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EP0368326B1 - Adhesive label to be stuck on a container - Google Patents

Adhesive label to be stuck on a container Download PDF

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Publication number
EP0368326B1
EP0368326B1 EP89120818A EP89120818A EP0368326B1 EP 0368326 B1 EP0368326 B1 EP 0368326B1 EP 89120818 A EP89120818 A EP 89120818A EP 89120818 A EP89120818 A EP 89120818A EP 0368326 B1 EP0368326 B1 EP 0368326B1
Authority
EP
European Patent Office
Prior art keywords
adhesive
adhesive label
film
container
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP89120818A
Other languages
German (de)
French (fr)
Other versions
EP0368326A2 (en
EP0368326A3 (en
Inventor
Hans-Peter Ast
Eberhard Paech
Werner Amberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STEINBEIS PACKAGING GMBH
Original Assignee
Zweckform Etikettiertechnik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zweckform Etikettiertechnik GmbH filed Critical Zweckform Etikettiertechnik GmbH
Priority to AT89120818T priority Critical patent/ATE102377T1/en
Publication of EP0368326A2 publication Critical patent/EP0368326A2/en
Publication of EP0368326A3 publication Critical patent/EP0368326A3/en
Application granted granted Critical
Publication of EP0368326B1 publication Critical patent/EP0368326B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0202Forms or constructions printed before use
    • G09F2003/0207Ticket
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0208Indicia
    • G09F2003/021Indicia behind the front foil
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0225Carrier web
    • G09F2003/0229Carrier roll
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/023Adhesive
    • G09F2003/0241Repositionable or pressure sensitive adhesive
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0264Shapes or borders
    • G09F2003/0266Shapes other than rectangular
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/906Roll or coil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397Single layer [continuous layer]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer

Definitions

  • the invention relates to an adhesive label for sticking to a container according to the preamble of claim 1.
  • DE-U-87 10 305 and EP-A-0 208 261 contain information on the use of polypropylene in adhesive labels.
  • an opaque, foamed label body made of polypropylene (PP), which is 80 ⁇ m thick, should be used.
  • Pressure sensitive adhesive layers made from an acrylic dispersion are known from the general prior art.
  • the object of the invention is to provide an adhesive label according to the preamble of claim 1, which is suitable for sticking onto a - preferably intended and preferably stackable - container made of PP and corresponds to the food legislation, but in a flawless, respectable manner can be printed.
  • the adhesive labels according to the invention also permit trouble-free stacking of stackable containers, for example before they are filled.
  • the pressure is protected by the PP film on the top of the PP film layer provided with the print, so that it cannot be impaired, for example, when stacking or when handling the containers.
  • the covering PP film is preferably highly glossy transparent.
  • the printed side of the PP film layer is preferably opaque, for example white.
  • PP film with embedded pressure practically eliminates the risk of contamination of the inside of the container, particularly if it is a cup, in the stack. This also minimizes the risk of germs forming and transferring to the inside of the containers, in particular the stacked cups.
  • an embodiment according to at least one of claims 2 to 6 is preferably provided.
  • Adhesive labels that are designed according to claim 2 not only meet the requirements mentioned, but can also be labeled wrinkle-free.
  • Foil layers according to claim 2 can be produced without difficulty with a surface energy for printing of more than 38 dynes and for the pressure-sensitive adhesive side of more than 36 dynes.
  • a particularly simple way of producing the film layer according to claim 2 is coextrusion.
  • the top side of PP film also facilitates the mechanical lifting (peeling) of the adhesive label from the carrier.
  • the adhesive label is to a high degree wet-proof, greaseproof and resistant to greases and oils.
  • the foamed PP core is not hygroscopic.
  • the adhesive label is tearproof.
  • the PP film layer with its foamed core significantly improves the thermal insulation effect of the container.
  • the container and the adhesive label consist of essentially the same plastic, namely PP, which increases their waste value.
  • Fig. 1 shows a section through a carrier tape with an adhesive label located on it.
  • Fig. 2 shows adhesive labels on a carrier tape wound from a roll.
  • Fig. 1 shows a carrier 1 preferably made of highly compressed kraft paper with a basis weight of 65 to 90 g / cm2, which is provided on the top with an adhesive layer 2 made of silicone.
  • an adhesive layer 2 made of silicone.
  • the core 4, 5, 6 is provided on the underside with an adhesive layer 3 made of an acrylic dispersion.
  • the print 7 is covered with a high-gloss transparent film 9 made of OPP, preferably of a thickness of 12 to 15 ⁇ m, which is glued onto the print 7 and thus onto the core 4, 5, 6 by means of a laminating adhesive 8.
  • FIG. 2 shows a winding 10 from a carrier tape 12 corresponding to the carrier 1, on which there are adhesive labels 14 with the structure of FIG. 1.
  • the winding 10 is wound with a uniform tension.
  • the edges 20, 22 of the labels 14 facing the edges 16, 18 of the carrier tape 12 have the same length and run at the same distance from the edges 16, 18.
  • the uniform winding hardness of the roll 10 and the described position of the adhesive labels 14 on the carrier tape 12 as well the dimensions mentioned allow a perfect automatic detachment of the adhesive labels 14 from the carrier tape 12 and an exact placement of the adhesive labels 14 on the containers.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Adhesive Tapes (AREA)
  • Wrappers (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)

