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EP0530933B1 - Appareil de chauffage électrique à accumulation thermiquement isolé - Google Patents

Appareil de chauffage électrique à accumulation thermiquement isolé Download PDF

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Publication number
EP0530933B1
EP0530933B1 EP92250234A EP92250234A EP0530933B1 EP 0530933 B1 EP0530933 B1 EP 0530933B1 EP 92250234 A EP92250234 A EP 92250234A EP 92250234 A EP92250234 A EP 92250234A EP 0530933 B1 EP0530933 B1 EP 0530933B1
Authority
EP
European Patent Office
Prior art keywords
insulating
slabs
storage heater
heater according
storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92250234A
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German (de)
English (en)
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EP0530933A1 (fr
Inventor
Leo Kaim
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Kkw Kulmbacher Klimagerate-Werk GmbH
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Kkw Kulmbacher Klimagerate-Werk GmbH
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Application filed by Kkw Kulmbacher Klimagerate-Werk GmbH filed Critical Kkw Kulmbacher Klimagerate-Werk GmbH
Publication of EP0530933A1 publication Critical patent/EP0530933A1/fr
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00Details
    • F24H9/02Casings; Cover lids; Ornamental panels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H7/00Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release
    • F24H7/02Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid
    • F24H7/04Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid
    • F24H7/0408Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid using electrical energy supply
    • F24H7/0416Storage heaters, i.e. heaters in which the energy is stored as heat in masses for subsequent release the released heat being conveyed to a transfer fluid with forced circulation of the transfer fluid using electrical energy supply the transfer fluid being air

