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EP0577693A1 - Emballage hydrosoluble. - Google Patents

Emballage hydrosoluble.

Info

Publication number
EP0577693A1
EP0577693A1 EP92907889A EP92907889A EP0577693A1 EP 0577693 A1 EP0577693 A1 EP 0577693A1 EP 92907889 A EP92907889 A EP 92907889A EP 92907889 A EP92907889 A EP 92907889A EP 0577693 A1 EP0577693 A1 EP 0577693A1
Authority
EP
European Patent Office
Prior art keywords
package according
package
water soluble
water
sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92907889A
Other languages
German (de)
English (en)
Other versions
EP0577693B1 (fr
Inventor
David Brian Edwards
William John Mccarthy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Agriculture Ltd
Original Assignee
Rhone Poulenc Agriculture Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB919107109A external-priority patent/GB9107109D0/en
Priority claimed from GB929201806A external-priority patent/GB9201806D0/en
Application filed by Rhone Poulenc Agriculture Ltd filed Critical Rhone Poulenc Agriculture Ltd
Priority to EP94103286A priority Critical patent/EP0608910B1/fr
Publication of EP0577693A1 publication Critical patent/EP0577693A1/fr
Application granted granted Critical
Publication of EP0577693B1 publication Critical patent/EP0577693B1/fr
Priority to GR970402281T priority patent/GR3024643T3/el
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/46—Applications of disintegrable, dissolvable or edible materials

