DE69413028T2 - Bleichmethoden mit peroxysäurenaktivatoren zusammen mit enzymen - Google Patents
Bleichmethoden mit peroxysäurenaktivatoren zusammen mit enzymenInfo
- Publication number
- DE69413028T2 DE69413028T2 DE69413028T DE69413028T DE69413028T2 DE 69413028 T2 DE69413028 T2 DE 69413028T2 DE 69413028 T DE69413028 T DE 69413028T DE 69413028 T DE69413028 T DE 69413028T DE 69413028 T2 DE69413028 T2 DE 69413028T2
- Authority
- DE
- Germany
- Prior art keywords
- group
- alkyl
- carbon atoms
- bleach
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000012190 activator Substances 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 title claims abstract description 78
- 238000004061 bleaching Methods 0.000 title claims abstract description 55
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 25
- 239000000203 mixture Substances 0.000 claims abstract description 133
- 239000007844 bleaching agent Substances 0.000 claims abstract description 118
- 239000003599 detergent Substances 0.000 claims abstract description 88
- 102000004190 Enzymes Human genes 0.000 claims abstract description 63
- 108090000790 Enzymes Proteins 0.000 claims abstract description 63
- 229940088598 enzyme Drugs 0.000 claims description 62
- 244000043261 Hevea brasiliensis Species 0.000 claims description 39
- 229920003052 natural elastomer Polymers 0.000 claims description 39
- 229920001194 natural rubber Polymers 0.000 claims description 39
- 125000000217 alkyl group Chemical group 0.000 claims description 37
- 238000005406 washing Methods 0.000 claims description 37
- 125000004432 carbon atom Chemical group C* 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 28
- 125000003118 aryl group Chemical group 0.000 claims description 21
- 102000004882 Lipase Human genes 0.000 claims description 20
- 108090001060 Lipase Proteins 0.000 claims description 20
- 238000004140 cleaning Methods 0.000 claims description 20
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 18
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 18
- 229940045872 sodium percarbonate Drugs 0.000 claims description 18
- 239000004367 Lipase Substances 0.000 claims description 15
- 108091005804 Peptidases Proteins 0.000 claims description 15
- 102000035195 Peptidases Human genes 0.000 claims description 15
- 235000019421 lipase Nutrition 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 14
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- 239000004744 fabric Substances 0.000 claims description 12
- ISBYGXCCBJIBCG-UHFFFAOYSA-N 2-[6-(nonanoylamino)hexanoyloxy]benzenesulfonic acid Chemical compound CCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O ISBYGXCCBJIBCG-UHFFFAOYSA-N 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 10
- GOKVKLCCWGRQJV-UHFFFAOYSA-N 2-[6-(decanoylamino)hexanoyloxy]benzenesulfonic acid Chemical compound CCCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O GOKVKLCCWGRQJV-UHFFFAOYSA-N 0.000 claims description 9
- FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical group C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 claims description 9
- 108010042388 protease C Proteins 0.000 claims description 8
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- 102000005575 Cellulases Human genes 0.000 claims description 7
- 230000001580 bacterial effect Effects 0.000 claims description 7
- JKZLOWDYIRTRJZ-UHFFFAOYSA-N 2-[6-(octanoylamino)hexanoyloxy]benzenesulfonic acid Chemical compound CCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O JKZLOWDYIRTRJZ-UHFFFAOYSA-N 0.000 claims description 6
- 108010065511 Amylases Proteins 0.000 claims description 6
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- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 5
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 5
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 5
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- 241000193422 Bacillus lentus Species 0.000 claims description 4
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910006067 SO3−M Inorganic materials 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000000732 arylene group Chemical group 0.000 claims description 4
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- 239000011734 sodium Substances 0.000 claims description 4
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- 239000012418 sodium perborate tetrahydrate Substances 0.000 claims description 4
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 claims description 4
- 230000003381 solubilizing effect Effects 0.000 claims description 4