Definitions

  • the invention relates to an electrical storage heater with a ceramic heat storage core.
  • the storage core consists of a material with high specific heat, preferably magnesia stones. Due to the high specific heat, the storage core is able to absorb a relatively large amount of heat.
  • the memory core is heated to a temperature level of around 800 ° C. Since the storage heaters are housed in living rooms, the storage cores must be heat-insulated and protected against accidental contact, because otherwise the stored heat would be released to the ambient air undesirably quickly and, on the other hand, every touch of the storage heater for the operator entails the risk of dangerous burns would.
  • the known electric storage heaters therefore all have an essentially closed protective housing, preferably composed of a plurality of metal sheets.
  • the memory core is arranged so that it cannot be touched in this protective housing.
  • An insulating layer which preferably consists of insulating plates, is also attached between the housing inner walls and the storage core.
  • the functionality of the electric storage heaters is as follows: The ceramic storage core is heated during the low-tariff night tariff period. The stored core slowly releases this stored heat into the ambient air to be heated up during the day. For this purpose, ambient air is sucked into the storage heater, passed over the storage core and expelled from the storage heater. The storage heater is therefore effective as a heat exchanger. To accelerate the heat exchange, a blower is also provided on the storage heater to accelerate the air flow to be heated.
  • Such an electric storage heater is known for example from DE-C-36 03 615.
  • thermal insulation mats have been used in the known storage heaters.
  • mineral fiber mats were used in places that allowed any wall thickness. These mineral fiber mats are inexpensive and, with the appropriate wall thickness, also have the required insulating properties.
  • soft heat insulation mats were used in the known storage heaters in areas with limited installation space. These soft thermal insulation mats have an extremely high insulating ability and can be designed with thin walls. From DE-A-2 611 115 a boiler is known which is thermally insulated by means of elastic insulating mats. However, the soft thermal insulation mats are high quality and accordingly expensive to buy.
  • DE-C-36 03 615 therefore proposes to manufacture at least the surfaces of an insulation block arranged below the storage core and facing the air flow from non-fibrous thermal insulation material.
  • Microporous silicon oxide is known as a fiber-free material for soft material thermal insulation boards.
  • the vermiculite insulation is also made, for example Römpp-Chemie-Lexikon, 9th edition, 1992, pp.4896f. ISBN 3-13-735109-X, Thieme Verlag, Stuttgart known. Vermiculite is also characterized by its good formability and dimensional stability DE-A-37 00 478 known.
  • a disadvantage of installation as insulating plates in a storage heater is that several hard insulating plates must be arranged horizontally and vertically to one another. Gaps often remain on the abutting surfaces of a vertically arranged and horizontally arranged hard insulating plate, that is to say in the region of the abutting edges of the insulating plates. These columns act as thermal bridges, so that heat escapes from the interior of the storage heater to the outside in an uncontrolled manner. So far, the sealing properties of such hard insulating plates have not been sufficient for electrical storage heating devices.
  • the invention is based on the problem of designing the hard insulating plates in such a way that their insulating effect also satisfies in the region of the abutting edges and such hard insulating plates are also suitable for use in storage heating devices. This object is achieved by the combination of features of claim 1.
  • the electric storage heater according to the invention also has the known heat storage core and the protective housing surrounding the storage core. Between the storage core and protective housing, the thermal insulation layer consisting of several fiber-free insulating plates is also attached.
  • the abutting edges of the insulating plates are designed as abutting surfaces according to the invention. As a result of this planar formation of the abutting edges, surface contact of the individual abutting surfaces occurs between two adjacent insulating plates in the final assembly state. This surface contact, which is to be dimensioned as large as possible, is effective in the manner of a surface seal. In this way, an absolutely heat-tight connection between the insulating plates is made.
  • the abutting surfaces of the insulating plates are developed in such a way that they are formed in the manner of a matrix and a patrix and, to a certain extent, interlock in the assembled state.
  • the abutting surfaces of the insulating plates according to claim 2 are consequently complementary to each other and interlock positively in the final assembly state. This form fit is effective in the manner of a labyrinth seal, so that the sealing effect in the joint areas is further improved.
  • a deformable sealing body is between the abutting surfaces of two adjacent insulating plates. Due to the surface pressure exerted by the abutting surfaces, this sealing body clings to the abutting surfaces and thus seals fine pores and uneven surfaces.
  • Suitable sealants are, for example, plastically deformable soft material plates (claim 4). The soft material adapts to the shape of the respective abutting surface when the neighboring insulating plates are braced against each other and thus provides a particularly good gap seal.
  • Also suitable as a sealant is elastically deformable, inorganic fiber fabric, quartz silk fabric or high-melting glass silk fabric is preferably used.
