EP0632423A2 - Panneau pour le positionnement, la fixation et le détachement répétitif de feuilles non-autoadhésives - Google Patents
Panneau pour le positionnement, la fixation et le détachement répétitif de feuilles non-autoadhésives Download PDFInfo
- Publication number
- EP0632423A2 EP0632423A2 EP94109803A EP94109803A EP0632423A2 EP 0632423 A2 EP0632423 A2 EP 0632423A2 EP 94109803 A EP94109803 A EP 94109803A EP 94109803 A EP94109803 A EP 94109803A EP 0632423 A2 EP0632423 A2 EP 0632423A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- adhesive
- substrate
- board according
- panel
- self
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000853 adhesive Substances 0.000 claims abstract description 72
- 239000000758 substrate Substances 0.000 claims abstract description 72
- 230000001070 adhesive effect Effects 0.000 claims abstract description 42
- 239000004831 Hot glue Substances 0.000 claims abstract description 41
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 21
- 239000006185 dispersion Substances 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 5
- 239000004744 fabric Substances 0.000 claims description 27
- 239000013039 cover film Substances 0.000 claims description 22
- 229920000728 polyester Polymers 0.000 claims description 14
- 239000004952 Polyamide Substances 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 11
- 229920002647 polyamide Polymers 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000011111 cardboard Substances 0.000 claims description 8
- -1 copolyamide Polymers 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 7
- 239000000123 paper Substances 0.000 claims description 7
- 239000012209 synthetic fiber Substances 0.000 claims description 7
- 229920002994 synthetic fiber Polymers 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 150000002736 metal compounds Chemical class 0.000 claims description 6
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 239000002985 plastic film Substances 0.000 claims description 5
- 229920006255 plastic film Polymers 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000004840 adhesive resin Substances 0.000 claims description 4
- 229920006223 adhesive resin Polymers 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 229920003051 synthetic elastomer Polymers 0.000 claims description 3
- 239000005061 synthetic rubber Substances 0.000 claims description 3
- 229920001634 Copolyester Polymers 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 239000007799 cork Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 239000002649 leather substitute Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
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- 229920002635 polyurethane Polymers 0.000 claims description 2
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- 239000000463 material Substances 0.000 abstract description 19
- 238000000034 method Methods 0.000 description 15
- 238000007639 printing Methods 0.000 description 13
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- 229920000573 polyethylene Polymers 0.000 description 10
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- 238000007650 screen-printing Methods 0.000 description 9
- 239000004793 Polystyrene Substances 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 238000007646 gravure printing Methods 0.000 description 6
- 229920002223 polystyrene Polymers 0.000 description 6
- 239000003351 stiffener Substances 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical class O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 239000011087 paperboard Substances 0.000 description 5
- 238000010022 rotary screen printing Methods 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical class OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 239000002390 adhesive tape Substances 0.000 description 4
- 238000007645 offset printing Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 238000007644 letterpress printing Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920001944 Plastisol Polymers 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000002723 alicyclic group Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000004999 plastisol Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- ATLWFAZCZPSXII-UHFFFAOYSA-N (2-octylphenyl) 2-hydroxybenzoate Chemical compound CCCCCCCCC1=CC=CC=C1OC(=O)C1=CC=CC=C1O ATLWFAZCZPSXII-UHFFFAOYSA-N 0.000 description 1
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical compound C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 description 1
- UIFVCPMLQXKEEU-UHFFFAOYSA-N 2,3-dimethylbenzaldehyde Chemical compound CC1=CC=CC(C=O)=C1C UIFVCPMLQXKEEU-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical class COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
- FXTXRXXCMFFRTL-UHFFFAOYSA-N 4-ethyl-2-methylideneoctanoic acid Chemical compound CCCCC(CC)CC(=C)C(O)=O FXTXRXXCMFFRTL-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KFFQABQEJATQAT-UHFFFAOYSA-N N,N'-dibutylthiourea Chemical compound CCCCNC(=S)NCCCC KFFQABQEJATQAT-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 241001085205 Prenanthella exigua Species 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000007774 anilox coating Methods 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
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- 229920000359 diblock copolymer Polymers 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical class CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 150000003097 polyterpenes Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
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- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F7/00—Signs, name or number plates, letters, numerals, or symbols; Panels or boards
- G09F7/02—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols
- G09F7/12—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F7/00—Signs, name or number plates, letters, numerals, or symbols; Panels or boards
- G09F7/02—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols
- G09F7/12—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like
- G09F2007/127—Signs, plates, panels or boards using readily-detachable elements bearing or forming symbols the elements being secured or adapted to be secured by self-adhesion, moisture, suction, slow-drying adhesive or the like by adhesive
Definitions
- the invention relates to a board for the repeatable positioning, fixing and redetachment of fabrics.
- the fabrics consist of a very thin, very flexible and smooth material, such as soft PVC.
- the board must also have a very smooth surface. Adhesive forces arise when the fabrics are positioned on the board. Since the fabrics only have a thickness in the range of 100 ⁇ m to 200 ⁇ m have, it is often cumbersome to remove the fabrics again. Furthermore, the requirements for adhering the fabrics to a smooth board surface are very extensive. Only a special material, such as soft PVC, which is also very flexible, can be used for the fabrics. The surface of the board must be clean of dirt and grease. Furthermore, the adhesive forces often decrease after some time, so that the fabrics detach at least partially from the panel.
- Adhesive forces of this kind are also very low, so that the sheetlike structures can easily detach under mechanical influence, such as during transport.
- the fabrics made of a very thin material are not easy to handle, and moving the fabrics on a surface such as a smooth table is also difficult.
- the object of the present invention is to provide a table and a set of table and fabrics with which the above-mentioned problems of the prior art can be avoided.
- the solution to the above problem is to create a board with a non-permanently self-adhesive, reversibly adhesive pressure-sensitive adhesive coating and to use non-self-adhesive sheets.
- the invention provides a board for the repeatable positioning, fixing and redetachment of non-self-adhesive sheets, the board comprising a substrate provided with a non-permanently self-adhesive pressure-sensitive adhesive coating.
- the non-permanently self-adhesive pressure-sensitive adhesive coating can be applied over the entire surface or partially on the substrate.
- the non-permanently self-adhesive pressure-sensitive adhesive coating consists of grid-shaped, preferably punctiform, dome-shaped adhesion points applied to the substrate, the base of which is firmly connected to the substrate.
- a pressure-sensitive adhesive coating on the one hand an excellent adhesive force can be achieved, at the same time the non-self-adhesive fabrics can be removed again without leaving any residue, i.e. without the adhesive sticking to them when the fabrics are removed.
- An additional adhesion-promoting layer between the dome-shaped adhesion points and the substrate can be particularly favorable.
- the adhesive layer can e.g. are made of rubber.
- the approximately hemispherical surfaces of the spherical caps face the flat structures to be positioned and fixed and enable the advantages of pressure-sensitive adhesive described above with regard to reversible, residue-free detachable bonding.
- the dome-shaped adhesive spots are applied to the substrate by gravure, flexographic or screen printing, with rotary screen printing being particularly preferred.
- An advantageous embodiment of the pressure sensitive adhesive coating comprises a hot melt adhesive which is not present in a carrier system before the coating, that is to say is applied without a carrier system.
- the hot melt adhesive is not dispersed or emulsified and is therefore not used for the coating in the form of a dispersion, emulsion, an organosol or a plastisol.
- the hot melt adhesive may contain additives such as e.g. Adhesive resins, plasticizers, viscosity reducing agents, stabilizers, and fillers.
- a particularly high bond strength and nonetheless residue-free removability can be obtained if a hot melt adhesive of the above type is used as the pressure sensitive adhesive, is applied to the substrate in a grid-like manner with dome-shaped adhesion points, and the ratio of the base area of the dome-shaped adhesion points to their height is in the range of 5: 1 to 30: 1 and preferably from 10: 1 to 25: 1 is observed.
- the base diameter of the dome-shaped adhesion points is preferably in the range from 80 to 500 ⁇ m, with 100 to 400 ⁇ m being particularly preferred.
- the dome-shaped traps are preferably applied to the substrate in a punctiform manner.
