DE69935332D1 - Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation - Google Patents
Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisationInfo
- Publication number
- DE69935332D1 DE69935332D1 DE69935332T DE69935332T DE69935332D1 DE 69935332 D1 DE69935332 D1 DE 69935332D1 DE 69935332 T DE69935332 T DE 69935332T DE 69935332 T DE69935332 T DE 69935332T DE 69935332 D1 DE69935332 D1 DE 69935332D1
- Authority
- DE
- Germany
- Prior art keywords
- lewis acid
- aluminum
- olefine polymerization
- arhal
- olefin polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000002841 Lewis acid Substances 0.000 title abstract 2
- 150000007517 lewis acids Chemical class 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- -1 Lewis acid aluminum compound Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9301798P | 1998-07-16 | 1998-07-16 | |
US93017P | 1998-07-16 | ||
PCT/US1999/015618 WO2000004058A1 (en) | 1998-07-16 | 1999-07-09 | Aluminum-based lewis acid cocatalysts for olefin polymerization |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69935332D1 true DE69935332D1 (de) | 2007-04-12 |
DE69935332T2 DE69935332T2 (de) | 2007-10-31 |
Family
ID=22236368
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69935332T Expired - Fee Related DE69935332T2 (de) | 1998-07-16 | 1999-07-09 | Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation |
Country Status (10)
Country | Link |
---|---|
US (2) | US6147174A (de) |
EP (1) | EP1097175B1 (de) |
JP (1) | JP2002520452A (de) |
AT (1) | ATE355308T1 (de) |
AU (1) | AU743367B2 (de) |
BR (1) | BR9912124A (de) |
CA (1) | CA2330775A1 (de) |
DE (1) | DE69935332T2 (de) |
ES (1) | ES2283125T3 (de) |
WO (1) | WO2000004058A1 (de) |
Families Citing this family (38)
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---|---|---|---|---|
US6130302A (en) * | 1996-08-19 | 2000-10-10 | Northwestern University | Synthesis and use of (polyfluoroaryl)fluoroanions of aluminum, gallium and indium |
US6262200B1 (en) | 1996-08-19 | 2001-07-17 | Northwestern University | (Polyfluoroaryl)fluoroanions of aluminum, gallium, and indium of enhanced utility, uses thereof, and products based thereon |
ATE220682T1 (de) * | 1998-08-17 | 2002-08-15 | Dow Chemical Co | Aluminiumverbindungsmischung-enthaltende aktivatorzusammensetzung |
US6147173A (en) * | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
IT1304181B1 (it) * | 1998-12-17 | 2001-03-08 | Enichem Spa | Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine. |
CA2296818A1 (en) * | 1999-01-22 | 2000-07-22 | Ube Industries, Ltd. | Modified diene elastomer and its preparation |
KR100614993B1 (ko) * | 1999-08-13 | 2006-08-25 | 바젤 폴리올레핀 게엠베하 | 에틸렌과 C₃-C₁₂α 올레핀의 공중합체 |
US6194527B1 (en) * | 1999-09-22 | 2001-02-27 | Equistar Chemicals, L.P. | Process for making polyolefins |
US6395847B2 (en) | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
WO2001036499A1 (en) * | 1999-11-19 | 2001-05-25 | Exxon Chemical Patents Inc. | Preparation of supported polymerization catalysts |
WO2002006358A1 (en) * | 2000-07-17 | 2002-01-24 | Univation Technologies, Llc | A catalyst system and its use in a polymerization process |
GB0021301D0 (en) | 2000-08-30 | 2000-10-18 | Borealis Tech Oy | Supported catalyst |
GB2383962B (en) * | 2001-08-31 | 2005-06-01 | Inst Francais Du Petrole | Catalytic composition and use therefor |
US6727331B2 (en) * | 2001-12-28 | 2004-04-27 | Equistar Chemicals, Lp | Preparation of polyethylene |
US6806328B2 (en) * | 2002-01-28 | 2004-10-19 | Univation Technologies, Llc | Polymerization catalyst activator complexes and their use in a polymerization process |
AU2003273316A1 (en) * | 2002-09-10 | 2004-04-30 | Union Carbide Chemicals And Plastics Technology Corporation | Polypropylene cable jacket compositions with enhanced melt strength and physical properties |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