  • This fiber fabric is an elastic sealant and expediently has a fiber thickness of more than 5 ⁇ m.
  • This inorganic fiber fabric according to claim 5 is further developed according to claim 6 in that it is in the form of a fabric tube. These fabric hoses are placed in the butt joints of two adjacent insulating plates and laid flat, so that a slightly resilient insulating layer is created, which additionally increases the sealing effect, in particular the gap seal.
  • Vermiculite and microporous silicon oxide are particularly suitable for this.
  • Most of the side thermal insulation boards are hard insulating boards made of inorganically bound vermiculite and the vertical, upper and lower thermal insulation boards are high-density soft-body boards made of microporous silicon oxide.
  • other arrangements, combinations and materials are also conceivable both for the hard insulating boards and for the high-insulation soft-body boards and expressly form part of this invention.
  • water glass i.e. alkali silicate
  • the plates made of microporous silicon oxide can be produced by pressing and then sintering suitable starting materials.
  • Claim 10 relates to an advantageous pair of seals between a hard insulating plate and a high-insulation soft body plate.
  • the abutting surface of the hard insulating plate slightly compresses the abutting surface of the high-insulation soft-body panel, as a result of which the abutting surface of the hard insulating plate acts as a sealing edge.
  • Claims 11 to 13 relate to thermal insulation boards with cavities. These thermal insulation boards make it possible to accommodate fibrous, well-insulating materials in the cavities. Furthermore, the cavities are also suitable for holding any highly insulating insulating materials. In particular, the design according to claims 12 and 13 allows easy filling of the cavities with the insulating material.
  • the insulating plates are designed in two parts, one insulating plate part forming a bowl-shaped hollow shell, while the other insulating plate part forms a cover-like covering shell.
  • the cover shell can be placed on the hollow shell like a pot lid on a pot. When the cover shell is attached, the cavity is completely hermetically sealed off from the surroundings.
  • claim 13 proposes to incorporate several separate cavities into the insulating plate.
  • such separate cavities can also be filled with different insulating materials. This is useful if parts of the insulating plate have to be particularly well insulated, while other parts have less insulation. The insulation can thus be variably adapted to the respective requirements.
  • Claims 14 and 15 relate to through openings for lines.
  • Such lines can, for example, for the introduction of radiator rods, temperature sensors or the like. serve.
  • the inner surfaces of the passage openings are made of fiber-free material analogous to the bowl edges forming the outer walls of the cavities.
  • the insulating plates are therefore completely fiber-free not only with respect to their outer sides but also with respect to the inner sides of the passage openings and are therefore reliable.
  • the cross-sections of the through openings which are not filled by the lines are sealed with flange-like sealing plates.
  • the sealing plates are expediently welded to the insulating plates in the final assembly state. It is also possible to provide the sealing plates with counter brackets in such a way that the flange-like sealing plates lie flat on all sides on the insulating material walls, so that no undesired thermal bridges occur at these points.
  • the electric storage heater essentially consists of the protective housing, the heat storage core and the thermal insulation layer arranged between them.
  • the protective housing is formed from the side parts 1, 1 ', the housing rear wall 2, the housing base 3, the housing cover 4 and the housing front wall, not shown in FIG. 1.
  • the hard insulating plates 5 are firmly connected to the side parts 1, 1 '.
  • the insulation in the area of the housing cover 4 is realized by the hard insulating plate 5, while the high-insulation soft-body plate 6 is arranged in the area of the housing base 3.
  • the spacer 7 is also arranged between the high-insulation soft-body panel 6 and the housing base 3, the spacer 7 being designed as an air outlet grill in the region of the front wall, which is not shown in FIG.
  • the protective housing 8 assembled in FIG. 2 again has, according to FIG. 2, the housing rear wall 2, the housing cover 4, the housing base 3 and the housing front wall 9, not shown in FIG. 1.
  • FIG. 2 further shows the hard insulating plate 5 that insulates the housing front wall 9 from the heat storage core 10.
  • the housing rear wall 2 and FIG Housing cover 4 each isolated from the environment by means of a hard insulating plate 5.
  • the housing base 3 is insulated from the heat storage core 10 by means of the high-insulation soft-body plate 6. Additional high-insulation soft-body panels 6 are also provided in the area of the housing cover 4 and the rear wall 2 of the housing.
  • an installation space 11 is kept free for additional components.
  • the installation space 11 serves as a switch room.
  • FIG. 3 shows an embodiment with a vermiculite insulating plate 12 and three silicon oxide insulating plates 13.
  • the drawing plane of FIG. 3 is spanned by the vertical direction 14 and the horizontal direction 15.
  • Two of the silicon oxide insulating plates 13 run according to their cross section in FIG. 3 in the vertical direction 14 and thus correspond to the insulating plates in the area of the housing side parts 1, 1 '.
  • the vermiculite insulating plate 12 is arranged in the horizontal direction 15.
  • the third silicon oxide insulating plate 13 resting on the vermiculite insulating plate 12 likewise runs in the horizontal direction 15.
