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EA200200481A1 - Способ получения производных 4-трифторметилсульфинилпиразола - Google Patents

Способ получения производных 4-трифторметилсульфинилпиразола

Info

Publication number
EA200200481A1
EA200200481A1 EA200200481A EA200200481A EA200200481A1 EA 200200481 A1 EA200200481 A1 EA 200200481A1 EA 200200481 A EA200200481 A EA 200200481A EA 200200481 A EA200200481 A EA 200200481A EA 200200481 A1 EA200200481 A1 EA 200200481A1
Authority
EA
Eurasian Patent Office
Prior art keywords
halogen
trifluoromethylsulfonylpyrazole
derivatives
producing
haloalkyl
Prior art date
Application number
EA200200481A
Other languages
English (en)
Other versions
EA005077B1 (ru
Inventor
Жан-Луи Клавель
Изабелль Пельта
Сильви Ле Бар
Филипп Шарро
Original Assignee
Авентис Кропсайенс С.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8167491&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EA200200481(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Авентис Кропсайенс С.А. filed Critical Авентис Кропсайенс С.А.
Publication of EA200200481A1 publication Critical patent/EA200200481A1/ru
Publication of EA005077B1 publication Critical patent/EA005077B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

Предложен способ получения соединения формулы (I), в котором Rозначает галоген, галоалкил, галоалкокси, RS(O)- или -SF; Rозначает водород или галоген; Rозначает галоген; Rозначает алкил или галоалкил и n означает 0,1 или 2; указанный способ включает окисление соединения формулы (II), в котором R, Rи W те же, что определены выше, трифторперуксусной кислотой в присутствии ингибитора коррозии.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA200200481A 1999-10-22 1999-10-22 Способ получения производных 4-трифторметилсульфинилпиразола EA005077B1 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP1999/008687 WO2001030760A1 (en) 1999-10-22 1999-10-22 Process for preparing 4-trifluoromethylsulphinylpyrazole derivative

Publications (2)

Publication Number Publication Date
EA200200481A1 true EA200200481A1 (ru) 2002-10-31
EA005077B1 EA005077B1 (ru) 2004-10-28

Family

ID=8167491

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200200481A EA005077B1 (ru) 1999-10-22 1999-10-22 Способ получения производных 4-трифторметилсульфинилпиразола

Country Status (30)

Country Link
US (2) US6620943B1 (ru)
EP (1) EP1222173B1 (ru)
JP (1) JP4666863B2 (ru)
KR (2) KR100665599B1 (ru)
CN (3) CN101445483B (ru)
AT (1) ATE273961T1 (ru)
AU (1) AU783139B2 (ru)
BG (1) BG65483B1 (ru)
BR (1) BR9917518B1 (ru)
CA (1) CA2384283C (ru)
CZ (1) CZ299822B6 (ru)
DE (1) DE69919599T2 (ru)
DK (1) DK1222173T3 (ru)
EA (1) EA005077B1 (ru)
ES (1) ES2222743T3 (ru)
HR (1) HRP20020438B1 (ru)
HU (1) HU229393B1 (ru)
IL (2) IL149152A0 (ru)
IN (2) IN2005MU00818A (ru)
ME (1) MEP7808A (ru)
MX (1) MX229662B (ru)
NZ (2) NZ527896A (ru)
PL (1) PL206482B1 (ru)
PT (1) PT1222173E (ru)
RO (1) RO121209B1 (ru)
TR (2) TR200201072T2 (ru)
TW (1) TW553936B (ru)
UA (1) UA73752C2 (ru)
WO (1) WO2001030760A1 (ru)
ZA (1) ZA200201961B (ru)

