laundry bleaching and detergent compositions
US4713245A (en) 1984-06-04 1987-12-15 Mitsui Toatsu Chemicals, Incorporated Granule containing physiologically-active substance, method for preparing same and use thereof
US4760025A (en) 1984-05-29 1988-07-26 Genencor, Inc. Modified enzymes and methods for making same
US4767557A (en) * 1985-06-28 1988-08-30 The Procter & Gamble Company Dry bleach and stable enzyme granular composition
EP0304331A2 (fr) 1987-08-21 1989-02-22 Novo Nordisk A/S Procédé pour la préparation d'un enzyme granulé
WO1989006270A1 (fr) 1988-01-07 1989-07-13 Novo-Nordisk A/S Detergent enzymatique
EP0170360B1 (fr) 1984-05-29 1989-08-09 Novo Nordisk A/S Granulés contenant des enzymes appropriés pour l'utilisation comme additifs détergents
WO1990009440A1 (fr) 1989-02-20 1990-08-23 Novo Nordisk A/S Granule contenant des enzymes et procede de production d'un tel granule
WO1990009428A1 (fr) 1989-02-20 1990-08-23 Novo Nordisk A/S Granule a additifs detergents et procede de production d'un tel granule
EP0304332B1 (fr) 1987-08-21 1993-07-14 Novo Nordisk A/S Granule contenant un enzyme et procédé pour sa préparation
WO1994002597A1 (fr) 1992-07-23 1994-02-03 Novo Nordisk A/S Alpha-amylase mutante, detergent, agent de lavage de vaisselle et de liquefaction
US5324649A (en) 1991-10-07 1994-06-28 Genencor International, Inc. Enzyme-containing granules coated with hydrolyzed polyvinyl alcohol or copolymer thereof
WO1994016064A1 (fr) * 1993-01-18 1994-07-21 Novo Nordisk A/S Granulat contenant en enzyme, procede de production de ce granulat et son utilisation
WO1994018314A1 (fr) 1993-02-11 1994-08-18 Genencor International, Inc. Alpha-amylase stable a l'oxydation
US5352604A (en) 1989-08-25 1994-10-04 Henkel Research Corporation Alkaline proteolytic enzyme and method of production
DE4315397A1 (de) * 1993-05-08 1994-11-10 Henkel Kgaa Reinigungsmittel mit Verhinderung des Anlaufens von Tafelsilber in Geschirrspülmaschinen
WO1996023873A1 (fr) 1995-02-03 1996-08-08 Novo Nordisk A/S Alleles d'amylase-alpha
WO1996023874A1 (fr) 1995-02-03 1996-08-08 Novo Nordisk A/S Technique de mise au point de mutants d'amylase-alpha dotes de proprietes predefinies
US5576282A (en) 1995-09-11 1996-11-19 The Procter & Gamble Company Color-safe bleach boosters, compositions and laundry methods employing same
WO1997000324A1 (fr) 1995-06-14 1997-01-03 Kao Corporation Gene codant une alpha-amylase liquefiante alcaline
US5595967A (en) 1995-02-03 1997-01-21 The Procter & Gamble Company Detergent compositions comprising multiperacid-forming bleach activators
US5597936A (en) 1995-06-16 1997-01-28 The Procter & Gamble Company Method for manufacturing cobalt catalysts
WO1997023606A1 (fr) 1995-12-22 1997-07-03 Genencor International, Inc. Granules enrobees contenant des enzymes
US5679630A (en) 1993-10-14 1997-10-21 The Procter & Gamble Company Protease-containing cleaning compositions
WO1997039116A1 (fr) 1996-04-12 1997-10-23 Novo Nordisk A/S Granules contenant une enzyme et technique de production
WO1997043424A1 (fr) 1996-05-14 1997-11-20 Genencor International, Inc. α-AMYLASES MODIFIEES POSSEDANT DES PROPRIETES MODIFIEES DE FIXATION DU CALCIUM
WO1998017767A1 (fr) 1996-10-18 1998-04-30 The Procter & Gamble Company Compositions detergentes
WO1998039406A1 (fr) 1997-03-07 1998-09-11 The Procter & Gamble Company Compositions de blanchiment
US5856164A (en) 1994-03-29 1999-01-05 Novo Nordisk A/S Alkaline bacillus amylase
WO1999023211A1 (fr) 1997-10-30 1999-05-14 Novo Nordisk A/S Mutants d'alpha-amylase
WO2000001793A1 (fr) 1998-06-30 2000-01-13 Novozymes A/S Nouveau granule ameliore contenant des enzymes
US6020303A (en) 1996-04-16 2000-02-01 The Procter & Gamble Company Mid-chain branched surfactants
WO2000012667A1 (fr) 1998-09-01 2000-03-09 Unilever Plc Composition et procede de blanchiment d'un substrat