  • the vermiculite insulating plate 12 and the silicon oxide insulating plate 13 resting thereon correspond to the housing cover 4 according to the illustration in FIG. 3.
  • the seal between the insulating plates 12 , 13 is shown on the basis of the butt joint area in the upper left corner according to the circle IV in FIG. 4.
  • the silicon oxide insulating plates 13, which are made of microporous silicon oxide, are encased with a quartz or glass fiber fabric for protection.
  • the silicon oxide insulating plate 13 running in the vertical direction 14 in FIG. 4 has the bulge 16 in its abutting surface area.
  • the bulge 16 is complementary to the cranked abutting surface 17 of the vermiculite insulating plate 12 extending in the horizontal direction 15.
  • the vermiculite insulating plate 12 fits exactly in the manner of a cover into the space between the two silicon oxide insulating plates 13 running in the vertical direction 14 In terms of its weight, the vermiculite insulating plate 12 lies with its two cranked abutting surfaces 17 in the bulges 16 of the silicon oxide insulating plates 13 arranged in the vertical direction 14.
  • the third silicon oxide insulation plate 13, which rests on the vermiculite insulation plate 12 in the horizontal direction 15, serves to weigh down the vermiculite insulation plate 12 and as additional insulation.
  • FIG. 5 shows the joint area of a hard insulating plate 5 running in the vertical direction 14 with a vermiculite insulating plate 12 running in the horizontal direction 15, the vermiculite insulating plate 12 in turn being weighted down by a silicon oxide insulating plate 13 likewise running in the horizontal direction 15.
  • Both the abutting surface 17 of the vermiculite insulating plate 12 and the hard insulating plate abutting surface 18 are made flat according to the exemplary embodiment in FIG. 5.
  • the sealing strip 19 is inserted between the abutting surface 17 of the vermiculite insulating plate 12 and the hard insulating plate abutting surface 18.
  • the sealing strip 19 is made either of quartz silk fabric or high-melting glass silk fabric.
  • 5 shows the embodiment of a flattened fabric hose as a sealing strip 19.
  • FIG. 6 shows a vermiculite insulating plate 12 running in the vertical direction 14.
  • the vermiculite insulating plate 12 has bulges 16 which are double angled at their abutting regions 20. These bulges 16 in turn form a receiving channel for the silicon oxide insulating plates 13 arranged in the horizontal direction 15.
  • the silicon oxide insulating plates 13 arranged in the horizontal direction 15 likewise have double-angled abutting surfaces 17 in the abutting regions 20.
  • the vermiculite insulating plates 12 and the silicon oxide insulating plates 13 are thus designed in the joint areas in the manner of a matrix and a matrix. In the final assembly state, a bulge 16 and an abutting surface 17 each form a wide-sealing, form-fitting surface seal.
  • the right half of Fig. 6 shows another embodiment according to the invention.
  • the vermiculite insulating plate 12 arranged in the vertical direction 14 is made in two parts according to the right half of FIG. 6 and consists of the bowl-shaped hollow shell 21 and the cover shell 22 placed on the bowl-shaped hollow shell.
  • the cavities 23 are introduced into the hollow shell 21.
  • the cavities 23 serve for recording Highly insulating materials, for example pebble, perlite, expanded clay or expanded slate etc.
  • the cavities 23 are filled with the insulating material before assembly and then the cover shell 22 is placed on the hollow shell 21 and firmly connected to it. In this way, the cavities 23 are hermetically cut off from the ambient air.
  • the passage opening 24 for the line part 25 is shown in FIG. 6.
  • the passage opening 24 breaks through both the cover shell 22 and the hollow shell 21.
  • the outer walls 26 forming the bowl edges of the bowl-shaped hollow shell 21 form the inner surfaces 27 of the passage opening 24.
  • the cavities 23 are thus also completely insulated from the passage opening 24.
  • the line part 25 can be introduced into the passage opening 24.
  • the line part 25 carries the flange-shaped sealing body 28 on its side facing the storage core 10 in the final assembly state.
  • the flange-shaped sealing body 28 is located in the flange groove 29 introduced on the storage core side on the through opening 24.
  • FIG. 7 The right-hand half of the vertically arranged, two-part vermiculite insulating plate 12 according to FIG. 6 and the silicon oxide insulating plate 13 arranged in the horizontal direction 15 is shown in FIG. 7.
  • the abutting surface 17 of the silicon oxide insulating plate 13 arranged in the horizontal direction 15 is flattened according to FIG. 7.
  • the insulating lug 30 projects from the covering shell 22 into the gusset 31 formed by the abutting surface 17 of the silicon oxide insulating plate 13 and the outer wall 26 of the hollow shell 21.
  • the insulating nose 30 snaps into the gusset 31, so to speak, according to the lock-key principle.
  • FIG. 8 shows an embodiment that differs from FIG. 7.
  • the insulating nose 30 according to FIG. 8 is a projection which only projects beyond the outer wall 26.
  • the insulating effect is achieved in this embodiment by the sealing strip 19.
  • the sealing strip 19 is positioned between the outside of the outer wall 26 of the hollow shell 21 and the side surface of the silicon oxide insulating plate 13 arranged in the horizontal direction 15 facing the hollow shell 21.
  • the sealing strip 19 from FIG. 8 otherwise corresponds to the sealing strip 19 from FIG. 5.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Central Heating Systems (AREA)
  • Resistance Heating (AREA)
  • Thermal Insulation (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)

