DE2460247A1 - Primaerglanzmittel-zusatzstoff fuer saure nickelgalvanisierungsbaeder - Google Patents
Primaerglanzmittel-zusatzstoff fuer saure nickelgalvanisierungsbaederInfo
- Publication number
- DE2460247A1 DE2460247A1 DE19742460247 DE2460247A DE2460247A1 DE 2460247 A1 DE2460247 A1 DE 2460247A1 DE 19742460247 DE19742460247 DE 19742460247 DE 2460247 A DE2460247 A DE 2460247A DE 2460247 A1 DE2460247 A1 DE 2460247A1
- Authority
- DE
- Germany
- Prior art keywords
- nickel
- compounds
- mixture
- butynediol
- baths
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000654 additive Substances 0.000 title claims description 20
- 239000002253 acid Substances 0.000 title claims description 11
- 230000000996 additive effect Effects 0.000 title claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title description 44
- 229910052759 nickel Inorganic materials 0.000 title description 22
- -1 alkyne compounds Chemical class 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 16
- 238000007747 plating Methods 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 229910052751 metal Chemical group 0.000 claims description 3
- 239000002184 metal Chemical group 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000002932 luster Substances 0.000 claims 1
- 238000009713 electroplating Methods 0.000 description 13
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 12
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 5
- 229940081974 saccharin Drugs 0.000 description 5
- 235000019204 saccharin Nutrition 0.000 description 5
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 150000002815 nickel Chemical class 0.000 description 4
- 235000010265 sodium sulphite Nutrition 0.000 description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 3
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 3
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- 150000003333 secondary alcohols Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- JHUFGBSGINLPOW-UHFFFAOYSA-N 3-chloro-4-(trifluoromethoxy)benzoyl cyanide Chemical compound FC(F)(F)OC1=CC=C(C(=O)C#N)C=C1Cl JHUFGBSGINLPOW-UHFFFAOYSA-N 0.000 description 2
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 241000080590 Niso Species 0.000 description 2
- 238000007171 acid catalysis Methods 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 229910001651 emery Inorganic materials 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 229910015900 BF3 Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- 150000001337 aliphatic alkines Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- JSPXPZKDILSYNN-UHFFFAOYSA-N but-1-yne-1,4-diol Chemical compound OCCC#CO JSPXPZKDILSYNN-UHFFFAOYSA-N 0.000 description 1
- 229960003369 butacaine Drugs 0.000 description 1
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical class C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- BBLSYMNDKUHQAG-UHFFFAOYSA-L dilithium;sulfite Chemical compound [Li+].[Li+].[O-]S([O-])=O BBLSYMNDKUHQAG-UHFFFAOYSA-L 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- IVPKPBSXQBDLGR-UHFFFAOYSA-N ethyl hexane-1-sulfonate;sodium Chemical compound [Na].CCCCCCS(=O)(=O)OCC IVPKPBSXQBDLGR-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000004820 halides Chemical group 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- OVQABVAKPIYHIG-UHFFFAOYSA-N n-(benzenesulfonyl)benzenesulfonamide Chemical compound C=1C=CC=CC=1S(=O)(=O)NS(=O)(=O)C1=CC=CC=C1 OVQABVAKPIYHIG-UHFFFAOYSA-N 0.000 description 1
- KERTUBUCQCSNJU-UHFFFAOYSA-L nickel(2+);disulfamate Chemical compound [Ni+2].NS([O-])(=O)=O.NS([O-])(=O)=O KERTUBUCQCSNJU-UHFFFAOYSA-L 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- PFMGQUFDGYODMW-UHFFFAOYSA-M sodium 3-chlorobut-1-ene-1-sulfonate Chemical compound ClC(C=CS(=O)(=O)[O-])C.[Na+] PFMGQUFDGYODMW-UHFFFAOYSA-M 0.000 description 1
- DGSDBJMBHCQYGN-UHFFFAOYSA-M sodium;2-ethylhexyl sulfate Chemical compound [Na+].CCCCC(CC)COS([O-])(=O)=O DGSDBJMBHCQYGN-UHFFFAOYSA-M 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
- C25D3/14—Electroplating: Baths therefor from solutions of nickel or cobalt from baths containing acetylenic or heterocyclic compounds