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WO2005023774A1 (en) * 2003-09-11 2005-03-17 Cheminova A/S Process for the preparation of a trifluoromethylthioether
CN100586934C (zh) * 2003-11-07 2010-02-03 凯米诺瓦有限公司 制备三氟甲基硫醚的方法
DE102004020069C5 (de) 2004-04-24 2013-12-05 Voith Patent Gmbh Verfahren zum Satinieren einer Papierbahn
AU2013203236A1 (en) * 2005-12-14 2013-05-02 Makhteshim Chemical Works Ltd. Polymorphs and amorphous forms of 5-amino-1-[2,6- dichloro-4-(trifluoromethyl)phenyl]-4- [(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile
JP5396085B2 (ja) 2005-12-14 2014-01-22 マクテシム・ケミカル・ワークス・リミテツド ５−アミノ−１−［２，６−ジクロロ−４−（トリフルオロメチル）フェニル］−４−［（トリフルオロメチル）スルフィニル］−１ｈ−ピラゾール−３−カルボニトリルの多形および非晶形
BRPI0621611B1 (pt) 2006-04-25 2015-08-18 Gharda Chemicals Ltd Processo para a preparação de fipronila, inseticida e pirazóis relacionados
CN101168529B (zh) * 2006-10-24 2011-03-23 温州大学 氟虫腈、乙虫腈及其衍生物的合成方法
MX2009004401A (es) 2006-11-10 2009-05-08 Basf Se Proceso para la sulfinilacion de un derivado de pirazol.
BRPI0718717A2 (pt) 2006-11-10 2013-11-26 Basf Se Modificação cristalina ii de fipronil, fipronil sólido, processo para preparar a modificação cristalina ii, mistura pesticida ou parasiticida sinergística, composição pesticida ou parasiticida, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, métodos para controlar pragas, para proteger uma planta da infestação e ataque por pragas, para proteger semente, e para tratar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas, semente, uso da modificação cristalina ii, ou do fipronil sólido, ou da mistura, ou da composição, e, processo para a preparação de uma composição para trtar, controlar, prevenir ou proteger animais contra infestação ou infecção por parasitas
DK2081908T3 (da) 2006-11-10 2013-07-29 Basf Agro B V Arnhem Nl Zuerich Branch Fremgangsmåde til sulfinylering af et pyrazolderivat
CA2667112C (en) * 2006-11-10 2015-08-11 Basf Se Crystalline modification of fipronil
HRP20110641T4 (hr) * 2006-11-10 2015-05-22 Basf Se Kristalna modifikacija fipronila
UA110598C2 (uk) * 2006-11-10 2016-01-25 Басф Се Спосіб одержання кристалічної модифікації фіпронілу
CN102171182B (zh) 2008-10-02 2015-07-22 巴斯夫欧洲公司 生产和提纯三氟甲烷亚磺酸的方法
WO2010049746A1 (en) * 2008-10-27 2010-05-06 Dynamit Nobel Gmbh Explosivstoff-Und Systemtechnic Process for the synthesis of fipronil
US8476459B2 (en) 2009-10-30 2013-07-02 Basf Se Process for the preparation of 4-sulfinyl-pyrazole derivatives
AU2010100462A4 (en) 2010-03-03 2010-06-17 Keki Hormusji Gharda A process for the synthesis of Fipronil
IT1400666B1 (it) 2010-07-07 2013-06-28 Finchimica Srl Procedimento per la sintesi di 5-amino, 1-fenil, 3-ciano, 4-trifluorometil sulfinil pirazoli.
BR112013000758A8 (pt) 2010-07-12 2018-02-14 Adama Makhteshim Ltd Processo para preparar- 5 amino -3- ciano-1- (2,6 dicloro-4 triflúor metil fenil)-4- triflúor metil sulfinil-pirazol
EP2663192A4 (en) * 2011-01-14 2015-06-03 Keki Hormusji Gharda POLYMORPHISMS IN 5-AMINO-1- (2,6-DICHLOR-4-TRIFLUOROMETHYLPHENYL-) 3-CYAN-4-TRIFLUOR-METHYL-SULFINYL-PYRAZOLE
WO2012164571A1 (en) 2011-05-30 2012-12-06 Keki Hormusji Gharda Process for synthesis of fipronil
CN102633722B (zh) * 2012-03-20 2015-05-06 金坛市凌云动物保健品有限公司 一种非泼罗尼的制备方法
TWI579274B (zh) * 2012-04-20 2017-04-21 龍馬躍公司 製備１－芳基－５－烷基吡唑化合物的改良方法
CN102690232A (zh) * 2012-05-30 2012-09-26 河南中医学院 一种氟虫腈中间体的合成方法
US8993613B2 (en) 2013-04-17 2015-03-31 The Hartz Mountain Corporation Ectoparasiticidal formulations
CN105254565A (zh) * 2015-09-30 2016-01-20 乐平市康鑫医药化工有限公司 由氰基吡唑一锅法合成硫醚的工艺方法
CN106977460A (zh) * 2017-04-19 2017-07-25 江苏托球农化股份有限公司 1‑(2,6‑二氯‑4‑三氟甲基)苯基‑3‑氰基‑4‑乙巯基‑5‑氨基吡唑的合成
EP3412658A1 (en) 2017-06-09 2018-12-12 Solvay Sa Processes for the manufacture of sulfur-substitued pyrazole derivatives
EP3412659A1 (en) 2017-06-09 2018-12-12 Solvay Sa Processes for the manufacture of sulfur-substituted pyrazole derivatives
CN112430213A (zh) * 2020-12-03 2021-03-02 江苏优普生物化学科技股份有限公司 一种三氟甲硫基吡唑合成工艺
CN113149909B (zh) * 2021-03-24 2022-04-19 台州达辰药业有限公司 5-氨基-3-氰基-1-(2,6-二氯-4-三氟甲基-苯基)吡唑二硫化物制备方法
CN113480482B (zh) * 2021-07-05 2022-11-18 海正药业南通有限公司 一种非泼罗尼中间体的合成方法
CN114213330A (zh) * 2021-12-29 2022-03-22 天和药业股份有限公司 一种氟虫腈精制母液的处理方法