- the hot melt adhesive itself preferably consists of thermoplastic backbone polymers, such as natural rubber; synthetic rubber, such as SBS, SIS, SEBS (styrene / ethylene / butadiene / styrene), SEPS (styrene / ethylene / propylene / styrene) (Triblock copolymers) and SB, SI, S-EP (diblock copolymers); Polyolefins such as atactic PP, ethylene-propylene-butadiene copolymer; Polyacrylates, such as polybutyl acrylic acid ester, poly (2-ethylhexyl acrylic acid ester), polymethacrylic acid esters and their copolymers with, for example, acrylic acid, methacrylic acid, vinyl acetate, maleic anhydride, diacetone acrylamide or acrylonitrile; Polyvinyl derivatives such as ethylene-vinyl acetate copolymer, (1-vinyl-2-pyrrol
- Suitable adhesive resins are e.g. aliphatic, alicyclic and aromatic hydrocarbons; Polyterpenes; Rosin esters such as rosin glycerin esters, hydrogenated rosin pentaerythritol esters, polymerized rosin diethylene glycol esters; polymerized rosin.
- Suitable plasticizers are e.g. Phthalates such as diethyl phthalate, dioctyl phthalate, diisodecyl phthalate; Phosphates such as tributyl phosphate, triphenyl phosphate; Dioctyl adipate; Dioctyl sebacate; Dibutyl maleate.
- Suitable viscosity reducing additives are e.g. aliphatic, alicyclic and aromatic hydrocarbons; liquid polybutene; liquid polystyrene; Xylene-formaldehyde resins; Coumarone indene resins.
- Suitable stabilizers are, for example, tetrakis [methylene-3- (3 ', 5'-di-tert-butyl-4'-hydroxyphenyl) propionate] methane; 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) benzene; 4,4'-thiobis (6-tert-butyl-m-cresol); Zinc dibutyl dithiocarbamate; Dibutylthiourea; Octylphenyl salicylate; 2-hydroxy-4- (2-hydroxy-3-methacryloxy) propiobenzophenone; Octadecyl 3- (3 ', 5'-di-tert-butyl-4'-hydroxyphenyl) propionate.
- Suitable fillers are e.g. mineral substances such as kaolin or talc.
- Preferred hot melt adhesives are those whose thermoplastic backbone polymers can be crosslinked by radiation, for example by UV or electron radiation. Suitable thermoplastic backbone polymers are, for example, acrylates; Polyester acrylates; synthetic rubbers.
- the radiation-crosslinkable hot melt adhesive is applied to the substrate of the fabric and only then radiation-hardened. Compared to non-post-crosslinkable hot melt adhesives, the radiation-crosslinkable hot melt adhesives are characterized by a noticeably higher temperature resistance.
- the hot-melt adhesive preferably has a melting range of 120 to 150 ° C. and a softening range of 50 to 180 ° C.
- Hot melt adhesives with a viscosity of approximately 1000 to 80,000 mPas at a processing temperature of 100 to 160 ° C. are preferred.
- the amount of adhesive is usually 3 to 15 g / m2, preferably 6 to 10 g / m2.
- the hot melt adhesive is preferably applied to the substrate to be coated in a dot pattern of 100 to 22500 points / 625 mm2, particularly preferably from 1600 to 10000 points / 625 mm2.
- the substrate is preferably coated with the hot melt adhesive by a screen printing process, a gravure printing process or a flexographic printing process.
- a flat screen or a circular screen can be used for the screen printing process.
- Three-roll processes are used for flexographic printing, with the rolls being heated.
- doctor blades instead of squeeze rollers.
- the pure well-doctor blade systems or well-roller systems can be used.
- the application systems can be closed or open systems. All these methods have in common that the substrate, which is to be coated with the hot-melt adhesive, is carried out between a counter-pressure roller and the pressure body, which applies the glue.
- the dot frequency and the size of the hot-melt adhesive dots can be controlled by a variable, separate printing body or either directly through the screen in screen printing, the cup roller in gravure printing or the anilox roller in flexographic printing.
- the hotmelt adhesive is applied in pure form, the hotmelt adhesive as such containing the additives mentioned above and possibly being crosslinked by UV or electron radiation.
- the ratio of the base area to the height of the hot melt adhesive points depends on the one hand on the rheological properties, such as on the structural viscosity, thioxotropy and the flowability of the hot melt adhesive used.
- the stated ratio of point base area to point height can be influenced, for example when using a sieve, by the ratio of hole diameter to wall thickness of the sieve used.
- the hot melt adhesive is preferably applied using a rotary screen printing system.
- the advantageous ratio of dot base area to dot height can be set particularly favorably if the screen used in the rotary screen printing system has a wall thickness of 85 to 170 ⁇ m and a passage for the hot melt adhesive of approximately 10 to 45%.