- 241000194108 Bacillus licheniformis Species 0.000 claims description 3
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- 108010022999 Serine Proteases Proteins 0.000 claims description 3
- 102000012479 Serine Proteases Human genes 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000003282 alkyl amino group Chemical group 0.000 claims description 3
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- SUJDDHCSXFSFRN-UHFFFAOYSA-N 3-(3,5,5-trimethylhexanoyl)azepan-2-one Chemical compound CC(CC(=O)C1C(=O)NCCCC1)CC(C)(C)C SUJDDHCSXFSFRN-UHFFFAOYSA-N 0.000 claims description 2
- VFIUQNHHBQTNNM-UHFFFAOYSA-N 3-decanoylazepan-2-one Chemical compound CCCCCCCCCC(=O)C1CCCCNC1=O VFIUQNHHBQTNNM-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 241000223258 Thermomyces lanuginosus Species 0.000 claims description 2
- 239000011591 potassium Chemical group 0.000 claims description 2
- 229910052700 potassium Chemical group 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims 1
- 238000010525 oxidative degradation reaction Methods 0.000 claims 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Natural products O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract description 29
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- 239000000243 solution Substances 0.000 description 16
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 13
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- VPOLVWCUBVJURT-UHFFFAOYSA-N pentadecasodium;pentaborate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] VPOLVWCUBVJURT-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 229940044652 phenolsulfonate Drugs 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 125000000341 threoninyl group Chemical group [H]OC([H])(C([H])([H])[H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 125000002987 valine group Chemical group [H]N([H])C([H])(C(*)=O)C([H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910009111 xH2 O Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/392—Heterocyclic compounds, e.g. cyclic imides or lactames
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6456393A | 1993-05-20 | 1993-05-20 | |
| US13369193A | 1993-10-07 | 1993-10-07 | |
| US15131693A | 1993-11-12 | 1993-11-12 | |
| US19632294A | 1994-02-15 | 1994-02-15 | |
| PCT/US1994/005372 WO1994028106A1 (en) | 1993-05-20 | 1994-05-12 | Bleaching compounds comprising peroxyacid activators used with enzymes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69413028D1 DE69413028D1 (de) | 1998-10-08 |
| DE69413028T2 true DE69413028T2 (de) | 1999-05-06 |
Family
ID=27490432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69413028T Expired - Fee Related DE69413028T2 (de) | 1993-05-20 | 1994-05-12 | Bleichmethoden mit peroxysäurenaktivatoren zusammen mit enzymen |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0699230B1 (cs) |
| JP (1) | JPH08510780A (cs) |
| CN (1) | CN1086734C (cs) |
| AT (1) | ATE170552T1 (cs) |
| AU (1) | AU6833594A (cs) |
| BR (1) | BR9406531A (cs) |
| CA (1) | CA2161212A1 (cs) |
| CZ (1) | CZ305995A3 (cs) |
| DE (1) | DE69413028T2 (cs) |
| ES (1) | ES2120047T3 (cs) |
| HU (1) | HUT73731A (cs) |
| MA (1) | MA23200A1 (cs) |
| PE (1) | PE56994A1 (cs) |
| WO (1) | WO1994028106A1 (cs) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5755992A (en) * | 1994-04-13 | 1998-05-26 | The Procter & Gamble Company | Detergents containing a surfactant and a delayed release peroxyacid bleach system |
| US5686015A (en) * | 1994-08-31 | 1997-11-11 | The Procter & Gamble Company | Quaternary substituted bleach activators |
| US5460747A (en) * | 1994-08-31 | 1995-10-24 | The Procter & Gamble Co. | Multiple-substituted bleach activators |
| US5584888A (en) * | 1994-08-31 | 1996-12-17 | Miracle; Gregory S. | Perhydrolysis-selective bleach activators |
| EP0792345A1 (en) * | 1994-11-18 | 1997-09-03 | The Procter & Gamble Company | Bleaching compositions and bleach-additives comprising bleach activators effective at low perhydroxyl concentrations |
| US5523434A (en) * | 1995-03-15 | 1996-06-04 | The Procter & Gamble Company | Synthesis of bleach activators |
| DE19609953A1 (de) * | 1996-03-14 | 1997-09-18 | Basf Ag | Feste Zusammensetzung aus heterocyclischen Verbindungen und/oder Oximestern und inerten porösen Trägermaterialien und ihre Verwendung als stabile Bleichaktivator-Komponente in Wasch-, Bleich- und Reinigungsmitteln |
| US6100080A (en) * | 1996-12-18 | 2000-08-08 | Novo Nordisk A/S | Method for enzymatic treatment of biofilm |
| CA2300943A1 (en) * | 1997-08-20 | 1999-02-25 | The Procter & Gamble Company | Process for preparing and/or purifying amido acid phenyl ester sulfonates |