Abstract

The invention relates to an adhesive label for adhering to a container of PP, intended preferably for receiving foodstuffs and preferably being stackable, having, on the underside, an adhesive layer and, on the upper side, a PP base layer provided with an imprint and on the upper side of the PP base layer a PP film has been adhered by a laminating adhesive.

Description

Die Erfindung betrifft ein Haftetikett zum Aufkleben auf ein Behältnis nach dem Oberbegriff des Anspruchs 1.The invention relates to an adhesive label for sticking to a container according to the preamble of claim 1.

Ein Haftetikett dieser Art ist nach der DE-PS 34 30 162 bekannt. Dort ist über das Material der Folienschicht und der Folie nichts ausgesagt.An adhesive label of this type is known from DE-PS 34 30 162. There is nothing said about the material of the film layer and the film.

Nach der US-PS 38 13 801 ist es bekannt, eine Verbundfolie mit einer Schicht aus geschäumtem Polyurethan (PU) zu versehen.According to US-PS 38 13 801 it is known to provide a composite film with a layer of foamed polyurethane (PU).

Das DE-U-87 10 305 und die EP-A-0 208 261 enthalten Angaben über die Verwendung von Polypropylen in Haftetiketten.DE-U-87 10 305 and EP-A-0 208 261 contain information on the use of polypropylene in adhesive labels.

Nach dem DE-GM 89 04 414 soll ein opaker, geschäumter Etikettenkörper aus Polypropylen (PP), der 80µm stark ist, eingesetzt werden.According to DE-GM 89 04 414, an opaque, foamed label body made of polypropylene (PP), which is 80 µm thick, should be used.

Aus dem allgemeinen Stand der Technik sind Haftklebstoffschichten aus einer Acryldispersion bekannt.Pressure sensitive adhesive layers made from an acrylic dispersion are known from the general prior art.

Aufgabe der Erfindung ist es, ein Haftetikett nach dem Oberbegriff des Anspruchs 1 anzugeben, das zum Aufkleben auf ein - vorzugsweise zur Aufnahme von Lebensmitteln bestimmtes und vorzugsweise stapelbares - Behältnis aus PP geeignet ist und der Lebensmittelgesetzgebung entspricht, dabei aber in einwandfreier, ansehnlicher Weise mit einem Druck versehen werden kann.The object of the invention is to provide an adhesive label according to the preamble of claim 1, which is suitable for sticking onto a - preferably intended and preferably stackable - container made of PP and corresponds to the food legislation, but in a flawless, respectable manner can be printed.

Die Lösung dieser Aufgabe ist in Anspruch 1 angegeben.The solution to this problem is specified in claim 1.

