DE283601C - - Google Patents
Info
- Publication number
- DE283601C DE283601C DENDAT283601D DE283601DA DE283601C DE 283601 C DE283601 C DE 283601C DE NDAT283601 D DENDAT283601 D DE NDAT283601D DE 283601D A DE283601D A DE 283601DA DE 283601 C DE283601 C DE 283601C
- Authority
- DE
- Germany
- Prior art keywords
- sulfuric acid
- regeneration
- solution
- air
- hydrogen sulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- RUTXIHLAWFEWGM-UHFFFAOYSA-H Iron(III) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 3
- 230000008929 regeneration Effects 0.000 claims description 3
- 238000011069 regeneration method Methods 0.000 claims description 3
- 229940032950 ferric sulfate Drugs 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 2
- 238000004140 cleaning Methods 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 238000002347 injection Methods 0.000 claims 1
- 239000007924 injection Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- GNVXPFBEZCSHQZ-UHFFFAOYSA-N iron(2+);sulfide Chemical compound [S-2].[Fe+2] GNVXPFBEZCSHQZ-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/105—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids containing metal compounds other than alkali- or earth-alkali carbonates, -hydroxides, oxides, or salts of inorganic acids derived from sulfur
- C10K1/106—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids containing metal compounds other than alkali- or earth-alkali carbonates, -hydroxides, oxides, or salts of inorganic acids derived from sulfur containing Fe compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Separation By Low-Temperature Treatments (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
in WIEN. ■ " ■in Vienna. ■ "■
Bisher konnte Schwefelwasserstoff durch Ferrisalze nur zu Schwefel oxydiert werden. Es hat sich jedoch gezeigt, daß wider Erwarten beim Einleiten schwefelwasserstoffhaltiger Gase in eine heiße, zweckmäßig stark schwefelsaure Ferrisulfatlösung, wenn abwechselnd oder gleichzeitig die Regeneration des gebildeten Ferrosulfates durch Luft oder Sauerstoff erfolgt, eine Oxydation zu SchwefelsäureSo far, hydrogen sulfide could only be oxidized to sulfur by ferric salts. However, it has been shown that, contrary to expectations, when introducing hydrogen sulfide-containing Gases in a hot, expediently strong sulfuric acid ferric sulfate solution, if alternately or at the same time the regeneration of the ferrous sulphate formed by air or oxygen occurs, an oxidation to sulfuric acid
ίο ohne Abscheidung von Schwefel stattfindet. Durch Einblasen von Luft oder Sauerstoff oder Oxydation auf andere Art wird das Ferrisulfat wieder regeneriert, und der primär ausgeschiedene Schwefel wird in der Wärme in der Schwefelsäure unter deren teilweiser Reduktion zu schwefliger Säure gelöst nach der Gleichungίο takes place without separation of sulfur. The ferric sulphate is made by blowing in air or oxygen or by oxidation in some other way regenerated again, and the primarily separated sulfur is in the heat in the sulfuric acid with its partial reduction to sulphurous acid solved according to the equation
2 (H2 S O4) + S + H2 O = 3 (H2 S O3).2 (H 2 SO 4 ) + S + H 2 O = 3 (H 2 SO 3 ).
Die schweflige Säure reduziert wieder das Ferri-Ion und wird dabei selbst zu Schwefelsäure oxydiert. Selbstverständlich gehen die beiden Reaktionen nebeneinander vor sich, und auch die Regeneration erfolgt nicht zeitlich verschieden. Die hierdurch gewonnene Schwefelsäure ist eisenhaltig und. kann entweder als solche verwendet oder zur Ammoniakbindung herangezogen werden, wobei man, wenn der Neutralisationspunkt erreicht ist, das nunmehr bestehen bleibende Eisensulfid vom Ammoniumsulfat trennen kann. Die Regeneration des Eisensulfides erfolgt durch neuerliches Aufgeben in die Oxydationslösung. The sulphurous acid reduces the ferric ion again and becomes sulfuric acid itself oxidized. Of course, the two reactions take place side by side, and the regeneration does not differ in time either. The resulting Sulfuric acid is ferrous and. can either be used as such or to bind ammonia can be used, with one when the neutralization point is reached is, the now existing iron sulfide can separate from the ammonium sulfate. The iron sulfide is regenerated by adding it again to the oxidation solution.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE283601C true DE283601C (en) |
Family
ID=539160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT283601D Active DE283601C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE283601C (en) |
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0
- DE DENDAT283601D patent/DE283601C/de active Active
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