| WO2000003369A2 (en) * | 1998-07-08 | 2000-01-20 | The Procter & Gamble Company | Methods for reducing or preventing the degradation of rubber in domestic bleach processes |
| DE19900939C2 (de) | 1999-01-13 | 2001-06-07 | Clariant Gmbh | Verfahren zur Herstellung von Amidosäurephenylestern |
| CN1205378C (zh) * | 2000-02-15 | 2005-06-08 | 宝洁公司 | 在纺织品前处理中使用疏水性漂白体系的方法 |
| AU2001245278A1 (en) | 2000-02-15 | 2001-11-07 | The Procter And Gamble Company | Method for the application of durable press finishes to textile components via the use of hydrophobic bleaching preparation |
| US6743761B2 (en) | 2000-02-15 | 2004-06-01 | The Procter & Gamble Company | Method for the one step preparation of textiles |
| US6830591B1 (en) | 2000-02-15 | 2004-12-14 | The Procter & Gamble Company | Method for the use of hydrophobic bleaching systems in textile preparation |
| US6527690B2 (en) | 2000-06-02 | 2003-03-04 | Bhaskar Krishna Arumugam | Purification of phenyl ester salts |
| US6500973B2 (en) * | 2000-06-02 | 2002-12-31 | Eastman Chemical Company | Extractive solution crystallization of chemical compounds |
| ES2252287T3 (es) | 2000-07-28 | 2006-05-16 | Henkel Kommanditgesellschaft Auf Aktien | Enzima amilolitico de bacillus sp. a7-7 (dsm 12368) asi com0 agentes de lavado y de limpieza con este nuevo enzima amilolitico. |
| US6569209B2 (en) * | 2001-02-27 | 2003-05-27 | The Procter & Gamble Company | Method for the use of hydrophobic bleaching systems in cold batch textile preparation |
| DE102006036889A1 (de) * | 2006-08-04 | 2008-02-07 | Clariant International Limited | Verwendung von Aminoacetonen und deren Salzen als Bleichkraftverstärker für Persauerstoffverbindungen |
| WO2013116734A1 (en) | 2012-02-01 | 2013-08-08 | Gurtler Industries, Inc. | Composition and method for removing stains derived from chlorhexidine gluconate |
| CN105907483B (zh) * | 2016-05-08 | 2019-01-15 | 浙江艾卡医学科技有限公司 | 一种含氧的多功能洗涤剂组合物 |
| WO2019204184A1 (en) * | 2018-04-16 | 2019-10-24 | Dow Global Technologies Llc | Tetraacetyldiamine and triacetyldiamine derivatives useful as bleach activators |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8310080D0 (en) * | 1983-04-14 | 1983-05-18 | Interox Chemicals Ltd | Bleach composition |
| GB8415909D0 (en) * | 1984-06-21 | 1984-07-25 | Procter & Gamble Ltd | Peracid compounds |
| US4852989A (en) * | 1987-05-08 | 1989-08-01 | The Procter & Gamble Company | Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain |
| JPH0696720B2 (ja) * | 1989-06-14 | 1994-11-30 | 花王株式会社 | 漂白剤及び漂白洗浄剤組成物 |
| DE3938526A1 (de) * | 1989-11-21 | 1991-05-23 | Basf Ag | Verwendung von heterocyclischen verbindungen als bleichaktivatoren oder optische aufheller in wasch- und reinigungsmitteln |
| BR9307300A (pt) * | 1992-10-23 | 1999-06-01 | Procter & Gamble | Detergentes granulares com enzima protease e alvejante |
-
1994
- 1994-05-12 CN CN94192168A patent/CN1086734C/zh not_active Expired - Fee Related
- 1994-05-12 AU AU68335/94A patent/AU6833594A/en not_active Abandoned
- 1994-05-12 HU HU9503301A patent/HUT73731A/hu unknown
- 1994-05-12 CA CA002161212A patent/CA2161212A1/en not_active Abandoned
- 1994-05-12 DE DE69413028T patent/DE69413028T2/de not_active Expired - Fee Related
- 1994-05-12 JP JP7500721A patent/JPH08510780A/ja not_active Ceased
- 1994-05-12 WO PCT/US1994/005372 patent/WO1994028106A1/en not_active Application Discontinuation
- 1994-05-12 BR BR9406531A patent/BR9406531A/pt not_active IP Right Cessation
- 1994-05-12 EP EP94916771A patent/EP0699230B1/en not_active Expired - Lifetime
- 1994-05-12 AT AT94916771T patent/ATE170552T1/de not_active IP Right Cessation
- 1994-05-12 CZ CZ953059A patent/CZ305995A3/cs unknown
- 1994-05-12 ES ES94916771T patent/ES2120047T3/es not_active Expired - Lifetime
- 1994-05-19 MA MA23510A patent/MA23200A1/fr unknown
- 1994-05-20 PE PE1994242837A patent/PE56994A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO1994028106A1 (en) | 1994-12-08 |
| CZ305995A3 (en) | 1996-05-15 |
| HU9503301D0 (en) | 1996-01-29 |
| PE56994A1 (es) | 1995-02-01 |
| ATE170552T1 (de) | 1998-09-15 |
| JPH08510780A (ja) | 1996-11-12 |
| AU6833594A (en) | 1994-12-20 |
| CN1086734C (zh) | 2002-06-26 |
| EP0699230B1 (en) | 1998-09-02 |
| BR9406531A (pt) | 1996-01-02 |
| EP0699230A1 (en) | 1996-03-06 |
| HUT73731A (en) | 1996-09-30 |
| ES2120047T3 (es) | 1998-10-16 |
| MA23200A1 (fr) | 1994-12-31 |
| CN1124036A (zh) | 1996-06-05 |
| CA2161212A1 (en) | 1994-12-08 |
| DE69413028D1 (de) | 1998-10-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |