EP1397473A1 - Paraffinzusammensetzung und ihre anwendung in laternen oder anderen behältern - Google Patents
Paraffinzusammensetzung und ihre anwendung in laternen oder anderen behälternInfo
- Publication number
- EP1397473A1 EP1397473A1 EP02727679A EP02727679A EP1397473A1 EP 1397473 A1 EP1397473 A1 EP 1397473A1 EP 02727679 A EP02727679 A EP 02727679A EP 02727679 A EP02727679 A EP 02727679A EP 1397473 A1 EP1397473 A1 EP 1397473A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- paraffin
- less
- candle
- combustion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 239000012188 paraffin wax Substances 0.000 title claims abstract description 40
- 239000011521 glass Substances 0.000 title claims description 11
- 230000008018 melting Effects 0.000 claims abstract description 12
- 238000002844 melting Methods 0.000 claims abstract description 12
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 8
- 229920001577 copolymer Polymers 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 5
- 229930195729 fatty acid Natural products 0.000 claims abstract description 5
- 239000000194 fatty acid Substances 0.000 claims abstract description 5
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 5
- 230000000295 complement effect Effects 0.000 claims abstract description 4
- 235000004977 Brassica sinapistrum Nutrition 0.000 claims description 5
- 244000188595 Brassica sinapistrum Species 0.000 claims description 4
- 229920001567 vinyl ester resin Polymers 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 22
- 239000003517 fume Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C5/00—Candles
- C11C5/008—Candles characterised by their form; Composite candles, e.g. candles containing zones of different composition, inclusions, or the like
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C5/00—Candles
- C11C5/002—Ingredients
Definitions
- the present invention relates to a new paraffin composition and its use as a main constituent for candles with improved burning time, arranged in particular in a glass enclosure or other containers.
- paraffin composition suitable for use as a lighting candle in a verrine is a complex operation, since many parameters must be taken into account, such as the quality and the rate of combustion, the latter being directly related to the point. of paraffin fusion.
- the objective sought is, in fact, to obtain a complete, but as slow as possible, combustion of the combustible mass, including along the wall of the glass, with an illuminating and smokeless flame, despite the low speed. of combustion sought.
- a candle composition which burns in a regular manner producing a luminous flame, of a satisfactory height, and without fumes, which is not likely to extinguish following an insufficient air supply. .
- the combustion speed then becomes too high, which reduces the life of the candle, and it turns out to be necessary to incorporate, in the paraffin composition, an additive capable of reducing its combustion speed, without altering either the ability of the candle to melt at low temperature, nor the quality of its combustion, in particular, the absence of production of black smoke.
- the present invention proposes to solve and it aims to propose for this purpose a paraffin composition usable as a candle in verrines, or any other type of container, with a relatively large cross section, which lends itself to combustion. very slow and perfectly regular, and whose flame causes the fusion along its entire upper surface, even when the glass enclosure has large transverse dimensions, without causing emission of fumes.
- the invention also aims to provide such a paraffin composition, which, used in a verrine or a container of large dimensions, has a burning time much greater than that of the compositions of the prior art.
- the invention finally aims to provide a composition of this type, capable of burning over long periods without risk of extinction and without production of fumes.
- the subject of the invention is a paraffin composition which can be used as a candle with a long burning time, characterized in that it comprises:
- a copolymer of the monoolefin-vinyl ester type intended to limit the rate of melting of the paraffin, the content of which by weight in the paraffin composition is less than 10% and, preferably, less than 7.5%; - A complement to 100% by weight of the composition consisting of at least one paraffin having a melting point of less than 65 ° C, and preferably less than 58 ° C, and possibly, the usual additives in such compositions.
- methyl ester of at least one fatty acid it is advantageously possible to use a mixture of methyl esters of rapeseed.
- the copolymer used of the monoolefin-vinyl ester type is advantageously an ethylene vinyl acetate copolymer or in short E.V.A.
- the additives used may be present in amounts generally less than 10% and preferably less than 5% by weight of the paraffin composition and include a colorant, a perfume, an insecticide, a surface-improving agent composition or others.
- the complement to 100% of the composition is produced with a paraffin of petroleum or other origin, with a low melting point of less than
- the total burning time of such a paraffin-based composition, equipped with an appropriate wick, in a verrine or other cylindrical container of large diameter and great height can reach, or even exceed, 12 days without incident.