- C25D3/16—Acetylenic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US42880873A | 1973-12-27 | 1973-12-27 | |
| US51213974A | 1974-10-04 | 1974-10-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2460247A1 true DE2460247A1 (de) | 1975-07-10 |
Family
ID=27027913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742460247 Pending DE2460247A1 (de) | 1973-12-27 | 1974-12-19 | Primaerglanzmittel-zusatzstoff fuer saure nickelgalvanisierungsbaeder |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS5099927A (pt) |
| AU (1) | AU7675674A (pt) |
| BR (1) | BR7410536D0 (pt) |
| DE (1) | DE2460247A1 (pt) |
| FR (1) | FR2256265B3 (pt) |
| GB (1) | GB1452650A (pt) |
| IT (1) | IT1028091B (pt) |
| NL (1) | NL7416939A (pt) |
| SE (1) | SE7416014L (pt) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0025694A1 (en) * | 1979-09-13 | 1981-03-25 | M & T Chemicals, Inc. | Bright nickel plating bath and process and composition therefor |
-
1974
- 1974-12-17 BR BR10536/74A patent/BR7410536D0/pt unknown
- 1974-12-19 DE DE19742460247 patent/DE2460247A1/de active Pending
- 1974-12-19 SE SE7416014A patent/SE7416014L/xx unknown
- 1974-12-23 GB GB5560674A patent/GB1452650A/en not_active Expired
- 1974-12-23 AU AU76756/74A patent/AU7675674A/en not_active Expired
- 1974-12-26 FR FR7442840A patent/FR2256265B3/fr not_active Expired
- 1974-12-27 NL NL7416939A patent/NL7416939A/xx unknown
- 1974-12-27 JP JP49149089A patent/JPS5099927A/ja active Pending
- 1974-12-27 IT IT31079/74A patent/IT1028091B/it active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0025694A1 (en) * | 1979-09-13 | 1981-03-25 | M & T Chemicals, Inc. | Bright nickel plating bath and process and composition therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2256265B3 (pt) | 1977-09-23 |
| IT1028091B (it) | 1979-01-30 |
| JPS5099927A (pt) | 1975-08-08 |
| GB1452650A (en) | 1976-10-13 |
| FR2256265A1 (pt) | 1975-07-25 |
| AU7675674A (en) | 1976-06-24 |
| BR7410536D0 (pt) | 1975-09-02 |
| NL7416939A (nl) | 1975-07-01 |
| SE7416014L (pt) | 1975-06-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69127394T2 (de) | Zinn-Elektroplattierung bei hoher Geschwindigkeit | |
| DE832982C (de) | Elektrolyt und Verfahren zur elektrolytischen Abscheidung von Kupfer | |
| DE3710368C2 (pt) | ||
| DE3001879C2 (de) | Wäßriges saures Bad und Verfahren zur galvanischen Abscheidung von glänzenden und eingeebneten Nickel-Eisen-Schichten | |
| DE2417952A1 (de) | Verfahren zur galvanischen abscheidung von nickel und/oder kobalt | |
| DE3534876A1 (de) | Waessriges saures bad und verfahren zur galvanischen abscheidung von zinklegierungen | |
| DE2630980C2 (pt) | ||
| DE3854551T2 (de) | Zinn-, Blei- und Zinn-Blei-Legierungs-Elektrolyten für Elekroplattieren bei hoher Geschwindigkeit. | |
| DE2537065C2 (pt) | ||
| DE3517968C2 (pt) | ||
| DE2460247A1 (de) | Primaerglanzmittel-zusatzstoff fuer saure nickelgalvanisierungsbaeder | |
| DE2404614A1 (de) | Zusammensetzung und verfahren zur galvanischen nickelabscheidung | |
| DE2215737C3 (de) | Wäßriges saures galvanisches Halbglanznickelbad | |
| DE3248503A1 (de) | Saures galvanisches zinkbad | |
| DE2643898A1 (de) | Glanzbildner fuer galvanische zinkbaeder und seine verwendung | |
| DE1793558C3 (de) | Cumarinderivate und Verfahren zu ihrer Herstellung | |
| DE3108466C2 (de) | Verwendung eines Acetylenalkohols in einem Bad zur galvanischen Abscheidung einer Palladium/Nickel-Legierung | |
| WO1995028512A1 (de) | Verfahren zur herstellung glänzender verzinkter oder mit einer zinklegierung überzogener formteile | |
| DE1916118B2 (de) | Saures, waessriges, galvanisches bad zur abscheidung halbglaenzender nickelniederschlaege | |
| DE1151159B (de) | Saure galvanische Kupferbaeder | |
| DE2607306C2 (de) | Wäßriges, elektrolytisches Palladium-Plattierungsbad | |
| DE2634128C2 (de) | Bad und Verfahren zum galvanischen Abscheiden von Nickel-Graphit-Dispersionsüberzügen | |
| US4062738A (en) | Acid nickel electroplating additive therefor and method of making said additive | |
| DE2450527C2 (de) | Wäßriges, saures Bad zur galvanischen Abscheidung von halbglänzenden Nickelüberzügen | |
| EP0244685B1 (de) | Wässriges saures galvanisches Bad |