DK0738235T3 - Fremgangsmåde til fremstilling af hydrogen/carbonmonoxidblandinger eller af hydrogen ud fra methan - Google Patents
Fremgangsmåde til fremstilling af hydrogen/carbonmonoxidblandinger eller af hydrogen ud fra methanInfo
- Publication number
- DK0738235T3 DK0738235T3 DK94917197.9T DK94917197T DK0738235T3 DK 0738235 T3 DK0738235 T3 DK 0738235T3 DK 94917197 T DK94917197 T DK 94917197T DK 0738235 T3 DK0738235 T3 DK 0738235T3
- Authority
- DK
- Denmark
- Prior art keywords
- hydrogen
- pct
- methane
- preparation
- carbon monoxide
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/31—Density
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1052—Nickel or cobalt catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
- C01B2203/1064—Platinum group metal catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL9300833A NL9300833A (nl) | 1993-05-13 | 1993-05-13 | Werkwijze voor de produktie van waterstof/koolmonoxide mengsels of waterstof uit methaan. |
Publications (1)
Publication Number | Publication Date |
---|---|
DK0738235T3 true DK0738235T3 (da) | 1998-05-18 |
Family
ID=19862400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK94917197.9T DK0738235T3 (da) | 1993-05-13 | 1994-05-16 | Fremgangsmåde til fremstilling af hydrogen/carbonmonoxidblandinger eller af hydrogen ud fra methan |
Country Status (12)
Country | Link |
---|---|
US (1) | US5714092A (da) |
EP (1) | EP0738235B1 (da) |
JP (1) | JPH09502414A (da) |
AT (1) | ATE159231T1 (da) |
AU (1) | AU6858694A (da) |
DE (1) | DE69406311T2 (da) |
DK (1) | DK0738235T3 (da) |
ES (1) | ES2110757T3 (da) |
GR (1) | GR3025614T3 (da) |
NL (1) | NL9300833A (da) |
NO (1) | NO954543L (da) |
WO (1) | WO1994026656A1 (da) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5905180A (en) | 1996-01-22 | 1999-05-18 | Regents Of The University Of Minnesota | Catalytic oxidative dehydrogenation process and catalyst |
JPH09315801A (ja) * | 1996-03-26 | 1997-12-09 | Toyota Motor Corp | 燃料改質方法と燃料改質装置ならびに該燃料改質装置を備えた燃料電池システム |
WO1999011572A1 (en) * | 1997-09-01 | 1999-03-11 | Laxarco Holding Limited | Electrically assisted partial oxidation of light hydrocarbons by oxygen |
FR2768424B1 (fr) * | 1997-09-01 | 1999-10-29 | Albin Czernichowski | Assistance electrique d'oxydation partielle d'hydrocarbures legers par l'oxygene |
US6254807B1 (en) * | 1998-01-12 | 2001-07-03 | Regents Of The University Of Minnesota | Control of H2 and CO produced in partial oxidation process |
DE69943241D1 (de) * | 1998-07-08 | 2011-04-14 | Toyota Motor Co Ltd | Vorrichtung zur reformierung von brennstoffen |
US6475960B1 (en) | 1998-09-04 | 2002-11-05 | Exxonmobil Research And Engineering Co. | Premium synthetic lubricants |
US6080301A (en) | 1998-09-04 | 2000-06-27 | Exxonmobil Research And Engineering Company | Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins |
NO317870B1 (no) * | 1998-09-16 | 2004-12-27 | Statoil Asa | Fremgangsmate for a fremstille en H<N>2</N>-rik gass og en CO<N>2</N>-rik gass ved hoyt trykk |
CA2282948A1 (en) | 1998-09-16 | 2000-03-16 | University Technologies International, Inc. | Low temperature autothermal steam reformation of methane in a fluidized bed |
US6613708B1 (en) * | 1999-06-07 | 2003-09-02 | Exxonmobil Chemical Patents Inc. | Catalyst selectivation |
WO2001076735A1 (en) * | 2000-04-07 | 2001-10-18 | Phillips Petroleum Company | Process for preparing fischer-tropsch catalyst |
US6436363B1 (en) * | 2000-08-31 | 2002-08-20 | Engelhard Corporation | Process for generating hydrogen-rich gas |
FR2817444B1 (fr) | 2000-11-27 | 2003-04-25 | Physiques Ecp Et Chimiques | Generateurs et circuits electriques pour alimenter des decharges instables de haute tension |
JP4098508B2 (ja) * | 2001-08-20 | 2008-06-11 | 財団法人 ひろしま産業振興機構 | 炭化水素と水蒸気とを反応させるための触媒の製造方法および当該触媒を使用した炭化水素から水素を製造する方法 |
US20030096880A1 (en) * | 2001-11-02 | 2003-05-22 | Conoco Inc. | Combustion deposited metal-metal oxide catalysts and process for producing synthesis gas |
CA2364212A1 (en) * | 2001-12-03 | 2003-06-03 | The University Of Western Ontario | Catalyst for hydrocarbon reforming reaction |
JP4102080B2 (ja) * | 2002-02-13 | 2008-06-18 | フジセラテック株式会社 | 燃料改質装置 |