- a sieve with 1600 to 10000 holes / 625 m2 is preferably used.
- the counter-pressure roller used in the system is provided with a thermal control.
- the necessary temperature of the counter-pressure roller results, among other things, from the softening and melting range of the hot-melt adhesive used, the production speed and the adhesive strength of the hot-melt adhesive on the wire, depending on the temperature and the viscosity of the hot-melt adhesive.
- a melting range from 80 to 250 ° C. and a softening range from 30 to 180 ° C. are preferred.
- the pressure-sensitive adhesive coating on the substrate is produced from an adhesive dispersion with a high solids content.
- the dispersion can be an aqueous dispersion, an organosol or a plastisol available. Thixotropic, aqueous dispersions with a solids content of 55 to 65% by weight are particularly preferred.
- the adhesive dispersion is further preferably composed of polymerized (meth) acrylic acid esters, the ester groups preferably representing alkyl radicals having 4 to 12 carbon atoms. If necessary, other monomers such as e.g. (Meth) acrylic acid with which (meth) acrylic acid esters are copolymerized.
- the high solids adhesive dispersion described above is typically applied at a basis weight of 1 to 20 g / m2.
- fiber materials such as paper or cardboard, synthetic fiber products or mixtures of synthetic and natural fibers, as well as various plastic films such as polyethylene (PE), polypropylene (PP), which can be stretched (OPP) , Polyester (PET), polystyrene (PS), polyamide (PA) or polyvinyl chloride (PVC), or their composites.
- substrates made of metals, metal compounds and metal alloys or their composites can also be used.
- the materials preferably have a thickness of 50 ⁇ m to 4 mm.
- a paper or cardboard material is used as the substrate, this can either be uncoated, coated, high-gloss, matt or laminated with a transparent film.
- the substrate can be printed with any number of colors on one or both sides, screen printing, offset printing, letterpress printing, flexographic printing and gravure printing being used as a printing process using the web and sheet processes.
- the substrate consists only of a transparent, clear (and not printed) material.
- Highly transparent paper and various plastic films such as e.g. PET, PE, PP, PA, PS and PVC.
- the material thickness is preferably in the range from 50 ⁇ m to 3 mm. In this embodiment it is possible to interchangeably place image motifs under the substrate.
- a non-adhesive cover film or non-adhesive paper is applied over the entire surface of the self-adhesive substrate.
- Siliconized papers, synthetic fiber products or mixtures of synthetic and natural fibers, as well as various plastic foils such as PET, PE, PP, PA, PS, PVC, are particularly suitable for the cover film.
- a weak adhesion of the adhesive on the substrate to the cover film and thus a slight detachment of the cover film from the adhesive on the substrate is controlled by adjusting the adhesive force of the pressure-sensitive adhesive coating.
- the cover film should be made of transparent, clear material, which means that it is not necessary to remove the cover film in order to view the panel motif and the flat fabric motifs.
- the material thickness of the cover film is preferably in the range from 50 ⁇ m to 500 ⁇ m, materials in the upper thickness range being preferred, since a certain stiffness and strength of the material make it easier to pull off the self-adhesive panel surface.
- the cover film is preferably attached to the upper edge, the left or right side edge of the substrate.
- a permanent adhesive tape is preferably used to attach the cover film to the substrate.
- the adhesive strip should be attached so that tearing off the cover film, in particular in the case of jerky tearing, can be avoided.
- the adhesive strip is therefore preferably folded over on the upper edge, the left or right side edge of the cover film and substrate, and the top side of the cover film is thus connected to the back of the substrate. In this way, the cover film is not torn off when it is quickly or jerkily torn, since the folding point functions as a kind of hinge.
- materials based on e.g. PE, PP, PET or PVC, but also paper, or their composites can be used.
- the adhesive strip itself contains pressure sensitive adhesive or, e.g. by heat, activatable adhesive and preferably has a width of 4 mm to 40 mm. In the best case, a clear and transparent adhesive tape is also used.
- the cover film Since the planar structures positioned and fixed on the substrate usually have a thickness of 50 ⁇ m to 4 mm, and the cover film over the entire area on the planar structures and lies on the substrate, the cover film is corrugated due to the different heights of the flat structures and the substrate, particularly in the case of a few, small-scale flat structures. According to a preferred embodiment, this can be prevented by a frame which is applied to the edge of the substrate and is flush with the outer contours of the substrate.