Claims (15)

  1. Appareil de chauffage électrique par accumulation comportant:
    a) un coeur d'accumulation de chaleur (10),
    b) un boîtier protecteur (8) qui entoure sensiblement le coeur d'accumulation (10) et
    c) une couche d'isolation thermique
    c1) qui isole thermiquement le coeur d'accumulation (10),
    c2) qui est disposée entre le coeur d'accumulation (10) et le boîtier protecteur (8),
       caractérisé en ce que
    d) la couche d'isolation thermique consiste en plusieurs plaques isolantes (5,6,12,13),
    e) les surfaces des plaques isolantes qui sont en contact avec le courant d'air qui doit être chauffé consistent en un matériau non fibreux, et
    f) à l'état de montage final les plaques isolantes forment un contact surfacique thermiquement étanche au niveau de leurs surfaces de contact (17).
  2. Appareil de chauffage par accumulation selon la revendication 1, caractérisé en ce que les surfaces de contact (17) des plaques isolantes (5,6,12,13) sont adaptées en section transversale les unes par rapport aux autres à la manière d'une matrice et d'un poinçon de sorte qu'à l'état de montage final elles s'interpénètrent par assemblage de forme pour la liaison thermiquement étanche des plaques isolantes (5,6,12,13) voisines dans le domaine des surfaces de contact (17).
  3. Appareil de chauffage par accumulation selon la revendication 2, caractérisé en ce qu'un agent d'étanchéité déformable est situé entre les surfaces de contact (17) de deux plaques isolantes (5, 6, 12, 13) voisines pour améliorer l'étanchéification de l'interstice.
  4. Appareil de chauffage par accumulation selon la revendication 3, caractérisé en ce que l'agent d'étanchéité est une plaque de matériau mou déformable plastiquement.
  5. Appareil de chauffage par accumulation selon la revendication 3, caractérisé en ce que l'agent d'étanchéité est un tissu fibreux inorganique élastiquement déformable présentant une grosseur de fibre supérieure à 5 µm.
  6. Appareil de chauffage par accumulation selon la revendication 3, caractérisé en ce que le tissu fibreux est un tuyau en tissu.
  7. Appareil de chauffage par accumulation selon une ou plusieurs des revendications précédentes, caractérisé en ce que les plaques isolantes (5, 6, 12, 13) sont sous forme de plaques isolantes dures (5) et consistent de préférence en vermiculite liée de manière inorganique.
  8. Appareil de chauffage par accumulation selon une ou plusieurs des revendications précédentes, caractérisé en ce que les plaques isolantes (5, 6, 12, 13) sont sous forme de plaques en matériau mou à haute capacité d'arrêt (6) et consistent de préférence en oxyde de silicium microporeux.
  9. Appareil de chauffage par accumulation selon une ou plusieurs des revendications précédentes, caractérisé en ce que la couche isolante consiste en partie en plaques isolantes dures (5) et en partie en plaques en matériau mou à haute capacité d'arrêt (6).
  10. Appareil de chauffage par accumulation selon la revendication 9, caractérisé en ce qu'à l'état de montage final les surfaces de contact (17) des plaques isolantes dures (5) s'adaptent aux surfaces de contact des plaques en matériau mou à haute capacité d'arrêt (6) de telle manière que les surfaces de contact (17) des plaques en matériau mou à haute capacité d'arrêt (6) sont comprimées par la pression surfacique des surfaces d'arrêt (17) des plaques isolantes dures (5) pour l'étanchéification des interstices.
  11. Appareil de chauffage par accumulation selon une ou plusieurs des revendications précédentes, caractérisé
    - en ce que des cavités (23) sont prévues dans les plaques isolantes (5, 6, 12, 13) et
    - en ce que les cavités (23) peuvent être remplies de matériau isolant à haute capacité d'arrêt.
  12. Appareil de chauffage par accumulation selon la revendication 11, caractérisé en ce que les plaques isolantes (5, 6, 12, 13) peuvent être constituées par une coque creuse (21) en forme d'auge destinée à recevoir le matériau isolant et en une coque de recouvrement (22) en forme de couvercle qui peut être appliquée sur la coque creuse (21).
  13. Appareil de chauffage par accumulation selon la revendication 11 et/ou selon la revendication 12, caractérisé en ce que la plaque isolante (5, 6, 12, 13) comporte plusieurs cavités (23) séparées.
  14. Appareil de chauffage par accumulation selon la revendication 13, caractérisé en ce que des ouvertures de passage (24) pour des conduites (25) sont pratiquées dans la coque de recouvrement (22) et en ce que les parois externes (26) des cavités (23) qui forment les bords des auges forment la surface interne (27) des ouvertures de passage (24) dans les coques creuses (21).
  15. Appareil de chauffage par accumulation selon la revendication 14, caractérisé en ce que les conduites (25) sont munies de corps d'étanchéité (28) en forme de brides pour la fermeture isolante des ouvertures de passage (24) à l'état de montage final.
EP92250234A 1991-08-31 1992-08-28 Appareil de chauffage électrique à accumulation thermiquement isolé Expired - Lifetime EP0530933B1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE4128980 1991-08-31
DE4128980 1991-08-31
DE9203839 1992-03-23
DE9203839U 1992-03-23

