DE60117939D1 - Verfahren zur Entfernung von Quecksilber aus Rauchgasen - Google Patents
Verfahren zur Entfernung von Quecksilber aus RauchgasenInfo
- Publication number
- DE60117939D1 DE60117939D1 DE60117939T DE60117939T DE60117939D1 DE 60117939 D1 DE60117939 D1 DE 60117939D1 DE 60117939 T DE60117939 T DE 60117939T DE 60117939 T DE60117939 T DE 60117939T DE 60117939 D1 DE60117939 D1 DE 60117939D1
- Authority
- DE
- Germany
- Prior art keywords
- flue gases
- removing mercury
- sulfide
- gas
- mercury
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003546 flue gas Substances 0.000 title abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052753 mercury Inorganic materials 0.000 title abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/004—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 specially adapted for marine propulsion, i.e. for receiving simultaneously engine exhaust gases and engine cooling water
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/003—Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/50—Inorganic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/60—Heavy metals; Compounds thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2217/00—Intercepting solids
- F23J2217/10—Intercepting solids by filters
- F23J2217/102—Intercepting solids by filters electrostatic
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/40—Sorption with wet devices, e.g. scrubbers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/60—Sorption with dry devices, e.g. beds
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Ocean & Marine Engineering (AREA)
- Treating Waste Gases (AREA)
- Chimneys And Flues (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/730,100 US6855859B2 (en) | 1999-03-31 | 2000-12-05 | Method for controlling elemental mercury emissions |
| US730100 | 2000-12-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60117939D1 true DE60117939D1 (de) | 2006-05-11 |
| DE60117939T2 DE60117939T2 (de) | 2006-10-26 |
Family
ID=24933901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60117939T Expired - Lifetime DE60117939T2 (de) | 2000-12-05 | 2001-10-11 | Verfahren zur Entfernung von Quecksilber aus Rauchgasen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6855859B2 (de) |
| EP (1) | EP1213046B1 (de) |
| JP (1) | JP4593850B2 (de) |
| KR (1) | KR100829351B1 (de) |
| AT (1) | ATE320301T1 (de) |
| CA (1) | CA2359304C (de) |
| DE (1) | DE60117939T2 (de) |
| ES (1) | ES2258513T3 (de) |
| MX (1) | MXPA01012507A (de) |
| TW (1) | TWI248831B (de) |
Families Citing this family (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7037474B2 (en) * | 1999-03-31 | 2006-05-02 | The Babcock & Wilcox Company | Use of sulfide-containing liquors for removing mercury from flue gases |
| US6284199B1 (en) * | 1999-03-31 | 2001-09-04 | Mcdermott Technology, Inc. | Apparatus for control of mercury |
| US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
| DE10107761B4 (de) * | 2001-02-16 | 2007-08-30 | Fisia Babcock Environment Gmbh | Verfahren zur Entfernung von Quecksilber aus Rauchgasen |
| US7048781B1 (en) * | 2002-10-07 | 2006-05-23 | Ada Technologies, Inc. | Chemically-impregnated silicate agents for mercury control |
| US7186985B2 (en) * | 2001-07-30 | 2007-03-06 | Dxray, Inc. | Method and apparatus for fabricating mercuric iodide polycrystalline films for digital radiography |
| US7628967B2 (en) | 2002-10-01 | 2009-12-08 | Airborne Industrial Minerals, Inc. | Removal of Hg, NOx, and SOx with using oxidants and staged gas/liquid contact |
| US6852542B2 (en) * | 2003-02-03 | 2005-02-08 | Spectra Gases, Inc. | Method and system for creating a mercury halide standard for use in testing a mercury analyzer system |
| US7517511B2 (en) * | 2003-05-01 | 2009-04-14 | The Regents Of The University Of California | Method and apparatus for mitigating mercury emissions in exhaust gases |
| US9321002B2 (en) | 2003-06-03 | 2016-04-26 | Alstom Technology Ltd | Removal of mercury emissions |