- This frame can be made of fiber materials such as paper or cardboard, synthetic fiber products or mixtures of synthetic and natural fibers, as well as various plastic foils such as polyethylene (PE), polypropylene (PP), polyester (PET), polystyrene (PS), polyamide (PA) or polyvinyl chloride (PVC), or their composites.
- frame structures made of metals, metal compounds and metal alloys, or their composites, can also be used.
- the frame material is either unprinted, printed or colored. Conventional offset printing, flexographic printing, letterpress printing, gravure printing or screen printing are used as printing processes.
- the frame material usually has a thickness of 50 ⁇ m to 4 mm, preferably a thickness that is equal to or greater than that of the flat structures.
- the width of the frame preferably varies between 1 mm and 20 mm.
- the frame is preferably coated with a non-permanent layer of pressure-sensitive adhesive.
- this coating can be applied using screen printing, gravure or flexographic printing.
- the frame is preferably attached to the substrate by applying a permanent adhesive only to the top of the substrate in the area of the frame, only on the back of the frame or on both of these sides.
- stiffening can be carried out on the back of the substrate.
- the substrate is either self-adhesive on the back, preferably permanently self-adhesive, and is laminated with the stiffening or is fixed on the stiffening with non-self-adhesive, preferably permanently adhesive.
- the fixing adhesive can be applied over the entire surface, in zones over the entire surface or in a grid pattern.
- Fiber materials such as e.g. Paper or cardboard, synthetic fiber products or mixtures of synthetic and natural fibers, as well as various plastic films made of PE, PET, PP, PA, PS or PVC, or their composites.
- stiffeners made of metals, metal compounds or metal alloys, or their compounds.
- the above materials usually have a thickness in the range from 50 ⁇ m to 5 mm.
- the format of the stiffening is preferably larger than the format of the substrate.
- the remaining free space on the front of the stiffener lends itself to printing information about the product, brand names and the like. Instructions for use can be provided on the back of the reinforcement.
- the stiffener can also be used to present the panel. Here, e.g. a euro hole punched into the free area of the stiffener for hanging the board in display stands.
- a parking strip consisting of a substrate, possibly plus stiffening, and not permanently self-adhesive Coating thereon, which can be positioned on the top, bottom, left or right edge of the panel, inside or outside the frame and serves as storage for the non-self-adhesive flat structures.
- the parking bar is outside the frame of the board, it is preferably given its own frame made of the same material, the same width and thickness as the frame of the board.
- the parking strip is preferably - depending on the positioning - as long or wide as the board or the stiffening of the board and as wide or long as desired.
- the substrate and the pressure sensitive adhesive coating of the parking strip are constructed and manufactured as explained in connection with the panel itself.
- a panel which includes a stiffener (1), a substrate (2) coated according to the invention, a frame (3), a cover film (4) and an adhesive strip (5).
- the stiffener (1) has a larger format than the substrate (2).
- the adhesive strip (5) is attached to the top of the front of the cover film (4), bent around the upper edge of the frame (3) and the substrate (2) and attached to the back of the substrate (2) at the top.
- FIG. 2 shows a special embodiment according to which the panel consists of a stiffening (1 '), a highly transparent transparent film (2') as the substrate, which is coated according to the invention, a frame (3 '), a cover film (4') and one Adhesive tape (5 ').
- a replaceable image sheet (6 ') can be placed under the transparent film.
- the invention comprises a set of a sheet according to the type of the invention described above and non-self-adhesive sheet-like structures.
- the flat structures have certain external shapes and sizes, depending on the use or the purpose of the display. These shapes are preferably either punched or cut or are pre-punched and then broken out by hand.
- fabrics made of metals, metal compounds or metal alloys, or their composites, can also be used. These materials usually have a thickness of 50 ⁇ m to 4 mm and can be unprinted, printed on one or both sides. Offset printing, screen printing, flexo printing, letterpress printing and gravure printing lend themselves as a suitable printing process.
- the fabrics are fixed on the panel according to the invention and cannot slip. Since the fabrics have no self-adhesive back and without residue Adhesive can be detached from the board, it is possible at any time to handle the flat structures and to easily move and rotate flat structures lying on a surface, for example a table.