Definitions

  • This invention relates to a water soluble or water dispersible package containing an agrochemical, eg a pesticidal composition, and to a process for producing such a package.
  • Agrochemicals include pesticides, e.g. herbicides, which are often potentially harmful materials and are commonly produced as a concentrated solution or dispersion in an organic liquid, as a gel or in solid form. Such chemicals are typically supplied in a metal or blow-moulded plastics container.
  • chemical pesticides e.g. herbicides
  • a quantity of the pesticide is measured out of the container in concentrated form and then mixed with a large volume of water before being sprayed onto a locus to be treated or onto plants.
  • concentrated materials are frequently highly toxic so great care must be taken in measuring and mixing them to avoid spillage and to avoid human or animal contact with the concentrated pesticide.
  • the present invention seeks to overcome the disadvantages of known packages and to provide a package which contains an agrochemical such as a pesticidal composition and has one or more of the following advantageous features: the packaged chemical is released only after contact with water in which it is to be dissolved or dispersed, minimising the possibility of accidental contact of the undiluted material with the environment or with humans or animals; the chemical can be provided in unit dosage form suitable for dilution with a predetermined amount of water removing the need for undiluted chemical to be measured out; the packaged chemical is easy to use : the packaged chemical can be simply placed in water prior to use of the chemicals; and the need for washing out of the residual chemical from containers to render them safe for disposal is removed: containers which have been in contact with the packaged chemical remain uncontaminated which facilitates their disposal.
  • an agrochemical such as a pesticidal composition
  • the present invention provides a package containing an agrochemical, eg a pesticidal composition, which package comprises a first sheet of non- planar water soluble or water dispersible material and a second sheet of water soluble or water-dispersible material superposed on the first sheet and sealed to it by a continuous closed water soluble or water dispersible seal along a continuous region of the superposed sheets.
  • the seal may be produced using a solvent, eg water, or using eg ultrasound but is preferably a heat seal.
  • the continuous region of the superposed sheets is preferably substantially planar.
  • the invention further provides a process for producing such a package which comprises: moulding a first, sheet of water soluble or water dispersible material to form a non-planar sheet comprising at least one recess adapted to retain an agrochemical, eg a pesticidal composition, said recess being bounded by a flange, which flange is preferably substantially planar; placing an agrochemical, eg a pesticidal composition in the at least one recess; placing a second sheet of water soluble or water dispersible material on the flange and across the or every recess; and sealing (preferably heat sealing) the first and second sheets along the flange to form a continuous closed water soluble or water dispersible seal.
  • the agrochemical may be, for example, a plant protection agent, a plant growth regulator or a plant nutrient.
  • a plant protection agent is a pesticide (such as an insecticide, fungicide, herbicide, acaricide or nematocide) .
  • the pesticidal composition may be in liquid form, or solid form, or gel form. It may comprise any conventional carrier or diluent or surfactant. Where the composition is in liquid form it may be in the form of a solution or of a dispersion in an organic liquid, e.g. an emulsion or a suspension. Similarly in gel form, the composition may contain pesticide either dissolved or dispersed in the substantially f dry medium.
  • the packages of the present invention generally contain from 0.1 grams to 7kg, preferably lg to 5kg, where the composition is in solid form. Where the composition is in liquid or gel form, the package typically contains from 1ml to 10 litres, preferably from 0.5 to 5 litres (0.1 litres to 1.5 litres is especially preferred) ; on a smaller scale a range of 5ml to 1 litre is also useful.
  • the package will contain at least a small amount of space, eg at least about 5% by volume, so as to minimise the likelihood of spillage of the composition during the production of the package.
  • the package produced is evacuated of air or the contents are under reduced pressure.
  • the package thus produced has a number of advantages, for example substantially increased resistance to shock.
  • a powder or granules in such a package is compacted and is, effectively, skin-packaged within the film. Compaction of the product makes the package more likely to sink when dropped into water and the package occupies less space during storage.
  • the advantages of packaging under reduced pressure include: a) the absence of gas surrounding the agrochemical composition reduces the possibility of the package failing for example, at low temperatures.