| US7381387B2 (en) * | 2003-08-14 | 2008-06-03 | General Electric Company | Mercury reduction system and method in combustion flue gas using coal blending |
| US8114123B2 (en) * | 2003-09-19 | 2012-02-14 | St. Jude Medical, Inc. | Apparatus and methods for tissue gathering and securing |
| US6895875B1 (en) * | 2003-11-18 | 2005-05-24 | General Electric Company | Mercury reduction system and method in combustion flue gas using staging |
| US20060185226A1 (en) * | 2005-02-24 | 2006-08-24 | Mcdonald Dennis K | Method of applying mercury reagent with coal |
| BRPI0606285A2 (pt) | 2005-03-17 | 2009-06-09 | Nox Ii International Ltd | redução de emissões de mercúrio a partir da queima de carvão |
| EP3424585B1 (de) | 2005-03-17 | 2022-06-08 | Nox II International, Ltd. | Verringerung der quecksilber- und schwefelemissionen bei der verbrennung von kohle |
| US7454952B2 (en) * | 2005-05-02 | 2008-11-25 | Thermo Fisher Scientific Inc. | Method and apparatus for monitoring mercury in a gas sample |
| US20060243096A1 (en) * | 2005-05-02 | 2006-11-02 | Dieter Kita | Method and apparatus for converting oxidized mercury into elemental mercury |
| US20060245974A1 (en) * | 2005-05-02 | 2006-11-02 | Dieter Kita | Method and apparatus for generating oxidized mercury having a measurable concentration |
| US7354553B2 (en) * | 2005-05-02 | 2008-04-08 | Dirk Appel | Method and apparatus for detecting the presence of elemental mercury in a gas sample |
| US7615101B2 (en) * | 2005-09-07 | 2009-11-10 | Energy & Environmental Research Foundation | High energy dissociation for mercury control systems |
| US20070092418A1 (en) * | 2005-10-17 | 2007-04-26 | Chemical Products Corporation | Sorbents for Removal of Mercury from Flue Gas |
| US7452517B2 (en) * | 2005-12-02 | 2008-11-18 | General Electric Company | Integrated approach to reduction of mercury emissions |
| US7767174B2 (en) * | 2006-09-18 | 2010-08-03 | General Electric Company | Method and systems for removing mercury from combustion exhaust gas |
| JP4388542B2 (ja) * | 2006-12-07 | 2009-12-24 | 三菱重工業株式会社 | 水銀除去方法及び水銀除去システム |
| JP5591446B2 (ja) * | 2007-11-22 | 2014-09-17 | 千代田化工建設株式会社 | 排ガス処理方法 |
| US8312822B2 (en) | 2007-07-02 | 2012-11-20 | Energy & Environmental Research Center Foundation | Mercury control using moderate-temperature dissociation of halogen compounds |
| JP4952935B2 (ja) * | 2007-10-18 | 2012-06-13 | 株式会社Ｉｈｉ | 排ガス処理方法及び排ガス処理装置 |
| US7507287B1 (en) | 2007-11-09 | 2009-03-24 | United States Gypsum Company | Activated carbon as mercury release control agent in gypsum calcination |
| PL2231308T3 (pl) * | 2007-12-03 | 2019-09-30 | Yissum Research Development Company Of The Hebrew University Of Jerusalem Ltd. | Płuczka i sposób usuwania metali ciężkich z gazów |
| KR100953535B1 (ko) * | 2008-07-17 | 2010-04-21 | 재단법인 포항산업과학연구원 | 염소계 화합물을 이용한 배가스 내 수은 제거 방법 |
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| CN102470317A (zh) * | 2009-07-24 | 2012-05-23 | 格雷厄姆·C·迪克森 | 用于从气体去除汞的设备和方法 |
| CA2788820C (en) | 2010-02-04 | 2021-09-21 | Michael Durham | Method and system for controlling mercury emissions from coal-fired thermal processes |
| US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| US11298657B2 (en) | 2010-10-25 | 2022-04-12 | ADA-ES, Inc. | Hot-side method and system |
| US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
| US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
| PL2545334T3 (pl) | 2010-03-10 | 2018-11-30 | ADA-ES, Inc. | Sposób wtryskiwania w fazie rozcieńczonej suchych materiałów alkalicznych do gazu |
| CN101850212A (zh) * | 2010-05-25 | 2010-10-06 | 华南理工大学 | 一种脱除燃煤烟气中总汞的方法 |
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| US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
| US9073008B2 (en) | 2013-03-07 | 2015-07-07 | Redox Technology Group, Llc | Use of ferrous sulfide suspension for the removal of mercury from flue gases |
| DE112014001129B4 (de) | 2013-03-07 | 2019-06-13 | Redox Technology Group Llc | Reagens zur Entfernung von Quecksilber aus industriellen Gasen und Verfahren zum Reduzieren von Quecksilberemissionen von industriellem Gas |
