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DE60033730D1 - Zusammensetzung eines thermoplastischen Elastomers zum Pulversintern, Pulver und daraus geformter Gegenstand - Google Patents

Zusammensetzung eines thermoplastischen Elastomers zum Pulversintern, Pulver und daraus geformter Gegenstand

Info

Publication number
DE60033730D1
DE60033730D1 DE60033730T DE60033730T DE60033730D1 DE 60033730 D1 DE60033730 D1 DE 60033730D1 DE 60033730 T DE60033730 T DE 60033730T DE 60033730 T DE60033730 T DE 60033730T DE 60033730 D1 DE60033730 D1 DE 60033730D1
Authority
DE
Germany
Prior art keywords
powder
thermoplastic elastomer
composition
powder molding
article molded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60033730T
Other languages
English (en)
Other versions
DE60033730T2 (de
Inventor
Hiroyuki Sugimoto
Yoshihiro Nakatsuji
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2000005605A external-priority patent/JP2001191456A/ja
Priority claimed from JP2000138362A external-priority patent/JP2001049052A/ja
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Application granted granted Critical
Publication of DE60033730D1 publication Critical patent/DE60033730D1/de
Publication of DE60033730T2 publication Critical patent/DE60033730T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/045—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/025—Polyolefin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y10T428/249991—Synthetic resin or natural rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y10T428/249991—Synthetic resin or natural rubbers
    • Y10T428/249992—Linear or thermoplastic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249987—With nonvoid component of specified composition
    • Y10T428/249991—Synthetic resin or natural rubbers
    • Y10T428/249992—Linear or thermoplastic
    • Y10T428/249993—Hydrocarbon polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31931—Polyene monomer-containing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)
DE2000633730 1999-06-04 2000-06-02 Zusammensetzung eines thermoplastischen Elastomers zum Pulversintern, Pulver und daraus geformter Gegenstand Expired - Fee Related DE60033730T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP15819599 1999-06-04
JP15819599 1999-06-04
JP2000005605A JP2001191456A (ja) 2000-01-14 2000-01-14 成形体及び成形体の製造方法
JP2000005605 2000-01-14
JP2000138362A JP2001049052A (ja) 1999-06-04 2000-05-11 粉末成形用熱可塑性エラストマー組成物、該組成物のパウダー、該パウダーを用いる粉末成形方法及び該パウダーを粉末成形してなる成形体
JP2000138362 2000-05-11

Publications (2)

Publication Number Publication Date
DE60033730D1 true DE60033730D1 (de) 2007-04-19
DE60033730T2 DE60033730T2 (de) 2007-12-06

Family

ID=27321302

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2000633730 Expired - Fee Related DE60033730T2 (de) 1999-06-04 2000-06-02 Zusammensetzung eines thermoplastischen Elastomers zum Pulversintern, Pulver und daraus geformter Gegenstand

Country Status (6)

Country Link
US (2) US6521705B1 (de)
EP (1) EP1057865B1 (de)
KR (1) KR100577876B1 (de)
CN (1) CN1131879C (de)
AT (1) ATE356170T1 (de)
DE (1) DE60033730T2 (de)