Vorteilhafte Ausgestaltungen der Erfindung sind in den Unteransprüchen angegeben.Advantageous embodiments of the invention are specified in the subclaims.

Die erfindungsgemäßen Haftetiketten gestatten auch eine störungsfreie Stapelung stapelbarer Behältnisse, etwa vor deren Befüllung.The adhesive labels according to the invention also permit trouble-free stacking of stackable containers, for example before they are filled.

Durch die PP-Folie auf der Oberseite der mit dem Druck versehenen PP-Folienschicht wird der Druck geschützt, so daß er etwa beim Stapeln oder bei der Handhabung der Behältnisse nicht beeinträchtigt werden kann. Bevorzugt ist die abdeckende PP-Folie hochglänzend transparent. Die mit dem Druck versehene Seite der PP-Folienschicht ist bevorzugt opak, etwa weiß.The pressure is protected by the PP film on the top of the PP film layer provided with the print, so that it cannot be impaired, for example, when stacking or when handling the containers. The covering PP film is preferably highly glossy transparent. The printed side of the PP film layer is preferably opaque, for example white.

Durch die Verwendung von PP-Folie mit eingebettetem Druck wird die Gefahr einer Verunreinigung der Innenseite des Behältnisses, insbesondere, wenn es sich dabei um einen Becher handelt, im Stapel praktisch ausgeschlossen. Dadurch wird auch die Gefahr des Bildens und des Übergangs von Keimen auf die Innenseite der Behältnisse, also inbesondere der gestapelten Becher, auf ein Minimum gebracht.The use of PP film with embedded pressure practically eliminates the risk of contamination of the inside of the container, particularly if it is a cup, in the stack. This also minimizes the risk of germs forming and transferring to the inside of the containers, in particular the stacked cups.

Um das Herstellen und das Verarbeiten des Haftetiketts, insbesondere das Bedrucken, das Stanzen und das Gitterabheben von einem Trägerband und das maschinelle Abheben des Haftetiketts von dem Trägerband zu erleichtern, bei der erforderlichen Flexibilität des Haftetiketts das Haftetikett aber dennoch hinreichend stabil machen zu können, ist bevorzugt eine Ausbildung nach wenigstens einem der Ansprüche 2 bis 6 vorgesehen. Haftetiketten, die nach Anspruch 2 ausgebildet sind, erfüllen nicht nur die genannten Forderungen, sondern lassen sich auch faltenfrei etikettieren. Folienschichten nach Anspruch 2 lassen sich ohne Schwierigkeit mit einer Oberflächenenergie zur Bedruckung von mehr als 38 dyn und zur Haftklebstoffseite von mehr als 36 dyn herstellen. Eine besonders einfache Herstellungsart der Folienschicht nach Anspruch 2 ist Koextrudieren.For the manufacture and processing of the adhesive label, in particular the printing, punching and lattice lifting of a carrier tape and the mechanical lifting of the adhesive label from the carrier tape, but still being able to make the adhesive label sufficiently stable given the flexibility of the adhesive label, an embodiment according to at least one of claims 2 to 6 is preferably provided. Adhesive labels that are designed according to claim 2 not only meet the requirements mentioned, but can also be labeled wrinkle-free. Foil layers according to claim 2 can be produced without difficulty with a surface energy for printing of more than 38 dynes and for the pressure-sensitive adhesive side of more than 36 dynes. A particularly simple way of producing the film layer according to claim 2 is coextrusion.

Die Oberseite PP-Folie erleichtert auch das maschinelle Abheben (Abziehen) des Haftetiketts vom Träger.The top side of PP film also facilitates the mechanical lifting (peeling) of the adhesive label from the carrier.

Das Haftetikett ist in hohem Maße naßfest, fettdicht sowie gegen Fette und Öle widerstandsfähig. Insbesondere ist der geschäumte PP-Kern nicht hygroskopisch.The adhesive label is to a high degree wet-proof, greaseproof and resistant to greases and oils. In particular, the foamed PP core is not hygroscopic.