US6060443A (en) 1996-04-16 2000-05-09 The Procter & Gamble Company Mid-chain branched alkyl sulfate surfactants
WO2000032601A2 (fr) 1998-11-30 2000-06-08 The Procter & Gamble Company Procede de preparation de tetraaza macrocycles pontes transversalement
US6093562A (en) 1996-02-05 2000-07-25 Novo Nordisk A/S Amylase variants
EP1022334A2 (fr) 1998-12-21 2000-07-26 Kao Corporation Nouvelles amylases
WO2000060060A2 (fr) 1999-03-31 2000-10-12 Novozymes A/S Polypeptides presentant une activite alcaline alpha-amylase et acides nucleiques les codant
US6218351B1 (en) 1998-03-06 2001-04-17 The Procter & Gamble Compnay Bleach compositions
US6225464B1 (en) 1997-03-07 2001-05-01 The Procter & Gamble Company Methods of making cross-bridged macropolycycles
US6268329B1 (en) 1998-06-30 2001-07-31 Nouozymes A/S Enzyme containing granule
US6306812B1 (en) 1997-03-07 2001-10-23 Procter & Gamble Company, The Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids
US6312936B1 (en) 1997-10-23 2001-11-06 Genencor International, Inc. Multiply-substituted protease variants
US6326348B1 (en) 1996-04-16 2001-12-04 The Procter & Gamble Co. Detergent compositions containing selected mid-chain branched surfactants
US6602841B1 (en) 1997-12-20 2003-08-05 Genencor International, Inc. Granule with hydrated barrier material
US20040033927A1 (en) 2002-07-01 2004-02-19 Novozymes A/S Stabilization of granules
WO2005052161A2 (fr) 2003-11-19 2005-06-09 Genencor International, Inc. Serine proteases, acides nucleiques codant des enzymes de serine et vecteurs et cellules hotes les integrant
US6939702B1 (en) 1999-03-31 2005-09-06 Novozymes A/S Lipase variant
WO2006002643A2 (fr) 2004-07-05 2006-01-12 Novozymes A/S Variants d'alpha-amylases presentant des proprietes modifiees
US7153818B2 (en) 2000-07-28 2006-12-26 Henkel Kgaa Amylolytic enzyme extracted from bacillus sp. A 7-7 (DSM 12368) and washing and cleaning agents containing this novel amylolytic enzyme
WO2007044993A2 (fr) 2005-10-12 2007-04-19 Genencor International, Inc. Utilisation et production d'une metalloprotease neutre stable au stockage
US7208459B2 (en) 2004-06-29 2007-04-24 The Procter & Gamble Company Laundry detergent compositions with efficient hueing dye
US20070173430A1 (en) 2006-01-23 2007-07-26 The Procter & Gamble Company Composition comprising a lipase and a bleach catalyst
US7262042B2 (en) 2001-12-20 2007-08-28 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Alkaline protease from Bacillus gibsonii (DSM 14393) and washing and cleaning products comprising said alkaline protease
US7273736B2 (en) 1999-10-01 2007-09-25 Novozymes A/S Method for preparing an enzyme containing granule
WO2007147698A1 (fr) 2006-06-19 2007-12-27 Unilever Plc Composition pour laver le linge en machine
US20080305982A1 (en) 2007-06-11 2008-12-11 Johan Smets Benefit agent containing delivery particle
WO2009021867A2 (fr) 2007-08-10 2009-02-19 Henkel Ag & Co. Kgaa Agents contenant des protéases
US7501389B2 (en) 2003-10-31 2009-03-10 Conopco Inc. Bispidon-derivated ligands and complexes thereof for catalytically bleaching a substrate
US20090217464A1 (en) 2008-02-29 2009-09-03 Philip Frank Souter Detergent composition comprising lipase
US20090247449A1 (en) 2008-03-26 2009-10-01 John Allen Burdis Delivery particle

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5950280B2 (ja) * 1980-10-24 1984-12-07 花王株式会社 酵素入り漂白剤組成物
US4404128A (en) 1981-05-29 1983-09-13 The Procter & Gamble Company Enzyme detergent composition
US4391723A (en) 1981-07-13 1983-07-05 The Procter & Gamble Company Controlled release laundry bleach product
DE3682443D1 (de) * 1985-06-28 1991-12-19 Procter & Gamble Granulierte zusammensetzung enthaltend ein trockenes bleichmittel und ein stabiles enzym.