  • the package may be advantageous for the package to hold the agrochemical substantially rigid within the package to prevent segregation and possible decomposition of the agrochemical (which may be incompatible with certain plasticisers: the plasticiser in the agrochemical may also be incompatible with the film) .
  • the two sheets of water soluble or water dispersible material are of the same material, but they may be different.
  • One sheet of the water soluble or water dispersible material may be easy to print upon.
  • the pesticidal composition is in liquid or gel form and comprises an organic solvent the water soluble or water dispersible material will be one which is insoluble in the organic solvent.
  • Suitable water soluble or dispersible materials are polyethylene oxide and methyl cellulose. More preferably a polyvinyl alcohol (PVOH) film is used. Such a PVOH film may a partially or fully alcoholised or hydrolysed e.g.40-99%, preferably 70-92% alcoholised or hydrolysed, polyvinyl acetate film. The film may be a cast film or, more preferably, a blo or extruded film.
  • PVOH polyvinyl alcohol
  • the polyvinyl alcohol film may be unoriented, mono axially oriented or bi-axially oriented.
  • Water soluble materials are preferred since they provide less disposal problems.
  • the materials used will generally be cold water soluble; cold water soluble polyvinyl alcohol is preferred. I will be understood that other materials may be used when the package is to be dissolved or dispersed in water or hot water. Generally the water soluble or water dispersible material will be flexible.
  • the maximum tensile strength of the material of th envelope is preferably at least 20, more preferably from 30 to 80, N/mm 2 and may be as much as 200N/mm 2 or more; and the elongation at break is preferably 200 to 380%, more preferably from 220 to 350% and may be as much as 500 per cent or more. Testing for these values is generally carried out at 23°c and 50% relative humidity.
  • the water soluble or water dispersible material will typically be a laminate, generally of two layers of different or preferably the same water soluble or water dispersible material, as pinholes are unlikely to coincide in two layers of material.
  • the laminates will consist of 2 layers of thickness from 20 ⁇ m to 1mm, preferably about 40 ⁇ rt, each. Generally however the thickness of the layers will be kept to the minimum needed to prevent rupture of the package, so that the water soluble or dispersible material is dissolved or dispersed as quickly as possible and the pesticide then released.
  • the sheets of water soluble or water dispersible material typically comprise a single layer of material.
  • the material will generally be from 20 to 500 ⁇ m, preferably 30 to lOO ⁇ , thick.
  • a laminate material of the type described above may be used.
  • the thickness of the water soluble dispersible material will generally be kept to a minimum in packages containing solid compositions.
  • the thickness of the first sheet will generally not be less than 20 ⁇ and (to maintain ease of processing) generally not more than 1 mm.
  • a preferred range is from 80-400 ⁇ , eg 100-400 , most preferably about 250 ⁇ .
  • the thickness of the second sheet may be less than that of the first sheet as the second sheet will not generally be thermoformed so that localised thinning of the sheet will not occur.
  • the thickness of the second sheet will generally not be less than lO ⁇ , preferably not less than 20 ⁇ .
  • the film will generally not be more than 1 mm thick, a preferred range being from 20 to 250 ⁇ , most preferably about 150 ⁇ .
  • the package is provided with a region which will more readily dissolve in water than the rest of the package.
  • This offers advantages, for example by speeding up the dispersion of the agrochemical contained in the package.
  • the region may be provided for example by making one sheet of the water-soluble or water dispersible material thinner than the other, or by making one portion of the package thinner than the rest.
  • the package does not possess a seam running down the centre of one of the faces of the package. This offers advantages over known packages, for example by reducing the likelihood of failure occurring in the package when it is subjected to shock, because packages having a seam running down the centre of one of the faces of the packages necessarily have a point at which two or more seals intersect which will be more likely to fail under shock than the equivalent package not having this point of intersection.
  • the two water soluble or water dispersible sheets in the packages are sealed together by a closed continuous heat seal.
  • the seal is water soluble and does not suffer from leakage, it is a single continuous seal and has no geometrical discontinuities, i.e. it does not comprise any angular intersections with itself. Therefore the heat seal will usually be curved, at least in portions, for instance at the corners of the package: the radius of curvature of the heat seal will generally not be less than 1mm, preferably not less than 5mm, and not more than half the width of the package.
  • Suitable pesticides which may be used in the package of the present invention include fungicides, insecticides and herbicides (for example hydroxybenzonitrile herbicides, e.g. bromoxynil or ioxynil or derivatives thereof such as salts or esters, e.g. heptanoates or octanoates) .