- the board according to the invention or the set of board and flat structures offers numerous possible uses, in particular in planning, designing and communicating. Special areas of application are e.g. Planning boards for architects, furniture stores, doctors (interior design, lighting plans), for landscape designers (garden design) and for switch cabinet construction (mounting plates).
- the object of the invention can be used to produce toys according to which the board represents a playing surface, the flat structures embody certain objects or figures, and any number of game scenes can be represented by the repeatable positioning, fixing and releasing of the flat structures.
- a substrate made of double-sided coated and bright white picture printing paper (brand: Luxo Magic, 170 g / m2, made by Schneidersöhne Textil / Ettlingen) with the dimensions 152 mm x 205 mm is printed on one side using sheetfed offset printing.
- the print motif represents the contours (outer walls, inner walls, doors, windows) of a multi-room apartment.
- the printed side of the substrate produced above is then coated over the entire area with a coating adhesive using rotary screen printing.
- the substrate is coated with the hot-melt adhesive using a sieve with a wall thickness of 130 ⁇ m, a passage of 10% and 1600 holes / 625 mm2.
- the hot melt adhesive used is PS 5002 from Novamelt Research GmbH (an SIS (styrene / isoprene / styrene) block copolymer, mixed with an adhesive resin in a ratio of 1: 1).
- This hot melt adhesive has a melting point of 120 oC . Its viscosity at 150 o C is 49500 mPas.
- the substrate is coated with the hot melt adhesive in a grid.
- the amount of adhesive is 6 g / m2.
- the ratio of the base area to the height of the hot melt adhesive point is 20: 1.
- the substrate coated with pressure sensitive adhesive in this way has an adhesive force of 4.3 N / 25 mm on window glass, measured according to the Finat test method FTM1 (FTM: Finat Test Method).
- a frame is applied to the printed substrate and coated with hot-melt adhesive on the edge of the substrate such that it is flush with the outer contours of the substrate.
- the frame consists of uncoated, colored cardboard (brand: Foldcard LB, 280 g / m2; from Iggesund / Hamburg) with a width of 4 mm and a thickness of 363 ⁇ m.
- a non-self-adhesive cover film (brand: Melinex OD 125, 125 ⁇ m; made by Deutsche ICI / Frankfurt) made of clear polyester material is attached to the top of the frame using a 12 mm wide, permanently adhesive polyester strip (brand: Q55; Fa Quaas / Wuppertal) attached. Furthermore, the top of the frame is coated with the same adhesive and under the same conditions as above, so that the cover film can be easily removed from the top of the frame.
- the flat structures represent interior furnishings, such as cupboards, tables, chairs, bathroom furnishings, etc., and their size is adapted to the outline of the apartment shown on the printed substrate.
- the fabrics consist of polypropylene PP (brand: Priplac; USI-Plast / Paris), have a thickness of 800 ⁇ m and are printed on both sides.
- the above example shows an application form of the table according to the invention or the set of table and flat structures.
- the interior furnishings, represented by the above flat structures can be positioned, fixed and detached any number of times on the substrate representing the outline of the apartment, so that various options for furnishing can be run through.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4322134 | 1993-07-02 | ||
DE4322134A DE4322134A1 (de) | 1993-07-02 | 1993-07-02 | Tafel zum wiederholbaren Positionieren, Fixieren und Wiederablösen von nicht selbstklebenden Flächengebilden |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0632423A2 true EP0632423A2 (fr) | 1995-01-04 |
EP0632423A3 EP0632423A3 (fr) | 1997-03-12 |
Family
ID=6491853
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94109803A Withdrawn EP0632423A3 (fr) | 1993-07-02 | 1994-06-24 | Panneau pour le positionnement, la fixation et le détachement répétitif de feuilles non-autoadhésives. |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0632423A3 (fr) |