| US9034285B1 (en) | 2014-02-28 | 2015-05-19 | Redox Technology Group Llc | Use of ferrous sulfide suspension for the removal of mercury from flue gases |
| WO2014150217A1 (en) * | 2013-03-15 | 2014-09-25 | Ecolab Usa Inc. | Method of oxidizing mercury in flue gas |
| US9889451B2 (en) | 2013-08-16 | 2018-02-13 | ADA-ES, Inc. | Method to reduce mercury, acid gas, and particulate emissions |
| US9308493B2 (en) | 2013-08-16 | 2016-04-12 | ADA-ES, Inc. | Method to reduce mercury, acid gas, and particulate emissions |
| US8865099B1 (en) | 2014-02-05 | 2014-10-21 | Urs Corporation | Method and system for removal of mercury from a flue gas |
| EP3147023B1 (de) * | 2014-05-21 | 2021-02-17 | Chiyoda Corporation | Verfahren zur behandlung von gas mit nullwertigem quecksilber und quecksilbertrennungsverfahren |
| US10350545B2 (en) | 2014-11-25 | 2019-07-16 | ADA-ES, Inc. | Low pressure drop static mixing system |
| CN104458804B (zh) * | 2014-12-05 | 2017-01-25 | 浙江大学宁波理工学院 | 富氧燃烧气氛下烟气中氧化性Cl形成装置 |
| AU2016200890A1 (en) * | 2015-02-13 | 2016-09-01 | The Babcock & Wilcox Company | Method and apparatus for removing mercury from a flue gas stream |
| US10471386B2 (en) * | 2016-02-10 | 2019-11-12 | The Babcock & Wilcox Company | Method and apparatus for removing mercury from a flue gas stream |
| US9797598B1 (en) | 2015-03-25 | 2017-10-24 | Great River Energy | Method for controlling gaseous mercury emission between two or more coal-fired combustion units |
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| PE20180409A1 (es) | 2015-08-21 | 2018-02-28 | Ecolab Usa Inc | Complejacion y eliminacion del mercurio de sistemas de desulfuracion de gas de combustion |
| US10947132B2 (en) | 2017-04-13 | 2021-03-16 | Carbonxt, Inc. | System and methods for removing dissolved metals from wastewater streams |
| CN106902628A (zh) * | 2017-04-26 | 2017-06-30 | 江苏和顺环保有限公司 | 垃圾焚烧烟气喷淋净化装置 |
| US11110393B2 (en) * | 2017-07-06 | 2021-09-07 | Ecolab Usa Inc. | Enhanced injection of mercury oxidants |
| US11319233B2 (en) | 2018-08-17 | 2022-05-03 | Steve Feeney Consulting, Llc | Control of aqueous arsenic, selenium, mercury or other metals from flue gas |
| CN111841253A (zh) * | 2020-07-22 | 2020-10-30 | 朱加招 | 一种双介质双循环脱硫除尘装置 |
| TWI740590B (zh) * | 2020-07-29 | 2021-09-21 | 超力生化股份有限公司 | 含氮氧化物廢氣處理系統及其操作方法 |
| CN113046144A (zh) * | 2021-04-14 | 2021-06-29 | 南阳豫能中原石油天然气有限公司 | 一种含汞天然气流体的净化处理装置及其方法 |
| CN114907889A (zh) * | 2021-12-08 | 2022-08-16 | 安徽格瑞鑫环保科技有限公司 | 一种高效高炉煤气脱氯脱硫系统及工艺 |
| CN117046278A (zh) * | 2023-07-27 | 2023-11-14 | 楚雄滇中有色金属有限责任公司 | 一种硫化法脱除火法冶炼烟气中汞的方法 |
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-
2000
- 2000-12-05 US US09/730,100 patent/US6855859B2/en not_active Expired - Fee Related
-
2001
- 2001-09-11 TW TW090122511A patent/TWI248831B/zh not_active IP Right Cessation
- 2001-10-09 KR KR1020010062157A patent/KR100829351B1/ko not_active Expired - Fee Related
- 2001-10-11 DE DE60117939T patent/DE60117939T2/de not_active Expired - Lifetime
- 2001-10-11 ES ES01308689T patent/ES2258513T3/es not_active Expired - Lifetime
- 2001-10-11 AT AT01308689T patent/ATE320301T1/de active
- 2001-10-11 EP EP01308689A patent/EP1213046B1/de not_active Expired - Lifetime
- 2001-10-18 CA CA002359304A patent/CA2359304C/en not_active Expired - Fee Related
- 2001-12-04 MX MXPA01012507A patent/MXPA01012507A/es active IP Right Grant
- 2001-12-04 JP JP2001369867A patent/JP4593850B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6855859B2 (en) | 2005-02-15 |
| DE60117939T2 (de) | 2006-10-26 |
| JP4593850B2 (ja) | 2010-12-08 |
| CA2359304C (en) | 2006-06-06 |
| TWI248831B (en) | 2006-02-11 |
| KR20020044537A (ko) | 2002-06-15 |
| JP2002239343A (ja) | 2002-08-27 |
| KR100829351B1 (ko) | 2008-05-13 |
| MXPA01012507A (es) | 2002-06-11 |
| EP1213046B1 (de) | 2006-03-15 |
| ES2258513T3 (es) | 2006-09-01 |
| US20020068030A1 (en) | 2002-06-06 |
| CA2359304A1 (en) | 2002-06-05 |
| ATE320301T1 (de) | 2006-04-15 |
| EP1213046A1 (de) | 2002-06-12 |
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