US5318714A (en) * 1988-03-14 1994-06-07 Novo Nordisk A/S Stabilized particulate composition
GB9407533D0 (en) * 1994-04-13 1994-06-08 Procter & Gamble Detergent compositions
AUPN502195A0 (en) * 1995-08-25 1995-09-14 Procter & Gamble Company, The Detergent composition with bleach system stabilized by enzymes
JP2002513563A (ja) * 1998-05-01 2002-05-14 ザ、プロクター、エンド、ギャンブル、カンパニー 修飾トランスフェラーゼを含有した洗濯洗剤および／または布帛ケア組成物
DE69908139T2 (de) * 1998-07-17 2004-04-08 The Procter & Gamble Company, Cincinnati Waschmitteltabletten und deren Herstellung
WO2001004279A1 (fr) * 1999-07-09 2001-01-18 Novozymes A/S Procede permettant de preparer un enzyme contenant un granule
US20050187131A1 (en) 2004-02-23 2005-08-25 The Procter & Gamble Company Granular laundry detergent composition comprising a ternary detersive surfactant system and low levels of, or no, zeolite builders and phosphate builders
US20050187130A1 (en) * 2004-02-23 2005-08-25 Brooker Alan T. Granular laundry detergent composition comprising an anionic detersive surfactant, and low levels of, or no, zeolite builders and phosphate builders
JP2009523904A (ja) * 2006-01-23 2009-06-25 ザ プロクター アンド ギャンブル カンパニー リパーゼと漂白剤触媒を含む組成物
DE102006018780A1 (de) * 2006-04-20 2007-10-25 Henkel Kgaa Granulat eines sensitiven Wasch- oder Reinigungsmittelinhaltsstoffs
EP2129757A2 (fr) * 2007-01-11 2009-12-09 Novozymes A/S Particules comprenant des composés actifs
WO2009102770A1 (fr) * 2008-02-14 2009-08-20 Danisco Us Inc., Genencor Division Petits granulés contenant une enzyme
CN101970631B (zh) * 2008-03-14 2012-10-10 荷兰联合利华有限公司 洗衣处理组合物
EP2377914B1 (fr) 2010-04-19 2016-11-09 The Procter & Gamble Company Composition de détergent solide à faible teneur en adjuvants pour le traitement des tissus comprenant de la perhydrolase
EP2502980A1 (fr) 2011-03-25 2012-09-26 The Procter & Gamble Company Particules de détergent pour le lavage du linge, séchées par atomisation

Patent Citations (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE680847A (fr) 1963-05-27 1966-11-14
US3451935A (en) * 1966-04-25 1969-06-24 Procter & Gamble Granular enzyme-containing laundry composition
US4016040A (en) 1969-12-10 1977-04-05 Colgate-Palmolive Company Preparation of enzyme-containing beads
US4106991A (en) 1976-07-07 1978-08-15 Novo Industri A/S Enzyme granulate composition and process for forming enzyme granulates
US4430243A (en) 1981-08-08 1984-02-07 The Procter & Gamble Company Bleach catalyst compositions and use thereof in laundry bleaching and detergent compositions
EP0170360B1 (fr) 1984-05-29 1989-08-09 Novo Nordisk A/S Granulés contenant des enzymes appropriés pour l'utilisation comme additifs détergents
US4760025A (en) 1984-05-29 1988-07-26 Genencor, Inc. Modified enzymes and methods for making same
US4713245A (en) 1984-06-04 1987-12-15 Mitsui Toatsu Chemicals, Incorporated Granule containing physiologically-active substance, method for preparing same and use thereof
US4767557A (en) * 1985-06-28 1988-08-30 The Procter & Gamble Company Dry bleach and stable enzyme granular composition
EP0304332B1 (fr) 1987-08-21 1993-07-14 Novo Nordisk A/S Granule contenant un enzyme et procédé pour sa préparation
EP0304331A2 (fr) 1987-08-21 1989-02-22 Novo Nordisk A/S Procédé pour la préparation d'un enzyme granulé