Das Haftetikett ist einreißfest. Die PP-Folienschicht mit ihrem geschäumten Kern verbessert wesentlich die Wärmeisolationswirkung des Behältnisses.The adhesive label is tearproof. The PP film layer with its foamed core significantly improves the thermal insulation effect of the container.

Besonders bemerkenswert ist auch, daß Behältnis und Haftetikett aus im wesentlichen dem gleichen Kunststoff, nämlich PP, bestehen, was ihren Abfallwert erhöht.It is also particularly noteworthy that the container and the adhesive label consist of essentially the same plastic, namely PP, which increases their waste value.

Die Erfindung wird im folgenden an einem Ausführungsbeispiel unter Hinweis auf die beigefügten Zeichnungen beschrieben.The invention is described below using an exemplary embodiment with reference to the accompanying drawings.

Fig. 1 zeigt einen Schnitt durch ein Trägerband mit einem auf ihm befindlichen Haftetikett.Fig. 1 shows a section through a carrier tape with an adhesive label located on it.

Fig. 2 zeigt Haftetiketten auf einem von einer Rolle gewickelten Trägerband.Fig. 2 shows adhesive labels on a carrier tape wound from a roll.

Fig. 1 zeigt einen Träger 1 bevorzugt aus hochverdichtetem Kraftpapier mit einem Flächengewicht von 65 bis 90 g/cm², das oberseitig mit einer abhäsiven Schicht 2 aus Silikon versehen ist. Auf der Schicht 2 befindet sich ablösbar ein Haftetikett mit einem Kern 4, 5, 6 aus der Reihe nach OPP weiß, PP weiß geschäumt, OPP weiß einer Gesamtstärke von 40 bis 80 µm, bevorzugt 40 bis 60µm. Der Kern 4, 5, 6 ist unterseitig mit einer Klebstoffschicht 3 aus einer Acryldispersion versehen. Auf der Folienschicht 4, 5, 6 befindet sich oberseitig ein Druck 7 aus einer bevorzugt lebensmittelechten Farbe. Der Druck 7 ist mit einer hochglänzenden transparenten Folie 9 aus OPP bevorzugt einer Stärke von 12 bis 15µm abgedeckt, die auf den Druck 7 und damit auf den Kern 4, 5, 6 mittels eines Kaschierklebers 8 aufgeklebt ist.Fig. 1 shows a carrier 1 preferably made of highly compressed kraft paper with a basis weight of 65 to 90 g / cm², which is provided on the top with an adhesive layer 2 made of silicone. On the layer 2 there is a detachable adhesive label with a core 4, 5, 6 from the sequence OPP white, PP white foamed, OPP white with a total thickness of 40 to 80 μm, preferably 40 to 60 μm. The core 4, 5, 6 is provided on the underside with an adhesive layer 3 made of an acrylic dispersion. On the film layer 4, 5, 6 there is a print 7 made of a preferably food-safe color. The print 7 is covered with a high-gloss transparent film 9 made of OPP, preferably of a thickness of 12 to 15 μm, which is glued onto the print 7 and thus onto the core 4, 5, 6 by means of a laminating adhesive 8.

Fig. 2 zeigt einen Wickel 10 aus einem dem Träger 1 entsprechenden Trägerband 12, auf dem sich Haftetiketten 14 mit dem Aufbau der Fig. 1 befinden. Der Wickel 10 ist mit gleichmäßiger Spannung gewickelt. Die den Kanten 16, 18 des Trägerbands 12 zugewandten Kanten 20, 22 der Etiketten 14 haben gleiche Länge und verlaufen in gleichem Abstand von den Kanten 16, 18. Die gleichmäßige Wickelhärte des Wickels 10 und die beschriebene Lage der Haftetiketten 14 auf dem Trägerband 12 sowie deren genannte Abmessungen gestatten ein einwandfreies automatisches Ablösen der Haftetiketten 14 von dem Trägerband 12 und eine genaue Plazierung der Haftetiketten 14 auf den Behältnissen.FIG. 2 shows a winding 10 from a carrier tape 12 corresponding to the carrier 1, on which there are adhesive labels 14 with the structure of FIG. 1. The winding 10 is wound with a uniform tension. The edges 20, 22 of the labels 14 facing the edges 16, 18 of the carrier tape 12 have the same length and run at the same distance from the edges 16, 18. The uniform winding hardness of the roll 10 and the described position of the adhesive labels 14 on the carrier tape 12 as well the dimensions mentioned allow a perfect automatic detachment of the adhesive labels 14 from the carrier tape 12 and an exact placement of the adhesive labels 14 on the containers.