CA2499951C (en) | 2002-10-15 | 2013-05-28 | Peijun Jiang | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
WO2004037871A1 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
WO2004037872A2 (en) * | 2002-10-24 | 2004-05-06 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
US6900154B2 (en) * | 2002-11-26 | 2005-05-31 | Univation Technologies, Llc | Methods of forming a supported activated catalyst composition |
DE60313362T2 (de) * | 2002-12-17 | 2007-08-16 | Ineos Europe Ltd., Lyndhurst | Geträgerter olefin polymerisationskatalysator |
KR100469470B1 (ko) * | 2003-01-30 | 2005-02-02 | 엘지전자 주식회사 | 열변형을 이용한 댐퍼 및 이를 구비한 세탁기 |
US7094848B2 (en) | 2003-05-13 | 2006-08-22 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalyst system |
US6958306B2 (en) * | 2003-08-28 | 2005-10-25 | Univation Technologies, Llc | Activated catalyst systems from substituted dialuminoxane complexes |
US6870010B1 (en) | 2003-12-01 | 2005-03-22 | Univation Technologies, Llc | Low haze high strength polyethylene compositions |
US7288596B2 (en) | 2003-12-22 | 2007-10-30 | Univation Technologies, Llc | Polyethylene compositions having improved tear properties |
EP1559730A1 (de) * | 2004-01-30 | 2005-08-03 | Total Petrochemicals Research Feluy | Aktivierende Träger zur Metallocenkatalyse |
WO2005075525A2 (en) * | 2004-01-30 | 2005-08-18 | Total Petrochemicals Research Feluy | Activating supports for metallocene catalysis. |
US7193017B2 (en) * | 2004-08-13 | 2007-03-20 | Univation Technologies, Llc | High strength biomodal polyethylene compositions |
EP1828109B1 (de) | 2004-11-12 | 2013-06-05 | UCL Business PLC | Guanidinderivate als ddah-inhibitoren |
US7312279B2 (en) * | 2005-02-07 | 2007-12-25 | Univation Technologies, Llc | Polyethylene blend compositions |
TW200936619A (en) | 2007-11-15 | 2009-09-01 | Univation Tech Llc | Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom |
BR112014010900B1 (pt) | 2011-11-08 | 2020-02-18 | Univation Technologies, Llc | Método de preparar um sistema de catalisador, sistema catalisador e processo de polimerização |
KR101924198B1 (ko) | 2015-12-23 | 2018-11-30 | 주식회사 엘지화학 | 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체 |
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US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US5763547A (en) * | 1992-10-02 | 1998-06-09 | The Dow Chemical Company | Supported catalyst complexes for olefin in polymerization |
US5763549A (en) * | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
US5387568A (en) * | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
EP0500944B1 (de) * | 1990-07-24 | 1998-10-07 | Mitsui Chemicals, Inc. | Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit |
JP2895199B2 (ja) * | 1990-10-02 | 1999-05-24 | 三井化学株式会社 | オレフィンの重合触媒 |
DE69127811T3 (de) * | 1990-11-30 | 2012-04-26 | Idemitsu Kosan Co., Ltd. | Verfahren zur herstellung von olefinpolymeren |
US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5288677A (en) * | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
US5710224A (en) * | 1991-07-23 | 1998-01-20 | Phillips Petroleum Company | Method for producing polymer of ethylene |
ES2108861T3 (es) * | 1991-11-25 | 1998-01-01 | Exxon Chemical Patents Inc | Composiciones cataliticas polionicas de metales de transicion. |
EP0574561B1 (de) * | 1992-01-06 | 1998-01-28 | The Dow Chemical Company | Katalysatorzusammensetzung |
US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
US5296433A (en) * | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
US5407882A (en) * | 1992-08-04 | 1995-04-18 | Tosoh Corporation | Olefin polymerization catalyst and olefin polymerization process |
KR100311244B1 (ko) * | 1993-02-22 | 2001-12-15 | 가지와라 야스시 | 에틸렌/α-올레핀공중합체의제조방법 |
US6313240B1 (en) * | 1993-02-22 | 2001-11-06 | Tosoh Corporation | Process for producing ethylene/α-olefin copolymer |
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US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
