[go: up one dir, main page]

DE69715213D1 - Olefinpolymerisationkatalysatorzusammensetzung die eine verbindung der gruppe 13 enthält - Google Patents

Olefinpolymerisationkatalysatorzusammensetzung die eine verbindung der gruppe 13 enthält

Info

Publication number
DE69715213D1
DE69715213D1 DE69715213T DE69715213T DE69715213D1 DE 69715213 D1 DE69715213 D1 DE 69715213D1 DE 69715213 T DE69715213 T DE 69715213T DE 69715213 T DE69715213 T DE 69715213T DE 69715213 D1 DE69715213 D1 DE 69715213D1
Authority
DE
Germany
Prior art keywords
group
connection
composition containing
catalyst composition
polymerization catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69715213T
Other languages
English (en)
Other versions
DE69715213T2 (de
Inventor
K Rosen
C Stevens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of DE69715213D1 publication Critical patent/DE69715213D1/de
Application granted granted Critical
Publication of DE69715213T2 publication Critical patent/DE69715213T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69715213T 1996-07-23 1997-07-18 Olefinpolymerisationkatalysatorzusammensetzung die eine verbindung der gruppe 13 enthält Expired - Lifetime DE69715213T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2206196P 1996-07-23 1996-07-23
PCT/US1997/012649 WO1998003558A1 (en) 1996-07-23 1997-07-18 Olefin polymerization catalyst composition comprising group 13 compound

Publications (2)

Publication Number Publication Date
DE69715213D1 true DE69715213D1 (de) 2002-10-10
DE69715213T2 DE69715213T2 (de) 2003-04-30

Family

ID=21807620

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69715213T Expired - Lifetime DE69715213T2 (de) 1996-07-23 1997-07-18 Olefinpolymerisationkatalysatorzusammensetzung die eine verbindung der gruppe 13 enthält

Country Status (17)

Country Link
US (1) US6017842A (de)
EP (1) EP0914353B1 (de)
JP (1) JP2000514858A (de)
KR (1) KR100466733B1 (de)
CN (1) CN1092668C (de)
AR (1) AR010516A1 (de)
AU (1) AU718544B2 (de)
BR (1) BR9710511A (de)
CA (1) CA2261174C (de)
CZ (1) CZ293472B6 (de)
DE (1) DE69715213T2 (de)
ES (1) ES2177995T3 (de)
HU (1) HU223376B1 (de)
PL (1) PL331324A1 (de)
TR (1) TR199900080T2 (de)
TW (1) TW434271B (de)
WO (1) WO1998003558A1 (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6294625B1 (en) * 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
KR100422025B1 (ko) * 1997-12-01 2004-03-10 아사히 가세이 가부시키가이샤 올레핀 중합용 촉매 및 상기 촉매를 사용한 올레핀의 중합방법
US6211312B1 (en) 1998-06-12 2001-04-03 Univation Technologies Olefin polymerization process using activated lewis acid-base complexes
ATE355308T1 (de) * 1998-07-16 2006-03-15 Univation Tech Llc Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
US6187940B1 (en) * 1998-08-17 2001-02-13 The Dow Chemical Company Three coordinate aluminum catalyst activator composition
WO2000009514A1 (en) * 1998-08-17 2000-02-24 The Dow Chemical Company Activator composition comprising aluminum compound mixture
US6559088B1 (en) * 1999-02-22 2003-05-06 Fina Technology, Inc. Ziegler-Natta catalyst with amine for polymerization
BE1012568A3 (fr) 1999-03-24 2000-12-05 Solvay Procede pour la polymerisation des alphaolefines.
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
ATE309252T1 (de) * 1999-12-09 2005-11-15 Exxonmobil Chem Patents Inc Gruppe 15-enthaltende olefinpolymerisationscokatalysatoren und verfahren damit
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
JP2003518169A (ja) 1999-12-20 2003-06-03 エクソンモービル・ケミカル・パテンツ・インク 担持イオン性触媒を使用するポリオレフィン樹脂の製造方法
JP2002293818A (ja) * 2001-03-30 2002-10-09 Sumitomo Chem Co Ltd オレフィン重合用触媒、およびオレフィン重合体の製造方法
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
ATE472562T1 (de) * 2002-12-13 2010-07-15 Dow Global Technologies Inc Olefinpolymerisationskatalysatorzusammensetzung gruppe 13-amid derivate enthaltend
ATE504349T1 (de) * 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
KR101084677B1 (ko) * 2008-05-14 2011-11-22 주식회사 엘지화학 올레핀 중합체의 제조방법
CN104677777B (zh) * 2013-11-29 2017-10-27 中国石油化工股份有限公司 岩石残余含气量测试装置及其测试方法
CN107848908A (zh) * 2015-05-13 2018-03-27 萨索尔化学品性能有限公司 通过配位链转移聚合的烯烃低聚方法
CN117999292A (zh) * 2021-09-10 2024-05-07 陶氏环球技术有限责任公司 用于烯烃聚合的烃溶性硼酸盐助催化剂
JP2024535749A (ja) * 2021-09-10 2024-10-02 ダウ グローバル テクノロジーズ エルエルシー ポリオレフィン製造用ボレート共触媒

