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DE2729270A1 - Electrolyte recovery from rinsing baths in electroplating plant - by feeding rinsing water into plating tank fitted with evaporator - Google Patents

Electrolyte recovery from rinsing baths in electroplating plant - by feeding rinsing water into plating tank fitted with evaporator

Info

Publication number
DE2729270A1
DE2729270A1 DE19772729270 DE2729270A DE2729270A1 DE 2729270 A1 DE2729270 A1 DE 2729270A1 DE 19772729270 DE19772729270 DE 19772729270 DE 2729270 A DE2729270 A DE 2729270A DE 2729270 A1 DE2729270 A1 DE 2729270A1
Authority
DE
Germany
Prior art keywords
rinsing
water
electrolyte
evaporator
fed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE19772729270
Other languages
German (de)
Other versions
DE2729270B2 (en
Inventor
Tim V Hofmann
Hans Ing Grad Stolle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DE19772729270 priority Critical patent/DE2729270B2/en
Publication of DE2729270A1 publication Critical patent/DE2729270A1/en
Publication of DE2729270B2 publication Critical patent/DE2729270B2/en
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/16Regeneration of process solutions
    • C25D21/18Regeneration of process solutions of electrolytes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The recovery is achieved by continuously feeding the electrolyte through a vacuum-evaporative cooling plant and then back to the electroplating tank. The water removed from the electrolyte in the evaporative cooling plant is pref. fed into the water rinsing bath(s); and the water in the first rinsing is pref. pumped into the electroplating tank. A closed system can be used in which no contaminated rinsing water is fed into the drains where it could cause environmental pollution. The rinsing water is fed into the electroplating tank, where the dilution effect is counter-balanced by evapn. The result is that a continuous supply of fresh water is not required; and expensive plant for the purificn. of effluent is eliminated.

Description

Beschreibung und PatentansprücheDescription and claims

Bezeichnung: Verfahren zur Rückgewinnung von verschleppten Elektrolyten in galvanischen Anlagen.Designation: Process for the recovery of electrolytes that have been carried over in galvanic systems.

Anwendungsgebiet: Die Erfindung betrifft ein Verfahren bei dem mit Hilfe der Vakuum-Kühl technik in galvanischen Anlagen verschlepptes Elektrolyt rückgewonnen werden kann.Field of application: The invention relates to a method in which with With the help of vacuum cooling technology in electroplating systems, electrolyte that has been carried over is recovered can be.

Zweck der Erfindung: Beim austauchen der Ware aus einem galvanischen Bad bleibt an dieser Badflüssigkeit -Elektrolyt - haften und wird in das nachgeschaltete Spülbecken verschleppt. Um die steigende Konzentration in dem besagten Spülbecken in Grenzen zu halten, muß diesem Spülbecken laufend Frischwasser zugeführt und entsprechend mit Elektrolyt angereichertes Wasser abgeführt werden. Dieses Abwasser muß, bevor es in die Kanalisation geleitet wird, entgiftet und die Schadstoffe ausgefällt werden. Dieses heute noch übliche Verfahren ist umweltfeindlich und sehr kostspielig. Es erfordert nicht nur hohe Anlagenkosten für die Abwasser-Aufbereitungsanlage sondern auch beträchtliche Betriebskosten für die erforderlichen Aufbereitungs-Chemikalien. Hinzu kommt noch der laufende Frischwasserbedarf.Purpose of the invention: When the goods emerge from a galvanic The bath remains attached to this bath liquid - electrolyte - and is transferred to the downstream Sink carried away. About the increasing concentration in the said sink To keep within limits, fresh water must be continuously supplied to this sink and accordingly water enriched with electrolyte discharged will. This sewage must, before it is discharged into the sewer system, detoxified and the pollutants precipitated will. This process, which is still used today, is harmful to the environment and very expensive. It not only requires high plant costs for the wastewater treatment plant, but also also significant operating costs for the required treatment chemicals. In addition, there is the ongoing need for fresh water.

Aufgabe der Erfindung: Der Erfindung liegt die Aufgabe zugrunde, das verschleppte Elektrolyt den galvanischen Bädern wieder zuzuführen und gleichzeitig das Spüiwasser imKreislauf zu fahren.Object of the invention: The invention is based on the object that to supply the electrolyte carried over to the galvanic baths again and at the same time to circulate the flushing water.

Lösung: Diese Aufgabe wird erfindungsmäßig dadurch gelöst, daß 1. das Elektrolyt ständig über eine Vakuum-Verdampfungskühlanlage umgewälzt wird 2. das Spülwasser nicht wie bisher über die Abwasseraufbereitung in die Kanalisation sondern in das galvanische Bad geleitet wird 3. das verdunstete Wasser kondensiert und dem Spülbad zugeführt wird.Solution: According to the invention, this object is achieved in that 1. the electrolyte is constantly circulated through a vacuum evaporative cooling system 2. the rinsing water does not go into the sewage system via the wastewater treatment as before it is instead fed into the galvanic bath 3. the evaporated water condenses and fed to the rinsing bath.

Ein Ausführungsbeispiel der Erfindung ist in der Zeichnung dargestellt und wird im folgenden näher beschrieben: Die galvanisierte Ware verlässt das galvanische Bad (1) u d wird nacheinander in die Spülbader (2 und 3) getaucht. Hierbei ist die Anzahl der Spülbäder unerheblich. Im Gegenstrom hierzu wird das Spülwasser gepumpt, hierdurch nimmt die Elektrolytkonzentration von Bad zu Bad ab. Das überlaufende Spülwasser aus dem Spülbad (2) hat die höchste Elektrolytkonzentration und wird in das galvanische Bad zurückgepumpt. Mit diesem zurückgepumpten Spülwasser wird auch das verschleppte Elektrolyt dem galvanischen Bad wieder zugeführt. Das Elektrolyt aus dem galvanischen Bad (1) wird ständig über den Vakuum-Verdampfungskühler (4) und die Pumpe (5) umgewälzt. Im Vakuum-Verdampfungskühler (4) wird die Wassermenge verdunstet die dem galvanischen Bad (1) aus dem Spülbad (2) zugeführt wurde. Da hierbei dem Elektrolyt Verdainpfungswärme entzogen wird, kühlt sich dieses ab. Das dampfförmig entweichende Wasser wird im Kondensator (6) kondensiert und von der Pumpe (7) in das Spülbad (3) zurückgepumpt. Die Vakuum-Pumpe (8) saugt die Leckverluste ab. An embodiment of the invention is shown in the drawing and is described in more detail below: The galvanized goods leaves the galvanic bath (1) and enters the rinsing baths (2 and 3) one after the other submerged. The number of rinsing baths is irrelevant here. In countercurrent to this the rinsing water is pumped, this decreases the electrolyte concentration of the bath to bathroom off. The overflowing rinse water from the rinse bath (2) has the highest electrolyte concentration and is pumped back into the galvanic bath. With this rinse water pumped back the entrained electrolyte is also fed back into the electroplating bath. That Electrolyte from the electroplating bath (1) is continuously fed through the vacuum evaporative cooler (4) and the pump (5) circulated. The amount of water in the vacuum evaporation cooler (4) evaporates which was fed to the galvanic bath (1) from the rinsing bath (2). There If evaporation heat is withdrawn from the electrolyte, it cools down. That Water escaping in vapor form is condensed in the condenser (6) and from the Pump (7) pumped back into the rinsing bath (3). The vacuum pump (8) sucks in the leakage losses away.

Claims (3)

Patentansprüche: (5. Verfahren zur Rückgewinnung von verschleppten Elektrolyten in galvanischen Anlagen, dadurch gekennzeichnet, daß das Elektrolyt ständig über eine Vakuum-Verdampfungskühlanlage umgewälzt wird.Claims: (5th method for the recovery of abducted Electrolytes in galvanic systems, characterized in that the electrolyte is constantly circulated through a vacuum evaporative cooling system. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das im Vakuum-Verdampfer dem Elektrolyt entzogene Wasser in das bzw. die dem galvanischen Bad nachgeschalteten Spülbädern zurückgeführt wird. 2. The method according to claim 1, characterized in that the im Vacuum evaporator the electrolyte withdrawn water in the or the galvanic Bad downstream rinsing baths is returned. 3. Anspruch nach 1 und 2, dadurch gekennzeichnet, daß aus dem Spülbecken, welches dem galvanischen Bad unmittelbar nachgeschaltet ist, Spülwasser in das galvanische Bad gepumpt wird. 3. Claim according to 1 and 2, characterized in that from the sink, which is immediately downstream of the galvanic bath, rinsing water in the galvanic Bath is being pumped.
DE19772729270 1977-06-29 1977-06-29 Method for recovering carried-over electrolyte Ceased DE2729270B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19772729270 DE2729270B2 (en) 1977-06-29 1977-06-29 Method for recovering carried-over electrolyte

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772729270 DE2729270B2 (en) 1977-06-29 1977-06-29 Method for recovering carried-over electrolyte

Publications (2)

Publication Number Publication Date
DE2729270A1 true DE2729270A1 (en) 1979-01-04
DE2729270B2 DE2729270B2 (en) 1980-06-12

Family

ID=6012644

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19772729270 Ceased DE2729270B2 (en) 1977-06-29 1977-06-29 Method for recovering carried-over electrolyte

Country Status (1)

Country Link
DE (1) DE2729270B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3634634A1 (en) * 1985-10-11 1987-04-16 Dominic Tenace ELECTRIC PLATING SYSTEM
US4781806A (en) * 1985-10-11 1988-11-01 Dominic Tenace Electroplating system
CN113737209A (en) * 2021-09-27 2021-12-03 长江勘测规划设计研究有限责任公司 Water electrolysis hydrogen production system adopting external circulation evaporation cooling full immersion and use method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0132719B1 (en) * 1983-07-30 1988-03-09 Instytut Mechaniki Precyzyjnej Method and device of conducting a closed cycle of the bath for plating of coatings

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3634634A1 (en) * 1985-10-11 1987-04-16 Dominic Tenace ELECTRIC PLATING SYSTEM
US4781806A (en) * 1985-10-11 1988-11-01 Dominic Tenace Electroplating system
CN113737209A (en) * 2021-09-27 2021-12-03 长江勘测规划设计研究有限责任公司 Water electrolysis hydrogen production system adopting external circulation evaporation cooling full immersion and use method

Also Published As

Publication number Publication date
DE2729270B2 (en) 1980-06-12

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