  • olluscicides suitable for addition to, for example, ponds or streams may also be employed.
  • the invention is not limited to specific agrochemicals. Agrochemicals which can be used in the invention include:
  • Fungicides such as Triadimefon, Tebuconazole, Prochloraz, Triforine, Tridemorph, Pro iconazole, Piri icarb, Iprodione, Metalaxyl, Bitertanol, Iprobenfos, Flusilazole, Fosetyl, Propyzamide, Chlorothalonil, Dichlone, Mancozeb, Anthraquinone, Maneb, Vinclozolin, Fenarimol, Bendiocarb, Captafol, Benalaxyl, Thiram, Captan, Fosetyl-Al, Zineb, Sulfur, Quintozene, Copper salts, Thiophanate-methyl, Tricyclazole, Dichloran, Chloroneb, Cyproconazole, Hexaconazole, Imazalil, Dodine, Diniconazole, Guazatine, Thiabendazole, Carboxin, Ferban, Glyodin, Fentin (triphen
  • Herbicides such as quizalofop and its derivatives, Acetochlor, Metolachlor, Imazapur and Imazapyr, Glyposate and Gluphosinate, Butachlor, Acifluorfen or Acifluorfen-sodium, Oxyfluorfen, Butralin, Fluazifop-butyl, Bifenox, Bromoxynil and Ioxynil and esters thereof, Diflufenican, Phenmedipham, Desmedipham, Oxadiazon, Mecoprop MCPA, MCPB, Linuron, Isoproturon, Flamprop and its derivatives, Ethofumesate, Diallate, Carbetamide, Alachlor, Chorpyralid, 2,4-D, Tribufos, Triclopyr, Diclofop-methyl, Sethoxydim, Pendimethalin, Trifluralin, Ametryn, Chloramben, Amitrole, Asula , D
  • Pesticidal composition is in liquid fo then suitable organic solvents which may be used as carriers the pesticidal composition include petroleum based solvents, *•> e.g. petroleum ethers, mineral oils, aliphatic or aromatic hydrocarbons, e.g. hexane, octane, cyclohexane, benzene, xylene and naphthalene, halogenated aliphatic or aromatic hydrocarbons, e.g.
  • compositions may comprise, in addition to, or in some cases instead of, an organic solvent as a carrier or diluent, a surfactant, which is reasonably dry in that it contains less than 2 to 3% water.
  • a surfactant may be of the ionic or non-ionic types: for example sulphoricinoleates, quaternary ammonium derivatives, products based on condensates of ethylene oxide with alkyl and polyaryl phenols, e.g.
  • nonyl- or o ⁇ tyl-phenols or carboxylic acid esters of anhydrosorbitols which have been rendered soluble by etherification of the free hydroxy groups by condensation with ethylene oxide, alkali and alkaline earth metal salts of sulphuric acid esters and sulphonic acids such as dinonyl- and dioctyl-sodium sulphonosuccinates and alkali and alkaline earth metal salts of high molecular weight sulphonic acid derivatives such as sodium and calcium lignosulphonates and sodium and calcium alkylbenzene sulphonates, and block ethylene oxide/propylene oxide copolymers.
  • alkali and alkaline earth metal salts of sulphuric acid esters and sulphonic acids such as dinonyl- and dioctyl-sodium sulphonosuccinates and alkali and alkaline earth metal salts of high molecular weight sulphonic acid derivatives such
  • the pesticidal composition may comprise up to 10%, e.g. from 0.05% to 10% of surfactant but, if desired, it may comprise higher proportions of surfactant for example up to 15% in liquid emulsifiable suspension concentrates and up to 25% in water soluble concentrates.
  • the contents of the package may be thickened or rendered thixotropic to provide a gel.
  • An increased viscosity in the contents can reduce the likelihood of rupture if the package is subjected to mechanical shock.
  • the contents of the package may be rendered more viscous or thixotropic by the inclusion of additives, for example, a modified organophile, or bentonite, lecithin, polymethylene oxide or silica gel.
  • concentrations of pesticide or herbicide dissolved or dispersed in the organic liquid or in the gel will generally be those conventionally used: in order to reduce the bulk of each package, however, concentrations may be increased.
  • Each package will preferably contain 100ml to 1.5 litres, preferably at least about 500 ml and will preferably contain a convenient standard volume, for example 500 ml or 1 litre, although it will be appreciated that any convenient standard volume may be chosen.
  • the pesticidal composition is in solid form then it may comprise any conventional carrier or diluent which is reasonably dry, in that it contains less than 2 to 3% of moisture.
  • suitable solid diluents or carriers are aluminium silicate, talc, calcined magnesia, kieselguhr, tricalcium phosphate, powdered cork, adsorbent carbon black and clays such as kaolin and bentonite.
  • Solid compositions may comprise surfactants, such as dispersing agents, for example those surfactants previously mentioned. In some cases such surfactants may also be used as diluents or carriers.
  • the concentration of pesticide in the solid pesticidal compositions may be as conventionally used: concentrations may however be increased to reduce the bulk of the package.
  • the pesticidal compositions used in the package of the present invention may be prepared by conventional means.
  • the packages of the present invention may be inside an additional outer container.
  • a container may provide additional strength and if water resistant may serve to protect the package of the present invention from accidental exposure to water.
  • the outer container is preferably sealed to avoid exposing the package of the present invention to undue moisture.