JP (1) | JPH0790234A (fr) |
KR (1) | KR950004075A (fr) |
DE (1) | DE4322134A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6482288B1 (en) | 1999-03-19 | 2002-11-19 | 3M Innovative Properties Company | Image graphic adhesive system and method for using same |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19609590A1 (de) * | 1996-03-12 | 1997-09-18 | Kontron Elektronik | Verfahren und Vorrichtung zur Beschichtung von Substraten, vorzugsweise Leiterplatten |
DE19647458B4 (de) * | 1996-11-16 | 2006-01-05 | Nordenia Technologies Gmbh | Flächengebilde aus zwei Außenlagen und einer klebenden Mittelschicht |
CA2321790A1 (fr) * | 1998-02-20 | 1999-08-26 | Genaro Aldrete-Frances | Composition polymere pour l'elaboration de figures auto-adhesives |
US6706649B2 (en) | 1999-02-01 | 2004-03-16 | Nordenia Technologies Gmbh | Web with two outer layers and an adhesive middle layer as well as process to produce said web |
KR20010098217A (ko) * | 2000-04-28 | 2001-11-08 | 김병미 | 아름다운 외관을 제공하는 한산 모시 |
DE20302310U1 (de) | 2003-02-13 | 2003-06-05 | F. Löffelmann GmbH, 86391 Stadtbergen | Folie, Matte o.dgl. mit rutschhemmender Unterseite |
KR101499644B1 (ko) * | 2012-12-28 | 2015-03-09 | 한국원자력연구원 | 방사선을 이용한 복합재료 접합 방법 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4148148A (en) * | 1976-04-27 | 1979-04-10 | Harald Riehle | Planning board |
GB2117547A (en) * | 1982-03-22 | 1983-10-12 | Kenney Graham George | Display board and poster assemblies |
US4618151A (en) * | 1984-05-14 | 1986-10-21 | Fadner Thomas A | Peelably adhesive game board and method of use |
GB2208141A (en) * | 1987-07-07 | 1989-03-01 | Norman Boyd | Information display |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE364388B (fr) * | 1968-07-01 | 1974-02-18 | J Swasey | |
DE3346100A1 (de) * | 1983-12-21 | 1985-07-04 | Beiersdorf Ag, 2000 Hamburg | Rueckstandsfrei wieder abloesbare haftklebrige flaechengebilde |
JPH0414434Y2 (fr) * | 1985-04-08 | 1992-03-31 | ||
US5016373A (en) * | 1988-09-19 | 1991-05-21 | Theno Mark H | Collage sheet having rollable releasable adhesive surface |
JP2748024B2 (ja) * | 1989-07-05 | 1998-05-06 | 株式会社サクラクレパス | 再剥離型固型糊 |
US5074593A (en) * | 1989-12-04 | 1991-12-24 | John Grosso | Insert holder with sealable opening |
DE9114600U1 (de) * | 1991-11-23 | 1992-05-27 | Gottfried Klüber Bilderrahmen, 69198 Schriesheim | Platte mit einer Schicht Kleber |
DE4221785A1 (de) * | 1992-07-02 | 1994-01-05 | Inga Werbemittel Spezialdrucke | Werbe- oder Informationsträger |
-
1993
- 1993-07-02 DE DE4322134A patent/DE4322134A1/de not_active Withdrawn
-
1994
- 1994-06-24 EP EP94109803A patent/EP0632423A3/fr not_active Withdrawn
- 1994-06-30 KR KR1019940015392A patent/KR950004075A/ko not_active Application Discontinuation
- 1994-07-01 JP JP6150752A patent/JPH0790234A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4148148A (en) * | 1976-04-27 | 1979-04-10 | Harald Riehle | Planning board |
GB2117547A (en) * | 1982-03-22 | 1983-10-12 | Kenney Graham George | Display board and poster assemblies |
US4618151A (en) * | 1984-05-14 | 1986-10-21 | Fadner Thomas A | Peelably adhesive game board and method of use |
GB2208141A (en) * | 1987-07-07 | 1989-03-01 | Norman Boyd | Information display |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6482288B1 (en) | 1999-03-19 | 2002-11-19 | 3M Innovative Properties Company | Image graphic adhesive system and method for using same |
US6491781B1 (en) | 1999-03-19 | 2002-12-10 | 3M Innovative Properties Company | Image graphic system comprising a highly tacky adhesive and method for using same |
US6531021B1 (en) | 1999-03-19 | 2003-03-11 | 3M Innovative Properties Company | Image graphic adhesive system using a non-tacky adhesive |
Also Published As
Publication number | Publication date |
---|---|
JPH0790234A (ja) | 1995-04-04 |
DE4322134A1 (de) | 1995-01-12 |
KR950004075A (ko) | 1995-02-17 |
EP0632423A3 (fr) | 1997-03-12 |
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