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3311604A (en) * 1961-02-04 1967-03-28 Snam Spa Process for polymerizing isoprene with a catalyst consisting of titanium tetrachloride and an aluminum hydride
US3255169A (en) * 1961-05-03 1966-06-07 Exxon Research Engineering Co Aluminum hydroaminate activators in olefin polymerization
US3624118A (en) * 1961-08-09 1971-11-30 Olin Mathieson Reaction products of alkali metal amides and trialkyl aluminum compounds
NL126040C (de) * 1963-05-24
NL129055C (de) * 1965-02-03 1900-01-01
NL125866C (de) * 1965-02-03
NL129054C (de) * 1965-02-03
NL125867C (de) * 1965-02-03
US3489736A (en) * 1965-04-23 1970-01-13 Showa Denko Kk Polymerization of olefins
US3723348A (en) * 1967-03-20 1973-03-27 Du Pont Coordination catalyst
BE759186A (fr) * 1969-11-26 1971-05-21 Inst Francais Du Petrole Nouveaux catalyseurs de deshydrogenation des alcools secondaires
DE2110195C3 (de) * 1970-03-11 1975-07-31 Snam Progetti S.P.A., Mailand (Italien) Aluminiumverbindung, Verfahren zu ihrer Herstellung und ihre Verwendung bei der Polymerisation von Olefinen, konjugierten oder nicht-konjugierten Dienen oder Gemischen davon
IT953411B (it) * 1972-02-15 1973-08-10 Snam Progetti Produzione di lubrificanti sinteti ci da alfa olefine con un sistema catalitico ternario
US4094818A (en) * 1977-02-11 1978-06-13 Exxon Research & Engineering Co. Ziegler type catalyst system
US4224182A (en) * 1979-03-07 1980-09-23 Exxon Research & Engineering Co. Novel hindered alkyl aluminum amide cocatalysts
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
BE1003968A3 (fr) * 1990-11-08 1992-07-28 Solvay Solide catalytique utilisable pour la polymerisation stereospecifique des alpha-olefines, procede pour le preparer et procede pour polymeriser des alpha-olefines en sa presence
JP3275211B2 (ja) * 1991-05-20 2002-04-15 ザ ダウ ケミカル カンパニー 付加重合触媒の製造方法
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
CA2105555C (en) * 1992-01-06 2003-12-30 Brian W. S. Kolthammer Improved catalyst composition
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US6313240B1 (en) * 1993-02-22 2001-11-06 Tosoh Corporation Process for producing ethylene/α-olefin copolymer
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
CA2129794A1 (en) * 1993-08-10 1995-02-11 Toshiyuki Tsutsui Olefin polymerization catalysts and methods of olefin polymerization
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom

Also Published As

Publication number Publication date
CA2261174A1 (en) 1998-01-29
CN1092668C (zh) 2002-10-16
CZ23999A3 (cs) 1999-04-14
KR20000067938A (ko) 2000-11-25
PL331324A1 (en) 1999-07-05
CZ293472B6 (cs) 2004-05-12
WO1998003558A1 (en) 1998-01-29
AU3805197A (en) 1998-02-10
EP0914353B1 (de) 2002-09-04
CN1225644A (zh) 1999-08-11
KR100466733B1 (ko) 2005-01-24
AR010516A1 (es) 2000-06-28
US6017842A (en) 2000-01-25
DE69715213T2 (de) 2003-04-30
EP0914353A1 (de) 1999-05-12
BR9710511A (pt) 1999-08-17
HUP9903962A3 (en) 2000-06-28
HUP9903962A2 (hu) 2000-03-28
CA2261174C (en) 2005-11-29
TR199900080T2 (xx) 1999-04-21
ES2177995T3 (es) 2002-12-16
JP2000514858A (ja) 2000-11-07
TW434271B (en) 2001-05-16
AU718544B2 (en) 2000-04-13
HU223376B1 (hu) 2004-06-28

Similar Documents

Publication Publication Date Title
DE69715213D1 (de) Olefinpolymerisationkatalysatorzusammensetzung die eine verbindung der gruppe 13 enthält
EG21245A (en) Catalyst composition for the production of olefin polymers
FI972230A0 (fi) Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus
DE69418332D1 (de) Kosmetische zusammensetzung, die hydroxysaeuren enthaelt
DE69319336D1 (de) N-acylierte 2'-deoxycytidine für die oligonukleotid synthese
TR199700447A3 (tr) "Polimerizasyon katalizörü"
FR2651294B1 (fr) Unite d'etancheite.
FI970580L (fi) Kantajalla oleva olefiinipolymerointikatalyytti
DE69210480D1 (de) Katalysatorbestandteil für die Olefinpolymerisation
DE69816281D1 (de) Katalysatorzusammensetzungen für die polymerisation von olefinen
DE69302117D1 (de) Butenpolymere
DE69418088D1 (de) Katalysatorzusammensetzung
DE69821087D1 (de) Kosmetische Zusammensetzung, die Phloroglucinol enthält
DE69611386D1 (de) Katalysatorzusammensetzung für die additionspolymerisation von olefinen
DE69823988D1 (de) Gruppe 8-10 übergangsmetallkatalysator für die polymerisation von olefinen
NO903929L (no) Slitasjebestandig katalysatorbaerer.
ZA957034B (en) Catalyst composition for olefin polymerizing
DE69416868D1 (de) Katalysatorzusammensetzung
DE69829644D1 (de) Katalysatorzusammensetzung für die olefinpolymerisation mit erhöhter aktivität
DE69514803D1 (de) Olefinpolymerisationskatalysator
FR2726487B1 (fr) Compositions catalytiques a base de composes du rhenium et de l'aluminium leur preparation et leur utilisation pour la metathese des olefines
GB8928955D0 (en) Anionic polymerization catalyst compositions
ID17795A (id) Proses-proses kontinyu untuk konversi 2,5-dihidrofuran menjadi 2,3 dihidrofuran
DE69520449D1 (de) Olefinpolymerisationskatalysator
DE69835373D1 (de) Olefin-polymerisationskatalysatorzusammensetzung, die übergangsmetallverbindungen in niedriger oxidationsstufe enthält

Legal Events

Date Code Title Description
8364 No opposition during term of opposition