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US6723776B2 (en) 2000-01-14 2004-04-20 Sumitomo Rubber Industries, Ltd. Low-modulus polymer composition and sealant using the same
WO2002081570A1 (en) * 2001-04-05 2002-10-17 Sumitomo Chemical Company, Limited Thermoplastic elastomer composition and molded object thereof
JP2003226791A (ja) * 2002-02-04 2003-08-12 Idemitsu Petrochem Co Ltd ポリプロピレン系複合樹脂組成物
US20060178485A1 (en) * 2003-03-14 2006-08-10 Jsr Corporation Hydrogenated diene copolymer, polymer composition, and molded object
US20060068193A1 (en) * 2004-09-29 2006-03-30 Lear Corporation Method and apparatus for making a trim panel with a self-skinning blown elastomer component
US7458631B2 (en) 2004-10-19 2008-12-02 International Automotive Components Group North America, Inc. Automotive armrest with soft feel and method of making the same
US20060082179A1 (en) * 2004-10-19 2006-04-20 Depue Todd L Automotive trim assembly having impact countermeasures and method of making the same
US7478854B2 (en) * 2004-10-19 2009-01-20 International Automotive Components Group North America, Inc. Automotive handle with soft feel and method of making the same
US7458604B2 (en) 2004-10-20 2008-12-02 International Automotive Components Group North America, Inc. Automotive trim assembly having an integrated airbag door
US7695386B2 (en) 2005-06-16 2010-04-13 Veyance Technologies, Inc. Fabric treatment for reinforced elastomeric articles
US7683136B2 (en) 2005-06-16 2010-03-23 VeyanceTechnologies, Inc. Elastomeric compound
KR100727231B1 (ko) * 2005-08-29 2007-06-11 주식회사 엘지화학 항균 특성이 우수한 열가소성 수지 조성물 및 이의제조방법
DE102007013449A1 (de) * 2007-03-21 2008-09-25 Benecke-Kaliko Ag Verfahren und Vorrichtung zur Herstellung von Formhäuten aus mehreren Kunststoffen
US9481962B2 (en) 2008-02-11 2016-11-01 Veyance Technologies, Inc. Method for treating textile material for use in reinforced elastomeric articles
US20090273116A1 (en) 2008-04-30 2009-11-05 International Automotive Components Group North America, Inc. Slush moldable olefin composition
TWI480339B (zh) * 2011-09-15 2015-04-11 Asahi Kasei Chemicals Corp A crosslinking composition, a method for producing a crosslinked composition, and a molded product
KR101405525B1 (ko) * 2013-11-29 2014-06-27 화인케미칼 주식회사 분말 슬러쉬 몰딩 조성물
WO2017170907A1 (ja) * 2016-03-31 2017-10-05 積水化学工業株式会社 架橋ポリオレフィン系樹脂発泡体、及びそれを用いた成形体
TWI766073B (zh) * 2017-07-21 2022-06-01 台橡股份有限公司 用於製備發泡體的組合物、發泡體以及包含該發泡體的鞋體
JP2019194278A (ja) * 2018-05-01 2019-11-07 スリーエム イノベイティブ プロパティズ カンパニー 振動吸収材
CN113474386B (zh) 2019-03-20 2023-11-07 旭化成株式会社 氢化嵌段共聚物

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EP0398758B1 (de) 1989-05-19 1999-03-03 Japan Synthetic Rubber Co., Ltd. (Modifiziertes) hydriertes Dien-Blockcopolymer und dieses enthaltende Zusammensetzung
JP2764746B2 (ja) 1989-05-19 1998-06-11 ジェイエスアール株式会社 水添ジエン系共重合体、変性水添ジエン系共重合体およびその組成物
JPH0693143A (ja) 1992-09-11 1994-04-05 Ube Ind Ltd 熱可塑性エラストマー組成物
JP3334194B2 (ja) 1992-10-22 2002-10-15 ジェイエスアール株式会社 熱可塑性樹脂組成物
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KR100474162B1 (ko) 1996-12-20 2005-05-16 스미또모 가가꾸 가부시끼가이샤 열가소성엘라스토머조성물,그의파우더또는펠릿,및그를포함하는성형체
JP3814998B2 (ja) * 1996-12-20 2006-08-30 住友化学株式会社 熱可塑性エラストマー組成物及び成形体
JPH1160826A (ja) 1997-08-07 1999-03-05 Jsr Corp 粉末樹脂組成物
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KR100517775B1 (ko) * 1998-01-29 2005-09-29 스미또모 가가꾸 가부시끼가이샤 열가소성 엘라스토머 조성물 파우더, 이 파우더를 사용하는 분말성형방법 및 성형체
KR19990083310A (ko) 1998-04-20 1999-11-25 고사이 아끼오 열가소성엘라스토머조성물,이조성물의분말및성형체

Also Published As

Publication number Publication date
EP1057865A1 (de) 2000-12-06
DE60033730T2 (de) 2007-12-06
KR20010007183A (ko) 2001-01-26
ATE356170T1 (de) 2007-03-15
CN1131879C (zh) 2003-12-24
US6521705B1 (en) 2003-02-18
EP1057865B1 (de) 2007-03-07
CN1277223A (zh) 2000-12-20
KR100577876B1 (ko) 2006-05-09
US6787076B2 (en) 2004-09-07
US20030176575A1 (en) 2003-09-18

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