WO1989006270A1 (fr) 1988-01-07 1989-07-13 Novo-Nordisk A/S Detergent enzymatique
WO1990009440A1 (fr) 1989-02-20 1990-08-23 Novo Nordisk A/S Granule contenant des enzymes et procede de production d'un tel granule
WO1990009428A1 (fr) 1989-02-20 1990-08-23 Novo Nordisk A/S Granule a additifs detergents et procede de production d'un tel granule
US5352604A (en) 1989-08-25 1994-10-04 Henkel Research Corporation Alkaline proteolytic enzyme and method of production
US5324649A (en) 1991-10-07 1994-06-28 Genencor International, Inc. Enzyme-containing granules coated with hydrolyzed polyvinyl alcohol or copolymer thereof
WO1994002597A1 (fr) 1992-07-23 1994-02-03 Novo Nordisk A/S Alpha-amylase mutante, detergent, agent de lavage de vaisselle et de liquefaction
WO1994016064A1 (fr) * 1993-01-18 1994-07-21 Novo Nordisk A/S Granulat contenant en enzyme, procede de production de ce granulat et son utilisation
WO1994018314A1 (fr) 1993-02-11 1994-08-18 Genencor International, Inc. Alpha-amylase stable a l'oxydation
DE4315397A1 (de) * 1993-05-08 1994-11-10 Henkel Kgaa Reinigungsmittel mit Verhinderung des Anlaufens von Tafelsilber in Geschirrspülmaschinen
US5679630A (en) 1993-10-14 1997-10-21 The Procter & Gamble Company Protease-containing cleaning compositions
US5856164A (en) 1994-03-29 1999-01-05 Novo Nordisk A/S Alkaline bacillus amylase
WO1996023873A1 (fr) 1995-02-03 1996-08-08 Novo Nordisk A/S Alleles d'amylase-alpha
WO1996023874A1 (fr) 1995-02-03 1996-08-08 Novo Nordisk A/S Technique de mise au point de mutants d'amylase-alpha dotes de proprietes predefinies
US5595967A (en) 1995-02-03 1997-01-21 The Procter & Gamble Company Detergent compositions comprising multiperacid-forming bleach activators
WO1997000324A1 (fr) 1995-06-14 1997-01-03 Kao Corporation Gene codant une alpha-amylase liquefiante alcaline
US5597936A (en) 1995-06-16 1997-01-28 The Procter & Gamble Company Method for manufacturing cobalt catalysts
US5576282A (en) 1995-09-11 1996-11-19 The Procter & Gamble Company Color-safe bleach boosters, compositions and laundry methods employing same
WO1997023606A1 (fr) 1995-12-22 1997-07-03 Genencor International, Inc. Granules enrobees contenant des enzymes
US6093562A (en) 1996-02-05 2000-07-25 Novo Nordisk A/S Amylase variants
WO1997039116A1 (fr) 1996-04-12 1997-10-23 Novo Nordisk A/S Granules contenant une enzyme et technique de production
US6020303A (en) 1996-04-16 2000-02-01 The Procter & Gamble Company Mid-chain branched surfactants
US6326348B1 (en) 1996-04-16 2001-12-04 The Procter & Gamble Co. Detergent compositions containing selected mid-chain branched surfactants
US6060443A (en) 1996-04-16 2000-05-09 The Procter & Gamble Company Mid-chain branched alkyl sulfate surfactants
WO1997043424A1 (fr) 1996-05-14 1997-11-20 Genencor International, Inc. α-AMYLASES MODIFIEES POSSEDANT DES PROPRIETES MODIFIEES DE FIXATION DU CALCIUM
WO1998017767A1 (fr) 1996-10-18 1998-04-30 The Procter & Gamble Company Compositions detergentes
WO1998039406A1 (fr) 1997-03-07 1998-09-11 The Procter & Gamble Company Compositions de blanchiment
US6225464B1 (en) 1997-03-07 2001-05-01 The Procter & Gamble Company Methods of making cross-bridged macropolycycles
US6306812B1 (en) 1997-03-07 2001-10-23 Procter & Gamble Company, The Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids
US6312936B1 (en) 1997-10-23 2001-11-06 Genencor International, Inc. Multiply-substituted protease variants
WO1999023211A1 (fr) 1997-10-30 1999-05-14 Novo Nordisk A/S Mutants d'alpha-amylase
US20080206830A1 (en) 1997-12-20 2008-08-28 Becker Nathaniel T Granule with hydrated barrier material
US6602841B1 (en) 1997-12-20 2003-08-05 Genencor International, Inc. Granule with hydrated barrier material
US6218351B1 (en) 1998-03-06 2001-04-17 The Procter & Gamble Compnay Bleach compositions
US6268329B1 (en) 1998-06-30 2001-07-31 Nouozymes A/S Enzyme containing granule
WO2000001793A1 (fr) 1998-06-30 2000-01-13 Novozymes A/S Nouveau granule ameliore contenant des enzymes
US6348442B2 (en) 1998-06-30 2002-02-19 Novozymes A/S Enzyme containing granule
WO2000012667A1 (fr) 1998-09-01 2000-03-09 Unilever Plc Composition et procede de blanchiment d'un substrat
WO2000032601A2 (fr) 1998-11-30 2000-06-08 The Procter & Gamble Company Procede de preparation de tetraaza macrocycles pontes transversalement
EP1022334A2 (fr) 1998-12-21 2000-07-26 Kao Corporation Nouvelles amylases
US6939702B1 (en) 1999-03-31 2005-09-06 Novozymes A/S Lipase variant
WO2000060060A2 (fr) 1999-03-31 2000-10-12 Novozymes A/S Polypeptides presentant une activite alcaline alpha-amylase et acides nucleiques les codant
US7273736B2 (en) 1999-10-01 2007-09-25 Novozymes A/S Method for preparing an enzyme containing granule
US7153818B2 (en) 2000-07-28 2006-12-26 Henkel Kgaa Amylolytic enzyme extracted from bacillus sp. A 7-7 (DSM 12368) and washing and cleaning agents containing this novel amylolytic enzyme
US7262042B2 (en) 2001-12-20 2007-08-28 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Alkaline protease from Bacillus gibsonii (DSM 14393) and washing and cleaning products comprising said alkaline protease
US20040033927A1 (en) 2002-07-01 2004-02-19 Novozymes A/S Stabilization of granules
US7501389B2 (en) 2003-10-31 2009-03-10 Conopco Inc. Bispidon-derivated ligands and complexes thereof for catalytically bleaching a substrate
WO2005052161A2 (fr) 2003-11-19 2005-06-09 Genencor International, Inc. Serine proteases, acides nucleiques codant des enzymes de serine et vecteurs et cellules hotes les integrant
WO2005052146A2 (fr) 2003-11-19 2005-06-09 Genencor International, Inc. Serine proteases, acides nucleiques codants pour les enzymes a serine et vecteurs et cellules hotes les contenant
US7208459B2 (en) 2004-06-29 2007-04-24 The Procter & Gamble Company Laundry detergent compositions with efficient hueing dye
WO2006002643A2 (fr) 2004-07-05 2006-01-12 Novozymes A/S Variants d'alpha-amylases presentant des proprietes modifiees
WO2007044993A2 (fr) 2005-10-12 2007-04-19 Genencor International, Inc. Utilisation et production d'une metalloprotease neutre stable au stockage
US20070173430A1 (en) 2006-01-23 2007-07-26 The Procter & Gamble Company Composition comprising a lipase and a bleach catalyst
WO2007147698A1 (fr) 2006-06-19 2007-12-27 Unilever Plc Composition pour laver le linge en machine
US20080305982A1 (en) 2007-06-11 2008-12-11 Johan Smets Benefit agent containing delivery particle
WO2009021867A2 (fr) 2007-08-10 2009-02-19 Henkel Ag & Co. Kgaa Agents contenant des protéases
US20090217464A1 (en) 2008-02-29 2009-09-03 Philip Frank Souter Detergent composition comprising lipase