  • the package of the present invention may comprise more than one compartment containing the same or different pesticidal compositions.
  • Such multi-compartment packages are particularly useful where a combination of components are to be employed together and where the components are incompatible for a prolonged period, for instance if they react chemically.
  • the packages according to the invention should release their contents in less than about 10 minutes.
  • the packages will be placed in the spray tank of a conventional sprayer.
  • the tank will generally be partly filled f with water, and the package added.
  • the tank is provided with means to agitate the water the contents of the bag will be released more rapidly. It is preferred that release should take place in less than about a minute, for example in 30 to 40 seconds. It will be understood that the time taken to release the pesticide will depend upon a number of factors apart from the nature of the bag, including the temperature of the water and the level of agitation.
  • the packages of the present invention may be obtained by first deforming a sheet of water soluble or dispersible material so as to form a recess adapted to retain a pesticidal composition. This may be achieved for example by vacuum forming where the sheet is deformed to conform to the shape of a suitable mould and may, if desired, be a thermoforming process to cause the sheet to retain its shape after release from the mould.
  • the mould may be equipped with pinholes through which the space between the mould and the sheet can be evacuated.
  • the sheet may be driven against the mould by vacuum forming, or by applying a superatmospheric pressure to the other side of the sheet (this may be effected using an operating pressure of, for example 4% to 6 bar) or by mechanical displacement of the sheet (plug forming) .
  • Thermoforming will generally be carried out using a temperature not less than 40°C and not more than 110°C. A temperature from 70-110°C is preferred, most preferably about 90°C.
  • the pesticidal composition is placed in the recess formed by the deformation, and a second substantially planar sheet of water soluble or water dispersible material is then placed across the recess.
  • the two sheets of water soluble or water dispersible material are then heat sealed so as to form a continuous closed heat seal.
  • the width of the heat seal itself is preferably 1-10 mm, preferably about 5 mm.
  • the dwell time for heat sealing will depend upon, for example, the material used, its thickness and the heat seal temperature. A dwell time of about 3 seconds is generally suitable when the thickness of the material is about 80 ⁇ . A sealed compartment is thus formed.
  • the heat sealing is generally carried out at 15 to 25°C and 15 to 85% relative humidity (RH) .
  • the relative humidity is preferably 35 to 55%.
  • Some routine experimentation may be required to obtain a suitable heat seal depending on the package material, e.g. the particular grade and thickness of PVOH chosen.
  • the quality of the seal can be checked, for example by visual inspection for areas of opacity or for bubbles. Imperfections in the seal may give rise to a lack of water solubility or water dispersibility of the seal.
  • the heat sealing process can be carried out on conventional heat sealing equipment which permits control variation of the sealing jaw temperature, jaw pressure and dwell time.
  • thermoforming apparatus The following Examples illustrate the invention.
  • the values for tensile strength refer to a seal of 25 mm width with a jaw separation speed of 300 mm/min.
  • EXAMPLE 1 A first sheet of polyvinyl alcohol (Vinex 2144: thickness 225i) is heated at 90°C and then thermoformed into a mould, the draw depth being 80 mm, with a forming time of 6 seconds. The product to be packaged is placed in the recess thus formed.
  • a second sheet of polyvinyl alcohol Solublon KA40/KA40, a laminate of two layers each of 40 ⁇ thickness: total thickness 80 ⁇
  • the operating air pressure of the thermoforming apparatus is 4.5 bar.
  • the tensile strength of the seal in the water-soluble bags thus produced is 32.4 N (mean).
  • the production of the water-soluble bags is carried out at 21 ⁇ C (room temperature) and a relative humidity of 38%.
  • EXAMPLE 2 A first sheet of polyvinyl alcohol (Vinex 2144: thickness 225 ⁇ ) is heated at 90°C and then thermoformed into a mould, the draw depth being 80 mm, with a forming time of 6 seconds. The product to be packaged is placed in the recess thus formed. A second sheet of polyvinyl alcohol (Vinex 2144: thickness 75 ⁇ ) is placed across the recess thus formed and heat sealed using a sealing temperature of 200 ⁇ C with a dwell time of 6 seconds. The operating air pressure of the thermoforming apparatus is 4.5 bar.
  • the tensile strength of the seal in the water-soluble bags thus produced is 28.7 N (mean).
  • the production of the water-soluble bags is carried out at 21°C (room temperature) and a relative humidity of 38%.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Wrappers (AREA)
  • Packages (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
  • Cultivation Of Plants (AREA)
  • Catching Or Destruction (AREA)
  • Laminated Bodies (AREA)