US20030162846A1 (en) | 2002-02-25 | 2003-08-28 | Wang Shoou-L | Process and apparatus for the production of synthesis gas |
JP4316323B2 (ja) * | 2002-10-04 | 2009-08-19 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素リフォーミング用触媒及びその製造方法 |
JP4870900B2 (ja) * | 2003-02-24 | 2012-02-08 | 戸田工業株式会社 | 炭化水素分解用触媒及びその製造方法、並びに該炭化水素分解用触媒を用いた水素製造方法 |
US7125913B2 (en) * | 2003-03-14 | 2006-10-24 | Conocophillips Company | Partial oxidation reactors and syngas coolers using nickel-containing components |
JP4332724B2 (ja) * | 2004-02-13 | 2009-09-16 | 戸田工業株式会社 | オートサーマルリフォーミング触媒及びその製造方法、並びに該オートサーマルリフォーミング触媒を用いた水素の製造方法 |
WO2005097319A1 (en) * | 2004-04-08 | 2005-10-20 | Sulzer Metco (Canada) Inc. | Supported catalyst for steam methane reforming and autothermal reforming reactions |
JP4340892B2 (ja) * | 2004-08-24 | 2009-10-07 | 戸田工業株式会社 | 炭化水素分解用触媒及びその製造法、該炭化水素分解用触媒を用いた水素の製造方法 |
JP4332733B2 (ja) * | 2004-08-24 | 2009-09-16 | 戸田工業株式会社 | 炭化水素分解用触媒及び該炭化水素分解用触媒を用いた水素の製造方法 |
WO2008008524A2 (en) | 2006-07-14 | 2008-01-17 | Ceramatec, Inc. | Apparatus and method of electric arc incineration |
US8618436B2 (en) | 2006-07-14 | 2013-12-31 | Ceramatec, Inc. | Apparatus and method of oxidation utilizing a gliding electric arc |
JP5180236B2 (ja) | 2007-02-23 | 2013-04-10 | セラマテック・インク | 滑動電気アーク用セラミック電極 |
DE102007038760B3 (de) * | 2007-08-16 | 2009-01-02 | Dge Dr.-Ing. Günther Engineering Gmbh | Verfahren und Anlage zur Herstellung von Synthesegas aus Biogas |
JP6802353B2 (ja) * | 2017-03-01 | 2020-12-16 | Toyo Tire株式会社 | メタンの二酸化炭素改質用触媒及びその製造方法、並びに合成ガスの製造方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB224765A (en) * | 1924-01-23 | 1924-11-20 | Louis Steinberger | Improvements in or relating to hairpins |
JPS55139837A (en) * | 1979-04-18 | 1980-11-01 | Fujimi Kenmazai Kogyo Kk | Catalyst for steam modification of hydrocarbon |
DE3382193D1 (de) * | 1982-09-30 | 1991-04-11 | Engelhard Corp | Verfahren zur herstellung von wasserstoffreichem gas aus kohlenwasserstoffen. |
GB2139644B (en) * | 1983-04-06 | 1987-06-24 | Ici Plc | Synthesis gas |
NL8800252A (nl) * | 1988-02-02 | 1989-09-01 | Veg Gasinstituut Nv | Katalysator op drager voor het niet-selectief oxyderen van organische verbindingen, werkwijze voor het niet-selectief oxyderen van, in het bijzonder, organische verbindingen. |
IT1242994B (it) * | 1990-08-29 | 1994-05-23 | Snam Progetti | Processo catalitico per la produzione di gas di sintesi mediante reazione di combustione e di reforming degli idrocarburi |
US5206202A (en) * | 1991-07-25 | 1993-04-27 | Corning Incorporated | Catalyst device fabricated in situ and method of fabricating the device |
-
1993
- 1993-05-13 NL NL9300833A patent/NL9300833A/nl not_active Application Discontinuation
-
1994
- 1994-05-16 AT AT94917197T patent/ATE159231T1/de not_active IP Right Cessation
- 1994-05-16 AU AU68586/94A patent/AU6858694A/en not_active Abandoned
- 1994-05-16 ES ES94917197T patent/ES2110757T3/es not_active Expired - Lifetime
- 1994-05-16 US US08/545,804 patent/US5714092A/en not_active Expired - Fee Related
- 1994-05-16 JP JP6525276A patent/JPH09502414A/ja active Pending
- 1994-05-16 WO PCT/NL1994/000115 patent/WO1994026656A1/en active IP Right Grant
- 1994-05-16 DK DK94917197.9T patent/DK0738235T3/da active
- 1994-05-16 EP EP94917197A patent/EP0738235B1/en not_active Expired - Lifetime
- 1994-05-16 DE DE69406311T patent/DE69406311T2/de not_active Expired - Fee Related
-
1995
- 1995-11-10 NO NO954543A patent/NO954543L/no not_active Application Discontinuation
-
1997
- 1997-12-05 GR GR970403263T patent/GR3025614T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
DE69406311T2 (de) | 1998-04-23 |
JPH09502414A (ja) | 1997-03-11 |
NL9300833A (nl) | 1994-12-01 |
AU6858694A (en) | 1994-12-12 |
US5714092A (en) | 1998-02-03 |
DE69406311D1 (de) | 1997-11-20 |
NO954543D0 (no) | 1995-11-10 |
GR3025614T3 (en) | 1998-03-31 |
WO1994026656A1 (en) | 1994-11-24 |
NO954543L (no) | 1995-11-10 |
ES2110757T3 (es) | 1998-02-16 |
EP0738235A1 (en) | 1996-10-23 |
ATE159231T1 (de) | 1997-11-15 |
EP0738235B1 (en) | 1997-10-15 |
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