US20090247449A1 (en) 2008-03-26 2009-10-01 John Allen Burdis Delivery particle

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
MICHAEL S. SHOWELL: "Powdered detergents", vol. 71, 1998, MARCEL DEKKER, pages: 140 - 142
MICHAEL S. SHOWELL: "Surfactant Science Series", vol. 71, 1998, MARCEL DEKKER, article "Powdered detergents", pages: 140 - 142

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014068109A3 (fr) * 2012-11-05 2014-08-28 Novozymes A/S Compositions d'enzyme permettant la réutilisation d'eau dans une lessive
WO2015057619A1 (fr) * 2013-10-15 2015-04-23 Danisco Us Inc. Granulé d'argile
CN105705622A (zh) * 2013-10-15 2016-06-22 丹尼斯科美国公司 粘土粒料
US20160244699A1 (en) * 2013-10-15 2016-08-25 Danisco Us Inc. Clay Granule
EP3037512A1 (fr) * 2014-12-22 2016-06-29 The Procter and Gamble Company Procédé pour le recyclage de sachets de détergent
WO2016106108A1 (fr) * 2014-12-22 2016-06-30 The Procter & Gamble Company Procédé de recyclage de sachets de détergent
US9938488B2 (en) 2014-12-22 2018-04-10 The Procter & Gamble Company Process for recycling detergent pouches
WO2017037097A1 (fr) * 2015-09-01 2017-03-09 Novozymes A/S Procédé de lessive
GB2544470A (en) * 2015-11-16 2017-05-24 Reckitt Benckiser Vanish Bv Composition
GB2544470B (en) * 2015-11-16 2019-06-05 Reckitt Benckiser Vanish Bv Laundry composition
WO2018083093A1 (fr) * 2016-11-01 2018-05-11 Novozymes A/S Granules à noyaux multiples
US11753605B2 (en) 2016-11-01 2023-09-12 Novozymes A/S Multi-core granules

Also Published As

Publication number Publication date
DK2674476T4 (da) 2022-01-03
BR112014030417A2 (pt) 2017-06-27
CN104364364A (zh) 2015-02-18
BR112014030417B1 (pt) 2024-02-27
RU2014149582A (ru) 2016-07-10
EP2674476A1 (fr) 2013-12-18
DK2674476T3 (en) 2018-07-16
IN2014DN10427A (fr) 2015-08-21
RU2612142C2 (ru) 2017-03-02
TR201809430T4 (tr) 2018-07-23
MX2014015172A (es) 2015-02-17
BR112014030417A8 (pt) 2021-04-13
ES2674940T3 (es) 2018-07-05
ES2674940T5 (es) 2022-03-17
ZA201408580B (en) 2017-04-26
MX370587B (es) 2019-12-17
EP2674476B1 (fr) 2018-04-18
JP2015528828A (ja) 2015-10-01
PL2674476T5 (pl) 2021-12-27
HUE038095T2 (hu) 2018-10-29
CN111205939A (zh) 2020-05-29
WO2013188331A1 (fr) 2013-12-19
EP2674476B2 (fr) 2021-11-10
PL2674476T3 (pl) 2018-09-28

Similar Documents

Publication Publication Date Title
EP2674476B1 (fr) Composition détergente
US9752103B2 (en) Detergent composition
EP3088506B1 (fr) Composition de detergent
EP3088505B1 (fr) Procédé de traitement d'un textile
EP2828339B1 (fr) Colorants carboxilate
EP2814934B1 (fr) Colorants pour des compositions d'entretien du linge
EP2714880B1 (fr) Procede d'entretien du linge avec des colorants
US9834682B2 (en) Laundry care composition comprising carboxylate dye
US9267098B2 (en) Laundry care composition comprising carboxylate dye
US20120322708A1 (en) Consumer products
EP3047010B1 (fr) Compositions d'entretien du linge contenant des colorants à base de thiophène azo carboxylate
US20180134995A1 (en) Laundry Care Compositions Containing Dyes
EP3047009B1 (fr) Composition d'entretien du linge comprenant un colorant carboxylate
EP3047007B1 (fr) Composition de soins du linge comprenant un colorant carboxylate
EP3047008B1 (fr) Composition d'entretien du linge comprenant un colorant carboxylate

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20140619