Publications (2)

Publication Number Publication Date
EP0530933A1 EP0530933A1 (fr) 1993-03-10
EP0530933B1 true EP0530933B1 (fr) 1997-03-05

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ID=25906874

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Application Number Title Priority Date Filing Date
EP92250234A Expired - Lifetime EP0530933B1 (fr) 1991-08-31 1992-08-28 Appareil de chauffage électrique à accumulation thermiquement isolé

Country Status (5)

Country Link
EP (1) EP0530933B1 (fr)
AT (1) ATE149666T1 (fr)
DE (1) DE59208098D1 (fr)
ES (1) ES2041239T1 (fr)
GR (1) GR930300090T1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4343056A1 (de) * 1993-12-16 1995-06-22 Wacker Chemie Gmbh Faserfreie, wärmedämmende Verbundplatte
US7672932B2 (en) 2005-08-24 2010-03-02 Yahoo! Inc. Speculative search result based on a not-yet-submitted search query

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1323627A (fr) * 1962-02-27 1963-04-12 Perfectionnement apporté aux appareils de chauflage par accumulation
GB1092621A (en) * 1964-10-20 1967-11-29 Chidlow And Company Ltd E Improvements in or relating to electrical thermal storage heaters
DE2611115C3 (de) * 1976-03-17 1979-04-19 Hans 3559 Battenberg Viessmann Isoliermantel, insbesondere für Heizungskessel
DE3603615A1 (de) * 1986-02-06 1987-08-13 Stiebel Eltron Gmbh & Co Kg Waermespeicherheizgeraet

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ES2041239T1 (es) 1993-11-16
EP0530933A1 (fr) 1993-03-10
ATE149666T1 (de) 1997-03-15
GR930300090T1 (en) 1993-09-30
DE59208098D1 (de) 1997-04-10

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