JP3369294B2 (ja) * | 1994-03-11 | 2003-01-20 | 出光興産株式会社 | 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法 |
IT1273701B (it) * | 1994-07-29 | 1997-07-09 | Enichem Elastomers | Derivati metallorganici del grupo iiia e procedimento per la loro preparazione |
US5643847A (en) * | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
ES2164774T3 (es) * | 1994-08-03 | 2002-03-01 | Exxonmobil Chem Patents Inc | Composicion catalitica ionica soportada. |
US5625087A (en) * | 1994-09-12 | 1997-04-29 | The Dow Chemical Company | Silylium cationic polymerization activators for metallocene complexes |
ES2116188B1 (es) * | 1994-12-30 | 1999-04-01 | Repsol Quimica Sa | Proceso de obtencion de poliolefinas con distribuciones de pesos moleculares anchas, bimodales o multimodales. |
US5554775A (en) * | 1995-01-17 | 1996-09-10 | Occidental Chemical Corporation | Borabenzene based olefin polymerization catalysts |
US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
WO1996026967A1 (en) * | 1995-03-01 | 1996-09-06 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borate complexes and catalysts derived therefrom |
US5721183A (en) * | 1995-03-10 | 1998-02-24 | The Dow Chemical Company | Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds |
TR199700932T1 (xx) * | 1995-03-10 | 1998-01-21 | The Dow Chemical Company | Desteklenmi� kataliz�r bile�eni, desteklenmi� kataliz�r, haz�rlama i�lemi, polimerizasyon i�lemi, kompleks bile�ikler ve bunlar�n haz�rlanmas�. |
ES2178704T3 (es) * | 1995-04-25 | 2003-01-01 | Equistar Chem Lp | Complejos matalicos de azaborolinilo como catalizadores de polimerizacion de olefinas. |
WO1997007141A1 (de) * | 1995-08-18 | 1997-02-27 | Targor Gmbh | Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren |
US5756609A (en) * | 1995-10-19 | 1998-05-26 | Amoco Corporation | Homogeneous metallocene-based olefin polymerization system with increased activity |
IT1275812B1 (it) * | 1995-10-27 | 1997-10-17 | Enichem Spa | Sistema catalitico attivato per la (co)polimerizzazione delle alfa-olefine |
EP0876407B1 (de) * | 1996-01-26 | 2000-12-27 | The Dow Chemical Company | Katalysatorzusammensetzung für die additionspolymerisation von olefinen |
JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
KR100466733B1 (ko) * | 1996-07-23 | 2005-01-24 | 다우 글로벌 테크놀로지스 인크. | 13족 화합물을 포함하는 올레핀 중합 촉매 조성물 |
DE59712644D1 (de) | 1996-08-13 | 2006-06-14 | Basell Polyolefine Gmbh | Geträgerte chemische Verbindung |
US5854166A (en) * | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
-
1999
- 1999-07-09 AT AT99935486T patent/ATE355308T1/de not_active IP Right Cessation
- 1999-07-09 CA CA002330775A patent/CA2330775A1/en not_active Abandoned
- 1999-07-09 WO PCT/US1999/015618 patent/WO2000004058A1/en active IP Right Grant
- 1999-07-09 AU AU50954/99A patent/AU743367B2/en not_active Ceased
- 1999-07-09 EP EP99935486A patent/EP1097175B1/de not_active Expired - Lifetime
- 1999-07-09 ES ES99935486T patent/ES2283125T3/es not_active Expired - Lifetime
- 1999-07-09 DE DE69935332T patent/DE69935332T2/de not_active Expired - Fee Related
- 1999-07-09 BR BR9912124-7A patent/BR9912124A/pt not_active Application Discontinuation
- 1999-07-09 US US09/350,521 patent/US6147174A/en not_active Expired - Lifetime
- 1999-07-09 JP JP2000560163A patent/JP2002520452A/ja active Pending
-
2000
- 2000-07-20 US US09/620,687 patent/US6476166B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CA2330775A1 (en) | 2000-01-27 |
AU5095499A (en) | 2000-02-07 |
ATE355308T1 (de) | 2006-03-15 |
WO2000004058A1 (en) | 2000-01-27 |
JP2002520452A (ja) | 2002-07-09 |
EP1097175B1 (de) | 2007-02-28 |
DE69935332T2 (de) | 2007-10-31 |
AU743367B2 (en) | 2002-01-24 |
ES2283125T3 (es) | 2007-10-16 |
BR9912124A (pt) | 2001-09-25 |
EP1097175A1 (de) | 2001-05-09 |
US6476166B1 (en) | 2002-11-05 |
US6147174A (en) | 2000-11-14 |
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