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FR2716453B1 (fr) 1994-02-22 1996-03-29 Rhone Poulenc Agrochimie Procédé de sulfinylation de composés hétérocycliques.
DE3602728A1 (de) * 1985-05-17 1986-11-20 Bayer Ag, 51373 Leverkusen Schaedlingsbekaempfungsmittel auf basis von pyrazolderivaten
US5547974A (en) * 1985-12-20 1996-08-20 Rhone-Poulenc Agriculture Ltd. Derivatives of N-phenylpyrazoles
US5232940A (en) 1985-12-20 1993-08-03 Hatton Leslie R Derivatives of N-phenylpyrazoles
GB8713768D0 (en) * 1987-06-12 1987-07-15 May & Baker Ltd Compositions of matter
CA2004776C (fr) * 1988-12-13 2000-04-25 Claude Wakselman Procede de preparation de perfluoroalkylthioethers

Also Published As

Publication number Publication date
US20040034234A1 (en) 2004-02-19
KR20020040899A (ko) 2002-05-30
UA73752C2 (en) 2005-09-15
EA005077B1 (ru) 2004-10-28
CZ20021384A3 (cs) 2002-08-14
NZ527896A (en) 2004-07-30
ATE273961T1 (de) 2004-09-15
US6620943B1 (en) 2003-09-16
WO2001030760A1 (en) 2001-05-03
HUP0203206A3 (en) 2005-11-28
BR9917518B1 (pt) 2009-08-11
US6881848B2 (en) 2005-04-19
IN2005MU00818A (ru) 2005-11-11
DK1222173T3 (da) 2004-09-20
CN1896066B (zh) 2011-06-15
KR100665598B1 (ko) 2007-01-10
MEP7808A (en) 2010-06-10
CZ299822B6 (cs) 2008-12-03
EP1222173B1 (en) 2004-08-18
KR20060097747A (ko) 2006-09-14
PT1222173E (pt) 2004-11-30
JP4666863B2 (ja) 2011-04-06
HRP20020438B1 (en) 2011-01-31
IN192712B (ru) 2004-05-15
PL206482B1 (pl) 2010-08-31
RO121209B1 (ro) 2007-01-30
IL149152A (en) 2008-08-07
IN2002MU00312A (ru) 2007-06-29
CN1332730A (zh) 2002-01-23
MX229662B (es) 2005-08-04
CN1896066A (zh) 2007-01-17
CN1163488C (zh) 2004-08-25
DE69919599D1 (de) 2004-09-23
CN101445483B (zh) 2011-03-30
PL354611A1 (en) 2004-02-09
BG106622A (en) 2002-12-29
BR9917518A (pt) 2002-06-18
CN101445483A (zh) 2009-06-03
AU783139B2 (en) 2005-09-29
EP1222173A1 (en) 2002-07-17
TR200202806T2 (tr) 2003-03-21
JP2003512456A (ja) 2003-04-02
IL149152A0 (en) 2002-11-10
TW553936B (en) 2003-09-21
MXPA02003944A (es) 2003-10-15
HRP20020438A2 (en) 2004-08-31
CA2384283A1 (en) 2001-05-03
DE69919599T2 (de) 2005-08-11
AU1270700A (en) 2001-05-08
NZ517770A (en) 2003-11-28
BG65483B1 (bg) 2008-09-30
CA2384283C (en) 2009-02-03
ES2222743T3 (es) 2005-02-01
HU229393B1 (en) 2013-11-28
KR100665599B1 (ko) 2007-01-10
ZA200201961B (en) 2003-05-28
HUP0203206A2 (hu) 2003-03-28
TR200201072T2 (tr) 2002-07-22

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Designated state(s): AM AZ KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): BY

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Designated state(s): RU