Claims (6)

  1. Adhesive label (14) for sticking onto a container having a film layer (4, 5, 6), which has on its underside an adhesive layer (3), on its upper side an imprint (7), and a film (9) stuck to the upper side of the film layer (4, 5, 6) by means of a laminating adhesive (8), characterised in that the film layer (4, 5, 6) and the film (9) for sticking onto a container of polypropylene (PP) - intended preferably for receiving foodstuffs and preferably being stackable - consist of polypropylene (PP).
  2. Adhesive label according to claim 1, characterised in that the PP film layer (4, 5, 6) has a foamed PP core (5) which is covered on both sides with drawn polypropylene (OPP) layers (4, 6).
  3. Adhesive label according to claim 1 or 2, characterised in that the PP film layer (4, 5, 6) has a thickness of 40 to 80 µm.
  4. Adhesive label according to any one of the preceding claims, characterised in that the film (9) consists of drawn polypropylene (OPP).
  5. Adhesive label according to any one of the preceding claims, characterised in that the film (9) consists of polypropylene and has a thickness of 12 to 15 µm.
  6. Adhesive label according to any one of the preceding claims, characterised in that the adhesive layer (3) consists of an acrylic dispersion.
EP89120818A 1988-11-09 1989-11-09 Adhesive label to be stuck on a container Expired - Lifetime EP0368326B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89120818T ATE102377T1 (en) 1988-11-09 1989-11-09 ADHESIVE LABEL FOR STICKING ON A CONTAINER.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3838027 1988-11-09
DE3838027A DE3838027A1 (en) 1988-11-09 1988-11-09 ADHESIVE LABEL FOR STICKING ON A PACKAGE OF PP

Publications (3)

Publication Number Publication Date
EP0368326A2 EP0368326A2 (en) 1990-05-16
EP0368326A3 EP0368326A3 (en) 1991-06-12
EP0368326B1 true EP0368326B1 (en) 1994-03-02

Family

ID=6366823

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89120818A Expired - Lifetime EP0368326B1 (en) 1988-11-09 1989-11-09 Adhesive label to be stuck on a container

Country Status (6)

Country Link
US (1) US5085906A (en)
EP (1) EP0368326B1 (en)
AT (1) ATE102377T1 (en)
DE (2) DE3838027A1 (en)
ES (1) ES2050206T3 (en)
HK (1) HK1001907A1 (en)

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US4764405A (en) * 1987-07-22 1988-08-16 Air Products And Chemicals, Inc. Method for increasing barrier properties of thermoplastic substrates
DE8710305U1 (en) * 1987-07-28 1987-11-05 Hoechst Ag, 65929 Frankfurt Laminate composition for covering flat structures
DE8904414U1 (en) * 1989-04-08 1989-05-18 Hoechst Ag, 6230 Frankfurt Can or cup-shaped packaging container

Also Published As

Publication number Publication date
ES2050206T3 (en) 1994-05-16
DE3838027A1 (en) 1990-05-10
HK1001907A1 (en) 1998-07-17
EP0368326A2 (en) 1990-05-16
EP0368326A3 (en) 1991-06-12
DE3838027C2 (en) 1992-04-16
DE58907092D1 (en) 1994-04-07
ATE102377T1 (en) 1994-03-15
US5085906A (en) 1992-02-04

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