- the invention also relates to the use of such a paraffin composition in a verrine or other container.
- paraffin composition in accordance with the invention has the following formulation, in% by weight:
- E.V.A an ethylene vinyl acetate copolymer, abbreviated as E.V.A., intended to slow down the rate of combustion (trade name OKERIM® 5415 H or equivalent): 5%.
- Table 1 Characteristics of paraffin with a low melting point.
- the RADIA® 7961 used is a mixture of rapeseed methyl esters, the characteristics of which are given in Table 2.
- OKERIM® 5415H is a blend of E.V.A copolymers. , usually used as a modifier of the crystalline properties of hydrocarbon paraffins (see Table 3)
- a candle was made comprising a wick armed with tin number 3, the combustion speed of which is 3 g / h and which is housed in a 30 cm glass cylindrical container of height and 8.5 cm in diameter.
- the glass thus produced has a total burning time of at least 12 days.
- the combustion of the paraffin composition is complete, including along the glass wall, the heat of the flame proving sufficient to melt the composition along its entire upper surface.
- the resulting flame is bright and smoke-free and it lights up satisfactorily, despite the low rate of combustion of the composition.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Fats And Perfumes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0105493A FR2823760B1 (fr) | 2001-04-24 | 2001-04-24 | Nouvelle composition de paraffine et son utilisation dans des verrines ou autres contenants |
FR0105493 | 2001-04-24 | ||
PCT/FR2002/001347 WO2002086040A1 (fr) | 2001-04-24 | 2002-04-19 | Nouvelle composition de paraffine et son utilisation dans des verrines ou autres contenants |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1397473A1 true EP1397473A1 (de) | 2004-03-17 |
EP1397473B1 EP1397473B1 (de) | 2004-10-13 |
Family
ID=8862625
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02727679A Expired - Lifetime EP1397473B1 (de) | 2001-04-24 | 2002-04-19 | Paraffinzusammensetzung und ihre anwendung in laternen oder anderen behältern |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1397473B1 (de) |
AT (1) | ATE279498T1 (de) |
DE (1) | DE60201605T2 (de) |
FR (1) | FR2823760B1 (de) |
HU (1) | HUP0303979A3 (de) |
PL (1) | PL363268A1 (de) |
WO (1) | WO2002086040A1 (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2847261B1 (fr) * | 2002-11-14 | 2006-11-24 | Totalfinaelf France | Composition de paraffines et leur utilisation pour la fabrication de bougies |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9222458D0 (en) * | 1992-10-26 | 1992-12-09 | Exxon Chemical Patents Inc | Oil additives and compositions |
AT402073B (de) * | 1995-03-28 | 1997-01-27 | Glasner Alfred | Verfahren zur herstellung von sicherheitskerzen |
JPH10237481A (ja) * | 1997-02-24 | 1998-09-08 | Nippon Oil Co Ltd | ろうそく用ワックス組成物 |
-
2001
- 2001-04-24 FR FR0105493A patent/FR2823760B1/fr not_active Expired - Lifetime
-
2002
- 2002-04-19 HU HU0303979A patent/HUP0303979A3/hu unknown
- 2002-04-19 WO PCT/FR2002/001347 patent/WO2002086040A1/fr not_active Application Discontinuation
- 2002-04-19 EP EP02727679A patent/EP1397473B1/de not_active Expired - Lifetime
- 2002-04-19 DE DE60201605T patent/DE60201605T2/de not_active Expired - Fee Related
- 2002-04-19 AT AT02727679T patent/ATE279498T1/de not_active IP Right Cessation
- 2002-04-19 PL PL02363268A patent/PL363268A1/xx not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO02086040A1 * |
Also Published As
Publication number | Publication date |
---|---|
ATE279498T1 (de) | 2004-10-15 |
WO2002086040A1 (fr) | 2002-10-31 |
DE60201605D1 (de) | 2004-11-18 |
FR2823760B1 (fr) | 2004-05-28 |
EP1397473B1 (de) | 2004-10-13 |
FR2823760A1 (fr) | 2002-10-25 |
DE60201605T2 (de) | 2005-11-03 |
PL363268A1 (en) | 2004-11-15 |
HUP0303979A2 (hu) | 2004-03-01 |
HUP0303979A3 (en) | 2008-03-28 |
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