Abstract

Un emballage contenant un produit agrochimique comprend une première feuille de matière hydrosoluble ou dispersible dans l'eau de type non planaire, définissant une concavité renfermant une composition agrochimique et une deuxième feuille de matière hydrosoluble ou dispersible dans l'eau collée à la première feuille par une fermeture étanche continue hydrosoluble ou dispersible dans l'eau.
EP92907889A 1991-04-05 1992-04-03 Emballage hydrosoluble Expired - Lifetime EP0577693B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP94103286A EP0608910B1 (fr) 1991-04-05 1992-04-03 Emballage pour pesticides
GR970402281T GR3024643T3 (en) 1991-04-05 1997-09-04 Package for pesticides.

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB9107109 1991-04-05
GB919107109A GB9107109D0 (en) 1991-04-05 1991-04-05 Package for pesticides
GB9201806 1992-01-28
GB929201806A GB9201806D0 (en) 1992-01-28 1992-01-28 Package for pesticides
PCT/GB1992/000603 WO1992017382A1 (fr) 1991-04-05 1992-04-03 Emballage hydrosoluble

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP94103286.4 Division-Into 1994-03-04

Publications (2)

Publication Number Publication Date
EP0577693A1 true EP0577693A1 (fr) 1994-01-12
EP0577693B1 EP0577693B1 (fr) 1997-06-18

Family

ID=26298687

Family Applications (2)

Application Number Title Priority Date Filing Date
EP94103286A Expired - Lifetime EP0608910B1 (fr) 1991-04-05 1992-04-03 Emballage pour pesticides
EP92907889A Expired - Lifetime EP0577693B1 (fr) 1991-04-05 1992-04-03 Emballage hydrosoluble

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP94103286A Expired - Lifetime EP0608910B1 (fr) 1991-04-05 1992-04-03 Emballage pour pesticides

Country Status (27)

Country Link
EP (2) EP0608910B1 (fr)
JP (3) JP3628688B2 (fr)
CN (1) CN1043419C (fr)
AP (1) AP348A (fr)
AT (2) ATE154565T1 (fr)
AU (1) AU663492B2 (fr)
BR (1) BR9205858A (fr)
CA (2) CA2433958C (fr)
CZ (1) CZ287886B6 (fr)
DE (2) DE69220501T2 (fr)
DK (2) DK0608910T3 (fr)
ES (2) ES2104906T3 (fr)
FI (1) FI934354L (fr)
GR (2) GR3024463T3 (fr)
HU (1) HU219180B (fr)
IE (1) IE81080B1 (fr)
IL (1) IL101490A (fr)
MA (1) MA22493A1 (fr)
MX (1) MX9201538A (fr)
MY (1) MY131091A (fr)
NZ (1) NZ242248A (fr)
PL (1) PL171812B1 (fr)
PT (1) PT100349A (fr)
RU (1) RU2099260C1 (fr)
SK (1) SK280565B6 (fr)
TR (1) TR27730A (fr)
WO (1) WO1992017382A1 (fr)

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GR3024463T3 (en) 1997-11-28
EP0608910B1 (fr) 1997-06-18
MA22493A1 (fr) 1992-12-31
HUT65226A (en) 1994-05-02
CZ287886B6 (cs) 2001-03-14
CN1065436A (zh) 1992-10-21
JP2002128138A (ja) 2002-05-09
PL171812B1 (pl) 1997-06-30
ATE154564T1 (de) 1997-07-15
MY131091A (en) 2007-07-31
JP3693653B2 (ja) 2005-09-07
EP0608910A1 (fr) 1994-08-03
CA2433958A1 (fr) 1992-10-15
HU9302799D0 (en) 1994-01-28
MX9201538A (es) 1992-10-01
HU219180B (hu) 2001-02-28
BR9205858A (pt) 1994-06-28
AP348A (en) 1994-07-28
DE69220501D1 (de) 1997-07-24
CN1043419C (zh) 1999-05-19
CZ206393A3 (en) 1994-03-16
GR3024643T3 (en) 1997-12-31
RU2099260C1 (ru) 1997-12-20
CA2433958C (fr) 2005-02-01
IL101490A0 (en) 1992-12-30
ES2104906T3 (es) 1997-10-16
TR27730A (tr) 1995-06-28
DE69220483D1 (de) 1997-07-24
AP9200374A0 (en) 1992-04-30
FI934354A0 (fi) 1993-10-04
DE69220483T2 (de) 1998-01-15
AU1533492A (en) 1992-11-02
SK280565B6 (sk) 2000-03-13
NZ242248A (en) 1995-01-27
IL101490A (en) 1995-03-15
IE921094A1 (en) 1992-10-07
PT100349A (pt) 1994-04-29
JP3628688B2 (ja) 2005-03-16
ATE154565T1 (de) 1997-07-15
AU663492B2 (en) 1995-10-12
JP2004043026A (ja) 2004-02-12
JPH06506173A (ja) 1994-07-14
DE69220501T2 (de) 1998-02-05
ES2106388T3 (es) 1997-11-01
IE81080B1 (en) 2000-02-23
DK0577693T3 (da) 1998-01-05
CA2107341C (fr) 2003-10-14
CA2107341A1 (fr) 1992-10-06
EP0577693B1 (fr) 1997-06-18
FI934354L (fi) 1993-11-26
WO1992017382A1 (fr) 1992-10-15
DK0608910T3 (da) 1997-12-29
SK107493A3 (en) 1994-06-08

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